Transcriber’s Notes:

  Underscores “_” before and after a word or phrase indicate _italics_
    in the original text.
  Equal signs “=” before and after a word or phrase indicate =bold=
    in the original text.
  Small capitals have been converted to SOLID capitals.
  Illustrations have been moved so they do not break up paragraphs.
  Typographical and punctuation errors have been silently corrected.




CHEMICAL WARFARE


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[Illustration]

                           CHEMICAL WARFARE

                                  BY
                             AMOS A. FRIES
                _Brigadier General, C. W. S., U. S. A.
                   Chief, Chemical Warfare Service_
                                  AND
                           CLARENCE J. WEST
               _Major, C. W. S. Reserve Corps, U. S. A.
                      National Research Council_

                             FIRST EDITION

                    McGRAW-HILL BOOK COMPANY, Inc.
                     NEW YORK: 370 SEVENTH AVENUE
                  LONDON: 6 & 8 BOUVERIE ST., E. C. 4
                                 1921

                        COPYRIGHT, 1921, BY THE
                    MCGRAW-HILL BOOK COMPANY, INC.




PREFACE


Shortly after the signing of the Armistice, it was realized that the
story of Chemical Warfare should be written, partly because of its
historical value, and partly because of the future needs of a textbook
covering the fundamental facts of the Service for the Army, the Reserve
Officer, the National Guard, and even the Civilian Chemist. The present
work was undertaken by both authors as a labor of patriotism and
because of their interest in the Service.

The two years which have elapsed since the initial discussion of the
outlines of the book have thoroughly convinced us of the need of such
a work. The Engineers, the Medical Department, and most of the other
branches of the Army have their recognized textbooks and manuals.
There has been no way, however, by which the uninformed can check the
accuracy of statements regarding Chemical Warfare. The present volume
will serve, in a measure, to fill this gap. That it does not do so
more completely is due in part to the fact that secrecy must still be
maintained about some of the facts and some of the new discoveries
which are the property of the Service. Those familiar with the work of
the Chemical Warfare Service will discover, though, that the following
pages contain many statements which were zealously guarded secrets two
years ago. This enlarged program of publicity on the part of the Chief
of the Service is being justified every day by the ever increasing
interest in this branch of warfare. Where five men were discussing
Chemical Warfare two years ago, fifty men are talking about the work
and the possibilities of the Service today. It is hoped that the facts
here presented may further increase the interest in Chemical Warfare,
for there is no question but that it must be recognized as a permanent
and a very vital branch of the Army of every country. Reasons for this
will be found scattered through the pages of this book.

It should be explained that this is in no sense a complete historical
sketch of the development and personnel of the Chemical Warfare
Service. At least two more volumes are needed,—one on the Manufacture
of Poisonous Gases and one on the Tactics of Chemical Warfare. We have
purposely refrained from an attempt to give credit to individuals for
the accomplishments of the various Divisions of the Service, because
such an attempt would have made the book too voluminous, and would
have defeated the primary purpose, namely, that it should present
the information in as concise manner as possible. The published and
unpublished materials of the files of all the Divisions have been
freely drawn upon in writing the various chapters, and many old C. W.
S. men will undoubtedly recognize whole sentences which they wrote
under the stress of the laboratory or plant “battle front.” May
these few lines be an acknowledgment of their contributions. Those
who desire to consult the literature of Chemical Warfare will find a
fairly complete bibliography (to about the middle of 1919) in “Special
Libraries” for November, 1919.

Special acknowledgment is made to Dr. G. J. Esselen, Jr., for having
read the manuscript and for helpful and constructive criticisms.
Many of the figures are reproduced by permission of the Journal of
Industrial and Engineering Chemistry; those showing the Nelson cell
were furnished by the Samuel M. Green Company.

                                            AMOS A. FRIES,
                                            CLARENCE J. WEST.

    Aug. 1, 1921.




FOREWORD


After all peaceful means of settling disputes between nations have
been resorted to and have failed, war is often declared by one of the
disputants for the purpose of imposing its will upon the other by
force. In order to accomplish this, a superiority must be established
over the adversary in trained men and in implements of war.

Men are nothing in modern war unless they are equipped with the most
effective devices for killing and maiming the enemy’s soldiers and
thoroughly trained in the use of such implements.

History proves that an effective implement of war has never been
discarded until it becomes obsolete.

It is impossible to humanize the act of killing and maiming the enemy’s
soldiers, and there is no logical grounds on which to condemn an
appliance so long as its application can be so confined. Experiments in
this and other countries during the World War completely established
the fact that gas can be so confined. The range of gas clouds is no
greater than that of artillery and the population in the area behind
the front line must, if they remain in such range, take their chance.
The danger area in the future will be known to all.

As the first Director of the Chemical Warfare Service, U. S. Army, I
speak with some experience when I say that there is no field in which
the future possibilities are greater than in chemical warfare, and no
field in which neglect to keep abreast of the times in research and
training would be more disastrous.

Notwithstanding the fact that gas was used in the World War two years
before the United States entered the fray, practically nothing was
done in this country before April, 1917, towards the development of
any chemical warfare appliances, offensive or defensive, and had it
not been for the ability of an ally to supply our troops with such
appliances, they would have been as defenseless as the Canadians were
at Ypres when the Germans sent over their first gas cloud.

This book recites the troubles and successes of this new service under
the stress of war for which it was unprepared and I trust that its
perusal will create a public opinion that will insist upon chemical
preparation for war.

I feel that this book will show that the genius and patriotism
displayed by the chemists and chemical engineers of the country were
not surpassed in any other branch of war work and that to fail to
utilize in peace times this talent would be a crime.

    WILLIAM L. SIBERT,
          Major General, United States Army,
             Retired.




CONTENTS


                                                                   PAGE
    PREFACE                                                         vii
    FOREWORD                                                         ix
    CHAPTER
            I. THE HISTORY OF POISON GASES                            1
           II. MODERN DEVELOPMENT OF GAS WARFARE                     10
          III. DEVELOPMENT OF THE CHEMICAL WARFARE SERVICE           31
           IV. THE CHEMICAL WARFARE SERVICE IN FRANCE                72
            V. CHLORINE                                             116
           VI. PHOSGENE                                             126
          VII. LACHRYMATORS                                         137
         VIII. CHLOROPICRIN                                         144
           IX. DICHLOROETHYLSULFIDE (MUSTARD GAS)                   150
            X. ARSENIC DERIVATIVES                                  180
           XI. CARBON MONOXIDE                                      190
          XII. DEVELOPMENT OF THE GAS MASK                          195
         XIII. ABSORBENTS                                           237
          XIV. TESTING ABSORBENTS AND GAS MASKS                     259
           XV. OTHER DEFENSIVE MEASURES                             272
          XVI. SCREENING SMOKES                                     285
         XVII. TOXIC SMOKES                                         313
        XVIII. SMOKE FILTERS                                        322
          XIX. SIGNAL SMOKES                                        330
           XX. INCENDIARY MATERIALS                                 336
          XXI. THE PHARMACOLOGY OF WAR GASES                        353
         XXII. CHEMICAL WARFARE IN RELATION TO STRATEGY AND TACTICS 363
        XXIII. THE OFFENSIVE USE OF GAS                             385
         XXIV. DEFENSE AGAINST GAS                                  405
          XXV. PEACE TIME USES OF GAS                               427
         XXVI. THE FUTURE OF CHEMICAL WARFARE                       435
               INDEX                                                440




CHEMICAL WARFARE




CHAPTER I

THE HISTORY OF POISON GASES[1]


The introduction of poison gases by the Germans at Ypres in April,
1915, marked a new era in modern warfare. The popular opinion is that
this form of warfare was original with the Germans. Such, however, is
not the case. Quoting from an article in the _Candid Quarterly Review_,
=4=, 561, “All they can claim is the inhuman adoption of devices
invented in England, and by England rejected as too horrible to be
entertained even for use against an enemy.” But the use of poison gases
is even of an earlier origin than this article claims.

[Footnote 1: This chapter originally appeared in Science, Vol. =49=,
pp. 412-417 (1919).]

The first recorded effort to overcome an enemy by the generation of
poisonous and suffocating gases seems to have been in the wars of the
Athenians and Spartans (431-404 B.C.) when, besieging the cities of
Platea and Belium, the Spartans saturated wood with pitch and sulfur
and burned it under the walls of these cities in the hope of choking
the defenders and rendering the assault less difficult. Similar uses
of poisonous gases are recorded during the Middle Ages. In effect
they were like our modern stink balls, but were projected by squirts
or in bottles after the manner of a hand grenade. The legend is told
of Prester John (about the eleventh century), that he stuffed copper
figures with explosives and combustible materials which, emitted from
the mouths and nostrils of the effigies, played great havoc.

The idea referred to by the writer in the _Candid Quarterly Review_,
is from the pen of the English Lord Dundonald, which appeared in the
publication entitled “The Panmure Papers.” This is an extremely dull
record of an extremely dull person, only rendered interesting by the
one portion, concerned with the use of poison gases, which, it is said,
“should never have been published at all.”

That portion of the article from the _Candid Quarterly Review_ dealing
with the introduction of poisonous gas by the Germans, and referred to
in the first paragraph above, is quoted in full as follows:

    “The great Admiral Lord Dundonald—perhaps the ablest
    sea captain ever known, not even excluding Lord
    Nelson—was also a man of wide observation, and no
    mean chemist. He had been struck in 1811 by the deadly
    character of the fumes of sulphur in Sicily; and, when
    the Crimean War was being waged, he communicated to
    the English government, then presided over by Lord
    Palmerston, a plan for the reduction of Sebastopol
    by sulphur fumes. The plan was imparted to Lord
    Panmure and Lord Palmerston, and the way in which it
    was received is so illustrative of the trickery and
    treachery of the politician that it is worth while to
    quote Lord Palmerston’s private communication upon it
    to Lord Panmure:

          “LORD PALMERSTON TO LORD PANMURE

               “‘HOUSE OF COMMONS, 7th August, 1855
    “‘I agree with you that if Dundonald will go out
    himself to superintend and direct the execution of
    his scheme, we ought to accept his offer and try his
    plan. If it succeeds, it will, as you say, save a great
    number of English and French lives; if it fails _in
    his hands_, we shall be exempt from blame, and if
    we come in for a small share of the ridicule, we can
    bear it, and the greater part will fall on him. You
    had best, therefore, make arrangement with him without
    delay, and with as much secrecy as the nature of things
    will admit of.’

    “Inasmuch as Lord Dundonald’s plans have already been
    deliberately published by the two persons above named,
    there can be no harm in now republishing them. They
    will be found in the first volume of ‘The Panmure
    Papers’ (pp. 340-342) and are as follows:

                  “‘(ENCLOSURE)

           “‘BRIEF PRELIMINARY OBSERVATIONS

    “‘It was observed when viewing the Sulphur Kilns, in
    July, 1811, that the fumes which escaped in the rude
    process of extracting the material, though first
    elevated by heat, soon fell to the ground, destroying
    all vegetation, and endangering animal life to a great
    distance, and it was asserted that an ordinance existed
    prohibiting persons from sleeping within the distance
    of three miles during the melting season.

    “‘An application of these facts was immediately made
    to Military and Naval purposes, and after mature
    consideration, a Memorial was presented on the subject
    to His Royal Highness the Prince Regent on the 12th
    of April, 1812, who was graciously pleased to lay it
    before a Commission, consisting of Lord Keith, Lord
    Exmouth and General and Colonel Congreve (afterwards
    Sir William), by whom a favorable report having been
    given, His Royal Highness was pleased to order that
    secrecy should be maintained by all parties.
                                  “‘(Signed) DUNDONALD

       “‘7th August, 1855’

                   “‘MEMORANDUM

    “‘Materials required for the expulsion of the Russians
    from Sebastopol: Experimental trials have shown that
    about five parts of coke effectually vaporize one part
    of sulphur. Mixtures for land service, where weight
    is of importance, may, however, probably be suggested
    by Professor Faraday, as to operations on shore I
    have paid little attention. Four or five hundred tons
    of sulphur and two thousand tons of coke would be
    sufficient.

    “‘Besides these materials, it would be necessary to
    have, say, as much bituminous coal, and a couple of
    thousand barrels of gas or other tar, for the purpose
    of masking fortifications to be attacked, or others
    that flank the assailing positions.

    “‘A quantity of dry firewood, chips, shavings, straw,
    hay or other such combustible materials, would also
    be requisite quickly to kindle the fires, which ought
    to be kept in readiness for the first favourable and
    steady breeze.
                                      “‘DUNDONALD

        “‘7th August, 1855’

    “‘=_Note._=—The objects to be accomplished
    being specially stated the responsibility of their
    accomplishment ought to rest on those who direct their
    execution.

    “‘Suppose that the Malakoff and Redan are the objects
    to be assailed it might be judicious merely to obscure
    the Redan (by the smoke of coal and tar kindled in ‘The
    Quarries’), so that it could not annoy the Mamelon,
    where the sulphur fire would be placed to expel
    the garrison from the Malakoff, which ought to have
    all the cannon that can be turned towards its ramparts
    employed in overthrowing its undefended ramparts.

    “‘There is no doubt but that the fumes will envelop all
    the defenses from the Malakoff to the Barracks, and
    even to the line of battleship, the Twelve Apostles, at
    anchor in the harbour.

    “‘The two outer batteries, on each side of the Port,
    ought to be smoked, sulphured, and blown down by
    explosion vessels, and their destruction completed by a
    few ships of war anchored under cover of the smoke.’

    “That was Lord Dundonald’s plan in 1855, improperly
    published in 1908, and by the Germans, who thus learnt
    it, ruthlessly put into practise in 1915.

    “Lord Dundonald’s memoranda, together with further
    elucidatory notes, were submitted by the English
    government of that day to a committee and subsequently
    to another committee in which Lord Playfair took
    leading part. These committees, with Lord Dundonald’s
    plans fully and in detail before them, both reported
    that the plans were perfectly feasible; that the
    effects expected from them would undoubtedly be
    produced; but that those effects were so horrible that
    no honorable combatant could use the means required to
    produce them. The committee therefore recommended that
    the scheme should not be adopted; that Lord Dundonald’s
    account of it should be destroyed. How the records
    were obtained and preserved by those who so improperly
    published them in 1908 we do not know. Presumably they
    were found among Lord Panmure’s papers. Admiral Lord
    Dundonald himself was certainly no party to their
    publication.”

One of the early, if not the earliest suggestion as to the use of
poison gas in shell is found in an article on “Greek Fire,” by B. W.
Richardson.[2]

[Footnote 2: _Popular Science Review_, =3=, 176 (1864).]

He says:

    “I feel it a duty to state openly and boldly, that if
    science were to be allowed her full swing, if society
    would really allow that ‘all is fair in war,’ war
    might be banished at once from the earth as a game
    which neither subject nor king dare play at. Globes
    that could distribute liquid fire could distribute
    also lethal agents, within the breath of which no man,
    however puissant, could stand and live. From the summit
    of Primrose Hill, a few hundred engineers, properly
    prepared, could render Regent’s Park, in an incredibly
    short space of time, utterly uninhabitable; or could
    make an army of men, that should even fill that space,
    fall with their arms in their hands, prostrate and
    helpless as the host of Sennacherib.

    “The question is, shall these things be? I do not
    see that humanity should revolt, for would it not be
    better to destroy a host in Regent’s Park by making
    the men fall as in a mystical sleep, than to let
    down on them another host to break their bones, tear
    their limbs asunder and gouge out their entrails with
    three-cornered pikes; leaving a vast majority undead,
    and writhing for hours in torments of the damned?
    I conceive, for one, that science would be blessed
    in spreading her wings on the blast, and breathing
    into the face of a desperate horde of men prolonged
    sleep—for it need not necessarily be a death—which
    they could not grapple with, and which would yield them
    up with their implements of murder to an enemy that in
    the immensity of its power could afford to be merciful
    as Heaven.

    “The question is, shall these things be? I think they
    must be. By what compact can they be stopped? It were
    improbable that any congress of nations could agree on
    any code regulating means of destruction; but if it
    did, it were useless; for science becomes more powerful
    as she concentrates her forces in the hands of units,
    so that a nation could only act, by the absolute and
    individual assent of each of her representatives.
    Assume, then, that France shall lay war to England, and
    by superior force of men should place immense hosts,
    well armed, on English soil. Is it probable that the
    units would rest in peace and allow sheer brute force
    to win its way to empire? Or put English troops on
    French soil, and reverse the question?

    “To conclude. War has, at this moment, reached, in its
    details, such an extravagance of horror and cruelty,
    that it can not be made worse by any art, and can only
    be made more merciful by being rendered more terribly
    energetic. Who that had to die from a blow would not
    rather place his head under Nasmyth’s hammer, than
    submit it to a drummer-boy armed with a ferrule?”

The _Army and Navy Register_ of May 29, 1915, reports that

    “among the recommendations forwarded to the Board of
    Ordnance and Fortifications there may be found many
    suggestions in favor of the asphyxiation process,
    mostly by the employment of gases contained in bombs
    to be thrown within the lines of the foe, with varying
    effects from peaceful slumber to instant death. One
    ingenious person suggested a bomb laden to its full
    capacity with snuff, which should be so evenly and
    thoroughly distributed that the enemy would be
    convulsed with sneezing, and in this period of paroxysm
    it would be possible to creep up on him and capture him
    in the throes of the convulsion.”

That the probable use of poisonous gas has often been in the minds
of military men during recent times is evidenced by the fact that at
the Hague Conference in 1899 several of the more prominent nations of
Europe and Asia pledged themselves not to use projectiles whose only
object was to give out suffocating or poisonous gases. Many of the
Powers did not sign this declaration until later. Germany signed and
ratified it on Sept. 4, 1900, but the United States never signed it.
Further, this declaration was not to be binding in case of a war in
which a non-signatory was or became a belligerent. Admiral Mahan, a
United States delegate, stated his position in regard to the use of gas
in shell (at that time an untried theory) as follows:

    “The reproach of cruelty and perfidy addressed against
    these supposed shells was equally uttered previously
    against fire-arms and torpedoes, although both are
    now employed without scruple. It is illogical and not
    demonstrably humane to be tender about asphyxiating
    men with gas, when all are prepared to admit that it
    is allowable to blow the bottom out of an ironclad
    at midnight, throwing four or five hundred men into
    the sea to be choked by the water, with scarcely the
    remotest chance to escape.”

At the Hague Congress of 1907, article 23 of the rules adopted for war
on land states:

    “It is expressly forbidden (_a_),
     to employ poisons or poisonous weapons.”

Before the War suffocating cartridges were shot from the
cartridge-throwing rifle of 26 mm. These cartridges were charged with
ethyl bromoacetate, a slightly suffocating and non-toxic lachrymator.
They were intended for attack on the flanking works of permanent
fortifications, flanking casements or caponiers, into which the enemy
tried to make the cartridges penetrate through the narrow slits used
for loopholes. The men who were serving the machine guns or the cannon
of the flanking works would have been bothered by the vapor from the
ethyl bromoacetate, and the assailant would have profited by their
disturbance to get past the obstacle presented by the fortification.
The employment of these devices, not entailing death, did not
contravene the Hague conventions.

The only memorable operations in the course of which these devices were
used before the War was the attack on the Bonnet gang at Choisy-le-roi.

In connection with the suggested use of sulfur dioxide by Lord
Dundonald and the proposed use of poisonous gases in shell, the
following description of a charcoal respirator by Dr. J. Stenhouse,[3]
communicated by Dr. George Wilson in 1854, is of interest.

[Footnote 3: _Trans. Royal Scottish Soc. Arts_, =4=, Appendix O, 198
(1854).]

    “Dr. Wilson commenced by stating that, having read with
    much interest the account of Dr. Stenhouse’s researches
    on the deodorizing and disinfecting properties
    of charcoal, and the application of these to the
    construction of a new and important kind of respirator,
    he had requested the accomplished chemist to send one
    of his instruments for exhibition to the society,
    which he had kindly done. Two of the instruments were
    now on the table, differing, however, so slightly in
    construction, that it would be sufficient to explain
    the arrangement of one of them. Externally, it had
    the appearance of a small fencing-mask of wire gauze,
    covering the face from the chin upwards to the bridge
    of the nose, but leaving the eyes and forehead free.
    It consisted, essentially, of two plates of wire
    gauze, separated from each other by a space of about
    one-fourth or one-eighth of an inch, so as to form a
    small cage filled with small fragments of charcoal. The
    frame of the cage was of copper, but the edges were
    made of soft lead, and were lined with velvet, so as to
    admit of their being made to fit the cheeks tightly and
    inclose the mouth and nostrils. By this arrangement, no
    air could enter the lungs without passing through the
    wire gauze and traversing the charcoal. An aperture is
    provided with a screw or sliding valve for the removal
    and replenishment of the contents of the cage, which
    consist of the siftings or riddlings of the lighter
    kinds of wood charcoal. The apparatus is attached to
    the face by an elastic band passing over the crown of
    the head and strings tying behind, as in the case of
    the ordinary respirator. The important agent in this
    instrument is the charcoal, which has so remarkable
    a power of absorbing and destroying irritating and
    otherwise irrespirable and poisonous gases or vapors
    that, armed with the respirator, spirits of hartshorn,
    sulphuretted hydrogen, hydrosulphuret of ammonia and
    chlorine may be breathed through it with impunity,
    though but slightly diluted with air. This result,
    first obtained by Dr. Stenhouse, has been verified by
    those who have repeated the trial, among others by Dr.
    Wilson, who has tried the vapors named above on himself
    and four of his pupils, who have breathed them with
    impunity. The explanation of this remarkable property
    of charcoal is two-fold. It has long been known to
    possess the power of condensing into its pores gases
    and vapors, so that if freshly prepared and exposed to
    these, it absorbs and retains them. But it has scarcely
    been suspected till recently, when Dr. Stenhouse
    pointed out the fact, that if charcoal be allowed
    to absorb simultaneously such gases as sulphuretted
    hydrogen and air, the oxygen of this absorbed and
    condensed air rapidly oxidizes and destroys the
    accompanying gas. So marked is this action, that if
    dead animals be imbedded in a layer of charcoal a few
    inches deep, instead of being prevented from decaying
    as it has hitherto been supposed that they would be by
    the supposed antiseptic powers of the charcoal, they
    are found by Dr. Stenhouse to decay much faster, whilst
    at the same time, no offensive effluvia are evolved.
    The deodorizing powers of charcoal are thus established
    in a way they never have been before; but at the
    same time it is shown that the addition of charcoal
    to sewage refuse lessens its agricultural value
    contemporaneously with the lessening of odor. From
    these observations, which have been fully verified, it
    appears that by strewing charcoal coarsely powdered to
    the extent of a few inches, over church-yards, or by
    placing it inside the coffins of the dead, the escape
    of noisome and poisonous exhalations may be totally
    prevented. The charcoal respirator embodies this
    important discovery. It is certain that many of the
    miasma, malaria and infectious matters which propagate
    disease in the human subjects, enter the body by the
    lungs, and impregnating the blood there, are carried
    with it throughout the entire body, which they thus
    poison. These miasma are either gases and vapors or
    bodies which, like fine light dust, are readily carried
    through the air; moreover, they are readily destroyed
    by oxidizing agents, which convert them into harmless,
    or at least non-poisonous substances, such as water,
    carbonic acid and nitrogen. There is every reason,
    therefore, for believing that charcoal will oxidize
    and destroy such miasma as effectually as it does
    sulphuretted hydrogen or hydrosulphuret of ammonia, and
    thus prevent their reaching and poisoning the blood.
    The intention accordingly is that those who are exposed
    to noxious vapors, or compelled to breathe infected
    atmospheres, shall wear the charcoal respirator,
    with a view to arrest and destroy the volatile
    poisons contained in these. Some of the non-obvious
    applications of the respirator were then referred to:

      “1. Certain of the large chemical manufacturers in
      London are now supplying their workmen with the
      charcoal respirators as a protection against the more
      irritating vapors to which they are exposed.

      “2. Many deaths have occurred among those employed
      to explore the large drains and sewers of London
      from exposure to sulphuretted hydrogen, etc. It may
      be asserted with confidence that fatal results from
      exposure to the drainage gases will cease as soon as
      the respirator is brought into use.

      “3. In districts such as the Campagna of Rome, where
      malaria prevails and to travel during night or to
      sleep in which is certainly followed by an attack of
      dangerous and often fatal ague, the wearing of the
      respirator even for a few hours may be expected to
      render the marsh poison harmless.

      “4. Those, who as clergymen, physicians or legal
      advisers, have to attend the sick-beds of sufferers
      from infectious disorders, may, on occasion, avail
      themselves of the protection afforded by Dr.
      Stenhouse’s instrument during their intercourse with
      the sick.

      “5. The longing for a short and decisive war has led
      to the invention of ‘a suffocating bombshell,’ which
      on bursting, spreads far and wide an irrespirable or
      poisonous vapor; one of the liquids proposed for the
      shell is the strongest ammonia, and against this it
      is believed that the charcoal respirator may defend
      our soldiers. As likely to serve this end, it is at
      present before the Board of Ordnance.

      “Dr. Wilson stated, in conclusion, that Dr. Stenhouse
      had no interest but a scientific one in the success of
      the respirators. He had declined to patent them, and
      desired only to apply his remarkable discoveries to the
      abatement of disease and death. Charcoal had long been
      used in filters to render poisonous water wholesome; it
      was now to be employed to filter poisonous air.”




CHAPTER II

MODERN DEVELOPMENT OF GAS WARFARE


The use of toxic gas in the World War dates from April 22, 1915, when
the Germans launched the first cylinder attack, employing chlorine, a
common and well known gas. Judging from the later experience of the
Allies in perfecting this form of attack, it is probable that plans for
this attack had been under way for months before it was launched. The
suggestion that poisonous gases be used in warfare has been laid upon
Prof. Nernst of the University of Berlin (Auld, “Gas and Flame,” page
15), while the actual field operations were said to have been under
the direction of Prof. Haber of the Kaiser Wilhelm Physical Chemical
Institute of Berlin. Some writers have felt that the question of
preparation had been a matter of years rather than of months, and refer
to the work on industrial gases as a proof of their statement. The fact
that the gas attack was not more successful, that the results to be
obtained were not more appreciated, and that better preparation against
retaliation had not been made, argues against this idea of a long
period of preparation, except possibly in a very desultory way. That
such was the case is most fortunate for the allied cause, for had the
German high command known the real situation at the close of the first
gas attack, or had that attack been more severe, the outcome of the war
of 1914 would have been very different, and the end very much earlier.


FIRST GAS ATTACK

The first suggestion of a gas attack came to the British Army through
the story of a German deserter. He stated that the German Army was
planning to poison their enemy with a cloud of gas, and that the
cylinders had already been installed in the trenches. No one listened
to the story, because, first of all, the whole procedure seemed so
impossible and also because, in spite of the numerous examples of
German barbarity, the English did not believe the Germans capable of
such a violation of the Hague rules of warfare. The story appeared in
the summary of information from headquarters (“Comic Cuts”) and as Auld
says “was passed for information for what it is worth.” But the story
was true, and on the afternoon of the 22nd of April, all the conditions
being ideal, the beginning of “gas warfare” was launched. Details of
that first gas attack will always be meager, for the simple reason that
the men who could have told about it all lie in Flanders field where
the poppies grow.

The place selected was in the northeast part of the Ypres salient, at
that part of the line where the French and British lines met, running
southward from where the trenches left the canal near Boesinghe. The
French right was held by the —— Regiment of Turcos, while on the
British left were the Canadians. Auld describes the attack as follows:

    “Try to imagine the feelings and the condition of
    the colored troops as they saw the vast cloud of
    greenish-yellow gas spring out of the ground and slowly
    move down wind towards them, the vapor clinging to the
    earth, seeking out every hole and hollow and filling
    the trenches and shell holes as it came. First wonder,
    then fear; then, as the first, fringes of the cloud
    enveloped them and left them choking and agonized in
    the fight for breath—panic. Those who could move broke
    and ran, trying, generally in vain, to outstrip the
    cloud which followed inexorably after them.”

It is only to be expected that the first feeling connected with
gas warfare was one of horror. That side of it is very thrillingly
described by Rev. O. S. Watkins in the _Methodist Recorder_ (London).
After describing the bombardment of the City of Ypres from April 20th
to 22nd he relates that in the midst of the uproar came the poison gas!

[Illustration: FIG. 1.—French Gas Attack as seen from an Aeroplane.

The French front, second and third line trenches are plainly visible.
The gas is seen issuing over a wide front from the front line and
drifting towards the German lines.]

    “Going into the open air for a few moments’ relief from
    the stifling atmosphere of the wards, our attention was
    attracted by very heavy firing to the north, where the
    line was held by the French. Evidently a hot fight—and
    eagerly we scanned the country with our field glasses
    hoping to glean some knowledge of the progress of
    the battle. Then we saw that which almost caused our
    hearts to stop beating—figures running wildly and in
    confusion over the fields.

    “‘The French have broken,’ we exclaimed. We hardly
    believed our words.... The story they told we could
    not believe; we put it down to their terror-stricken
    imaginings—a greenish-gray cloud had swept down upon
    them, turning yellow as it traveled over the country,
    blasting everything it touched, shriveling up the
    vegetation. No human courage could face such a peril.

    “Then there staggered into our midst French soldiers,
    blinded, coughing, chests heaving, faces an ugly purple
    color—lips speechless with agony, and behind them, in
    the gas-choked trenches, we learned that they had left
    hundreds of dead and dying comrades. The impossible was
    only too true.

    “It was the most fiendish, wicked thing I have ever
    seen.”

It must be said here, however, that this was true only because the
French had no protection against the gas. Indeed, it is far from being
the most horrible form of warfare, provided both sides are prepared
defensively and offensively. Medical records show that out of every
100 Americans gassed less than two died, and as far as records of
four years show, very few are permanently injured. Out of every 100
American casualties from all forms of warfare other than gas more than
25 per cent died, while from 2 to 5 per cent more are maimed, blinded
or disfigured for life. Various forms of gas, as will be shown in the
following pages, make life miserable or vision impossible to those
without a mask. Yet they do not kill.

Thus instead of gas warfare being the most horrible, it is the most
humane where both sides are prepared for it, while against savage
or unprepared peoples it can be made so humane that but very few
casualties will result.

The development of methods of defense against gas will be discussed
in a later chapter. It will suffice to say here that, in response to
an appeal from Lord Kitchener, a temporary protection was quickly
furnished the men. This was known as the “Black Veiling” respirator,
and consisted of a cotton pad soaked in ordinary washing soda solution,
and later, in a mixture of washing soda and “hypo,” to which was added
a little glycerine. These furnished a fair degree of protection to the
men against chlorine, the only gas used in the early attacks.


PHOSGENE INTRODUCED

The use of chlorine alone continued until the introduction on December
19, 1915, of a mixture of phosgene with the chlorine. This mixture
offered many advantages over the use of chlorine alone (see Chapter VI).

The Allies were able, through warning of the impending use of phosgene,
to furnish a means of protection against it. It was at this time
that the P and the PH helmets were devised, the cotton filling being
impregnated with sodium phenolate and later with a mixture of sodium
phenolate and hexamethylenetetramine. This helmet was used until the
Standard Box Respirator was developed by the late Lt. Col. Harrison.


ALLIES ADOPT GAS

For a week or two the Allies were very hesitant about adopting gas
warfare. However, when the repeated use of gas by the Germans made
it evident that, in spite of what the Hague had to say about the
matter, gas was to be a part, and as later developments showed, a very
important part of modern warfare, they realized there was no choice on
their part and that they had to retaliate in like manner. This decision
was reached in May of 1915. It was followed by the organization of a
Gas Service and intensive work on the part of chemists, engineers and
physiologists. It was September 25, 1915, however, before the English
were in a position to render a gas attack. From then on the Service
grew in numbers and in importance, whether viewed from the standpoint
of research, production, or field operations.

The Allies of course adopted not only chlorine but phosgene as well,
since both were cheap, easy of preparation and effective. They felt
during the early part of the War that they should adopt a substance
that would kill instantly, and not one that would cause men to suffer
either during the attack or through symptoms which would develop later
in a hospital. For this reason a large amount of experimental work was
carried out on hydrocyanic acid, particularly by the French. Since this
gas has a very low density, it was necessary to mix with it substances
which would tend to keep it close to the ground during the attack.
Various mixtures, all called “vincennite,” were prepared,—chloroform,
arsenic trichloride and stannic chloride being used in varying
proportions with the acid. It was some time before it was definitely
learned that these mixtures were far from being successful, both from
the standpoint of stability and of poisonous properties. While the
French actually used these mixtures in constantly decreasing quantities
on the field for a long time, they were ultimately abandoned, though
not until American chemists had also carried out a large number
of tests. However, following the recommendation of the American
Gas Service in France in December, 1917, no vincennite was ever
manufactured by the United States.


LACHRYMATORS

Almost simultaneously with the introduction of the gas wave attacks, in
which liquefied gas under pressure was liberated from cylinders, came
the use of lachrymatory or tear gases. These, while not very poisonous
in the concentrations used, were very effective in incapacitating men
through the effects produced upon their eyes. The low concentration
required (one part in ten million of some lachrymators is sufficient
to make vision impossible without a mask) makes this form of gas
warfare very economical as well as very effective. Even if a mask
does completely protect against such compounds, their use compels an
army to wear the mask indefinitely, with an expenditure of shell far
short of that required if the much more deadly gases were used. Thus
Fries estimates that one good lachrymatory shell will force wearing
the mask over an area that would require 500 to 1000 phosgene shell
of equal size to produce the same effect. While the number of actual
casualties will be very much lower, the total effect considered from
the standpoint of the expenditure of ammunition and of the objectives
gained, will be just as valuable. So great is the harassing value
of tear and irritant gases that the next war will see them used in
quantities approximating that of the more poisonous gases.

The first lachrymator used was a mixture of the chlorides and bromides
of toluene. Benzyl chloride and bromide are the only valuable
substances in this mixture, the higher halogenated products having
little or no lachrymatory value. Xylyl bromide is also effective.
Chloroacetone and bromoacetone are also well known lachrymators, though
they are expensive to manufacture and are none too stable. Because of
this the French modified their preparation and obtained mixtures to
which they gave the name “martonite.” This is a mixture of 80 per cent
bromoacetone and 20 per cent chloroacetone, and can be made with nearly
complete utilization of the halogen. Methyl ethyl ketone may also be
used, which gives rise to the “homomartonite” of the French. During
the early part of the War, when bromine was so very expensive, the
English developed ethyl iodoacetate. This was used with or without the
addition of alcohol. Later the French developed bromobenzyl cyanide,
C₆H₅CH(Br)CN. This was probably the best lachrymator developed during
the War and put into large scale manufacture, though very little
of it was available on the field of battle before the War ended.
Chloroacetophenone would have played an important part had the War
continued.


DISADVANTAGE OF WAVE ATTACKS

As will be discussed more fully in the chapters on “The Tactics of
Gas,” the wave attacks became relatively less important in 1916
through the use of gas in artillery shell. This was the result of many
factors. Cloud gas attacks, as carried out under the old conditions,
required a long time for the preliminary preparations, entailed a
great deal of labor under the most difficult conditions, and were
dangerous of execution even when weather conditions became suitable.
The difficulties may be summarized as follows:

(1) The heavy gas cylinders used required a great deal of
transportation, and not only took the time of the Infantry but
rendered surprise attacks difficult owing both to the time required
and to the unusual activity behind the lines that became, with the
development of aeroplanes, more and more readily discerned.

(2) Few gases were available for wave attacks—chlorine, phosgene and,
to a less extent, chloropicrin proving to be the only ones successfully
used by either the Allies or the Germans. Hydrogen sulfide, carbon
monoxide and hydrocyanic acid gas were suggested and tried, but were
abandoned for one reason or another.

(3) Gas cloud attacks were wholly dependent upon weather conditions.
Not only were the velocity and direction of the wind highly important
as regards the successful carrying of the wave over the enemy’s line,
but also to prevent danger to the troops making the attack due to a
possible shift of the wind, which would carry the gas back over their
own line.

(4) The use of gas in artillery shell does not require especially
trained troops inasmuch as gas shell are fired in the same manner as
ordinary shell, and by the same gun crews. Moreover, since artillery
gas shell are used generally only for ranges of a mile or more, the
direction and velocity of the wind are of minor importance. Another
factor which adds to the advantage of artillery shell in certain cases
is the ability to land high concentrations of gas suddenly upon a
distant target through employing a large number of the largest caliber
guns available for firing gas.

Notwithstanding the above named disadvantages of wave attacks it was
felt by the Americans from the beginning that successful gas cloud
attacks were so fruitful in producing casualties and were such a strain
upon those opposed to it, that they would continue. Furthermore, since
artillery shell contain about 10 per cent gas, while gas cylinders may
contain 50 per cent, or even more of the total weight of the cylinder,
the efficiency of a cloud gas attack for at least the first mile of the
enemy’s territory is far greater than that of the artillery gas attack.
It was accordingly felt that the only thing necessary to make cloud gas
attacks highly useful and of frequent occurrence in the future was the
development of mobile methods—methods whereby the gas attack could be
launched on the surface of the ground and at short notice. For these
reasons gas wave attacks may be expected to continue and to eventually
reach a place of very decided importance in Chemical Warfare.


GAS SHELL

The firing of gas in artillery shell and in bombs has another great
advantage over the wave attack just mentioned. There is a very great
latitude in the choice of those gases which have a high boiling point
or which, at ordinary temperatures, are solids. Mustard gas is an
example of a liquid with a high boiling point, and diphenylchloroarsine
an example of a gas that is ordinarily solid. For the above reason the
term “gas warfare” was almost a misnomer at the close of the War, and
today is true only in the sense that all the substances used are in a
gaseous or finely divided condition immediately after the shell explode
or at least when they reach the enemy.


PROJECTOR ATTACKS

Still another method of attack, developed by the British and first
used by them in July, 1917, was the projector (invented by Captain
Livens). This was used very successfully up to the close of the War,
and though the German attempted to duplicate it, his results were never
as effective. The projector consists of a steel tube of uniform cross
section, with an internal diameter of about 8 inches. By using nickel
steel the weight may be decreased until it is a one man load. The
projector was set against a pressed steel base plate (about 16 inches
in diameter) placed in a very shallow trench.

[Illustration: FIG. 2.—Livens’ Projector.

The Type shown is an 18 cm. German Gas Projector, captured during the
2d Battle of the Marne.]

Until about the close of the war projectors were installed by digging
a triangular trench deep enough to bring the muzzles of the projectors
nearly level with the surface of the ground. They were then protected
by sand bags or canvas covers, or camouflaged with wire netting to
which colored bits of cloth were tied to simulate leaves and shadows.
The projectors were fired by connecting them in series with ordinary
blasting machines operated by hand from a convenient point in the
rear. The digging in of the projectors in No Man’s Land or very close
to it was a dangerous and laborious undertaking. The Americans early
conceived the idea that projectors could be fired just as accurately
by digging a shallow trench just deep enough to form a support for
the base plate, and then supporting the outer ends of the projector
on crossed sticks or a light frame work of boards. This idea proved
entirely practical except for one condition. It was found necessary to
fire with a single battery all the projectors near enough together to
be disturbed by the blast from any portion of them. Inasmuch as most of
the blasting machines used for firing had a capacity of only 20 to 30
projectors, it was necessary to so greatly scatter a large projector
attack that the method was very little used. However, investigations
were well under way at the close of the War to develop portable
firing batteries that would enable the discharge of at least 100 and
preferably 500 projectors at one time. By this arrangement a projector
attack could be prepared and launched in two to four hours, depending
upon the number of men available. This enabled the attack to be decided
upon in the evening (if the weather conditions were right), and to have
the attack launched before morning, thereby making it impossible for
aeroplane observers, armed with cameras, to discover the preparation
for the projector attack. Since the bombs used in the projector may
carry as high as 30 pounds of gas (usually phosgene), some idea of the
amount of destruction may be gained when it is known that the British
fired nearly 2500 at one time into Lens.


STOKES’ MORTAR

Another British invention is the Stokes’ gun or trench mortar. The
range of this gun is about 800 to 1000 yards. It is therefore effective
only where the front lines are relatively close together. The shell
consists of a case containing the high explosive, smoke material or
gas, fitted to a base filled with a high charge of propelling powder.
The shell is simply dropped into the gun. At the bottom of the gun
there is a projection or stud that strikes the primer, setting off
the small charge and expelling the projectile. In order to obtain any
considerable concentration of gas in a particular locality, it is
necessary to fire the Stokes’ continuously (15 shots per minute being
possible under battle conditions) for two to five minutes since the
bomb contains only seven pounds of gas.


SUPERPALITE

It is believed that the first gas shell contained lachrymators or tear
gases. Although the use of these shell continued up to and even after
the introduction of mustard gas, they gradually fell off in number—the
true poison gas shell taking their place. Towards the end of 1915 Auld
states that the Germans were using chloromethyl chloroformate (palite)
in shell. In 1916, during the battle of the Somme, palite was replaced
by superpalite (trichloromethyl chloroformate, or diphosgene) which
is more toxic than palite, and about as toxic as phosgene. It has the
advantage over phosgene of being much more persistent. In spite of the
fact that American chemists were not able to manufacture superpalite
on a large scale, or at least so successfully that it would compete in
price with other war gases, the Germans used large quantities of it,
alone and mixed with chloropicrin, in shell of every caliber up to and
including the 15 cm. Howitzer.

[Illustration: FIG. 3.—Stokes’ Mortar.]


CHLOROPICRIN

The next gas to be introduced was chloropicrin, trichloronitromethane
or “vomiting gas.” It has been stated that a mixture of chloropicrin
(25 per cent) and chlorine (75 per cent) has been used in cloud
attacks, but the high boiling point of chloropicrin (112° C.) makes its
considerable use for this purpose very unlikely. The gas is moderately
toxic and somewhat lachrymatory, but it was mainly used because of
its peculiar property of causing vomiting when inhaled. Its value was
further increased at first because it was particularly difficult to
prepare a charcoal which would absorb it. Its peculiar properties are
apt to cause it to be used for a long time.


SNEEZING GAS

During the summer of 1917 two new and very important gases were
introduced, and, as before, by the Germans. One of these was
diphenylchloroarsine, “sneezing gas” or “Blue Cross.” This is a white
solid which was placed in a bottle and embedded in TNT in the shell.
Upon explosion of the shell the solid was atomized into very fine
particles. Since the ordinary mask does not remove smoke or mists,
the sneezing gas penetrates the mask and causes violent sneezing.
The purpose, of course, is to compel the removal of the mask in an
atmosphere of lethal gas. (The firing regulations prescribed its use
with phosgene or other lethal shell.) The latest type masks protect
against this dust, but as it is extraordinarily powerful, its use will
continue.


MUSTARD GAS

The second gas was dichloroethyl sulfide, mustard gas, Yellow Cross or
Yperite. Mustard gas, as it is commonly designated, is probably the
most important single poisonous substance used in gas warfare. It was
first used by the Germans at Ypres, July 12, 1917. The amount of this
gas used is illustrated by the fact that at Nieuport more than 50,000
shell were fired in one night, some of which contained nearly three
gallons of the liquid.

Mustard gas is a high boiling and very persistent material, which is
characterized by its vesicant (skin blistering) action. Men who come in
contact with it, either in the form of fine splashes of the liquid or
in the form of vapor, suffer severe blistering of the skin. The burns
appear from four to twelve hours after exposure and heal very slowly.
Ordinary clothing is no protection against either the vapor or the
liquid. Other effects will be considered in Chapter IX.

Since then there has been no important advance so far as new gases
are concerned. Various arsenic derivatives were prepared in the
laboratory and tested on a small scale. The Germans did actually
introduce ethyldichloroarsine and the Americans were considering
methyldichloroarsine. Attempts were made to improve upon mustard gas
but they were not successful.


LEWISITE

It is rather a peculiar fact that so few new chemical compounds were
used as war gases. Practically all the substances were well known
to the organic chemist long before the World War. One of the most
interesting and valuable of the compounds which would have found
extensive use had the War continued, is an arsenic compound called
Lewisite from its discoverer, Capt. W. Lee Lewis, of Northwestern
University. The chemistry of this compound is discussed in Chapter X.
Because of the early recognized value of this compound, very careful
secrecy was maintained as to all details of the method of preparation
and its properties. As a result, strange stories were circulated about
its deadly powers. Characteristic of these was the story that appeared
in the _New York Times_ early in 1919. Now that the English have
published the chemical and pharmacological properties, we can say that,
although Lewisite was never proven on the battle field, laboratory
tests indicate that we have here a very powerful agent. Not only is it
a vesicant of about the same order of mustard gas, but the arsenical
penetrates the skin of an animal, and three drops, placed on the
abdomen of a mouse, are sufficient to kill within two to three hours.
It is also a powerful respiratory irritant and causes violent sneezing.
Its possible use in aeroplane bombs has led General Fries to apply the
term “The Dew of Death” to its use in this way.


CAMOUFLAGE GASES

Considerable effort was spent on the question of camouflage gases. This
involved two lines of research:

(1) To prevent the recognition of a gas when actually present on the
field, by masking its odor.

                                TABLE I
                    CHEMICAL WARFARE GASES

    ----------------------+-----------+--------------+------------------
          Chemical        |Belligerent|   Effect     | Means of
                          |           |              |    Projection
    ----------------------+-----------+--------------+------------------
    Acrolein              |  French   |Lachrymatory  |Hand grenades
        (allylaldehyde)   |           |Lethal        |
    Arsenic chloride      |           |(In mixtures. |
                          |           |   See below) |
    Benzyl iodide         |  French   |Lachrymatory  |Artillery shell
    Benzyl chloride       |  French   |Lachrymatory  |Artillery shell
                          |           |              |
    Bromoacetone          |  French   |Lachrymatory  |Artillery shell
                          |           |Lethal        |
    Bromobenzylcyanide    |  French   |Lachrymatory  |Artillery shell
    Bromomethylethylketone|  German   |Lachrymatory  |Artillery shell
                          |           |Lethal        |Artillery shell
                          |           |              |
    Benzyl bromide        |  German   |Lachrymatory  |Artillery shell
                          |  French   |              |
    Chlorine              |  German   |Lethal        |Cylinders
                          |  British  |              |    (cloud gas)
                          |  French   |              |
                          |  American |              |
    Chlorosulfonic acid   |  German   |Irritant      |Hand grenades,
                          |           |              | light minenwerfer
    Chloroacetone         |  French   |Lachrymatory  |Artillery shell
    Chlorobenzene         |  German   |Lachrymatory  |Artillery shell
        (as solvent)      |           |              |
    Chloropicrin          |  British  |Lethal        |Artillery shell
                          |  French   |Lachrymatory  |Trench mortar
                          |  German   |              |        bombs
                          |  American |              |Projectors
    Cyanogen bromide      |  Austrian | Lethal       |Artillery shell
    Dichloromethylether   |  German   | Lachrymatory |Artillery shell
       (as solvent)       |           |              |
    Diphenylchloroarsine  |  German   | Sternutatory |Artillery shell
                          |           | Lethal       |
    Dichloroethylsulfide  |  German   | Vesicant     |Artillery shell
                          |  French   | Lethal       |
                          |  British  | Irritant     |
                          |  American |              |
                          |           |              |
    Ethyldichloroarsine   |  German   | Lethal       |Artillery shell
    Ethyliodoacetate      |  British  | Lachrymatory |Artillery shell,
                          |           |              |4-in. Stokes’
                          |           |              |     mortars,
                          |           |              |hand grenades
    Hydrocyanic acid      |  French   | (In mixtures.|
                          |           |   See below) |
    Methylchlorosulfonate |  German   | Irritant     |Minenwerfer
    Monochloromethyl-     |  German   | Lethal       |Artillery shell
            chloroformate |  French   | Lachrymatory |
                          |           |              |
    Phosgene              |  British  | Lethal       |Projectors,
                          |  French   |              |  trench mortars,
                          |  German   |              |  artillery shell,
                          |  American |              |  cylinders
    Phenylcarbylamine     |  German   | Lachrymatory |Artillery shell
            chloride      |           | Irritant     |
    Trichlormethyl        |  German   | Lethal       |Artillery shell
         chloroformate    |           |              |
    Stannic chloride      |  British  | Irritant     |Hand grenades
                          |  French   | Cloud forming|Artillery
                          |  American |              |Projectors
                          |           |              |   4-in. Stokes’
                          |           |              |    mortar bombs
    Sulfuric anhydride    |  German   | Irritant     |Hand grenades,
                          |           |              |  minenwerfer,
                          |           |              |  artillery shell
    Xylyl bromide         |  German   | Lachrymatory |Artillery shell
    ----------------------+-----------+--------------+------------------

                                TABLE I--_Continued_

    ---------------------------+-----------+------------+---------------
               Chemical        |Belligerent|  Effect    |Means of
                               |           |            |   Projection
    ---------------------------+-----------+------------+---------------
                               |           |            |
        MIXTURES[4]            |         |             |
    Bromoacetone (80%) and     |           |            |
    Chloroacetone (20%)        |  French   |Lachrymatory|Artillery shell
                               |           |Lethal      |
                               |           |            |
    Chlorine (50%) and         |  British  |Lethal      |Cylinders
    Phosgene (50%)             |  German   |            |
                               |           |            |
    Chlorine (70%) and         |  British  |Lethal      |Cylinders
    Chloropicrin (30%)         |           |Lachrymatory|
                               |           |            |
    Chloropicrin (65%) and     |  British  |Lethal      |Cylinders
    Hydrogen sulfide (35%)     |           |Lachrymatory|
                               |           |            |
    Chloropicrin (80%) and     |  British  |Lethal      |Artillery shell
    Stannic chloride (20%)     |  French   |Lachrymatory|Trench mortar
                               |           |            |  bombs
                               |  American |Irritant    |Projectors
    Chloropicrin (75%) and     |  British  |Lethal      |Artillery shell
    Phosgene (25%)             |           |Lachrymatory|Trench mortar
                               |           |            |  bombs,
                               |           |            |  projectors
    Dichloroethyl sulfide (80%)|  German   |Vesicant    |Artillery shell
    and                        |  French   |Lethal      |
    Chlorobenzene (20%)        |  British  |            |
                               |  American |            |
    Ethyl carbazol (50%) and   |  German   |Sternutatory|Artillery shell
    Diphenylcyanoarsine (50%)  |           |Lethal      |
                               |           |            |
    Ethyldichloroarsine (80%)  |  German   |Lethal      |Artillery shell
             and               |           |Lachrymatory|
    Dichloromethylether (20%)  |           |            |
                               |           |            |
    Ethyliodoacetate (75%) and |  British  |Lachrymatory|Artillery shell,
    Alcohol (25%)              |           |            | 4-in. Stokes’
                               |           |            |   mortars,
                               |           |            | hand grenades
                               |           |            |
    Hydrocyanic acid (55%)     |  British  |Lethal      |Artillery shell
    Chloroform (25%) and       |           |            |
    Arsenious chloride (20%)   |           |            |
                               |           |            |
    Hydrocyanic acid (50%),    |  French   |Lethal      |Artillery shell
    Arsenious chloride (30%),  |           |            |
    Stannic chloride (15%) and |           |            |
    Chloroform (5%)            |           |            |
                               |           |            |
    Phosgene (50%) and         |  British  |Lethal      |Artillery shell
    Arsenious chloride (50%)   |           |            |
                               |           |            |
    Dichloroethyl sulfide (80%)|  German   |Vesicant    |Artillery shell
            and                |  French   |Lethal      |
    Carbon tetrachloride (20%) |  British  |            |
                               |  American |            |
                               |           |            |
    Phosgene (60%) and         |  British  |Lethal      |Artillery shell
    Stannic chloride (40%)     |  French   |Irritant    |
                               |           |            |
    Methyl sulfate (75%) and   |  French   |Lachrymatory|Artillery shell
    Chloromethyl sulfate (25%) |           |Irritant    |
    ---------------------------+-----------+------------+---------------

[Footnote 4: In the mixtures the percentages indicate proportions by
weight.]

(2) To simulate the presence of a toxic gas. This may be done either by
using a substance whose odor in the field strongly suggests that of the
gas in question, or by so thoroughly associating a totally different
odor with a particular “gas” in normal use that, when used alone, it
still seems to imply the presence of that gas. This use of imitation
gas would thus be of service in economizing the use of actual “gas” or
in the preparation of surprise attacks.

While there was some success with this kind of “gas,” very few such
attacks were really carried out, and these were in connection with
projector attacks.


GASES USED

Table I gives a list of all the gases used by the various armies, the
nation which used them, the effect produced and the means of projection
used.

Table II gives the properties of the more important war cases (compiled
by Major R. E. Wilson, C. W. S.).

The gases used by the Germans may also be classified by the names
of the shell in which they were used. Table III gives such a
classification.


MARKINGS FOR AMERICAN SHELL

In selecting markings for American chemical shell, red bands were used
to denote persistency, white bands to denote non-persistency and lethal
properties, yellow bands to denote smoke, and purple bands to denote
incendiary action. The number of bands indicates the relative strength
of the property indicated; thus, three red bands denote a gas more
persistent than one red band.

The following shell markings were actually used:

    1 White                    Diphenylchloroarsine
    2 White                    Phosgene
    1 White, 1 red             Chloropicrin
    1 White, 1 red, 1 white    75% Chloropicrin, 25% Phosgene
    1 White, 1 red, 1 yellow   80% Chloropicrin, 20% Stannic Chloride
    1 Red                      Bromoacetone
    2 Red                      Bromobenzylcyanide
    3 Red                      Mustard Gas
    1 Yellow                   White Phosphorus
    2 Yellow                   Titanium Tetrachloride

                              TABLE II

          PHYSICAL CONSTANTS OF IMPORTANT WAR GASES
    ----------------------+---------------+-----------+----------
                          |               |           | Liquid
                          |               |           | Density
          Name of Gas     |    Formula    | Molecular | at 20° C.
                          |               |  Weight   |  under
                          |               |           |   Own
                          |               |           | Pressure
    ----------------------+---------------+-----------+----------
    Bromoacetone          | C₃H₅BrO       |  136.98   | 1.7(?)
    Carbon monoxide       | CO            |   28.00   | (Gas)
    Cyanogen bromide      | BrCN          |  106.02   | 2.01
    Cyanogen chloride     | ClCN          |   61.56   | 1.186
    Chlorine              | Cl₂           |   70.92   | 1.408
    Chloropicrin          | Cl₃C(NO₂)     |  164.39   | 1.654
    Dichloroethyl sulfide | (CH₃CHCl₂)S   |  169.06   | 1.274
    Diphenylchloroarsine  | (C₆H₅)₂AsCl   |  264.56   | 1.422
    Hydrocyanic acid      | HCN           |   27.11   |  .697
    Phenyldichloroarsine  | C₆H₅AsCl₂     |  210.96   | 1.640
    Phosgene              | COCl₂         |   98.92   | 1.38
    Stannic chloride      | SnCl₄         |  260.54   | 2.226
    Superpalite           | CCl₃COOCl     |  197.85   | 1.65
    Xylyl bromide         |( CH₃)C₆H₄CH₂Br|  185.03   | 1.381
    ----------------------+---------------+-----------+-----------
    ----------------------+---------+---------+----------
                          |         |         |
                          |         |         |  Vapor
          Name of Gas     | Melting | Boiling | Pressure
                          |  point, |  point, | at 20° C.
                          |   °C.   |   °C.   | (mm. Hg)
                          |         |         |
    ----------------------+---------+---------+----------
    Bromoacetone          |  - 54   |   126   |    9(?)
    Carbon monoxide       |  -207   |  -190   |   (Gas)
    Cyanogen bromide      |    52   |    61.3 |   89
    Cyanogen chloride     |  -  6   |    15   | 1002
    Chlorine              |  -101.5 |    33.6 | 5126
    Chloropicrin          |  - 69.2 |   112   |   18.9
    Dichloroethyl sulfide |    12.5 |   216   |     .06
    Diphenylchloroarsine  |    44   |   333   |     .0025
    Hydrocyanic acid      |  - 14   |    26.1 |  603
    Phenyldichloroarsine  |   ...   |   253   |     .022
    Phosgene              |   ...   |     8.2 | 1215
    Stannic chloride      |  - 33   |   114   |   18.58
    Superpalite           |   ...   |   128   |   10.3
    Xylyl bromide         |  -  2   |   214.5 |   ...
    ----------------------+---------+---------+----------

                               TABLE III

                         GERMAN SHELL
    -----------------------+-----------------------------+------------
         Name of Shell     |        Shell Filling        | Nature of
                           |                             |   Effect
    -----------------------+-----------------------------+------------
    B-shell [K₁ shell      | Bromoketone (Bromo-         | Lachrymator
        (White B or BM)]   |        methylethyl ketone)  |
                           |                             |
    Blue Cross             | (_a_) Diphenylchloroarsine  | Sternutator
                           | (_b_) Diphenylcyanoarsine   | Sternutator
                           | (_c_) Diphenylchloroarsine, |
                           |       Ethyl carbazol        |
                           |                             |
    C-shell (Green Cross)  | Superpalite                 | Asphyxiant
        (White C)          |                             |
                           |                             |
    D-shell (White D)      | Phosgene                    | Lethal
                           |                             |
    Green Cross            | (_a_) Superpalite           | Asphyxiant
                           | (_b_) Phenylcarbylamine     |
                           |         chloride            |
                           |                             |
    Green Cross 1          | Superpalite 65%,            | Asphyxiant
                           | Chloropicrin 35%            |
                           |                             |
    Green Cross 2          | Superpalite,                |
                           | Phosgene,                   |
                           | Diphenylchloroarsine        | Asphyxiant
                           |                             |
    Green Cross 3          | Ethyldichloroarsine,        | Asphyxiant
        (Yellow Cross 1)   | Methyldibromoarsine,        |
                           | Dichloromethyl ether        |
                           |                             |
    K-shell (Yellow)       | Chloromethyl                | Lachrymator
                           |   chloroformate (Palite)    | Asphyxiant
                           |                             |
    T-shell                | Xylyl bromide,              | Lachrymator
        (Black or green T) | Bromo ketone                |
                           |                             |
    Yellow Cross           | Mustard gas,                | Vesicant
                           | Diluent (CCl₄, C₆H₅Cl,      |
                           |   C₆H₅NO₂)                  |
                           |                             |
    Yellow Cross 1         | See Green Cross 3           |
    -----------------------+-----------------------------+------------




CHAPTER III

DEVELOPMENT OF THE CHEMICAL WARFARE SERVICE


Modern chemical warfare dates from April 22, 1915. Really, however, it
may be said to have started somewhat earlier, for Germany undoubtedly
had spent several months in perfecting a successful gas cylinder and a
method of attack. The Allies, surprised by such a method of warfare,
were forced to develop, under pressure, a method of defense, and then,
when it was finally decided to retaliate, a method of gas warfare.
“Offensive organizations were enrolled in the Engineer Corps of the two
armies and trained for the purpose of using poisonous gases; the first
operation of this kind was carried out by the British at the battle of
Loos in September, 1915.

“Shortly after this the British Army in the field amalgamated all the
offensive, defensive, advisory and supply activities connected with
gas warfare and formed a ‘Gas Service’ with a Brigadier General as
Director. This step was taken almost as a matter of necessity, and
because of the continually increasing importance of the use of gas in
the war (Auld).”

At once the accumulation of valuable information and experience was
started. Later this was very willingly and freely placed at the
disposal of American workers. Too much cannot be said about the hearty
co-operation of England and France. Without it and the later exchange
of information on all matters regarding gas warfare, the progress of
gas research in all the allied countries would have been very much
retarded.

While many branches of the American Army were engaged in following the
progress of the war during 1915-1916, the growing importance of gas
warfare was far from being appreciated. When the United States declared
war on Germany April 6, 1917, there were a few scattered observations
on gas warfare in various offices of the different branches, but there
was no attempt at an organized survey of the field, while absolutely no
effort had been made by the War Department to inaugurate research in
a field that later had 2,000 men alone in pure research work. Equally
important was the fact that no branch of the Service had any idea of
the practical methods of gas warfare.

The only man who seemed to have the vision and the courage of his
convictions was Van H. Manning, Director of the Bureau of Mines. Since
the establishment of the Bureau in 1908 it had maintained a staff
of investigators studying poisonous and explosive gases in mines,
the use of self-contained breathing apparatus for exploring mines
filled with noxious gases, the treatment of men overcome by gas, and
similar problems. At a conference of the Director of the Bureau with
his Division Chiefs, on February 7, 1917, the matter of national
preparedness was discussed, and especially the manner in which the
Bureau could be of most immediate assistance with its personnel and
equipment. On February 8, the Director wrote C. D. Walcott, Chairman
of the Military Committee of the National Research Council, pointing
out that the Bureau of Mines could immediately assist the Navy and
the Army in developing, for naval or military use, special oxygen
breathing apparatus similar to that used in mining. He also stated that
the Bureau could be of aid in testing types of gas masks used on the
fighting lines, and had available testing galleries at the Pittsburgh
experiment station and an experienced staff. Dr. Walcott replied on
February 12 that he was bringing the matter to the attention of the
Military Committee.

A meeting was arranged between the Bureau and the War College, the
latter organization being represented by Brigadier General Kuhn
and Major L. P. Williamson. At this conference the War Department
enthusiastically accepted the offer of the Bureau of Mines and agreed
to support the work in every way possible.

The supervision of the research on gases was offered to Dr. G. A.
Burrell, for a number of years in charge of the chemical work done by
the Bureau in connection with the investigation of mine gases and
natural gas. He accepted the offer on April 7, 1917. The smoothness
with which the work progressed under his direction and the importance
of the results obtained were the result of Colonel Burrell’s great
tact, his knowledge of every branch of research under investigation and
his imagination and general broad-mindedness.

Once, however, that the importance of gas warfare had been brought to
the attention of the chemists of the country, the response was very
eager and soon many of the best men of the university and industrial
plants were associated with Burrell in all the phases of gas research.
The staff grew very rapidly and laboratories were started at various
points in the East and Middle West.

It was immediately evident that there should be a central laboratory
in Washington to co-ordinate the various activities and also to
considerably enlarge those activities under the joint direction of
the Army, the Navy and the Bureau of Mines. Fortunately a site was
available for such a laboratory at the American University, the use
of the buildings and grounds having been tendered President Wilson on
April 30, 1917. Thus originated the American University Experiment
Station, later to become the Research Division of the Chemical Warfare
Service.

Meanwhile other organizations were getting under way. The procurement
of toxic gases and the filling of shell was assigned to the Trench
Warfare Section of the Ordnance Department. In June, 1917, General
Crozier, then Chief of the Ordnance Department, approved the general
proposition of building a suitable plant for filling shell with toxic
gas. In November, 1917, it was decided to establish such a plant at
Gunpowder Neck, Maryland. Owing to the inability of the chemical
manufacturers to supply the necessary toxic gases, it was further
decided, in December, 1917, to erect at the same place such chemical
plants as would be necessary to supply these gases. In January, 1918,
the name was changed to Edgewood Arsenal, and the project was made a
separate Bureau of the Ordnance Department, Col. William H. Walker, of
the Massachusetts Institute of Technology, being soon afterwards put in
command.

While, during the latter part of the War, gas shell were handled
by the regular artillery, special troops were needed for cylinder
attacks, Stokes’ mortars, Livens’ projectors and for other forms of gas
warfare. General Pershing early cabled, asking for the organization and
training of such troops, and recommended that they be placed, as in the
English Army, under the jurisdiction of the Engineer Corps. On August
15, 1917, the General Staff authorized one regiment of Gas and Flame
troops, which was designated the “30th Engineers,” and was commanded by
Major (later Colonel) E. J. Atkisson. This later became the First Gas
Regiment, of the Chemical Warfare Service.

About this time (September, 1917) the need of gas training was
recognized by the organization of a Field Training Section, under the
direction of the Sanitary Corps, Medical Department. Later it was
recognized that neither the Training Section nor the Divisional Gas
Officers should be under the Medical Department, and, in January, 1918,
the organization was transferred to the Engineer Corps.

All of these, with the exception of the Gas and Flame regiment, were
for service on this side. The need for an Overseas force was recognized
and definitely stated in a letter, dated August 4, 1917. On September
3, 1917, an order was issued establishing the Gas Service, under
the command of Lt. Col. (later Brigadier General) A. A. Fries, as a
separate Department of the A. E. F. in France. In spite of a cable on
September 26th, in which General Pershing had said

    “Send at once chemical laboratory, complete
    equipment and personnel, including physiological and
    pathological sections, for extensive investigation of
    gases and powders....”

it was not until the first of January, 1918, that Colonel R. F. Bacon
of the Mellon Institute sailed for France with about fifty men and a
complete laboratory equipment.

Meantime a Chemical Service Section had been organized in the United
States. This holds the distinction of being the first recognition of
chemistry as a separate branch of the military service in any country
or any war. This was authorized October 16, 1917, and was to consist
of an officer of the Engineers, not above the rank of colonel, who was
to be Director of Gas Service, with assistants, not above the rank of
lieutenant colonel from the Ordnance Department, Medical Department
and Chemical Service Section. The Section itself was to consist of 47
commissioned and 95 non-commissioned officers and privates. Colonel C.
L. Potter, Corps of Engineers, was appointed Director and Professor
W. H. Walker was commissioned Lieutenant Colonel and made Assistant
Director of the Gas Service and Chief of the Chemical Service Section.
This was increased on Feb. 15, 1918 to 227 commissioned and 625
enlisted men, and on May 6, 1918 to 393 commissioned and 920 enlisted
men. Meanwhile Lt. Col. Walker had been transferred to the Ordnance and
Lt. Col. Bogert had been appointed in his place.

At this time practically every branch of the Army had some connection
with Gas Warfare. The Medical Corps directed the Gas Defense
production. Offense production was in the hands of the Ordnance
Department. Alarm devices, etc., were made by the Signal Corps. The
Engineers contributed their 30th Regiment (Gas and Flame) and the Field
Training Section. The Research Section was still in charge of the
Bureau of Mines, in spite of repeated attempts to militarize it. And
in addition, the Chemical Service Section had been formed primarily
to deal with overseas work. While the Director of the Gas Service was
expected to co-ordinate all these activities, he was given no authority
to control policy, research or production.

In order to improve these conditions Major General Wm. L. Sibert, a
distinguished Engineer Officer who built the Gatun Locks and Dam of the
Panama Canal and who had commanded the First Division in France, was
appointed Director of the Chemical Warfare Service on May 11, 1918.
Under his direction the Chemical Warfare Service was organized with the
following Divisions:

    Overseas                   Brigadier General Amos A. Fries
    Research                   Colonel G. A. Burrell
    Development                Colonel F. M. Dorsey
    Gas Defense Production     Colonel Bradley Dewey
    Gas Offense Production     Colonel Wm. H. Walker
    Medical                    Colonel W. J. Lyster
    Proving                    Lt. Col. W. S. Bacon
    Administration             Brigadier General H. C. Newcomer
    Gas and Flame              Colonel E. J. Atkisson

The final personnel authorized, though never reached owing to the
signing of the Armistice, was 4,066 commissioned officers and 44,615
enlisted men; this was including three gas regiments of eighteen
companies each.

General Sibert brought with him not only an extended experience in
organizing and conducting big business, but a strong sympathy for the
work and an appreciation of the problem that the American Army was
facing in France. He very quickly welded the great organization of
the Chemical Warfare Service into a whole, and saw to it that each
department not only carried on its own duties but co-operated with
the others in carrying out the larger program, which, had the war
continued, would have beaten the German at his own game.

More detailed accounts will now be given of the various Divisions of
the Chemical Warfare Service.


ADMINISTRATION DIVISION

The Administration Division was the result of the development which has
been sketched in the preceding pages. It is not necessary to review
that, but the organization as of October 19, 1918 will be given:

    Director                            Major General Wm. L. Sibert
    Staff:
      Medical Officer                   Colonel W. J. Lyster
      Ordnance Officer                  Lt. Col. C. B. Thummel
      British Military Mission          Major J. H. Brightman
    Assistant Director                  Colonel H. C. Newcomer
    Office Administration               Major W. W. Parker
    Relations Section                   Colonel M. T. Bogert
    Personnel Section                   Major F. E. Breithut
    Contracts and Patents Section       Captain W. K. Jackson
    Finance Section                     Major C. C. Coombs
    Requirements and Progress Section   Capt. S. M. Cadwell
    Confidential Information Section    Major S. P. Mullikin
    Transportation Section              Captain H. B. Sharkey
    Training Section                    Lt. Col. G. N. Lewis
    Procurement Section                 Lt. Col. W. J. Noonan

The administrative offices were located in the Medical Department
Building. The function of most of the sections is indicated by their
names.

The Industrial Relations Section was created to care for the interests
of the industrial plants which were considered as essential war
industries. Through its activity many vitally important industries
were enabled to retain, on deferred classification or on indefinite
furlough, those skilled chemists without which they could not have
maintained a maximum output of war munitions.

In the same way the University Relations Section cared for the
educational and research institutions. In this way our recruiting
stations for chemists were kept in as active operation as war
conditions permitted.

Another important achievement of the Administration Section was to
secure the order from The Adjutant General, dated May 28, 1918, that
read:

    “Owing to the needs of the military service for a
    great many men trained in chemistry, it is considered
    most important that all enlisted men who are graduate
    chemists should be assigned to duty where their
    special knowledge and training can be fully utilized.

     *       *       *       *       *

    “Enlisted men who are graduate chemists will not
    be sent overseas unless they are to be employed on
    chemical duties....”

While this undoubtedly created a great deal of feeling among the men
who naturally were anxious to see actual fighting in France, it was
very important that this order be carried out in order to conserve our
chemical strength. The following clipping from the September, 1918,
issue of _The Journal of Industrial and Engineering Chemistry_ shows
the result of this order.


“CHEMISTS IN CAMP

    “As the result of the letter from The Adjutant General
    of the Army, dated May 28, 1918, 1,749 chemists have
    been reported on. Of these the report of action to
    August 1, 1918, shows that 281 were ordered to remain
    with their military organization because they were
    already performing chemical duties, 34 were requested
    to remain with their military organization because they
    were more useful in the military work which they were
    doing, 12 were furloughed back to industry, 165 were
    not chemists in the true sense of the word and were,
    therefore, ordered back to the line, and 1,294 now
    placed in actual chemical work. There were being held
    for further investigation of their qualifications on
    August 1, 1918, 432 men. The remaining 23 men were
    unavailable for transfer, because they had already
    received their overseas orders.

    “The 1,294 men, who would otherwise be serving in a
    purely military capacity and whose chemical training is
    now being utilized in chemical work, have, therefore,
    been saved from waste.

    “Each case has been considered individually, the man’s
    qualifications and experience have been studied with
    care, the needs of the Government plants and bureaus
    have been considered with equal care, and each man has
    been assigned to the position for which his training
    and qualifications seem to fit him best.

    “Undoubtedly, there have been some cases in which
    square pegs have been fitted into round holes, but, on
    the whole, it is felt that the adjustments have been as
    well as could be expected under the circumstances.”


RESEARCH DIVISION

The American University Experiment Station, established by the Bureau
of Mines in April, 1917, became July 1, 1918 the Research Division
of the Chemical Warfare Service. For the first five months work was
carried out in various laboratories, scattered over the country. In
September, 1917, the buildings of the American University became
available; a little later portions of the new chemical laboratory
of the Catholic University, Washington, were taken over. Branch
laboratories were established in many of the laboratories of the
Universities and industrial plants, of which Johns Hopkins, Princeton,
Yale, Ohio State, Massachusetts Institute of Technology, Harvard,
Michigan, Columbia, Cornell, Wisconsin, Clark, Bryn Mawr, Nela Park and
the National Carbon Company were active all through the war.

At the time of the signing of the armistice the organization of the
Research Division was as follows:

    Col. G. A. Burrell       Chief of Research Division
    Dr. W. K. Lewis          In Charge of Defense Problems
    Dr. E. P. Kohler[5]      In Charge of Offense Problems
    Dr. Reid Hunt            Advisor on Pharmacological Problems
    Lt. Col. W. D. Bancroft  In Charge of Editorial Work and Catalytic
                                           Research
    Lt. Col. A. B. Lamb[6]   In Charge of Defense Chemical Research
    Dr. L. W. Jones[7]       In Charge of Offense Chemical Research
    Major A. C. Fieldner     In Charge of Gas Mask Research
    Major G. A. Richter      In Charge of Pyrotechnic Research
    Capt. E. K. Marshall[8]  In Charge of Pharmacological Research
    Dr. A. S. Loevenhart[9]  In Charge of Toxicological Research
    Major R. C. Tolman       In Charge of Dispersoid Research
    Major W. S. Rowland[10]  In Charge of Small Scale Manufacture
    Major B. B. Fogler[11]   In Charge of Mechanical Research and
                                           Development
    Captain G. A. Rankin     In Charge of Explosive Research
    Major Richmond Levering  In Charge of Administration Section

[Footnote 5: Succeeded Dr. John Johnson who went to the National
Research Council.]

[Footnote 6: At first Lt. Col. J. F. Norris was in charge of all
chemical research. About December, 1917, it was divided into Offense
and Defense, and Lt. Col. Lamb was placed in charge of Defense. When
Col. Norris went to England as Liaison Officer, Dr. Jones took his
place.]

[Footnote 7: At first Lt. Col. J. F. Norris was in charge of all
chemical research. About December, 1917, it was divided into Offense
and Defense, and Lt. Col. Lamb was placed in charge of Defense. When
Col. Norris went to England as Liaison Officer, Dr. Jones took his
place.]

[Footnote 8: At first Lt. Col. J. F. Norris was in charge of all
chemical research. About December, 1917, it was divided into Offense
and Defense, and Lt. Col. Lamb was placed in charge of Defense. When
Col. Norris went to England as Liaison Officer, Dr. Jones took his
place.]

[Footnote 9: In the early organization of the Bureau of Mines, Dr.
Yandall Henderson was in charge of the Medical Sciences. Associated
with him were Dr. F. P. Underhill, in charge of Therapeutic Research;
Major M. C. Winternitz, in c of Pathological Research and Captain
E. K. Marshall in charge of Pharmacological Research. About May 1,
1918, Pharmacological Research became so extensive that the Section
was made into two, with Marshall and Loevenhart in charge, while Dr.
Hunt was appointed special adviser on pharmacological problems. When
the transfer to the War Department was made, Henderson, Underhill,
Winternitz and Marshall were transferred to the Medical Division.]

[Footnote 10: Lt. Col. McPherson was formerly in charge, and was later
transferred to Ordnance.]

[Footnote 11: This Section was originally under H. H. Clark. Later
it was split into two, with Clark and Fogler in charge, and finally
consolidated under Fogler.] The chief functions of the Research
Division were:

1. To prepare and test compounds which might be of value in gas
warfare, determining the properties of these substances and the
conditions under which they might be effective in warfare.

2. To develop satisfactory methods of making such compounds as seemed
promising (Small Scale).

3. To develop the best methods of utilizing these compounds.

4. To develop materials which should absorb or destroy war gases,
studying their properties and determining the conditions under which
they might be effective.

5. To develop satisfactory methods of making such absorbents as might
seem promising.

6. To develop masks, canisters, protective clothing, etc.

7. To develop incendiaries, smokes, signals, etc., and the best methods
of using the same.

[Illustration: FIG. 4.—American University Experiment Station, showing
Small Scale Plants.]

8. To co-operate with the manufacturing divisions in regard to
difficulties arising during the operations of manufacturing war gases,
absorbents, etc.

9. To co-operate with other branches of the Government, civil and
military, in regard to war problems.

10. To collect and make available to the Director of the Chemical
Warfare Service all information in regard to the chemistry of gas
warfare.

The relation of the various sections may best be shown by outlining the
general procedure used when a new toxic substance was developed.

The substance in question may have been used by the Germans or the
Allies; it may have been suggested by someone outside the station; or
the staff may have thought of it from a search of the literature, from
analogy or from pure inspiration. The Offense Research Section made the
substance. If it was a solid it was sent to the Dispersoid Section,
where methods of dispersing it were worked out. When this had been
done, or, at once, if the compound was a liquid or vapor, it was sent
to the Toxicological Section to be tested for toxicity, lachrymatory
power, vesicant action, or other special properties. If these tests
proved the compound to have a high toxicity or a peculiar physiological
behavior, it was then turned over to a number of different sections.

The Offense Research Section tried to improve the method of
preparation. When a satisfactory method had been found, the Chemical
Production or Small Scale Manufacturing Section endeavored to make it
on a large scale (50 pounds to a ton) and worked out the manufacturing
difficulties. If further tests showed that the substance was valuable,
the manufacture was then given to the Development Division or the Gas
Offense Production Division for large scale production.

Meanwhile the Analytical Section had been working on a method for
testing the purity of the material and for analyzing air mixtures,
and the Gas Mask Section had run tests against it with the standard
canisters. If the protection afforded did not seem sufficient, the
Defense Chemical Section studied changes in the ingredients of the
canister or even developed a new absorbent or mixture of absorbents to
meet the emergency. If a change in the mechanical construction of the
canister was necessary, this was referred to the Mechanical Research
Section; this work was especially important in case the material was to
be used as a toxic smoke.

The compound was also sent to the Pyrotechnic Section, which studied
its behavior when fired from a shell, or, if suitable, when used in a
cylinder. If it proved stable on detonation, large field tests were
then made by the Proving Division, in connection with the Pyrotechnic
and Toxicological Sections of the Research Division, to learn the
effect when shell loaded with the compound were fired from guns on
a range, with animals placed suitably in or near the trenches. The
Analytical Section worked out methods of detecting the gas in the
field, wherever possible.

The Medical Division, working with the Toxicological and
Pharmacological Sections, studied pathological details, methods of
treating gassed cases, the effect of the gas on the body, and in some
cases even considered other questions, such as the susceptibility of
different men.

If the question of an ointment or clothing entered into the matter
of protection, these were usually attacked by several Sections from
different points of view.

Out of the 250 gases prepared by the Offense Chemical Research Section,
very few were sufficiently valuable to pass all of these tests and
thus the number of gases actually put into large scale production were
less than a dozen. This had its advantages, for it made unnecessary a
large number of factories and the training of men in the manufacturing
details of many gases. As one British report stated, “The ultimate
object of chemical warfare should be to produce two substances only;
one persistent and the other non-persistent; both should be lethal and
both should be penetrants.” They might well have added that both should
be instantly and powerfully lachrymatory.

Since most of the work of the Research Division will be covered in
detail in later chapters, only a brief summary of the principal
problems will be given here.

The first and most important problem was the development of a gas mask.
This was before Sections had been organized and was the work of the
entire Division. After comparing the existing types of masks it was
decided that the Standard Box Respirator of the British was the best
one to copy. Because we were entirely new at the game that meant work
on charcoal, soda-lime, and the various mechanical parts of the mask,
such as the facepiece, elastics, eyepieces, mouthpiece, noseclip, hose,
can, valves, etc. The story of the “first twenty thousand” is very well
told by Colonel Burrell.[12]

[Footnote 12: _J. Ind. Eng. Chem._, =11=, 93 (1919).]


              “THE FIRST TWENTY THOUSAND

    “About the first of May, 1917, Major L. P. Williamson,
    acting as liaison officer between the Bureau of
    Mines and the War Department, put the last ounce of
    ‘pep’ into the organization by asking us to build
    20,000 gas masks for shipment overseas. 20,000 masks
    did not seem like a very large order. We did not
    fully appreciate all the conditions which a war gas
    mask had to encounter, so we readily and willingly
    accepted the order. Then began a struggle with can
    manufacturers, buckle makers, manufacturers of straps,
    rubber facepieces, eyepieces, knapsacks, etc. The
    country was canvassed from the Atlantic Coast to the
    Mississippi River for manufacturers who could turn out
    the different parts acceptably and in a hurry.

    “Charcoal was made from red cedar by the Day Chemical
    Co. of Westline, Pennsylvania; soda-lime permanganate
    was manufactured by the General Chemical Company;
    knapsacks by the Simmons Hardware Company in St.
    Louis; facepieces by the Goodrich and Goodyear Rubber
    Companies at Akron; canisters by the American Can
    Company; and the assembly made at one of the plants of
    the American Can Company in Long Island City.

    “The writer cannot recall all the doubts, fears,
    optimism, and enthusiasm felt in turn by different
    members of the organization during the fabrication
    of those first 20,000 masks. We were performing an
    important task for the War Department. Night became
    day. Dewey, Lewis, Henderson, Gibbs, and others stepped
    from one train to another, and we used the telephone
    between Washington and St. Louis or Boston as freely as
    we used the local Washington telephone.

    “We thought we could improve on the English box
    respirator on various points. We made the canister
    larger, and have been glad ever since that we did.
    We thought the English mouthpiece was too flexible
    and too small, and made ours stiff and larger, and
    were sorry we made the change. We tested the fillings
    against chlorine, phosgene, prussic acid, etc., and
    had a canister that was all that was desired for
    absorbing these gases. But, alas, we did not know
    that chloropicrin was destined to be one of the most
    important war gases used by the various belligerents.
    Further, it was not fully appreciated that the
    rubberized cloth used in making the facepiece had to
    be highly impermeable against gases, that hardness as
    much as anything else was desired in the make-up of
    the soda-lime granules in order to withstand rough
    jolting so that the fines would not clog the canister,
    and raise the resistance to breathing to a prohibitive
    figure. Neither was it appreciated at that time by any
    of the allies, that the gas mask really should be a
    be a fighting instrument, one that men could work hard
    in, run in, and wear for hours, without too serious
    discomfort.

    “The first 20,000 masks sent over to England were
    completed by the Research Division in record time.
    As compared with the French masks, they were far
    superior, giving greater protection against chlorine,
    phosgene, superpalite, prussic acid, xylyl bromide,
    etc. The French mask was of the cloth type, conforming
    to the face, and consisting of twenty layers of
    cheesecloth impregnated with sodium phenate and
    hexamethylenetetramine. Chloropicrin went through this
    like a shot. Just before the masks were sent abroad,
    we received disturbing rumors of the contemplated
    use of large quantities of chloropicrin. The French,
    apparently, had no intention of changing the design
    of their mask, and did not do so for months to come.
    We therefore released the masks, they were sent
    abroad, and an anxious research group on this side
    of the water waited expectantly for the verdict. It
    came. A brief cablegram told us what our English
    cousins thought of us. It was a subject they had been
    wrestling with for two years and a half. They had had
    battlefield experience; they had gone through the grief
    of developing poor masks into better ones, knew the
    story better than we did, and after a thorough test
    ‘hammered’ the American design unmercifully.

    “This experience put the Research Division on its
    mettle. Our first attempt had given us the necessary
    preliminary experience; cablegrams and reports traveled
    back and forth; an expert or two eventually came to
    this country from England in response to previous
    appeals for assistance, and we turned with adequate
    information to the development of a real mask.”

The story of mustard gas is given later. It probably occupied more time
and thought on the part of the Research Division, as well as that of
Edgewood Arsenal and the Development Division, than any other gas.

Diphenylchloroarsine led to the preparation of a series of arsenic
compounds, some more easily prepared and more or less effective.

Cyanogen chloride and cyanogen bromide, reported by the Italians as
having been used by the Germans, were extensively studied.

The Inorganic Section was early interested in special incendiary
materials which were developed for bombs, shells, darts and grenades,
and which were later taken over by the Pyrotechnic Section, and finally
adopted by the Ordnance Department.

In discussing the work one can very well start with the Offense
Section. This Section had two aims in view always, to develop methods
of making the gases used by the Germans more economically than they
were making them, and to develop better gases if possible. When we
entered the war, chlorine, phosgene and chloropicrin were the lethal
gases used, while bromoacetone and xylyl bromide were the lachrymators.
It was not a difficult matter to prepare these. But the introduction
of mustard gas in the summer of 1917 and of diphenylchloroarsine in
the autumn of the same year, not only made our chemists ponder over
a manufacturing method, but also so revised our notions of warfare
that the possibility of using other substances created the need for
extensive research. The development of bromobenzylcyanide by the French
likewise opened a new field among lachrymatory substances.

Colored rockets and smokes were developed for the Navy and Army.
The smoke box was also studied but the work was taken over by the
Pyrotechnic Section.

A large amount of pure inorganic research on arsine and arsenides,
fluorine, hydrofluoric acid and fluorides, cyanides, cyanogen sulfide
and nitrogen tetroxide was carried out, sometimes successfully and at
other times with little or no success.

The Analytical Section not only carried out all routine analyses but
developed methods for many new gases.

The Offense Section worked in very close contact with the Small Scale
Manufacturing Section (Chemical Production Section). Often it happened
that a method, apparently successful in the laboratory, was of no
value in the plant. Small scale plants were developed for mustard gas,
hydrocyanic acid, cyanogen chloride, arsenic trichloride, arsenic
trifluoride, magnesium arsenide, superpalite and bromobenzylcyanide.

The Chemical Defense Section, organized January, 1918, was occupied
with problems relating to protection, such as charcoal, soda-lime, and
special absorbents, eyepieces, smoke filters, efficiency of absorbents,
and special work with mustard gas.

Charcoal demanded extensive research. Raw materials required a
world-wide search, carbonizing methods had to be developed, and
impregnating agents were thoroughly studied. This story is told in
Chapter XIII.

Soda-lime was likewise a difficult problem. Starting with the British
formula, the influence of the various factors was studied and a balance
between a number of desirable qualities, absorptive activity, capacity,
hardness, resistance to abrasion, chemical stability, etc., obtained.
The final product consisted of a mixture of lime, cement, kieselguhr,
sodium permanganate and sodium hydroxide.

Equally valuable work was performed in the perfection of two carbon
monoxide absorbents for the Navy. The better of these consisted of a
mixture of suitably prepared oxides which acts catalytically under
certain conditions, and causes the carbon monoxide to react with the
oxygen of the air. Since there are color changes connected with the
iodine pentoxide reaction (the first absorbent) it has been possible
to develop this so as to serve as a very sensitive detector for the
presence of carbon monoxide in air.

While the question of smoke filters was so important that it occupied
the attention of several Sections, the Defense Section developed, as a
part of its work, a standard method of testing and comparing filters,
and did a great deal of work on the preparation of paper for this
purpose.

Various problems related to mustard gas were also studied. The question
of a protective ointment was solved as successfully as possible under
the circumstances, but was dropped when it appeared doubtful if under
battlefield conditions of concentration and length of exposure, any
ointment offered sufficient protection to pay for the trouble of
applying it. The removal of mustard gas from clothing was investigated,
especially by the accelerating effect of turkey red oil. Another phase
of the work concerned the destruction of mustard gas on the ground,
while a fourth phase related to the persistency of mustard (and other
gases) on the field of battle.

The Gas Mask Research Section concerned itself largely with developing
methods of testing canisters and with routine tests. When one
considers the number of gases studied experimentally, the large
number of experimental canisters developed, all of which were tested
against two or more gases, and further that the Section assisted in the
control of the production at Long Island City, it is seen that this
was no small job. In addition, the effect of various conditions, such
as temperature, humidity, ageing, size of particles, were studied in
their relation to the life of absorbents and canisters. Man tests and
mechanical tests will be discussed in a later chapter. Other studies
were concerned with weathering tests of gas mask fabrics, mustard gas
detector, and covering for dugout entrances (dugout blankets), which
were impregnated with a mixture of mineral and vegetable oils. In
studying the course of gases through a canister the “wave front” method
was of great value in detecting defects in canister design and filling.

The Pyrotechnic Section was composed of a number of units, each with
its own problem. The gas shell was studied, with special reference
to the stability of gases and toxic solids, both on storage and on
detonation. Extensive work was carried out on smoke screens—a Navy
funnel, an Army portable smoke apparatus, using silicon tetrachloride,
a grenade, a Livens, and various shell being developed for that
purpose. The smoke screen was adapted to the tank and the airplane as
well as to the funnel of a ship. Several types of incendiary bombs
and darts were perfected. The liquid fire gun was studied but the
results were never utilized because of the abandonment as useless of
that form of warfare. Various forms of signal lights, flares, rockets
and colored smokes were studied and in most cases specifications were
written. Extensive studies were also carried out on gas shell linings,
from which a lead and an enamel lining were evolved. Many physical
properties of war gases and their mixtures were determined.

The Dispersoid Section studied the production of smokes or mists from
various solid and liquid substances. Apparatus were developed to study
the concentration of smoke clouds and their rate of settling. The
efficiency of various filters and canisters was determined, and among
other things, a new smoke candle was perfected.

Mechanical research at first was related to design and construction of
a canister and mask, based on the English type. During the latter part
of 1917 the Tissot type of mask was studied and then turned over to
the Gas Defense Division. A Navy Head Mask and canister was perfected.
The horse mask was developed along the lines of the British type, and
also a dog mask of the same general nature. Horse boots were also
constructed, though they never were used at the front. Many Ordnance
and Pyrotechnic problems were also successfully completed, not the
least of which was a noiseless gas cylinder. This section developed the
first special poison gas suit, composed of an oilcloth suit, a mask and
helmet and a special canister.

The Manufacturing Development Section had general charge of the defense
problems, and really acted as an emergency section, filling in as
occasion demanded. They developed mustard gas clothing and a horse
mask. They constructed a hydrogen plant at Langley Field, assisted in
solving the difficulties relating to Batchite charcoal at Springfield,
Mass., and co-operated in the study of paper and felt as filtering
materials for smokes. Towards the close of the war the Section was
interested in the application of the gas mask to the industries.

The Physiological work is discussed under the Medical Division.

The Editorial Section received reports from all the other Sections,
from which a semi-monthly report was written, and distributed to
authorized representatives of the Army and Navy and to our Allies.
Reports were also received from abroad and the information thus
received was made available to the Research Division. As the number of
reports increased the work was collected together into monographs on
the various war gases, absorbents, smokes, etc. After the signing of
the armistice these were revised and increased in number, so that about
fifty were finally turned over to the Director of the Chemical Warfare
Service.


GAS DEFENSE DIVISION

The story of the Gas Defense Division is largely the story of the
gas mask. Colonel (then Mr.) Bradley Dewey was in charge of the
“first twenty thousand.” Soon after that work was undertaken, he was
commissioned Major in the Gas Defense Division of the Sanitary Corps
and was placed in charge of the entire manufacturing program. The work
of the Division included the development and manufacture as well as the
testing and inspection of gas masks, and other defense equipment. The
magnitude of the work is seen from the following record of production:
5,692,000 completed gas masks, 3,614,925 of which were produced at the
Long Island City Plant, while the remainder were assembled at the Hero
Manufacturing Company’s Plant at Philadelphia, 377,881 horse masks,
191,388 dugout blankets, 2,450 protective suits and 1,773 pairs of
gloves, 1,246 tons of protective ointment, 45,906 gas warning signals
(largely hand horns), 50,549 trench fans and many oxygen inhalators.

[Illustration: FIG. 5.—The Defective Gas Mask.

Successfully used by the Gas Defense Division to stimulate care in
every part of the operation of the manufacture of Gas Masks.]

The story of the “first twenty thousand” has already been told on page
43. That these masks were far from satisfactory is no reflection upon
the men who made them. Even with the standard design of the British as
a pattern, it was impossible to attain all the knowledge concerning gas
masks in two months. The experience gained in this struggle enabled
the Army to take up the manufacture of gas masks, in July, 1917, with
a more complete realization of the seriousness of the task. The masks
were not lost, either, for they were sent to the various camps as
training masks and served a very useful purpose.

The first order after this was for 1,100,000 masks, to be completed
within a year from date. For this production there was authorized
one major, two captains, and ten lieutenants. How little the problem
was understood is evident when we realize that in the end there were
12,000 employees in the Gas Defense Plant at Long Island City, N. Y.
The first attempts were to secure these through existing concerns.
The Hero Manufacturing Company of Philadelphia undertook the work and
carried on certain portions of it all through the War. Experience soon
showed, however, that because of the necessity for extreme care in
the manufacture and inspection of the mask, the ordinary commercial
organization was not adapted to carry on their manufacture on the scale
necessitated by the Army program. Consequently, on Nov. 21, 1917, the
Secretary of War authorized the establishment of a government operated
plant, and experienced officials were drawn from New York, Chicago,
Boston and other manufacturing centers to carry on the work. Buildings
in Long Island City, not far from the chemical plant (charcoal and soda
lime) at Astoria, were taken over by the officers of the Gas Defense
Service, until in July, 1918, five large buildings were occupied,
having a total floor space of 1,000,000 square feet (23 acres). The
organization grew from the original thirteen officers until it included
some 12,000 employees of whom about 8,500 were women. Because of the
care required in all the work, attempt was made to secure, as far as
possible, those who had relatives with the A. E. F. The thought was
that their personal interest in the work would result in greater care
in manufacture and inspection. The personnel was unique in that the
authority was apparently divided between civilian and military, but
there was no friction because of this. The efficiency of the entire
organization is shown by the fact that the masks manufactured at Long
Island City cost fifty cents less per mask than those manufactured
under contract.

The first actual shipment (overseas) of box respirators was made from
the Gas Defense Plant on March 4, 1918. From this date the production
increased by leaps and bounds. As mentioned above, between this date
and November 26, when the last mask was manufactured, 3,146,413 masks
of the box respirator type were passed through final inspection in the
plant. The greatest daily production, 43,926 masks, was reached on
October 26, 1918. The process of manufacture will be discussed under
the chapter on the Gas Mask.

During the last half of 1918 the Kops Tissot mask was manufactured.
This mask had been perfected during the months preceding August,
1918, when its manufacture was started. Considerable difficulty was
encountered in its production, but the first mask was completed on
September 14, and between that time and the Armistice, 189,603 masks of
this type had been manufactured.

Along with this manufacturing development went the building up of
an elaborate procurement force charged with the responsibility of
providing parts to be assembled at the Gas Defense Plant and at the
Hero Manufacturing Company. This Section faced a hard and intricate
task, but, though there were instances where the shortage of parts
temporarily caused a slowing down of production, these were remarkably
rare. Not only had the parts to be standardized, and specifications
written, but a field inspection force had to be trained in order that
the finished parts might be suitable for the final assembly plant.
The problem was further complicated by the fact that the design was
constantly changing, as improvement followed improvement. Officers,
trained in inspection in a day, were sent out to train inspectors in
the industrial centers.

In February, 1918, shortly before the German drive commenced,
requisitions were received for sample lots of oiled mittens and oiled
union suits as protection against mustard gas. These were prepared in
quantity and sent to the front, as was also a considerable amount of
chloride of lime for neutralizing the mustard gas in the field.

Another phase of the work consisted of the Field Testing Section, which
was organized to provide field testing conditions for the regular
product and for the development organization. Later there were added
a preliminary course of training for officers for overseas duty in
chemical warfare, the military training of the Gas Defense officers
located in and near New York and the training of boat crews engaged in
carrying offensive gas supplies. The Field Testing Section rendered
valuable service in pointing out weaknesses of designs as developments
took place and especially those uncomfortable features of the masks
which were apparent only through long wear. During the course of this
work the section built a complete trench system in the Pennsylvania
Railroad yards with an elaborate dugout, the equal of any of the famous
German quarters on the Western front.

The chapters on Charcoal, Soda-Lime and the Gas Mask must be read
in this connection to gain an idea of the work carried out by this
Division. It is summed up in the statement that American soldiers were
provided with equipment which neutralized the best effects of German
chemical knowledge as evidenced by the offensive methods and materials
employed.

The organization of the Gas Defense Division, as of Nov. 11, 1918, was
as follows:

    Colonel Bradley Dewey    Officer in Charge
    Lieut. Col. A. L. Besse  Asst. Officer in Charge
    Major M. L. Emerson      Administration Section
    Major H. P. Schuit       Comptrolling Section
    Mr. R. Skemp             Procurement Section
    Major C. R. Johnson      Technical Director
    Capt. K. Atterbury       Field Testing Section
    Major J. C. Woodruff     Chemical Manufacturing and Development
    Mr. R. R. Richardson     Manager, Gas Defense Plant
    Capt. H. P. Scott        Officer in Charge, Hero Manufacturing Co.
    Major L. W. Cottman      Engineering Branch
    Major T. L. Wheeler      Chemical Development
    Major I. W. Wilson       Astoria Branch
    Capt. W. E. Brophy       San Francisco Branch
    Lt. E. J. Noble          Cleveland Branch
    Lt. L. Merrill           Springfield Branch


EDGEWOOD ARSENAL

The Ordnance Department, in making plans for a shell filling plant,
thought to interest existing chemical firms in the manufacture of the
required toxic materials. As plans developed, however, difficulties
arose in carrying out this program. The manufacture of such material
at private plants necessitated its shipment to the filling plant at
Edgewood. The transportation of large quantities of highly toxic gases
seemed attended with great danger. The Director General of Railroads
ruled that all such shipments must be made by special train, a very
expensive method of transportation. Still more serious objections were
encountered in the attempt to enlist the co-operation of existing
firms. They recognized that the manufacture of such material would be
attended by very great danger; that the work would be limited to the
duration of the war; and that the processes involved, as well as the
plants necessary for carrying out their processes, would have little
post-war value. Moreover, such firms as had the personnel and equipment
were already over-worked. With a few exceptions (notably the American
Synthetic Color Company, the Oldbury Electro-Chemical Co., Zinsser &
Co., and the Dow Chemical Company) they were unwilling to undertake
work of this character on any terms whatever.

Early in December, 1917, therefore, it was decided to erect, on
the site of the shell filling plant, such chemical plants as would
be necessary to furnish the toxic materials required for filling
the shell. The Arsenal is situated in an isolated district, twenty
miles east of Baltimore, Maryland, on the Pennsylvania Railroad, and
comprises 3,400 acres. Since the main line of the Pennsylvania Railroad
runs on one side of the tract, while on another is the Bush River,
only a few miles from its mouth in Chesapeake Bay, the tract was
ideally situated for shipping. This site was referred to, at first, as
“Gunpowder Reservation,” but on May 4, 1918, the name was officially
changed to “Edgewood Arsenal.”

[Illustration: FIG. 6.—Edgewood Arsenal.

The upper view shows the site as it appeared Oct. 24, 1917. The lower
view shows the same as it appeared nine months later.]

Some idea of the extent of the work may be gained from the following
facts. On October 1, 1918, there were 233 officers, 6,948 enlisted men
and 3,066 civilians engaged in work at Edgewood. 86 cantonments were
built, accommodating about 8,500 men, while the five officers’ barracks
provided accommodations for 290. The completed hospital unit consisted
of 34 buildings, accommodating 420 patients under ordinary conditions.
The total number of buildings erected on the Arsenal grounds was 550.
14.8 miles of improved roads were built, and 21 miles of standard gauge
and 15 miles of narrow gauge railway. A system furnishing 9.5 million
gallons of salt water and another furnishing two millions of fresh
water daily were successfully installed. Large power plants were built
in connection with the shell filling plants and the chlorine plant.

Plants for phosgene, chloropicrin, mustard gas, chlorine and sulfur
chloride were built and placed in successful operation. Most of the raw
materials, with the exception of sulfur chloride, were obtained from
commercial firms. The other gases and manufactured materials used, such
as phosphorus, tin and silicon tetrachlorides, bromobenzylcyanide and
arsenic derivatives were supplied by various plants scattered through
the East and Middle West States.

The raw materials used by the Arsenal in 1918 were as follows:

    Salt               17,358,000 pounds
    Bleach             42,384,000   “
    Picric acid         3,718,000   “
    Alcohol             3,718,000   “
    Sulfur             24,912,000   “
    Sulfur chloride     6,624,000   “
    Bromine               238,000   “
    Benzyl chloride        26,000   “

The production of toxic materials and the amount shipped overseas in
bulk follow:

    -----------------------+-------------+-------------
                           | Production, | Shipped in
                           |   Pounds    | Bulk, Pounds
    -----------------------+-------------+-------------
    Chlorine:              |             |
      Liquid               |  5,446,000  | 2,976,000
      Gaseous              |  2,208,000  |
    Chloropicrin           |  5,552,000  | 3,806,000
    Phosgene               |  3,233,070  |   840,000
    Mustard gas            |  1,422,000  |   380,000
    Bromobenzyl cyanide    |     10,000  |
    White phosphorus       |  2,012,000  |   342,000
    Tin tetrachloride      |  2,012,000  |   212,000
    Titanium tetrachloride |    362,000  |
    -----------------------+-------------+-------------

For nearly a month previous to the signing of the Armistice, the
various plants at the Arsenal had shut down or were operated only to
an extent sufficient to maintain the machinery and equipment in good
working order, on account of the lack of shell into which to fill
the gas, so that the above figures do not at all represent maximum
productive capacity.

These plants will be described in the appropriate chapters.

The shell filling plant was really composed of several small
plants, each of which was made up of units radiating from a central
refrigeration plant which would serve all the units. Each unit could
then be fitted with machinery adapted for filling shell of a different
size, and for a particular gas. Moreover, an accident in one of the
units would in no way impair the working of the remainder.

The problem involved in the filling of a shell with toxic material
(which is always a liquid or a solid and never a gas under the
conditions in which it is loaded in the shell) is similar in a way
to that of filling bottles with carbonated water. In the development
of plans for the filling plant, many suggestions were obtained from
a study of the apparatus used in commercial bottling plants. It was
necessary to keep in mind not only the large number of shell to be
filled, but also the highly toxic character of the filling material to
be used. It was essential that the work of filling and closing the
shell should be done by machinery in so far as that was possible, and
that the operation should be carried out in a thoroughly ventilated
room or tunnel, arranged so that the machinery contained in the tunnel
could be operated from the outside. Special care was taken in closing
the shell, the closing being accomplished by motors actuated by
compressed air, which, in the closing process were driven until they
stalled. In this way a uniform closing torque was obtained. The final
results secured were admirable, as is evidenced by the fact, reported
by the Quartermaster Officer at Vincennes on November 15, 1918, that
not a single leaky shell had been found among the 200,000 shell
received up to that date.

[Illustration: FIG. 7.—A Typical Shell filling Plant at Edgewood
Arsenal.]

Details of the filling process will be found in the chapter on Phosgene.

Besides the ordinary gas filling plants (of which one was completed
and two were 80 per cent completed) there was a plant for stannic
chloride grenades, one for white phosphorus grenades, and one for smoke
shell also filled with phosphorus and a plant for filling incendiary
bombs.

Shell are designated by their diameter in inches or millimeters. The
approximate amount of toxic gas required for filling each type of shell
(10.5 per cent void) is as follows:

    ---------+-----------+-----------+-------------
    Shell    | Phosgene, | N. C.,[13] | Mustard Gas,
             |  Pounds   |  Pounds   |   Pounds
    ---------+-----------+-----------+-------------
    75 mm    |    1.32   |    1.75   |     1.35
    4.7 inch |    4.27   |    6.20   |     4.20
    155 mm   |   11.00   |   15.40   |    10.35
    8 inch   |   22.00   |   30.30   |    21.60
    Livens   |   30.00   |           |
    ---------+-----------+-----------+-------------

[Footnote 13: N.C. is a mixture of 80 per cent chloropicrin and 20 per
cent stannic chloride.]

The gas grenades held 0.446 pound of stannic chloride, and the smoke
grenades held 0.67 pound of white phosphorus.

The only type of shell filled was the 75 mm. variety, because either
the shell of the other sizes or the accompanying boosters (bursting
charges) were not available.

The work done by the filling plant is shown by the following figures,
representing the number of shell, grenades, etc.

             _75 mm. Shell_
    ------------------+---------+---------
                      | Filled  | Shipped
                      |         | Overseas
    ------------------+---------+---------
    Phosgene          |   2,009 |
    N. C.             | 427,771 | 300,000
    Mustard gas       | 155,025 | 150,000
    ------------------+---------+---------

              _Livens Drum_
    ------------------+---------+---------
    Phosgene          |  25,689 |  18,600
    ------------------+---------+---------

                _Grenades_
    ------------------+---------+---------
    White phosphorus  | 440,153 | 224,984
    Tin tetrachloride | 363,776 | 175,080
    ------------------+---------+---------

          _Incendiary Drop Bomb_
    ------------------+---------+---------
    Mark I.           |   542   |
    Mark II.          | 2,104   |
    ------------------+---------+---------

The total monthly capacity of the filling plants at the date of the
Armistice was as follows:

                         Pounds
    75 mm. shell       2,400,000
    4.7 inch shell       450,000
    155 mm. shell        540,000
    6 inch shell         180,000
    Gas grenade          750,000
    Smoke grenade        480,000
    Livens drum           30,000

One point relating to the casualties resulting from the work should
perhaps be mentioned here. The number of casualties should change the
mind of anyone who feels that men chose this work as being “safe”
instead of going to France. During the six months from June to December
there were 925 casualties, of which three were fatal, two being due to
phosgene and one to mustard gas. These were divided among the different
gases as follows:

    Mustard gas           674
    Stannic chloride       50
    Phosgene               50
    Chloropicrin           44
    Chlorine               62
    Other material         45

Of these 279 occurred during August, 197 during September and 293
during October. Since production stopped early in November, there were
only 14 during that month and three during December.

The Staff at Edgewood Arsenal at the signing of the Armistice was as
follows:

    Commanding Officer            Colonel Wm. H. Walker
                                { Lt. Colonel George Cahoon, Jr.
    Administrative Officers     { Lt. Col. Edward M. Ellicott
                                { Lt. Col. Wm. C. Gallowhur

                                { Lt. Col. Wm. McPherson
    In Charge of Outside Plants { Major Adrian Nagelvoort
                                { Major Charles R. Wraith
                                { Captain John D. Rue
    Shell Filling Plant           Lt. Col. Edwin M. Chance
    Chlorine Plant                Lt. Col. Charles Vaughn
    Chemical Plants               Major Dana J. Demorest
    Chemical Laboratory           Major William L. Evans

As the work of the Arsenal expanded it was necessary to manufacture
certain of the chemicals at outside plants. The men in charge of these
plants were:

    Bound Brook, N. J.            Lt. William R. Chappell
    Stamford, Conn.               Lt. V. E. Fishburn
    Hastings-on-Hudson, N. Y.     Major F. G. Zinnsser
    Niagara Falls, N. Y.          Major A. Nagelvoort
    Buffalo, N. Y.                Lt. A. W. Davison
    Kingsport, Tenn.              Lt. E. M. Hayden
    Charleston, W. Va.            Lt. M. R. Hoyt
    Midland, Mich.                Major M. G. Donk
    Croyland, Pa.                 Capt. A. S. Hulburt

After the Armistice, Edgewood Arsenal was selected as the logical home
of the Chemical Warfare Service, and all the outside activities of the
Service were gradually closed up and the physical property and files
moved to Edgewood. At first the command of the Arsenal was in the hands
of Lt. Col. Fries, but when he was appointed Chief of the Service,
Major E. J. Atkisson, who had so successfully commanded the First Gas
Regiment, A. E. F., was happily chosen his successor. At the present
time (July 1, 1921), the organization of Edgewood Arsenal is as follows:

    Commanding Officer            Major E. J. Atkisson
    Executive Officer             Major R. C. Ditto
    Technical Director            Dr. J. E. Mills
    Chemical Division             Mr. D. B. Bradner
    Mechanical Division           Mr. S. P. Johnson
    Plant Division                Capt. E. G. Thompson
    Chemical Warfare School       Major O. R. Meredith
    Property                      Major A. M. Heritage
    First Gas Regiment            Major C. W. Mason
    Mask Production Division      Lt. L. A. Elliott
    Medical Department            Major T. L. Gore
    Pathological Division         Lt. H. A. Kuhn
    Quartermaster Department      Capt. H. L. Hudson
    Finance Department            Capt. C. R. Insley


DEVELOPMENT DIVISION

The Development Division had its origin in the research laboratories
of the National Carbon Company and of the National Lamp Works of the
General Electric Company. Both of these companies knew charcoal, and
they were asked to produce a satisfactory absorbent charcoal. The
success of this undertaking will be seen in the chapter on Absorbents.
After a short time all the laboratory work was taken over by the
National Carbon Co., while the developmental work was assigned to
the National Lamp Works. When the final organization of the Chemical
Warfare Service took place, the National Carbon Laboratory became part
of the Research Division, while the National Lamp Works became the
Defense Section of the Development Division.

The Development Division may be considered as having been composed of
the following sections:

    1. Defense
    2. Offense
    3. Midland
    4. Willoughby
    5. Special Investigation.

The work of the Defense Section consisted of the development of a
charcoal suitable for use in gas masks, and its manufacture. While the
details will be given later, it may be mentioned here that three weeks
after the organization of the Section (April 28, 1917) the furnaces
of the National Carbon Company were turning out cedar charcoal, using
a straight distillation procedure. Cedar was selected from a large
variety of materials as giving the highest absorptive value against
chlorine. But phosgene and chloropicrin were also being used, and it
was found that the cedar charcoal was not effective against either.
Proceeding on a definite hypothesis, fifty materials were investigated
to find the charcoal with the highest density. Cocoanut hulls furnished
the raw material, which yielded the most active charcoal. By a
process of air activation a charcoal was obtained which possessed
high absorptive power for such gases as chloropicrin and phosgene.
Later this air process was changed to one in which steam is used;
the cocoanut shell charcoal activated with steam was given the name
“Dorsite.”

Complete apparatus for this air process was installed at the plant of
the Astoria Light, Heat & Power Company, Long Island City, and the
first charcoal was prepared during September, 1917. This was followed
by a large amount of experimental work, relating to the raw material,
the method of activation, and the type of furnace used. Because of the
shortage of cocoanut hulls, it later became necessary to use a mixture
of cocoanuts with cohune nuts, apricot and peach pits, cherry pits and
vegetable ivory. Another substitute for cocoanut charcoal was found
in a steam activated product from high grade anthracite coal, called
“Batchite.”

The Offense Section and the Midland Section were concerned with the
manufacture of mustard gas. This work was greatly delayed because
of the unsatisfactory nature of the so-called chlorohydrin process.
Another difficulty was the development of a satisfactory ethylene
furnace. Finally in February, 1918, Pope in England discovered the
sulfur chloride method of making mustard gas. At once all the energies
of the Research Division were concentrated on this process, and
in March steps were taken to put this process into production. An
experimental plant was established at Cleveland; no attempt was made
to manufacture mustard gas on a large scale, but the results obtained
in the experimental studies were immediately transmitted to the
manufacturing plants at Edgewood Arsenal, the Hastings-on-Hudson plant,
the National Aniline & Chemical Company (Buffalo) plant, and the Dow
Chemical Company (Midland) plant. The details of the work on mustard
gas will be given in a later chapter.

Special investigations were undertaken to develop a booster casing and
adapter for 75 mm. gas shell, and to duplicate the French process of
lining gas shell with glass.

The organization of the Development Division at the signing of the
Armistice was as follows:

    Colonel F. M. Dorsey          Chief of the Division
    Major L. J. Willien           Supt., Offense Section
    Capt. O. L. Barnebey          Supt., Defense Section
    Lt. Col. W. G. Wilcox         Supt., Experimental Station
    Capt. Duncan MacRae           Special Investigation Section
    Dr. A. W. Smith               Midland Section
    Capt. J. R. Duff              Administrative Section


PROVING DIVISION

The Proving Division had its origin in the decision to build an
Experimental Ground for gas warfare under the direction of the Trench
Warfare Section of the Ordnance Department. While this decision was
reached about September, 1917, actual work on the final location
(Lakehurst, N. J.) was not started until March 26, 1918, and the
construction work was not completed until August 1, 1918. However,
firing trials were started on April 25, 1918, and in all 82 were
carried out.

The Proving Division was created to do two things: To experiment
with gas shell before they reached the point where they could be
manufactured safely in large numbers for shipment overseas; and to
prove gas shell, presumably perfect and ready for shipment, to guard
against any mechanical inaccuracies in manufacture or filling. It
is evident that the second proposition is dependent upon the first.
Shell can not be proved to ascertain the effect of gases under various
conditions and concentrations until the mechanical details of the
shell itself, purely an Ordnance matter, have been standardized.
Unfortunately many of the tests carried out had to do with this very
question of testing Ordnance.

For field concentration work two complete and separate lines of
trenches were used and also several impact grounds. The trenches were
built to simulate the trenches actually used in warfare. Each line of
trench contained several concrete shell-proof dugouts and was also
equipped with shelves into which boxes could be placed for holding
the sample bottles. At intervals of one yard throughout the trenches
there were electrical connections available for electrical sampling
purposes. The various impact grounds were used for cloud gas attacks,
and experiments with mustard gas or in many cases for static trials.
The samples were collected by means of an automatic sampling apparatus.

The work of the Division consisted in the first instance of determining
the proper bursting charge. While a great deal of this work had been
carried out in Europe, American gas shell were enough different to
require that tests be carried out on them. The importance of this work
is obvious, since phosgene, a substance with a low boiling point, would
require a smaller bursting charge to open the shell and allow the
substance to vaporize than would mustard gas, where the bursting charge
must be not only sufficient to fragment the shell but also to scatter
the liquid so that it would be atomized over the largest possible area.
In the case of low boiling liquids it was necessary that the charge be
worked out very carefully as a difference of one or two grams would
seriously affect the concentration. Too small a charge would allow a
cup to be formed by the base of the shell which would carry some of the
liquid into the ground, while too great an amount of explosive tended
to throw the gas too high into the air.

After the bursting charge had been determined a large number of shell
were repeatedly fired into the trenches, wooded areas, rolling and
level ground, and the concentration of gas produced and the effect upon
animals placed within the area ascertained. From the results of these
experiments the Proving Division was able to furnish the artillery
with data regarding how many shell of given caliber should be used,
with corrections for ranges, wind velocities, temperatures, ground
conditions, etc. Trials were also held to determine how many high
explosive (H.E.) shell could be fired with gas shell on the same area
without unduly affecting the concentration. This was important, because
H.E. shell were useful in disguising gas bombardments. Gas shell can
usually be distinguished by the small detonation on bursting.

Experiments were performed to determine the decomposition of various
gases on detonation. The shell were fired at a large wooden screen and
burst on impact. Samples of gas were taken immediately and analyzed.

Co-operative tests were carried out with the Gas Defense Division to
determine the value of given masks under field conditions. Companies of
infantry, fully equipped for the field, would wear masks for hours at
a time digging trenches, cutting timber, drilling, etc., and imitating
in every way, as far as possible, actual field conditions. During
these activities tons of gas in cylinders were released in such a way
that the men were enveloped in a far higher concentration than would
probably ever be the case in actual battle. These tests gave valuable
data for criticizing gas mask construction.

Another line of activity consisted of a study of the persistency and
relative effectiveness of various samples of mustard gas, in which the
liquid was distributed uniformly upon the surface of grassy zones one
to three feet in width, which formed the periphery of circular areas 14
to 21 feet in diameter, the central part of each circle being occupied
by animals.

The work of the Proving Division was brought to an end (by the
Armistice) just at the time when it had reached its greatest
usefulness. Not only were the physical properties and personnel of the
Division developed to the maximum degree, but the production of gas
shell in this country for shipment to France had just reached the stage
where the Proving Ground could have been used to its fullest extent in
their proving.


TRAINING DIVISION

From the standpoint of the man at the front the Training Division
is one of the most important. To him gas warfare is an ever present
titanic struggle between poisonous vapors that kill on one side, and
the gas mask and a knowledge of how and when to wear it, on the other.
Because of this it is rather surprising that we did not hear more about
this branch of the Service. It did exist, however, and credit must be
given to those camp gas officers who remained in the United States
performing an inconspicuous and arduous duty in the face of many local
obstacles.

[Illustration: FIG. 8.]

The Field Training Division of the Gas Defense Service in the United
States was organized in September, 1917, and consisted of Major J. H.
Walton and 45 first lieutenants, all chemists. These men were given a
three months’ military training at the American University. The arrival
of Major (now Colonel) Auld during this time was very helpful, as he
was able to give the Section first-hand knowledge. About 12 of the 45
men wore sent to France, while the remainder, together with British Gas
Officers, were assigned to various Divisions still in training. There
was little idea at that time as to what constituted real gas training.
No one knew how much gas training would be received in France, and
since little was often received due to lack of time, many men went
into action with no idea of what this training really meant. Moreover,
an order that the gas officers should not go to France with their
Divisions had, as was only natural, a discouraging effect upon the men
and upon gas training and discipline generally.

In January, 1918, the gas officers were transferred to the Engineers,
and designated as the 473d Engineers. Later an Army Gas School was
established at Camp Humphreys. Because of the rapidly changing
personnel, owing to overseas assignments, the policy was adopted of
sending specialized gas officers only to Divisional Camps and the
larger training centers. The need of a larger unit and increased
authority was recognized by all intimately associated with the work,
but little was accomplished until the transfer to the Chemical Warfare
Service. Upon the appointment of Brigadier General H. C. Newcomer as
Assistant Director of the Chemical Warfare Service, he was placed in
charge of all military affairs of the Service, and the administrative
officers of the Training Section became his “military assistants.” A
few weeks later the Training Section of the Administration Division,
C.W.S. was formed.

At this time new duties fell to the lot of this Section, among the more
important being:

    (1) The organization of gas troops and casual
        detachments for overseas duty;

    (2) The establishment of a Chemical Warfare Training
        Camp;

    (3) The procurement and training of officers for
        overseas duty.

For this purpose a training camp was established near the Proving
Ground (Camp Kendrick) to hold 1300 officers and men. Line officers
were sent from the larger camps for training, the best of whom might
later be transferred to the Chemical Warfare Service for duty as Gas
Officers.

The work of the Section eventually grew to such proportions that it was
recognized as the Training Division of the Chemical Warfare Service. It
differed from other Divisions in that all administrative routine was
carried on through the offices of the Director, and with the assistance
and co-operation of its various Sections.

Because of the formation of the Chemical Warfare Service and the
apparent need for officers, the office was soon flooded with
applications for commissions. These were carefully examined and the
men were sent first, by courtesy of the Chief of Engineers, to Camp
Humphreys for a month’s course of military training. At the end of this
period they were sent to Camp Kendrick as students of the Army Gas
School. Toward the last of October all the officers and enlisted men
were transferred to Camp Kendrick where an Officers’ Training Battalion
was organized.

It is obvious that the gas training of troops was the most responsible
duty of the Training Division. There was constantly in mind an ideal
of supervised and standardized training for all troops in the United
States, and the Division, at the time of the Armistice, for the first
time found itself with a nearly adequate corps of officers through whom
this ideal could be realized.


MEDICAL DIVISION

Dr. Yandell Henderson of Yale University was the logical man to
inaugurate the medical work of the Bureau of Mines, because of his
experience with oxygen rescue apparatus. A member of the first
committee of the Bureau, he secured, in July, 1917, an appropriation
for the study of toxic gases at Yale. This was in charge of Doctors
Underhill, therapy; Marshall, pharmacology; and Winternitz, pathology.
When the American University Station was opened Marshall was given
charge of the pharmacology. About the same time a factory protection
unit was organized under the direction of Doctors Bradley, Eyster
and Loevenhart. At first this committee reported to the Ordnance
Department, but later the work was transferred to the Gas Defense
Service.

In December, 1917, the Medical Advisory Board was organized. This
included all the men who were carrying on experimental work of a
medical nature. This board had as its object the correlation of
all medical work; new work was outlined and attempts were made to
secure the co-operation of scientific men throughout the country.
The following groups of workers assisted in this effort: At Yale,
Underhill studied therapy, turning his animals over to Winternitz
for pathological study. Henderson was specially interested in the
physiology of aviation. At the American University Marshall carried
on pharmacological research, specially as regards mustard gas, the
toxicology being covered by Loevenhart. A pathological laboratory
was also started, under Winternitz, where many valuable studies
were made.[14] At Cleveland Sollmann was busy with mustard gas and
protective agents. Pearce, working in co-operation with Dr. Geer of
the Goodrich Rubber Company, perfected the Goodrich Lakeside Mask. His
study was very valuable as concerning the physiology of the gas mask.
At Ann Arbor Warthin and Weller[15] were studying the physiology and
pathology of mustard gas. Wells, Amberg, Helmholz and Austin of the
Otho Sprague Memorial Institute were interested in protective clothing,
while at Madison, Eyster, Loevenhart and Meek were engaged in a study
of the chronic effect of long exposures to low concentrations, and
later expanded their work to protective ointments and certain problems
in pathology.

[Footnote 14: See the Pathology of War Gas Poisoning, 1920, Yale Press.]

[Footnote 15: See Medical Aspects of Mustard Gas Poisoning, 1919, C. O.
Mosby Co.]

In the spring of 1918 many of these men were commissioned into the Gas
Defense Service of the Sanitary Corps, and were later transferred to
the Chemical Warfare Service as the Medical Division, with Colonel W.
J. Lyster, M.C., in charge.

One of the most important functions of this Division was the daily
testing of a large number of compounds for toxicity, lachrymatory or
vesicant properties. The accuracy of these tests might and probably did
save a large amount of unnecessary experimental work on the part of the
Research Division. These tests are described in a later chapter.

Very interesting and likewise valuable was the study of mustard gas by
Marshall, Lynch and Smith. They were able to work out the mechanism of
its action and the varying degrees of susceptibility in individuals
(see page 171).

Another interesting point was the fact that in the case of certain
gases there is a cumulative effect. With superpalite and mustard gas
the lethal concentration (that concentration which is fatal after a
given exposure) is lower on longer exposures. On the other hand there
is no cumulative effect with hydrocyanic acid. Whether the action is
cumulative or not depends on the rate at which the system destroys or
eliminates the poison.


LIAISON OFFICERS

This chapter should not be closed without reference to the Liaison
Service that was established between the United States and her Allies,
especially England.

During the early days no one in the States was familiar with the
details of gas warfare. At the request of the Medical Corps, upon the
urgent representations of the Gas Service, A.E.F., Captain (now Major)
H. W. Dudley was sent to this country (Sept., 1917) to assist in the
development and manufacture of gas masks. For some time he was the
Court of Appeal on nearly all technical points regarding matters of
defense. Dudley’s continual insistence on the need for maintaining the
highest possible standard of factory inspection was one of the factors
resulting in the excellent construction of the American Mask. In March,
1918, Lieut. Col. Dewey and Captain Dudley made a trip to England
and France, during which the idea of a liaison between the defense
organizations of the two countries originated. Dudley was transferred
to the Engineers, promoted and placed in charge of the Liaison service.
While the time until the Armistice was too short to really test the
idea, enough was accomplished to show the extreme desirability of some
such arrangement.

Probably the best known liaison officer from the British was Colonel
S. J. M. Auld, also sent upon the urgent representations of the Gas
Service, A.E.F. He arrived in this country about the middle of October,
1917, in charge of 28 officers and 28 non-commissioned officers, who
were to act as advisers in training and many other military subjects
besides gas warfare. Since Auld had had personal experience with gas
warfare as then practiced at the front, his advice was welcomed most
heartily by all the different branches of the Army then handling gas
warfare. On questions of general policy Auld was practically the sole
foreign adviser. The matter of gas training was transferred from the
Medical Corps to the Engineers, and was greatly assisted by four
pamphlets on Gas Warfare issued by the War College, which were prepared
by Major Auld with the assistance of Captain Walton and Lieut. Bohnson.
Later Auld gave the American public a very clear idea of gas warfare
in his series of articles appearing in the Saturday Evening Post, and
re-written as “Gas and Flame.”

Major H. R. LeSueur, who was at Porton previous to his arrival in this
country in December, 1917, rendered valuable aid in establishing the
Experimental Proving Ground and in its later operations.

Towards the close of the war the British War Office had drawn up a
scheme for a Gas Mission, which was to correlate all the gas activities
of England and America. This was never carried through because of the
signing of the Armistice.

The French representatives, M. Grignard, Capt. Hanker and Lt. Engel
furnished valuable information as to French methods, but they were
handicapped by the fact that French manufacturers did not disclose
their trade secrets even to their own Government.

About August, 1918, Lieut. Col. James F. Norris opened an office in
London. His duties were to establish cordial and intimate relations not
only with the various agencies of the British Government which were
connected with gas warfare, but also with the various laboratories
where experiments were being conducted, that important changes might be
transmitted to America with the least possible delay. The English made
Colonel Norris a member of the British Chemical Warfare Committee. Here
again the signing of the Armistice prevented a full realization of the
importance of this work.




CHAPTER IV

THE CHEMICAL WARFARE SERVICE IN FRANCE


It is worth noting here that the Chemical Warfare Service was organized
as a separate service in the American Expeditionary Forces nearly ten
months before it was organized in the United States, and that the
organization in the United States as heretofore described was patterned
closely on that found so successful in France.

Very soon after the United States declared war against the Central
Powers, a commission was sent abroad to study the various phases of
warfare as carried on by the Allies, and as far as possible by the
enemy. Certain members of this commission gave attention to chemical
warfare. One of those who did this was Professor Hulett of Princeton
University. He, with certain General Staff officers, gathered what
information they could in England and France concerning the gases
used and methods of manufacturing them, and to a very slight extent
the methods of projecting those gases upon the enemy. Some attention
was paid to gas masks, but there being nobody on the General Staff,
or anywhere else in the Regular Army, whose duty it was to look out
particularly for chemical warfare materials, these studies produced no
results.

As has already been stated, the Medical Department started the
manufacture of masks, and the Bureau of Mines, under the leadership
of the Director, Mr. Manning, began studies upon poisonous gases and
the methods of manufacturing them just before or shortly after war was
declared.

Nevertheless, although American troops left for France in May, 1917,
it was not until the end of August—the 17th to be exact—that definite
action was taken toward establishing a Chemical Warfare Service, or,
as it was then known, a Gas Service in the American Expeditionary
Forces. On that date a cablegram was sent to the United States to the
effect that it was desired to make Lieut. Col. Amos A. Fries, Corps of
Engineers, Chief of the Gas Service, and requesting that no assignments
to the regiment of gas troops authorized in the United States be made
which would conflict with this appointment. On August 22d, Lieut. Col.
Fries entered upon his duties as Chief of the Gas Service.

There were then in France about 30 miles from the German lines, some
12,000 American troops without any gas masks or training whatever in
Chemical Warfare. Immediate steps were taken to teach the wearing of
the masks, and English and French gas masks were obtained for them at
the earliest possible moment. At the same time efforts were made to
obtain officer personnel for the C. W. S., and to have sent to France
a laboratory for making such emergency researches, experiments, and
testing as might become necessary. From that time to the end of the war
the C. W. S. continued to develop on broad lines covering research,
development, and manufacture; the filling of shell and other containers
with poisonous gases, smoke and incendiary materials; the purchase
of gas masks and other protective devices, as well as the handling
and supply of these materials in the field; the training of the Army
in chemical warfare methods, both in offense and defense; and the
organization, equipment and operation of special gas troops.

This gave an ideal organization whereby research was linked with the
closest possible ties to the firing line, and where the necessities
of the firing line were brought home to the supply and manufacturing
branches and to the development and research elements of the Service
instantly and with a force that could not have been obtained in any
other manner. The success of the C. W. S. in the field and at home was
due to this complete organization. To the Commander-in-Chief, General
Pershing, is due the credit for authorizing this organization and for
backing it up whenever occasion demanded. Other details of this work
will be considered under the following heads: Administrative; Training;
Chemical Warfare Troops; Supply; Technical; Intelligence; and Medical.


ADMINISTRATIVE DUTIES

The duties of administration covered those necessary for a general
control of research, of supply, of training, and the operation of
special gas troops. At first the Chief of the Gas Service comprised the
whole of the Service since he was without personnel, material, rules,
regulations, or anything else of a chemical warfare nature.

The experience in getting together this organization should be
sufficient to insure that the United States will never place on any
other man’s shoulders the burden of organizing a new and powerful
service in the midst of war, 4,000 miles from home, without precedent,
material, or anything else on which to base action. It is true the
Americans had available the experience of the English and the French,
and it should be said to the credit of both of these nations that
they gave of their experience, their time, and their material with
the greatest freedom and willingness, but just as Americans are
Americans and were Americans in 1917, just so the methods of the French
and English or of the enemy were not entirely suitable to American
conditions.

If there is any one thing needed in the training of U. S. Army leaders
of today and for the future, it is vision—vision that can foresee the
size of a conflict and make preparations accordingly. We do not mean
vision that will order, as happened in some cases, ten times as much
material as could possibly be used by even 5,000,000 troops, but the
sort of vision that could foresee in the fall of 1917 that 2,000,000
men might be needed in France and then make preparations to get
materials there for those troops by the time they arrived.

In order to cover the early formative period of the C. W. S. in France
and to show some of the difficulties encountered, the following running
account is given of some of the early happenings without regard to the
subdivisions under which they might properly be considered.

=Assignment of Chief of the Gas Service.= Sailing from the United
States on the 23d of July, 1917, Fries arrived in Paris on the morning
of August 14, 1917, and was immediately assigned the task of organizing
a highway service for the American Expeditionary Forces. Five days
later and before the highway order was issued, he was asked what he
would think if his orders were changed so as to make him Chief of the
newly proposed Gas Service. Being given one night to think it over he
told the General Staff he would undertake the work. The road work was
immediately closed up and on the 22d of August the organization of a
Gas Service was actively started.

At that time some information concerning gases and gas troops had been
gathered by Colonel Barber of the General Staff. Likewise, Colonel
(later Brigadier General) Hugh A. Drum had made a rough draft of
an order accompanied by a diagram for the establishment of the Gas
Service. This information was turned over to Fries who was told to
complete the draft of the order, together with an organization chart,
for the action of the Commander-in-Chief. After one and a half days
had been put on this work the draft and chart were considered in good
enough shape to submit to General Pershing, Commander-in-Chief.

=First Trip to British Gas Headquarters.= Noting that the proposed
organization provided for the handling of 4-inch Stokes’ mortars by
gas troops, General Pershing asked why this work could not be done
by regular trench mortar companies. He was told that gas operations
were too technical and dangerous to be intrusted to any but especially
trained troops, and that, furthermore, it was understood that 4-inch
Stokes’ mortars were used only by the British troops. General Pershing
said, “You had better beat it to the British Gas Headquarters in the
field and settle definitely that and certain other minor points.”
Fries told him he was only too glad to do this, and, having completed
preparations, left on the morning of August 25th with Colonel Church
and Captain Boothby, both of the Medical Department, for St. Omer,
Headquarters of the British Gas Service in the Field.

Colonel Church of the Medical Department had been in France nearly
one and a half years prior to the entry of the United States into the
war, and had taken sufficient interest in Gas Warfare to collect
considerable information and a number of documents from French sources
bearing on the defensive side of the subject. Captain Boothby had done
the same with the British, including a course in a British Gas Defense
School. On this trip they took up the defensive side with the British,
while Fries took up the offensive side of the Service. The latter
included gases used, gas troops, and ammunition and guns used in Gas
Warfare by the Artillery and other branches of the Service. The trip
included a brief visit to the headquarters of the First British Army in
the vicinity of Lens, where the British Gas Service had a large depot
of offensive gas material.

=Order Forming Service.= Returning on the 28th of August the order,
together with a chart organizing the Service, was completed and
submitted to the General Staff. This was published as G. O. 31,
September 3, 1917. As a result of a study of the information submitted
by Colonel Barber and General Drum, together with his own observations
of British organization and work, Fries decided it was advisable to
make the Service cover as complete a scope as possible and to make
the order very general, leaving details to be worked out as time and
experience permitted. This proved to be a very wise decision, because
the entire absence of gas knowledge among Americans either in France
or the United States made it necessary to build from the bottom up
and do it rapidly. At that time, and at all times since, it was found
utterly impossible to separate the defensive side from the offensive
side. Indeed, many of the worst troubles of the British with their Gas
Service throughout nearly the whole war arose from such a division of
duties in their Service. Thus, the development of masks must be kept
parallel with the development of gases and methods of discharging
them. Otherwise a new gas invented may penetrate existing masks and
preparations be carried far towards using it before the development of
masks are undertaken to care for the new gas. Obviously a gas which our
own masks will not take care of cannot be safely used by our own troops
until new masks are developed to protect against it.

=American and British Masks.= Just prior to Fries’s assignment as
Chief of the Gas Service twenty thousand American-made masks or box
respirators were received from the United States. Through the energy
of Captain Boothby several of these had been sent at once to the
British for test. The test showed that the granules in the canisters
were entirely too soft, the charcoal of poor quality, and more than
all else, the fabric of the face piece was so pervious to gases that
chloropicrin became unbearable to the eyes in less than a minute
under the standard test used by the British. A cable containing this
information had been framed and sent to the United States just prior to
Fries’s appointment as Chief of the Service.

August 23d, the day after Fries took charge, it was decided to adopt
the British mask or box respirator as the principal mask and the French
M-2 as an emergency, both to be carried by the soldier, the French M-2,
however, to be used only when the British mask became lost or unfit
for use. A requisition for one hundred thousand of each was at once
submitted and very shortly approved by the General Staff.

=Getting Gas Supplies.= It should be stated here that inasmuch as
no Gas Service had been organized in the United States, no money
appropriation had been made for it, thereby making it necessary for
the Gas Service to obtain all its supplies through other departments
ordinarily handling the same or similar materials. Thus defensive
supplies were obtained through the Medical Department and offensive
supplies through the Ordnance Department, while other miscellaneous
equipment was obtained through the Engineer Department, the
Quartermaster Department, or the Signal Corps. This procedure proved
exceedingly embarrassing, cumbersome and inefficient. To begin with it
was necessary to get some agreement between the departments as to what
each would supply. This was very difficult, resulting in delays and
consumption of time which was urgently needed on other work.

Not only was there trouble in getting orders accepted and started on
the way but following them up became practically impossible. None of
the Departments furnishing the materials were especially interested in
them nor in many instances did they realize the vital nature of them.
Accordingly in order to get any action it was necessary to continually
follow up all orders and doing this through another department created
friction and misunderstanding. Officers of these departments took
the attitude that the whole question of obtaining supplies should be
left to them, once the requisition was turned in. This could not be
done. The Chief of the Gas Service was absolutely responsible for gas
supplies, and he fully realized that no excuses would be accepted,
no matter who stood in the way. It was necessary to get action.
Finally the matter was settled, some six months after the Service was
organized, by giving the Chemical Warfare Service the right of direct
purchase.

=Purchase of Offensive Gas Supplies.= Realizing the difficulty that
would probably be encountered in getting supplies at all times from
the British and French, two requisitions for offensive gas supplies to
be purchased from the British were submitted on September 8th and 10th
respectively. It would seem proper to state here that investigation
showed the British gas organization to be far superior to the French.
Indeed, the latter practically had no organization.

Consequently it was determined to purchase complete equipment for gas
troops and for the defensive side of the service from the British and
to make no attempt to produce new materials, methods or equipment
until ample supplies of the standard equipment of the British were
at hand or in process of manufacture or delivery. This was another
exceedingly wise conclusion. No supplies of any kind were received from
the United States for the next eight months, and then only masks and
certain defensive supplies. Indeed, no cylinders, mortars, projectors
or artillery shell containing gas were received from the United States
until just before the Armistice, though gas had been available in the
United States for months in large quantities, over 3,600 tons having
been shipped in one ton containers to the English and French. The
Ordnance material was what was lacking.

=Obtaining Personnel.= On September. 8, Colonel R. W. Crawford was
assigned to duty with the Gas Service. This matter of obtaining
personnel became immediately, and continued for almost a year to be,
one of the most serious difficulties facing the new Gas Service. The
troubles here again were the same as those in respect to supplies. None
of the old departments were especially interested in gas and hence none
of them desired to let good officers be transferred.

Officers were scarce in the early days in France in every department
of the Service, consequently a new department with no organization in
the United States and no precedents or opportunities for promotion made
the obtaining of officers almost a matter of impossibility. Further
than this, while the Engineer Department was at first supposed to
furnish most of the officer personnel, it failed to do so, apparently
looking upon the Gas Service as an unimportant matter when compared
with the regular work of the Engineers. It was necessary to make
direct application to the Chief of Staff to obtain Colonel Crawford
and shortly thereafter to cable directly to the United States for
officers. A year later enough officers were obtained but only after the
organization of a separate Service in the United States.

=Supplies for Gas Troops.= Colonel Crawford was at once put in Charge
of all supplies for the Gas Service, including the location and
construction of separate depots for that Service. Prior to this the
General Staff had decided to have chemical supplies stored in depots
separate from those of other supplies on account of the poisonous
nature of the gases which might prove very annoying if leakage occurred
near any other class of supplies. Colonel Crawford took hold of this
work with zeal and energy and so conducted it as to relieve the Chief
of the Gas Service of all anxiety in that matter. As before stated,
on the 10th of September a requisition for a very large quantity
of offensive supplies for gas troops was submitted to the General
Staff for approval. Inasmuch as this involved approximately 50,000
gas cylinders, 50,000 Liven’s drums, with at least 20,000 Liven’s
projectors and a large number of Stokes’ mortars and bombs, there was
considerable difficulty in getting it approved. Finally Colonel Malone
of the Training Section, who took an active interest in the Chemical
Warfare Service, got it approved. Then began the difficulty of getting
the order placed and of trying to expedite the filling of the order on
time. These difficulties were never overcome until after the entire
purchase of supplies was, as previously related, taken care of by the
Gas Service.

=First Inter-allied Gas Conference.= The first inter-allied gas
conference was held in Paris on September 16th, and consisted of
American, British, French, Italian, and Belgian delegates. The
conference busied itself mainly with questions of the medical treatment
of gassed cases and of defense against gas.

=Mustard Gas.= The principal topic under consideration at this
conference was the effects of the new mustard gas first used at Ypres
against the British on the nights of the 11th and 12th of July, 1917.
The British suffered nearly 20,000 casualties from this gas during the
first six weeks of its use, and were so worried over it that the start
of the attacks carried out later in the fall of 1917 against Ypres were
delayed several days. The casualties were particularly heavy because
the smell of the gas was entirely new and not unpleasant and because
of the delayed action of the gas, whereby men got no indication of its
seriousness until 4 to 8 hours after exposure. For these reasons men
simply took shelter from the bombardment without putting on masks or
taking other precautions. As a result of the Paris conference a long
cable was sent to the United States asking among other things that
immediate report be made on the possibilities of producing ethylene
chlorhydrin, one of the essentials in the manufacture of mustard gas by
the only method then known.

Within two weeks after this conference, there occurred an incident
which illustrates the very great danger in taking the views of any one
man unless certain that he is in a position to be posted on all sides
of the question under discussion. A high British official was asked
what he had heard in regard to the new mustard gas, and what and how it
was considered. He said with emphasis that the British had no further
fear of it since they had learned what it was and how to take care of
themselves and that it had ceased to be any longer a problem with them.

Fries, knowing what he did, was convinced that this did not represent
the attitude of the British authorities who knew what the gas was
doing, and the statement was not allowed to influence the American Gas
Service in the least. This was a very fortunate thing as events later
proved. It should also be added that a quite similar report was made by
a French officer in regard to mustard gas some time in the month of
October. The French officer had more reason for his attitude than the
British officer as up to that time mustard gas had not been largely
used against the French. However, both cases simply emphasize the
danger of accepting the views of any man who has seen but one angle of
a problem so complicated as gas in war.


TRAINING

=Training in Gas Defense.= In the latter part of October seventeen
young engineer officers, who had just arrived in France, were assigned
to the Gas Service and were promptly sent to British Gas Schools for
training in mask inspection, salvage and repair and in training men
to wear masks and take other necessary precautions against gas in the
field. It was also necessary at this time to establish gas training in
the First Division, and Captain Boothby was assigned to that work.

[Illustration: FIG. 9.—Destroying Mustard Gas on the Battle Field.]

It is important to note that the Gas Service had to begin operations
immediately upon its organization although it had almost no facilities
of any kind to work with. At one and the same time it was necessary
to decide upon the kinds of masks to be used and then to obtain them;
to decide upon methods of training troops in gas defense and start at
once to do it; to decide upon gases to be used and manufactured in the
United States and then obtain and send the necessary data and finally
to decide what weapons gas troops were to use and to purchase those
weapons, since none of them existed in the United States. Worse still
no one in the United States was taking any interest in them.

=New Mask.= About November 1, Major Karl Connell of the Medical
Department, National Guard of New York, reported for duty in response
to a cablegram that had been sent asking for him by name. It was
intended to send him to a British School to learn the art of teaching
gas defense. However, learning after a short talk with him that he had
been interested in making masks for administering anæsthesia, there
was at once turned over to him samples of all the masks in use by both
the Allies and the Germans, with a view to getting his ideas for a new
mask. Within two or three hours he suggested a new mask having a metal
face piece with sponge rubber against the face and with a canister to
be carried on the back of the head.

At that early date it was realized that a new mask must be invented
which would be far more comfortable and give better vision than the
British respirators adopted for use. Connell, thirty-six hours after
reporting, had so far developed his idea that he was sent to Paris to
make the first model, which he succeeded in doing in about three weeks.
This first mask was good enough to risk testing in a high concentration
of chlorine and while it leaked to some extent it indicated that the
idea was sound. The problem then was to perfect the mask and determine
how it could be produced commercially on the large scale necessary to
equip an army.

Since the British at this time and practically throughout the war were
much ahead of the French in all phases of gas warfare, Connell was
sent to London. There he succeeded in getting additional models in
such shape that one of them was sent to the United States during the
first few days of January, 1918. Connell’s work and experiments were
continued so successfully that after a model had been submitted to the
General Staff, as well as to General Pershing himself, one thousand
were ordered to be made early in May with a view to an extensive field
test preparatory to their adoption for general use in the United States
Army.

In this connection, during November, 1917, a letter was written to the
United States stating that while the Gas Service in France insisted
on the manufacture of British respirators exactly as the British
were making them, they desired to have experiments pushed on a more
comfortable mask to meet the future needs of the Army.

The following four principles were set down in that letter: (_a_)
That the mask must give protection and that experience had shown that
suitable protection could only be obtained by drawing the air through a
box filled with chemicals and charcoal. (_b_) That there must be clear
vision and that experience to date indicated that the Tissot method of
bringing the inspired air over the eyepieces was by far the best, (_c_)
That the mask must be as comfortable as compatible with reasonable
protection, and that this meant the mouthpiece and noseclip must be
omitted. (_d_) That the mask must be as nearly fool proof as it could
be made. That is, it should be of quick and accurate adjustment, in the
dark or in the trenches, and be difficult to disarrange or injure once
in position.

=Gas Training and Battle of Picardy Plains.= On March 21, 1918, as is
known to everyone, the Germans began their great drive from Cambrai
across the Picardy Plains to Amiens. While the battle was expected
it came as a complete surprise so far as the tactics used, and the
extent and force of the attack, were concerned. Lieutenant Colonel
G. N. Lewis, who had been sent about March 1 to British Gas Schools,
and had been assigned to one of the schools run by the Canadians, was
thus just on the edge of the attack. This gave him an opportunity to
actually observe some of that attack and to learn from eye-witnesses
a great deal more. The school, of course, was abandoned hurriedly and
the students ordered back to their stations. Lewis submitted two brief
reports covering facts bearing on the use of gas and smoke by the
Germans. These reports exhibited such a grasp of gas and smoke battle
tactics that he was immediately ordered to headquarters as assistant on
the Defense side of gas work, that is, on training in gas defense. Up
to that time no one had been able to organize the Defensive side of gas
work in the way it was felt it must be organized if it were to prove
a thorough success. A month later he was put at the head of the Gas
Defense Section, and in two months he had put the Defense Division on a
sound basis. He was then ordered to the United States to help organize
Gas Defense Training there.

[Illustration: FIG. 10.—Close Burst of a Gas Shell. The 6th Marines in
the Sommediene Sector near Verdun, April 30, 1918.]

=Cabled Report on Picardy Battle.= Based partly on Colonel Lewis’s
written and oral reports, and also on information contained in
Intelligence dispatches and the newspapers, a cablegram of more than
300 words was drafted reciting the main features of the battle so far
as they pertained to the use of gas. This cablegram ended with the
statement that “the above illustrates the tremendous importance of
comfort in a mask” and that “the future mask must omit the mouthpiece
and noseclip.”

=Keeping the General Staff Informed of Work.= In the early part of
May, 1918, the Americans arrived in the vicinity of Montdidier, south
of Amiens, on the most threatened point of the western front. It was
on May 18, 1918, that the Americans attacked, took, and held against
several counter-attacks the town of Cantigny. Shortly afterward they
were very heavily shelled with mustard gas and suffered in one night
nearly 900 casualties. Investigation showed that these casualties were
due to a number of causes more or less usual, but also to the fact that
the men had to wear the mask 12 to 15 hours if they were to escape
being gassed. Such long wearing of the British mask with its mouthpiece
and noseclip is practically an impossibility and scores became gassed
simply through exhaustion and inability to wear the mask.

An inspector from General Headquarters in reporting on supplies and
equipment in the First Division, stated that one of the most urgent
needs was a more comfortable mask. The First Division suggested a mask
on the principles of the new French mask which was then becoming known
and which omitted the mouthpiece and noseclip. The efforts of the
American Gas Service in France to perfect a mask without a mouthpiece
and noseclip were so well known and so much appreciated that they did
not even call upon the Gas Service for remark. The assistant to the
Chief of Staff who drew up the memorandum to the Chief simply said the
matter was being attended to by the Gas Service. This illustrates the
value of keeping the General Staff thoroughly informed of what is being
done to meet the needs of the troops on the firing line.

Then, as always, it was urged that a reasonably good mask was far more
desirable than the delay necessary to get a more perfect one. Based on
these experiences with mask development, the authors are convinced that
the whole tendency of workers in general, in laboratories far from the
front, is to over-estimate the value of perfect protection based on
laboratory standards. It is difficult for laboratory workers to realize
that battle conditions always require a compromise between perfection
and getting something in time for the battle. It was early evident to
the Gas Service in France that we were losing, and would continue to
lose, vastly more men through removal of masks of the British type, due
to discomfort and exhaustion, than we would from a more comfortable
but less perfect mask. In other words when protection becomes so much
of a burden that the average man cannot or will not stand it, it is
high time to find out what men will stand, and then supply it even at
the expense of occasional casualties. Protection in battle is always
relative. The only perfect protection is to stay at home on the farm.
The man who cannot balance protection against legitimate risks has no
business passing on arms, equipment or tactics to be used at the Front.

As early as September, 1917, gas training was begun in the First
Division at Condrecourt. This training school became the First Corps
School. Later a school was established at Langres known as the Army
Gas School while two others known as the Second and Third Corps Gas
Schools were established elsewhere. The first program of training for
troops in France provided for a total period of three months. Of this,
two days were allowed the Gas Service. Later this was reduced to six
hours, notwithstanding a vigorous protest by the Gas Service. However,
following the first gas attacks against the Americans with German
projectors in March, 1918, followed a little later by extensive attacks
with mustard gas, the A. E. F. Gas Defense School was established at
the Experimental Field. Arrangements were made for the accommodation
of 200 officers for a six-day course. The number instructed actually
averaged about 150, due to the feeling among Division Commanders that
they could not spare quite so many officers as were required to furnish
200 per week.

This school was conducted under the Commandant of Hanlon Field,
Lieutenant Colonel Hildebrand, by Captain Bush of the British Service.
This Gas Defense School became one of the most efficient schools in
the A. E. F., and was developing methods of teaching that were highly
successful in protecting troops in the field.

=Failure of German Gas.= The losses of the Americans from German gas
attacks fluctuated through rather wide limits. There were times in the
early days during training when this reached 65 per cent of the total
casualties. There were other times in battle, when due to extremely
severe losses from machine gun fire in attacks, that the proportion of
gas losses to all other forms of casualties was very small. On the
whole the casualties from gas reached 27.3 of all casualties. This
small percentage was due solely to the fact that when the Americans
made their big attacks at San Mihiel and the Argonne, the German supply
of gas had run very low. This was particularly true of the supply of
mustard gas.

[Illustration: FIG. 11.—German Gas Alarms.]

Fries was at the front visiting the Headquarters of the First Army and
the Headquarters of the 1st, 3d, and 5th Corps from two days before
the beginning of the battle of the Argonne to four days afterwards. He
watched reports of the battle on the morning of the attack at the Army
Headquarters and later at the 1st, 5th and 3d Corps headquarters in
the order named. No reports of any gas casualties were received. This
situation continued throughout the day. It was so remarkable that he
told the Chief of Staff he could attribute the German failure to use
gas to only one of two possible conditions; first, the enemy was out of
gas; second, he was preparing some master stroke. The first proved to
be the case as examination after the Armistice of German shell dumps
captured during the advance revealed less than 1 per cent of mustard
gas shell. Even under these circumstances the Germans caused quite a
large number of gas casualties during the later stages of the fighting
in the Argonne-Meuse sector.

Evidently the Germans, immediately after the opening of the attack, or
more probably some days before, began to gather together all available
mustard gas and other gases along the entire western battle front,
and ship them to the American sector. This conclusion seems justified
because the enemy never had a better chance to use gas effectively than
he did the first three or four days of the Argonne fight, and knowing
this fact he certainly would never have failed to use the gas if it had
been available. Had he possessed 50 per cent of his artillery shell in
the shape of mustard gas, our losses in the Argonne-Meuse fight would
have been at least 100,000 more than it was. Indeed, it is more than
possible we would never have succeeded in taking Sedan and Mezieres in
the fall of 1918.

=Officers’ Training Camp.= The first lot of about 100 officers were
sent to France in July, 1918, with only a few days’ training, and in
some cases with no training at all. Accordingly, arrangements were made
to train these men in the duties of the soldier in the ranks, and then
as officers. Their training in gas defense and offense followed a month
of strenuous work along the above mentioned lines.

This camp was established near Hanlon (Experimental) Field, at a
little town called Choignes. The work as laid out included squad and
company training for the ordinary soldier, each officer taking turns in
commanding the company at drill. They were given work in map reading as
well as office and company administration.

This little command was a model of cleanliness and military discipline,
and attracted most favorable comment from staff officers on duty at
General Headquarters less than two miles distant. Just before the
Armistice arrangements were made to transfer this work to Chignon,
about 25 miles southeast of Tours, where ample buildings and grounds
were available to carry out not alone training of officers but of
soldiers along the various lines of work they would encounter, from the
handling of a squad, to being Chief Gas Officer of a Division.

=Educating the Army in the Use of Gas.= As has been remarked before,
the Medical Department in starting the manufacture of gas masks and
other defensive appliances, and the Bureau of Mines in starting
researches into poisonous gases as well as defensive materials, were
the only official bodies who early interested themselves in gas
warfare. Due to this early work of the Bureau of Mines and the Medical
Department in starting mask manufacture as well as training in the
wearing of gas masks, the defensive side of gas warfare became known
throughout the army very far in advance of the offensive side. On the
other hand, since the Ordnance Department, which was at first charged
with the manufacture of poisonous gases, made practically no move for
months, the offensive use of gas did not become known among United
States troops until after they landed in France.

Moreover, no gas shell was allowed to be fired by the artillery in
practice even in France, so that all the training in gas the artillery
could get until it went into the line was defensive, with lectures on
the offensive.

The work of raising gas troops was not begun until the late fall of
1917 and as their work is highly technical and dangerous, they were not
ready to begin active work on the American front until June, 1918.

By that time the army was getting pretty well drilled in gas defense
and despite care in that respect were getting into a frame of mind
almost hostile to the use of gas by our own troops. Among certain staff
officers, as well as some commanders of fighting units, this hostility
was outspoken and almost violent.

Much the hardest, most trying and most skillful work required of
Chemical Warfare Service officers was to persuade such Staffs
and Commanders that gas was useful and get them to permit of a
demonstration on their front. Repeatedly Chemical Warfare Service
officers on Division staffs were told by officers in the field that
they had nothing to do with gas in offense, that they were simply
defensive officers. And yet no one else knew anything about the use of
gas. Gradually, however, by constantly keeping before the General Staff
and others the results of gas attacks by the Germans, by the British,
by the French, and by ourselves, headway was made toward getting our
Armies to use gas effectively in offense.

But so slow was this work that it was necessary to train men
particularly how to appeal to officers and commanders on the subject.
Indeed the following phrase, used first by Colonel Mayo-Smith,
became a watchword throughout the Service in the latter part of the
war—“Chemical Warfare Service officers have got to go out and sell gas
to the Army.” In other words we had to adopt much the same means of
making gas known that the manufacturer of a new article adopts to make
a thing manufactured by him known to the public.

[Illustration: FIG. 12.—A Typical Shell Dump near the Front.]

This work was exceedingly trying, requiring great skill, great
patience and above all a most thorough knowledge of the subject. As
illustrating some of these difficulties, the Assistant Chief of Staff,
G-3 (Operations) of a certain American Corps refused to consider a
recommendation to use gas on a certain point in the battle of the
Argonne unless the gas officer would state in writing that if the gas
was so used it could not possibly result in the casualty of a single
American soldier. Such an attitude was perfectly absurd.

The Infantry always expects some losses from our own high explosive
when following a barrage, and though realizing the tremendous value of
gas, this staff officer refused to use it without an absolute guarantee
in writing that it could not possibly injure a single American soldier.
Another argument often used was that a gas attack brought retaliatory
fire on the front where the gas was used. Such objectors were narrow
enough not to realize that the mere fact of heavy retaliation indicated
the success of the gas on the enemy for everyone knows an enemy does
not retaliate against a thing which does not worry him.

But on the other hand, when the value of gas troops had become fully
known, the requests for them were so great that a single platoon had to
be assigned to brigades, and sometimes even to whole Divisions. Thus
it fell to the Lieutenants commanding these platoons to confer with
Division Commanders and Staffs, to recommend how, when and where to use
gas, and do so in a manner which would impress the Commanding General
and the Staff sufficiently to allow them to undertake the job. That no
case of failure has been reported is evidence of the splendid ability
of these officers on duty with the gas troops. Efficiency in the big
American battles was demanded to an extent unheard of in peace, and had
any one of these officers made a considerable failure, it certainly
would have been reported and Fries would have heard of it.

Equally hard, and in many cases even more so, was the work of the gas
officers on Division, Corps and Army Staffs, who handled the training
in Divisions, and who also were required to recommend the use of gas
troops, the use of gas in artillery shell and in grenades, and the
use of smoke by the infantry in attack. However, the success of the
Chemical Warfare Service in the field with these Staff officers was
just as great as with the Regiment.

To the everlasting credit of those Staff Officers and the Officers of
the Gas Regiment from Colonel Atkisson down, both Staff Gas officers
and officers of the Gas Regiment worked together in the fullest harmony
with the single object of defeating the Germans.


CHEMICAL WARFARE TROOPS

Chemical Warfare troops were divided into two distinct divisions—gas
regiments and staff troops.

[Illustration: FIG. 13.—Firing a 155-Millimeter Howitzer.

The men are wearing gas masks to keep out the enemy gas fired at them
in Oct., 1918.]

=Staff Troops.= The staff troops of the Chemical Warfare Service
performed all work required of gas troops except that of actual
fighting. They handled all Chemical Warfare Service supplies from
the time they were unloaded from ships to the time they were issued
to the fighting troops at the front, whether the fighting troops
were Chemical Warfare or any other. They furnished men for clerical
and other services with the Army, Corps and Division Gas Officers,
and they manufactured poisonous gases, filled gas shells and did all
repairing and altering of gas masks. Though these men received none of
the glamour or glory that goes with the fighting men at the front, yet
they performed services of the most vital kind and in many cases did
work as dangerous and hair raising as going over the top in the face of
bursting shell and screaming machine gun bullets.

Think of the intense interest these men must have felt when carrying
from the field of battle to the laboratory or experimental field,
shell loaded with strange and unheard of compounds and which might any
moment burst and end forever their existence! Or watch them drilling
into a new shell knowing not what powerful poison or explosive it might
contain or what might happen when the drill “went through”!

And again what determination it took to work 12 or 16 hours a day way
back at the depots repairing or altering masks, and, as was done at
Chateroux, alter and repair 15,000 masks a day and be so rushed that
at times they had a bare day’s work of remodeled masks ahead. But they
kept ahead and to the great glory of these men no American soldier ever
had to go to the front without a mask. And what finer work than that
of these men who, in the laboratory and testing room, toyed with death
in testing unknown gases with American and foreign masks even to the
extent of applying the gases to their own bodies.

Heroic, real American work, all of it and done in real American style
as part of the day’s work without thought of glory and without hope of
reward.

=The First Gas Regiment.= In the first study of army organization made
by the General Staff it was decided to recommend raising under the
Chief of Engineers one regiment of six companies of gas troops.

Shortly after the cable of August 17, 1917, was sent stating that
Lieut. Colonel Fries would be made Chief of the Gas Service, the War
Department promoted him to be Colonel of the 30th Engineers which
later became the First Gas Regiment. At almost the same time, Captain
Atkisson, Corps of Engineers, was appointed Lieut. Col. of the
Regiment. Although Colonel Fries remained the nominal Commander of the
regiment, he never acted in that capacity, for his duties as Chief of
the Gas Service left him neither time nor opportunity. All the credit
for raising, training, and equipping the First Gas Regiment belongs to
Colonel E. J. Atkisson and the officers picked by him.

Immediately upon the formation of the Gas Service, the Chief urged
that many more than six companies of gas troops should be provided.
These recommendations were repeated and urged for the next two months
or until about the first of November, when it became apparent that an
increase could not be obtained at that time and that any further urging
would only cause irritation. The matter was therefore dropped until a
more auspicious time should arrive. This arrived the next spring when
the first German projector attack against United States troops produced
severe casualties, exactly as had been forecasted by the Gas Service.
About the middle of March, 1918, an increase from two battalions to
six battalions (eighteen companies) was authorized. A further increase
to three regiments of six battalions each (a total of fifty-four
companies) was authorized early in September, 1918, after the very
great value of gas troops had been demonstrated in the fight from the
Marne to the Vesle in July.

[Illustration: FIG. 14.—Receiving and Transmitting Data for Firing Gas
Shell while Wearing Gas Masks. Battlefield of the Argonne, October,
1918.]

=No Equipment for Gas Troops.= About the first of December a
cablegram was received from the United States stating that due to
lack of equipment the various regiments of special engineers recently
authorized, including the 30th (Gas and Flame) would not be organized
until the spring of 1918. An urgent cablegram was then sent calling
attention to the fact that gas troops were not service of supply troops
but first line fighting troops, and consequently that they should be
raised and trained in time to take the field with the first Americans
going into the line. At this same time the 30th regiment was given
early priority by the General Staff, A. E. F., on the priority lists
for troop shipments from the United States. The raising of the first
two companies was then continued under Colonel Atkisson at the American
University in Washington.

About January 15 word was received that the Headquarters of the
regiment and the Headquarters of the First Battalion together with
Companies A and B of the 30th Engineers (later the First Gas Regiment)
were expected to arrive very soon. Some months prior General Foulkes,
Chief of the British Gas Service in the field, had stated that he would
be glad to have the gas troops assigned to him for training. It was
agreed that the training should include operations in the front line
for a time to enable the American Gas Troops to carry on gas operations
independently of anyone else and with entire safety to themselves and
the rest of the Army.

Due to the fact that the British were occupying their gas school,
the British General Headquarters were a little reluctant to take the
American troops Feb. 1. However, General Foulkes made room for the
American troops by moving his own troops out. He then placed his best
officers in charge of their training and at all times did everything
in his power to help the American Gas Troops learn the gas game and
get sufficient supplies to operate with. Colonel Hartley, Assistant to
General Foulkes, also did everything he could to help the American Gas
Service. These two officers did more than any other foreign officers in
France to enable the Chemical Warfare Service to make the success it
did.

=Second Battle of the Marne.= The Chief of the Gas Service, following
a visit to the British Gas Headquarters, and the Headquarters of the
American 2d Corps then operating with the British, arrived on the
evening of July 17, 1918, at 1st Corps Headquarters at La Ferte sous
Jouarre about 10 miles southeast of Château-Thierry.

Two companies of the First Gas Regiment would have been ready in 48
hours to put off a projector attack against an excellent target just
west of Belleau Wood had not the 2d battle of the Marne opened when
it did. It is said that General Foch had kept this special attack so
secret that the First American Corps Commander knew it less than 48
hours prior to the hour set for its beginning. Certainly the Chief of
the Gas Service knew nothing of it until about 9:00 P.M., the night of
July 17th. Consequently the gas attack was not made. At that time so
little was known of the usefulness of gas troops that they were started
on road work. At Colonel Atkisson’s suggestion that gas troops could
clean out machine gun nests, he was asked to visit the First Corps
headquarters and take up his suggestion vigorously with the First Corps
Staff.

=Attacking Machine Gun Nests.= Thereupon the Gas troops were allowed
to try attacking machine gun nests with phosphorus and thermite. This
work proved so satisfactory that not long afterwards the General Staff
authorized an increase in gas troops from 18 companies to 54 companies,
to be formed into three regiments of two battalions each. The 6
companies in France did excellent work with smoke and thermite during
all the second battle of the Marne to the Vesle river, where by means
of smoke screens they made possible the crossing of that river and the
gaining of a foothold on the north or German side.

With the assembling of American troops in the sector near Verdun in
September, 1918, the gas troops were all collected there with the
exception of one or two companies and took a very active part in
the capture of the St. Mihiel salient. It was at this battle that
the Chemical Warfare Service really began to handle offensive gas
operations in the way they should be handled. Plans were drawn for
the use of gas and smoke by artillery and gas troops both. The use of
high explosives in Liven’s bombs was also planned. Those plans were
properly co-ordinated with all the other arms of the service in making
the attack. Gas was to be used not alone by gas troops but by the
artillery. Plans were made so that the different kinds of gases would
be used where they would do the most good. While these plans and their
execution were far from perfect, they marked a tremendous advance and
demonstrated to everyone the possibilities that lay in gas and smoke
both with artillery and with gas troops.

Following the attack on the St. Mihiel salient, came the battle of the
Argonne, where plans were drawn as before, using the added knowledge
gained at St. Mihiel. The work was accordingly more satisfactory.
However, the attempt to cover the entire American front of nine
divisions with only six companies proved too great a task. Practically
all gas troops were put in the front line the morning of the attack.
Due to weather conditions they used mostly phosphorus and thermite
with 4 inch Stokes’ mortars. Having learned how useful these were in
taking machine gun nests, plans were made to have them keep right up
with the Infantry. This they did in a remarkable manner considering the
weight of the Stokes’ mortar and the base plates and also that each
Stokes’ mortar bomb weighed about 25 pounds. There were cases where
they carried these mortars and bombs for miles on their backs, while in
other cases they used pack animals.

[Illustration: FIG. 15.—Setting Up a Smoke Barrage with Smoke Pots.]

Not expecting the battle to be nearly continuous as it was for three
weeks, the men, as before stated, were all put in the front line
the morning of the attack. This resulted in their nearly complete
exhaustion the first week, since they fought or marched day and night
during nearly the whole time. Taking a lesson from this, in later
attacks only half the men were put in the line in the first place, no
matter if certain sectors had to be omitted. Fully as good results were
obtained because, as the men became worn out, fresh ones were sent
in and the others given a chance to recuperate. Officers relate many
different occurrences showing the discipline and character of these gas
troops. On one occasion where a battalion of infantry was being held up
by a machine gun nest, volunteers were called for. Only two men, both
from the gas regiment, volunteered though they were joined a little
later by two others from the same regiment, and these four took the
guns. While it was not considered desirable for gas troops to attempt
to take prisoners, yet the regiment took quite a number, due solely
to the fact that they were not only with the advancing infantry but
at times actually in front of it. On another occasion a gas officer,
seeing a machine gun battalion badly shot up and more or less rattled,
took command and got them into action in fine shape.

At this stage the Second Army was formed to the southeast of Verdun
and plans were drawn for a big attack about November 14. The value of
gas troops was appreciated so much that the Second Army asked to have
British gas troops assigned to them since no American gas troops were
available. Accordingly in response to a request made by the American
General Headquarters, the British sent 10 companies of their gas
troops. These reached the front just before the Armistice, and hence
were unable to carry out any attacks there.

This short history of the operations of the First Gas Regiment
covers only the high spots in its organization and work. It covers
particularly its early troubles, as those are felt to be the ones most
important to have in mind if ever it be necessary again to organize
C. W. S. troops on an extensive scale. The Regiment engaged in nearly
200 separate actions with poisonous gases, smoke and high explosives,
and took part in every big battle from the second battle of the Marne
to the end of the War. They were the first American troops to train
with the British, and were undoubtedly the first American troops
to take actual part in fighting the enemy as they aided the British
individually and as entire units in putting off gas attacks, in
February and March, 1918. It would be a long history itself to recite
the actions in which the First Gas Regiment took part and in which it
won distinction.[16]

[Footnote 16: Story of the First Gas Regiment, James T. Addison.
Houghton Mifflin Co., 1919.]

No better summary of the work of this Regiment can be written than that
of Colonel Atkisson in the four concluding paragraphs of his official
report written just after the Armistice:

    “The First Gas Regiment was made up largely of
    volunteers—volunteers for this special service. Little
    was known of its character when the first information
    was sent broadcast over the United States, bringing
    it to the attention of the men of our country. The
    keynote of this information was a desire for keen,
    red-blooded men who wanted to fight. They came into it
    in the spirit of a fighting unit, and were ready, not
    only to develop, but to make a new service. No effort
    was spared to make the organization as useful as the
    strength of the limited personnel allowed.

    “The first unit to arrive in France moved to the
    forward area within eight weeks of its arrival, and,
    from that time, with the exception of four weeks, was
    continuously in forward areas carrying on operations.
    The third and last unit moved forward within six weeks
    of its arrival in France, and was continuously engaged
    until the signing of the Armistice.

    “That the regiment entered the fight and carried the
    methods developed into execution where they would be of
    value, is witnessed by the fact that over thirty-five
    percent of the strength of the unit became casualties.

    “It is only fitting to record the spirit and true
    devotion which prompted the officers and men who
    came from civil life into this Regiment, mastered
    the details of this new service, and, through their
    untiring efforts and utter disregard of self, made
    possible any success which the Regiment may have had.
    It was truly in keeping with the high ideals which have
    prompted our entire Army and Country in this conflict.
    They made the motto of ‘Service,’ a real, living,
    inspiring thing.”


SUPPLY

As previously stated it was decided early that the Chemical Warfare
Service should have a complete supply service including purchase,
manufacture, storage and issue, and accordingly separate supply depots
were picked out for the Gas Service early in the fall by Col. Crawford.
Where practicable these were located in the same area as all other
depots though in one instance the French forced the Gas Service to
locate its gas shell and bomb depot some fifteen miles from the general
depots through an unreasonable fear of the gas.

=Manufacture of Gases.= Due to the time required and the cost of
manufacturing gases, an early decision became imperative as to what
gases should be used by the Americans, and into what shells and bombs
they should be filled. As there was no one else working on the subject
the sole responsibility fell upon the Chief of the Gas Service. The
work was further complicated by the fact that the British and French
did not agree upon what gases should be used. The British condemned
viciously Vincennite (hydrocyanic acid gas with some added ingredients)
of the French, while the French stated that chloropicrin, used by the
British principally as a lachrymator, was worthless. Fries felt the
tremendous responsibility that rested upon him and finally after much
thought and before coming to any conclusion, wrote the first draft of
a short paper on gas warfare. In that paper he took up the tactical
uses to which gases might be put and then studied the best and most
available gases to meet those tactical needs.

Without stating further details it was decided to recommend the
manufacture and use of chlorine, phosgene, chloropicrin, bromoacetone
and mustard gas. As the gas service was also charged with handling
smoke and incendiary materials, smoke was prescribed in the proportion
of 5 per cent of the total chemicals to be furnished. The smoke
material decided upon was white phosphorus.

The paper on Gas Warfare was then re-drafted and submitted to the
French and British and written up in final form prescribing the gases
above mentioned on October 26. Following this a cable was drawn and
submitted to the General Staff. After many conferences and some delay
the cable went forward on November 3.


              CABLE 268, NOVEMBER 4, 1917

    Paragraph 12. For chief of Ordnance. With reference to
    paragraph 2 my cablegram 181, desire prompt information
    as to whether recommendation is approved that phosgene,
    chloropicrin, hydrocyanic acid, and chlorine be
    purchased in France or England and filling plants
    established in France for filling shells and bombs with
    those gases.

    Subparagraph A. Reference to your telegram 253,
    recommend filling approximately 10 per cent all shells
    with gases as given below, but that filling plants
    and gas factories be made capable of filling a total
    of 25 per cent. Unless ordinary name is given, gases
    are designated by numbers in chemical code War Gas
    investigations. Of 75 millimeter shells fill 1 per cent
    Vincennite, 4 per cent phosgene or trichloromethyl
    chloroformate, 2 per cent chloropicrin, 2½ per cent
    mustard gas, ½ per cent with bromoacetone and ½ per
    cent with smoke material. According to French 75
    millimeter steel shells should not be filled with
    Vincennite more than three months before being used.
    No trouble with other gases or other sized shells
    except that bromoacetone must be in glass lined shells.
    Of 4.7 inch shells fill 5 per cent with phosgene
    or trichloromethyl chloroformate, 2 per cent with
    chloropicrin, 2½ per cent with mustard gas, ½ per cent
    with bromoacetone and ½ per cent with smoke material.
    Provide same percentage for all other shells up to and
    including 8 inch caliber as for 4.7 inch shells. 4 inch
    Stokes’ mortar will use same gases and smoke shells and
    in addition thermit. 8 inch projector bombs will use
    the same as the Stokes’ mortar and also oil to break
    into flame on _bursting_. Cloud gas cylinders
    will be filled with 50 or 60 per cent phosgene, mixed
    with 40 to 50 per cent chlorine, or phosgene and some
    other gas. Renew recommendation that filling plants be
    established in France to provide sudden shifts in gas
    warfare of all kinds, as well as for filling all 4 inch
    Stokes’ mortar bombs, 8 inch projector bombs and cloud
    gas cylinders. It is strongly recommended that efforts
    be made to produce white phosphorus on large scale for
    its usefulness both as smoke screens and to produce
    casualties.

    Subparagraph B. For the Adjutant General of the Army.
    With reference to paragraph 2, my cablegram 181, desire
    information as to whether recommendation is approved
    that an engineer officer assisted by Professor Hulett
    be assigned to Gas Service in Washington to handle all
    orders and correspondence concerning gas.

    Subparagraph C. For Surgeon General. With reference to
    paragraph 2 your cablegram 205, and paragraph 2, my
    cablegram 181, what is status of chemical laboratory
    for France? Also have the 12 selected Reserve Officers
    for training in gas defense sailed for France?

    Subparagraph D. With reference to paragraph 17 your
    cablegram 165 and paragraph 2 my cablegram 181,
    Tissot has constructed simpler model of his mask for
    attachment to any box. Have ordered 6 which will be
    completed in two weeks, 3 of which will be forwarded
    at once. A simple type such as this may prove useful
    for large number of troops. Letter of permission to
    manufacture Tissot masks being forwarded.

    Subparagraph E. With reference to paragraph 8 your
    cablegram 143, and paragraph 4 your cablegram 247, in
    considering charcoal and other fillers for canister of
    box respirator it should be remembered that the front
    is very damp, the air being nearly saturated during
    greater part of winter, fall and spring.

This cable is given in full to show that not later than November 4,
1917, it was known in the United States not only what gases would be
required but also in what shells, bombs, guns and mortars each would
be used. While a small quantity of Vincennite was recommended in this
cable, another cable sent within a month requested that no Vincennite
whatever be manufactured. This decision as to gases and guns in which
they were to be used, while very progressive, proved entirely sound
and remained unchanged, with slight exceptions due to new discoveries,
until the end of the war. Without a thorough understanding of tactics a
proper choice of gases could not have been made. This fact emphasizes
the necessity of having a trained technical army man at the head of any
gas service.

Due to the absence of a Chemical Warfare Service in the United States
at this time, a very great deal of the information sent from France,
whether by cable or by letter, never reached those needing it.

=Smoke.= About the first of December after a study of results obtained
by the British and the Germans in the use of smoke in artillery shells
for screening purposes, the Gas Service decided that much more smoke
than had been stated in cable 268 to the United States was desirable.
The General Staff, however, refused to authorize any increase, but did
allow to be sent in a cable a statement to the effect that a large
increase in smoke materials might be advisable for smoke screens, and
that accordingly the amount of phosphorus needed in a year of war would
probably be three or four times the one and a half million pounds of
white phosphorus stated to have been contracted for by the Ordnance
Department in the United States. This advanced position of the Gas
Service in regard to smoke proved sound in 1918, when every effort was
made to increase the quantity of white phosphorus available and to
extend its use in artillery shells including even the 3 inch Stokes’
mortar.

[Illustration: FIG. 16.—Troops Advancing Behind a Smoke Barrage
(Phosphorus).]

=Overseas Repair Section No. 1.= During the latter part of November,
1917, Overseas Repair Section No. 1, under the command of Captain
Mayo-Smith, Sanitary Corps, with four other officers and 130 men,
arrived in France. Since mask development and manufacture in the United
States was still under the Medical Department, this mask repair section
was organized as a part of the Sanitary Corps. As there were at that
time no masks to be repaired and no laboratory equipment or buildings
for that purpose on hand and none likely to be for months to come,
Captain Mayo-Smith was assigned to duty under Colonel Crawford, Chief
Gas Officer with the Line of Communication, in Paris. A site for a mask
repair plant was located at Châteauroux, and a site for a gas depot at
Gievres was investigated. Inasmuch as there was at that time greater
need for men to learn the handling of poisonous gases than to repair
masks, some 40 or 50 of the company were put in gas shell filling
plants at Aubervilliers and Vincennes in the suburbs of Paris, while
later still others were assigned to Pont de Claix near Grenoble. The
remainder of the company were used in the Gas Depot at Gievres and in
the office in Paris.

It was not until the latter part of June, 1918, that the mask repair
plant began operations. In the meantime these men did very valuable
work in shell filling and in learning the manufacture of gases.
Several of them were sent to the United States, some of them remaining
throughout the war to aid in gas manufacture and in shell filling.

=Construction Division, Gas Service.= The Construction Division
under Colonel Crawford in Paris made complete plans for phosgene
manufacturing plants, for shell filling plants and for the Mask Repair
Plant. These plans included a complete layout of the work for all
persons to be employed in the plants. During this same time a very
careful study of the possibilities for manufacturing gas for filling
shell in France was made.

Finally about March 1, in accordance with the strong recommendations
of these men, Fries reported to General Pershing in person that the
manufacture of gas as well as the filling of shell in France was
inadvisable from every point of view and accordingly he recommended
that gas manufacture and shell filling in France be given up. General
Pershing strongly approved the recommendation and a cablegram was at
once sent to the United States to that effect. The main reason for
this action was the lack of chlorine, since chlorine was the principal
ingredient of nearly all poisonous gases then in use. Chlorine takes,
besides salt, electric power and lots of it. Electric power requires
coal or water power. Neither of the latter sources were available in
France. This question was gone into very thoroughly. The only place
where power might have been developed was in a remote spot near Spain,
and the outlook there was such that it appeared impossible to begin
the manufacture of chlorine under two years. On the other hand the
shipment of chlorine from the United States required from 75 per
cent to 100 per cent of the tonnage required to ship the manufactured
gases themselves, to say nothing of the labor, raw materials, and the
machinery that would have had to be shipped in order to manufacture gas
in France.

=Mustard Gas.= As previously stated Mustard Gas was first used by the
Germans against the British at Ypres on the nights of July 11 and 12,
1917. It was not used much against the French until more than two
months later. Indeed, gas was never used by the Germans to the same
extent against the French as against the English. There are probably
two reasons for this; first, the Germans had a deeper hatred for the
British than the French; second, the British morale was higher than the
French in 1917, and the German thought that if he could break down this
British morale, he could win the war.

The first attack came as a surprise and accordingly got an unusually
large number of casualties. As previously stated the casualties
numbered about 20,000 in about six weeks. This number was considered
so serious that the beginning of the series of attacks against Ypres
in the fall of 1917, was delayed by the British for 10 days or two
weeks until they could study better how to avoid such great losses from
mustard gas. While the composition of the gas was known within two or
three days, as well as the laboratory method by which it was first
manufactured by Victor Meyer in 1886, it took some 11 months to develop
reliable and practical methods of manufacturing it on a large scale.
The Inter-allied Gas Conference in September, 1917, gave a great deal
of attention to mustard gas and methods of combating it both from the
view point of prevention and of curing those gassed by it.

Just following the close of that conference a cable was sent to
the United States asking the possibility of manufacturing ethylene
chlorhydrin, the principal element in the manufacture of mustard gas
by the only process then known. Later, that is about the middle of
October, a cablegram was sent urging investigation into the manufacture
of this gas. It is believed a great deal of time might have been saved
had the policy of undue secrecy not been adopted by the British and
others before the Americans entered the war. In fact we were only told
in whispers the formula for mustard gas, and where a description of it
could be found in German chemistries. This was arrant nonsense since if
the Germans had gotten all mustard gas information then in the hands
of the British they would have received far less information than they
already possessed on mustard gas.

[Illustration: FIG. 17.—“Who Said Gas?”]

Whether the information sent to the United States on mustard gas
ultimately proved of any great value is an open question since the
methods adopted in the United States were very greatly superior to
those used in England and in France. It probably helped by suggestion
rather than by actual details of design. Anyhow it all emphasizes the
difficulties encountered in war when so vital a substance as mustard
gas must be investigated after the enemy has begun using it on a large
scale.

=Delay of British Masks.= As December 1 approached, and as nothing
further had been heard of the order for 300,000 British Respirators
placed about the middle of October, a telegram was sent to England
asking if deliveries would be made as required in the order for the
masks. This order required the first 75,000 to be delivered December 1,
1917. In reply it was stated that the British could not furnish these
masks, and that they understood that the Americans were just beginning
a large output of masks in the United States. An exchange of cablegrams
with the United States showed that no masks could be expected from
there for 3 to 5 months. Moreover it became increasingly evident that
the Americans were going into the battle line sooner than at first
contemplated. Another cablegram was then sent to England urging the
delivery of these masks. The reply was to the effect that the English
Government could not deliver the masks because they did not have enough
for their own use. This situation was very serious. Unless the order
for 300,000 masks placed with the British could be filled, we were
facing the necessity of sending American troops into the front line
with only the French M-2 mask. While the M-2 mask was then the only
mask used by the French, it was well known to afford practically no
protection against the high concentrations of phosgene obtained from
cloud or projector attacks. And it was just such attacks as these that
our men would encounter in the front line during training. Accordingly
arrangements were made for a hurried trip to England.

Colonel Harrison of the British Royal Engineers was in charge of
the British manufacture of masks and it is desired here to express
appreciation of his uniform courtesy and great helpfulness. He
exhibited their methods and facilities and assured us they could meet
any requirements of ours for masks up to a half million, or even more
if necessary, provided they were given time to establish additional
facilities. Finally after a further exchange of cables the masks were
obtained.

During December, 1917 and January, 1918, when every effort was being
made to hurry a lot of masks from Havre—Havre being the British supply
base in France from which the masks were issued to the United States,
the severe cold and snow had so disorganized French traffic that it
was extremely difficult to get cars moving at all. In an effort to
get the masks, priority of shipment was obtained and two or three
officers were assigned to convoy the cars. Notwithstanding convoying,
one carload of 4,000 masks, mainly threes and fours, became lost and
only turned up five weeks later. To make matters worse the British were
sending us very many more of the small sized No. 2 masks than we could
use. The loss of this carload of 4,000 number threes and fours was all
but a tragedy. Indeed, in order to get the First Brigade of the First
Division equipped in time it was necessary to take a large number of
masks already issued to men of the Second Brigade. These masks were
first thoroughly washed and disinfected and then re-issued.

This all emphasizes the great difficulties that are encountered when
a new and vital service must be organized in war 4,000 miles overseas
without material, home supplies, or men to draw from. This struggle
to get sufficient masks to keep all men fully equipped remained very
acute until in July, 1918, when the arrival of hundreds of thousands
of masks from the United States made the situation entirely safe. Even
then the necessity of weakening the elastics and shortening the rubber
tubing of the mouthpieces on some 700,000 masks, doubled up our work
tremendously, and added enormously to our troubles in getting masks to
the front in time.

Notwithstanding these troubles the Chemical Warfare Supply Service
never failed and finally forged to the very forefront of all American
supply services. Its method of issuing supplies to troops at the front
has been adopted as the standard for American field armies of the
future.


TECHNICAL

=Gas Laboratory in Paris.= Early in January, 1918, the first members
of the Chemical Service Section, National Army, under the command
of Colonel R. F. Bacon, arrived in France and reported for duty.
Previously, a laboratory site at Puteaux, a suburb of Paris, had been
selected. This plant had been built by a society for investigation
into tuberculosis. Previous to the arrival of the Chemical Service
Section, information had been requested from the United States by cable
as to the size of the laboratory section to be sent over. The reply
stated that the number would probably total about 100 commissioned
and enlisted. The site at Puteaux was accordingly definitely decided
upon. Just following this decision two cables, one after the other,
came from the United States recommending certain specified buildings in
Paris for the laboratory. It was found upon investigation in both cases
that the buildings were either absolutely unsuited or unfinished. This
was another case of trying to fight a war over 4,000 miles of cable.
Colonel Bacon was made head of the Technical Division, which position
he held throughout the war.

[Illustration: FIG. 18.—Shaper for Opening Captured Gas Shell.]

=Technically Trained Men.= In January, 1918, in response to a cable
from the United States a request had been made on the French Government
to send six of their ablest glass blowers to the United States to aid
in making glass lined shells. The French Gas authorities said that it
would be impossible to send those or indeed any other men trained in
the manufacture or handling of poisonous gases or gas containers as
they did not have enough such men for their own work. Accordingly a
cablegram was drafted and sent to the United States, requesting that
50 men experienced in various lines of technical and chemical work be
sent to France. The French authorities said they would put them in any
factories, laboratories or experimental places that the Chief of the
Gas Service desired. A second inquiry about these men was sent but
nevertheless no answer was ever received and no men were sent.

=Protection Against Particulate Clouds.= Just at this time, about the
first of February, 1918, the danger that the Germans might devise some
better method of sending over diphenylchloroarsine than by pulverizing
it in high explosive shell was felt to be serious. The British had just
then perfected protection against diphenylchloroarsine by employing
unsized sulfate wood pulp paper—48 to 60 layers being required. This
number of layers was found to be necessary as they are very thin and
porous. The British had developed a method of putting this paper around
a canister and yet keeping the canister small enough to fit into the
knapsack by reversing its position therein; that is, putting the
canister in the compartment of the knapsack made for the face piece
and putting the face piece in the other compartment. Some of our own
officers and enlisted men were sent to England to work with the British
on this and an order given them for 200,000 of the protected canisters.
They improved on the methods of the British and as it was found that
sulfate paper was very scarce, investigations were made to see if any
of it could be manufactured in France. Very soon thereafter such a
place was located near the city of Nancy. Following this a cablegram
was sent to the United States giving complete specifications for making
this diphenylchloroarsine protection. From this cablegram successful
samples were made though somewhat more bulky than those developed in
England. Very few, however, of these were made in the United States
due, we were informed, to the poor quality of the sulfate paper. Work
was however begun energetically in the United States on other methods
of protection against diphenylchloroarsine.

=Numbers of Chemists Needed.= It was figured that out of a total force
of some 1,400 gas officers there would be needed in the A. E. F.,
exclusive of those in regiments, approximately 200 chemists, i.e.,
about 15 per cent of the whole. We arranged to have a good chemist on
each Division, Corps and Army Staff, and a certain number with the gas
troops. It was proposed to put 20 to 40 in the laboratory in Paris and
not to exceed 20 at the experimental field. This subject of personnel
is touched on for the reason that a few people seem to have the idea
that the Chemical Warfare Service should be made up of chemists
exclusively. This is very far from being true. It was and is believed
that the Chemical Warfare Service should be composed of men from every
walk of life. In three positions out of every four in the field a good
personality combined with energy, hard work and common sense count for
more than mere technical training.

=Hanlon (Experimental) Field.= As early as December 15, 1917, it
was decided that an experimental field in France was necessary, and
a letter was written to the General Staff requesting authority to
establish one. After considerable delay the authority was granted and
search for a site begun. This was no easy task. While the French were
loading millions of gas shells at the edge of Paris, they appeared
unwilling at first to have us establish a gas experimental field
except in abandoned or inaccessible spots. Finally a very good site
was found and agreed to by the French some 7 miles south of General
Headquarters. Just when we were ready to start work the French
discovered that the proposed field included a portion of one of their
artillery firing ranges. They then suggested another site within 3
miles of General Headquarters. This was a rather fortunate accident as
the site suggested was a better one than at first picked out. The field
was roughly rectangular from 7 to 8 miles in length, and 3 to 4 miles
in width. The total area was about 20 square miles. The work of this
experimental field proved a great success and was rapidly becoming the
real center of the Gas Service in France.

The old saying that the history of a happy country is very brief
applies to this story of the Technical Section of the Gas Service in
France. Its work did not begin as early as that of the other sections,
and as considerable of it was of a nature that could be put off without
immediate fatal effects, the Section was enabled to grow without
the very serious drawbacks encountered by other Sections of the Gas
Service.

Nevertheless its usefulness was very great. Those of the Technical
Section either at the experimental field or at the laboratory were
charged with the opening of all sorts of known and unknown gas and high
explosive shells, fuses and similar things to determine their contents
and their poisonous or explosive qualities. This was work of a very
technical nature, and at the same time highly dangerous.

As stated elsewhere, the determination of the life of the masks became
one of the problems which the laboratory was trying to solve. Hundreds
of canisters were tested, and hundreds per month would have continued
to have been tested throughout the remainder of the war had the war
gone into 1919. It was on the Technical Section that devolved the duty
of determining at the earliest possible moment the physical properties
as well as the physiological effects of any new gas.

Also on that Section fell the preliminary reports as to the probable
usefulness in war of a new gas whether sent over by the enemy or
suggested by our own Technical men, or those of our Allies. This
was indeed a task by itself, as it required a wide knowledge of the
methods of using gases, methods of manufacturing them, and methods of
projecting them on the field of battle.

In addition, it was the duty of the Technical Section to keep the
Chief of the Service fully informed on all the latest developments in
gases and to get that information in shape so that the Chief with his
increasingly wide range of duties would be enabled to keep track of
them without reading the enormous amount ordinarily written.

A much earlier start on technical work would have proved of immense
advantage. In case of another war, the technical side of chemical
warfare should be taken up with the very first expedition that proceeds
to the hostile zone. Had that been done in France, we would have had
masks and gases and proper shells and bombs at least six months before
we did.


INTELLIGENCE

While Intelligence was for a long time under the Training or Technical
Divisions, it finally assumed such importance that it was made a
separate Division. It was so thoroughly organized that by the time of
the Armistice the Chief of the Division could go anywhere among the
United States forces down to companies and immediately locate the Gas
Intelligence officer.

=Intelligence Division.= This work was started by Lieutenant
Colonel Goss within a month after he reported in October, 1917. The
Intelligence Division developed the publication of numerous occasional
pamphlets and also a weekly gas bulletin. So extensive was the work
of this Division that three mimeograph machines were kept constantly
going. The weekly bulletin received very flattering notice from the
British Assistant Chief of Gas Service in the Field. He stated that it
contained a great deal of information he was unable to get from any
other source.

Among other work undertaken by this Intelligence Division was the
compilation of a History of the Chemical Warfare Service in France.
This alone involved a lot of work. In order that this history might
be truly representative, about three months before the Armistice both
moving and still pictures were taken of actual battle conditions, as
well as of numerous works along the Service of Supplies.

Without going into further detail it is sufficient to say that when the
Armistice was signed there were available some 200 still pictures, and
some 8,000 feet of moving picture films. Steps were immediately taken
to have this work continued along definite lines to give a complete and
continuous history of the Chemical Warfare Service in France in all its
phases.

The intelligence work of the Gas Service, while parallel to a small
extent with the General Intelligence Service of the A. E. F., had to
spread to a far greater extent in order to get the technical details
of research, manufacture, development, proving, and handling poisonous
gases in the field. It included also obtaining information at the
seats of Government of the Allies, as well as from the enemy and other
foreign sources.

The most conspicuous intelligence work done along these lines was by
Lieutenant Colonel J. E. Zanetti, who was made Chemical Warfare liaison
officer with the French in October, 1917. He gathered together and
forwarded through the Headquarters of the Chemical Warfare Service
to the United States more information concerning foreign gases, and
foreign methods of manufacturing and handling them, than was sent from
all other sources combined. By his personality, energy and industry
he obtained the complete confidence of the French and British. This
confidence was of the utmost importance in enabling him to get
information which could have been obtained in no other way. Suffice to
say that in the 13 months he was liaison officer with the French during
the war, he prepared over 750 reports, some of them very technical and
of great length.

As a whole, the Intelligence Division was one of the most successful
parts of the Chemical Warfare Service. Starting 2½ years after the
British and French, the weekly bulletin and occasional papers sent
out by the Chemical Warfare Service on chemical warfare matters came
to be looked upon as the best available source for chemical warfare
information, not alone by our own troops but also by the British.


MEDICAL

The Medical Section of the Chemical Warfare Service was composed of
officers of the Medical Department of the Army attached to the Chemical
Warfare Service. These were in addition to others who worked as an
integral part of the Chemical Warfare Service, either at the laboratory
or on the experimental field in carrying out experiments on animals to
determine the effectiveness of the gases.

The Medical Section was important for the reason that it formed the
connecting link between the Chemical Warfare Service and the Medical
Department. Through this Section, the Medical Department was enabled to
know the kinds of gases that would probably be handled, both by our own
troops and by the enemy, and their probable physiological effects.

Colonel H. L. Gilchrist, Medical Department, was the head of this
Section. It was through his efforts that the Medical Department
realized in time the size of the problem that it had to encounter in
caring for gas patients. Indeed, records of the war showed that out of
224,089 men, exclusive of Marines, admitted to the hospitals in France,
70,552 were suffering from gas alone. These men received a total of
266,112 wounds, of which 88,980, or 33.4 per cent, were gas. Thus ⅓ of
all wounds received by men admitted to the hospital were gas. While
the records show that the gas cases did not remain on the average in
the hospitals quite as long as in the case of other classes of wounds,
yet gas cases became one of the most important features of the Medical
Department’s work in the field.

The Medical Section, through its intimate knowledge of what was going
on in the Chemical Warfare Service as well as what was contemplated
and being experimented with, was enabled to work out methods of
handling all gas cases far in advance of what could have been done
had there been no such section. One instance alone illustrates this
fully. It became known fairly early that if a man who had been gassed
with mustard gas could get a thorough cleansing and an entire change
of clothing within an hour after exposure, the body burns could
be eliminated or largely decreased in severity. This led to the
development of degassing units. These consisted of 1,200 gallon tanks
on five-ton trucks equipped with a heater. Accompanying this were
sprinkling arrangements whereby a man could be given a shower bath,
his nose, eyes and ears treated with bicarbonate of soda, and then be
given an entire change of clothing. These proved a very great success,
although they were not developed in time to be used extensively before
the war closed.

There is an important side to the Medical Section during peace, that
must be kept in mind. The final decision as to whether a gas should
be manufactured on a large scale and used extensively on the field of
battle depends upon its physiological and morale effect upon troops. In
the case of the most powerful gases, the determination of the relative
values of those gases so far as their effects on human beings is
concerned is a very laborious and exacting job. Such gases have to be
handled with extreme caution, necessitating many experiments over long
periods of time in order to arrive at correct decisions.




CHAPTER V

CHLORINE


Chlorine is of interest in chemical warfare, not only because it was
the first poison gas used by the Germans, but also because of its
extensive use in the preparation of other war gases. The fact that,
when Germany decided upon her gas program, her chemists selected
chlorine as the first substance to be used, was the direct result of an
analysis of the requirements of a poison gas.

To be of value for this purpose, a chemical must satisfy at least the
following conditions:

    (1) It must be highly toxic.
    (2) It must be readily manufactured in large quantities.
    (3) It must be readily compressible to a liquid and yet
        be more or less easily volatilized when the pressure
        is released.
    (4) It should have a considerably higher density than
        that of air.
    (5) It should be stable against moisture and other
        chemicals.

Considering the properties of chlorine in the light of these
requirements, we find:

    (1_a_) Chlorine is fairly toxic, though its lethal
      concentration (2.5 milligrams per liter of air) is
      very high when compared with some of the later gases
      developed. This figure is the concentration necessary
      to kill a dog after an exposure of thirty minutes. Its
      effects during the first gas attack showed that, with
      no protection, the gas was very effective.

    (2_a_) Chlorine is very readily manufactured by
      the electrolysis of a salt (sodium chloride) solution.
      The operation is described below. In 100-pound
      cylinders, the commercial product sold before the War
      for 5 cents a pound. Therefore on a large scale, it can
      be manufactured at a very much smaller figure.

    (3_a_) Chlorine is easily liquefied at the
      ordinary temperature by compression, a pressure of 16.5
      atmospheres being required at 18° C. The liquid which
      is formed boils at -33.6° C. at ordinary atmospheric
      pressure, so that it readily vaporizes upon opening
      the valve of the containing cylinder. Such rapid
      evaporation inside would cause a considerable cooling
      of the cylinder, but this is overcome by running
      the outlet pipe to the bottom of the tank, so that
      evaporation takes place at the end of the outlet pipe.

    (4_a_) Chlorine is 2.5 times as heavy as air,
      and therefore the gas is capable of traveling over a
      considerable distance before it dissipates into the
      atmosphere.

    (5_a_) The only point in which chlorine does not
      seem to be an ideal gas, is in the fact that it is a
      reactive substance. This is best seen in the success of
      the primitive protection adopted by both the British
      and the French during the days immediately following
      the first gas attack.

At first, however, chlorine proved a very effective weapon. During the
first six months of its use, its value was maintained by devising new
methods of attack. When these were exhausted, phosgene was added (see
next chapter). With the decline in importance of cloud gas attacks, and
the development of more deadly gases, chlorine was all but discarded as
a true war gas, but remained as a highly important ingredient in the
manufacture of other toxic gases.


MANUFACTURE IN THE UNITED STATES

It was at first thought that the existing plants might be able to
supply the government’s need of chlorine. The pre-war production
averaged about 450 tons (900,000 pounds) per day. The greater amount
of this was used in the preparation of bleach, only about 60,000
pounds per day being liquefied. Only a few of the plants were capable
of even limited expansion. In an attempt to conserve the supply, the
paper mills agreed to use only half as much bleach during the war,
which arrangement added considerably to the supply available for war
purposes. It was soon recognized that even with these accessions, large
additions would have to be made to the chlorine output of the country
in order to meet the proposed toxic gas requirements.

After a careful consideration of all the factors, the most important
of which was the question of electrical energy, it was decided to
build a chlorine plant at Edgewood Arsenal, with a capacity of 100
tons (200,000 pounds) per day. The Nelson cell was selected for use
in the proposed plant. During the process of erection of the plant,
the Warner-Klipstein Chemical Company, which was operating the Nelson
cell in its plant in Charleston, West Virginia, agreed that men might
be sent to their plant to acquire the special knowledge required for
operating such a plant. Thus when the plant was ready for operation,
trained men were at once available.

[Illustration: FIG. 19.—Chlorine Plant, Edgewood Arsenal.]

[Illustration: FIG. 20.—Ground Plan of Chlorine Caustic Soda Plant,
Edgewood Arsenal.]

The following description of the plant is taken from an article by S.
M. Green in _Chemical and Metallurgical Engineering_ for July 1, 1919:

“The chlorine plant building, a ground plan of which is shown in
Figure 20, consisted of a salt storage and treating building, two
cell buildings, a rotary converter building, etc. In connection with
the chlorine plant, there was also constructed a liquefying plant for
chlorine and a sulfur chloride manufacturing and distilling plant.

“The salt storage and treating building was located on ground much
below the cell buildings, which allowed the railroad to enter the
brine building on the top of the salt storage tanks. These tanks were
constructed of concrete. There were seven of these tanks, 34 feet long,
28 feet wide and 20 feet deep having a capacity for storing 4,000 tons
of salt. There would have been 200 tons of salt used per day when the
plant was running at full capacity.

“On the bottom of each tank distributing pipes for dissolving-water
supply were installed, and at the top of each, at the end next to the
building, there was an overflow trough and skimmer board arranged so
that the dissolving-water after flowing up through the salt, overflowed
into this trough and then into a piping system and into either of two
collecting tanks. The system was so arranged that, if the brine was
not fully saturated, it could be passed through another storage tank
containing a deep body of salt. The saturated brine was pumped from the
collecting tanks to any one of 24 treating tanks, each of which had a
capacity of 72,000 gallons.

“The eighth storage bin was used for the storage of soda ash, used in
treating the saturated brine. This was delivered from the bin on the
floor level of the salt building to the soda ash dissolving tanks. From
these tanks it was pumped to any one of the 24 treating tanks. After
the brine was treated and settled, the clear saturated brine was drawn
from the treating tanks through decanting pipes and delivered by pumps
to any one of the four neutralizing tanks. These were located next
to a platform on the level of the car body. This was to provide easy
handling of the hydrochloric acid, which was purchased at first, though
later prepared at the plant from chlorine and hydrogen. The neutralized
brine was delivered from the tanks by a pump to a tank located at a
height above the floor so that the brine would flow by gravity to the
cells in the cell building.

“There were to be two cell buildings, each 541 feet long by 82 feet
wide, and separated by partitions into four sections, containing six
cell circuits of 74 cell units. Each section is a complete unit in
itself, provided with separate gas pump, drying and cooling equipment,
and has a guaranteed capacity of 12.5 tons of chlorine gas per 24 hours.

“Each Nelson electrolytic cell unit consists of a complete fabricated
steel tank 13 by 32 by 80 inches, a perforated steel diaphragm spot
welded to supporting angle irons, plate glass dome, fourteen Acheson
graphite electrodes 2.5 inches in diameter, 12 inches long and fourteen
pieces of graphite 4 by 4 by 17 inches, and various accessories.
(The cell is completely described in _Chemical and Metallurgical
Engineering_, August 1st, 1919.) Each cell is operated by a current
of 340 amperes and 3.8 volts and is guaranteed to produce 60 pounds
of chlorine gas and 65 pounds of caustic soda using not more than 120
pounds of salt per 24 hours, the gas to be at least 95 per cent pure.

[Illustration: FIG. 21.—Interior View of the Cell Building.]

“The salt solution from the cell feed tank, located in the salt
treating building, flows by gravity through a piping system located in
a trench running the length of each cell building, and is delivered to
each cell unit through an automatic feeding device which maintains a
constant liquor level in the cathode compartment.

“The remaining solution percolates from the cathode compartment through
the asbestos diaphragm into the anode compartment and flows from the
end of the cell, containing from 8 to 12 per cent caustic soda, admixed
with 14 to 16 per cent salt, into an open trough and into a pipe in the
trench and through this pipe by gravity to the weak caustic storage
tanks located near the caustic evaporator building.

[Illustration: FIG. 22.—Nelson Electrolytic Cell, showing the Interior
Arrangement of the Cell.]

“The gas piping from the individual cell units to and including the
drying equipment is of chemical stoneware. The piping is so designed
that the gas can be drawn from the cells through the drying equipment
at as near atmospheric pressure as possible in order that the gas can
be kept nearly free of air. When operating, the suction at the pump was
kept at ¹/₂₀ inch or less. The quality of the gas was maintained at a
purity of 98.5 to 99 per cent. The coolers used were very effective,
the gas being cooled to within one degree of the temperature of the
cooling water, no refrigeration being necessary. The drying apparatus
consisted of a stoneware tower of special design containing a large
number of plates, and thus giving a very large acid exposure. There
was practically no loss of vacuum through the drying tower and cooler.
The gas pumping equipment consisted of two hydroturbine pumps using
sulfuric acid as the compressing medium. The acid was cooled by
circulation through a double pipe cooler similar to those used in
refrigerating work. The gas was delivered under about five pounds
pressure into large receiving tanks located just outside the pump
rooms, and from these tanks into steel pipe mains which conducted the
gas to the chemical plant.”

The purity of the gas was such that it was not found necessary to
liquefy it for the preparation of phosgene.


PROPERTIES

Chlorine, at ordinary atmospheric pressure and temperature, is a
greenish yellow gas (giving rise to its name), which has a very
irritating effect upon the membranes of the nose and throat. As
mentioned above, at a pressure of 16.5 atmospheres at 18° C., chlorine
is condensed to a liquid. If the gas is first cooled to 0°, the
pressure required for condensation is decreased to 3.7 atmospheres.
This yellow liquid has a boiling point of -33.6° C. at the ordinary
pressure. If very strongly cooled, chlorine will form a pale yellow
solid (at -102° C.). Chlorine is 2.5 times as heavy as air, one liter
weighing 3.22 grams. 215 volumes of chlorine gas will dissolve in 100
volumes of water at 20°. It is very slightly soluble in hot water or in
a concentrated solution of salt.

Chlorine is a very reactive substance and is found in combination in a
large number of compounds. Among the many reactions which have proved
important from the standpoint of chemical warfare, the following may be
mentioned:

Chlorine reacts with “hypo” (sodium thiosulfate) with the formation of
sodium chloride. Hypo is able to transform a large amount of chlorine,
so that it proved a very satisfactory impregnating agent for the early
cloth masks.

Water reacts with chlorine under certain conditions to form
hypochlorous acid, HOCl. In the presence of ethylene, this forms
ethylene chlorhydrin, which was the basis for the first method of
preparing mustard gas. In the later method, in which sulfur chloride
was used, chlorine was used in the manufacture of the chloride.

Chlorine reacts with carbon monoxide, in the sunlight, or in the
presence of a catalyst, to form phosgene, which is one of the most
valuable of the toxic gases.

Chlorine and acetone react to form chloroacetone, one of the early
lachrymators. The reaction of chlorine with toluene forms benzyl
chloride, an intermediate in the preparation of bromobenzylcyanide.

In a similar way, it is found that the greater number of toxic gases
use chlorine in one phase or another of their preparation. One author
has estimated that 95 per cent of all the gases used may be made
directly or indirectly by the use of chlorine.

Chlorine has been used in connection with ammonia and water vapor
for the production of smoke clouds. The ammonium chloride cloud thus
produced is one of the best for screening purposes. In combination
with silicon or titanium as the tetrachloride it has also been used
extensively for the same purpose.

On the other hand one may feel that, whatever bad reputation chlorine
may have incurred as a poison gas, it has made up for it through the
beneficial applications to which it has lent itself. Among these we may
mention the sterilization of water and of wounds.

In war, where stationary conditions prevail only in a small number
of cases, the use of liquid chlorine for sterilization of water is
impractical. To meet this condition, an ampoule filled with chlorine
water of medium concentration has been developed, which furnishes a
good portable form of chlorine as a sterilizing agent for relatively
small quantities of water.

Chlorine has also been applied, in the form of hypochlorite, to the
sterilization of infected wounds. The preparation of the solution and
the technique of the operation were worked out by Dakin and Carrel.
This innovation in war surgery has decreased enormously the percentage
of deaths from infected wounds.




CHAPTER VI

PHOSGENE


The first cloud attack, in which pure chlorine was used, was very
effective, but only because the troops attacked with it were entirely
unprotected. Later, in spite of the varied methods of attack, the
results were less and less promising, due to the increased protection
of the men and also to the gas discipline which was gradually being
developed. During this time the Allies had started their gas attacks
(Sept., 1915), and it soon became evident that, if Germany was to keep
her supremacy in gas warfare, new gases or new tactics would have to be
introduced.

The second poison gas was used in December, 1915, when about 20-25
per cent of phosgene was mixed with the chlorine. Here again the
Germans made use of an industry already established. Phosgene is used
commercially in the preparation of certain dyestuffs, especially methyl
violet, and was manufactured before and during the war by the Bayer
Company and the Badische Anilin und Soda Fabrik.

Phosgene can not be used alone in gas cylinders because of its high
boiling point (8° C.). While this is considerably below ordinary
temperatures, especially during the summer months, the rate of
evaporation is so slow that a cloud attack could never be made with it
alone. However, when a mixture of 25 per cent phosgene and 75 per cent
chlorine, or 50 per cent phosgene and 50 per cent chlorine is used in
warm weather there is no difficulty in carrying out gas attacks from
cylinders. At the same time the percentage of phosgene in the mixture
is sufficiently high to secure the advantages which it possesses. These
advantages are at least three:

(_a_) Phosgene is more toxic than chlorine. It requires 2.5 milligrams
per liter of chlorine to kill a dog on an exposure of 30 minutes, but
0.3 milligram of phosgene will have the same effect. This of course
means that a cloud of phosgene containing one-eighth (by weight) of the
concentration of a chlorine cloud will have the same lethal properties.

(_b_) Phosgene is much less reactive than chlorine, so that the matter
of protection becomes more difficult. Fortunately, word was received
by the British of the intended first use of phosgene against them
and consequently they were able to add hexamethylenetetramine to the
impregnating solution used in the cloth masks.

(_c_) The third, and a very important, factor in the use of phosgene is
the so-called delayed effect. In low concentrations, men may breathe
phosgene for some time with apparently no ill effects. Ten or twelve
hours later, or perhaps earlier if they attempt any work, the men
become casualties.

Pure phosgene has been used in projector attacks (described in Chapter
II). The substance has also been used in large quantities in shell;
the Germans also used shell containing mixtures with superpalite
(trichloromethyl chloroformate) or sneezing gas (diphenylchloroarsine).


MANUFACTURE

Phosgene was first prepared by John Davy in 1812, by exposing a
mixture of equal volumes of carbon monoxide and chlorine to sunlight;
Davy coined the name “phosgene” from the part played by light in the
reaction. While phosgene may be prepared in the laboratory by a number
of other reactions, it was quite apparent that the first mentioned
reaction is the most economical of these for large scale production.
The reaction is a delicate one, however, and its application required
extended investigation.

The United States was fortunate in that, for some months previous to
the war, the Oldbury Electrochemical Company had been working on the
utilization of their waste carbon monoxide in making phosgene. The
results of these investigations were given to the government and aided
considerably in the early work on phosgene at the Edgewood plant.

[Illustration: FIG. 23.—Furnace for Generating Carbon Monoxide.]

Of the raw materials necessary for the manufacture of phosgene, the
chlorine was provided, at first by purchase from private plants, but
later through the Edgewood chlorine plant. After a sufficient supply of
chlorine was assured the next question was how to obtain an adequate
supply of carbon monoxide. A method for this gas had not been developed
on a large scale because it had never been necessary to make any
considerable quantity of it. The French and English passed oxygen up
through a gas producer filled with coke; the oxygen combines with the
carbon, giving carbon monoxide. The oxygen was obtained from liquid
air, for which a Claude liquid air machine may be used. The difficulty
with this method of preparing carbon monoxide was that the amount of
heat generated was so great that the life of the generators was short.
Our engineers conceived the idea of using a mixture of carbon dioxide
and oxygen. The union of carbon dioxide with carbon to form carbon
monoxide is a reaction in which heat is absorbed. Therefore by using
the mixture of the two gases, the heat of the one reaction was absorbed
by the second reaction. In this way a very definite temperature could
be maintained, and the production of carbon monoxide was greatly
increased.

[Illustration: FIG. 24.—Catalyzer Boxes Used in the Manufacture of
Phosgene.]

Carbon dioxide was prepared by the combustion of coke. The gas was
washed and then passed into a solution of potassium carbonate. Upon
heating, this evolved carbon dioxide.

Phosgene was then prepared by passing the mixture of carbon monoxide
and chlorine into catalyzer boxes (8 feet long, 2 feet 9 inches deep
and 11 inches wide), which are made of iron, lined with graphite and
filled with a porous form of carbon. Two sets of these boxes were used.
In the first the reaction proceeds at room temperature, and is about
80 per cent complete. The second set of boxes were kept immersed in
tanks filled with hot water, and there the reaction is completed.

The resulting phosgene was dried with sulfuric acid and then condensed
by passing it through lead pipes surrounded by refrigerated brine.

The Germans prepared their phosgene by means of a prepared charcoal
(wood or animal). Carbon monoxide was manufactured by passing carbon
dioxide over wood charcoal contained in gas-fired muffles and was
washed by passing through sodium hydroxide. This was mixed with
chlorine and the mixture passed downward through a layer of about 20
cm. of prepared charcoal contained in a cast iron vessel 80 cm. in
diameter and 80 cm. deep. By regulating the mixture so that there was
a slight excess of carbon monoxide, the phosgene was obtained with
only one-quarter of one per cent free chlorine. The charcoal (wood)
was prepared by washing with hydrochloric and other acids until free
from soluble ash; it was then washed with water and dried in vacuum.
The size of the granules was about one-quarter inch mesh. Their life
averaged about six months.


PROPERTIES

Phosgene is a colorless gas at room temperatures, but becomes a liquid
at 8°. The odor of phosgene is suggestive of green corn or musty hay.
One liter of phosgene vapor weighs 4.4 grams (chlorine weights 3.22
grams). At 0° C., the liquid is heavier than water, having a specific
gravity of 1.432. At 25°, the vapor exerts a pressure of about 25
pounds per square inch. Phosgene is absorbed by solid materials,
such as pumice stone and celite. Pumice stone absorbs more than its
own weight of phosgene. Thus 5.7 grams of pumice absorbed 7.4 grams
phosgene, which completely evaporated in 60 minutes. German shell
have been found which contained such a mixture (phosgene and pumice
stone). While the apparent reason for their use is to prevent the rapid
evaporation of the phosgene, it is a question whether such is the case,
for a greater surface is really present in the case of pumice stone
than where the phosgene is simply on the ground. Phosgene is slowly
decomposed by cold water, rapidly by hot water. This reaction is
important because there is always moisture in the air, which would tend
to lower the concentration of the gas.

Phosgene is absorbed and decomposed by hexamethylenetetramine
(urotropine). This reaction furnished the basis of the first protection
used by the British. Later the catalytic decomposition of phosgene
into carbon dioxide and hydrochloric acid by the charcoal in the mask
furnished protection.

For most purposes a trace of chlorine in phosgene is not a
disadvantage; for example, when it is used in cylinders or projectors.
Under certain conditions, as when used as a solvent for sneezing gas,
the presence of chlorine must be avoided, since it reacts with the
substance in solution, usually producing a harmless material. Chlorine
may be removed from phosgene by passing the mixture through cotton seed
oil.


PROTECTION

It was mentioned above that hexamethylenetetramine (urotropine) was
used in the early pads (black veil and similar masks) and flannel
helmets. This was found to be satisfactory against chlorine and
phosgene, in the concentrations usually found during a cylinder attack.
The mixture used consisted of urotropine, sodium thiosulfate (“hypo”),
sodium carbonate and glycerine. The glycerine tended to keep the pads
moist, while the other chemicals acted as protective agents against the
mixture of phosgene and chlorine.

The introduction of the Standard Box Respirator with its charcoal-soda
lime filling increased very materially the protection against phosgene.
In this filling, the charcoal both absorbs the phosgene and catalyzes
the reaction with the moisture of the air with which the phosgene is
mixed, to form hydrochloric acid and carbon dioxide. Soda-lime absorbs
phosgene but does not catalyze its decomposition. This shows the
advantage of the mixture, since the hydrochloric acid, which is formed
through the action of the charcoal, is absorbed by the soda-lime.
Experiments seem to indicate that it does not matter which material
is placed in the bottom of the canister, but that an intimate mixture
is the best arrangement. Using a concentration of 5,000 parts per
million (20.2 mg. per liter) a type _H_ canister (see page 217) will
give complete protection for about 40 minutes; when the air-gas mixture
passes at the rate of 16 liters per minute the efficiency or life of a
canister increases with a decrease in temperature, as is seen in the
following table (the concentration was 5,000 parts per million, the
rate of flow 16 liters per minute)

    Temperature       Efficiency
       ° C.        (Time in minutes)
        -10               223
          0               172
         10               146
         20               130
         30               125
         40                99

From these figures it is seen that at -10° C. the life is about 50 per
cent greater than at summer temperature. As would be expected the life
of a canister is shortened by increasing the concentration of phosgene
in the phosgene air mixture. This is illustrated by the following
figures:

    Concentration          Life
       p.p.m.        (Time in minutes)

        5,000               177
       10,000               112
       15,000                72
       20,000                58
       25,000                25

    (25,000 p.p.m. is equal to 101.1 mg. per liter.)

There is rather a definite relation between the concentration of the
gas and the life of a canister at any given rate of flow. Many of these
relations have been expressed by formulas of which the following is
typical. At 32 liters per minute flow, =C⁰˙⁹ × Tb = 101,840=, in which
=C= is the concentration and =T= the time.


SHELL FILLING

The empty shell, after inspection, are loaded on trucks, together with
the appropriate number of “boosters,” which screw into the top of the
shell and thereby close them. The trucks are run by an electric storage
battery locomotive to the filling unit. The shell are transferred by
hand to a conveyor, which carries the shell slowly through a cold room.
During this passage of about 30 minutes, the shell are cooled to about
0° F. The cooled shell are transferred to shell trucks, each truck
carrying 6 shell. These trucks are drawn through the filling tunnel by
means of a chain haul operated by an air motor to the filling machine.
Here the liquid phosgene is run into the shell by automatic machines,
so arranged that the 6 shell are at the same time automatically filled
to a constant void. The truck then carries the filled shell forward a
few feet to a small window, at which point the boosters are inserted
into the nose of the shell by hand. The final closing of the shell is
then effected by motors operated by compressed air. The filling and
closing machines are all operated by workmen on the outside of the
filling tunnel.

[Illustration: FIG. 25.—Filling Livens’ Drums with Phosgene.]

The filled shell are conveyed to the shell dump, where they are stored
for 24 hours, nose down on skids, in order to test for leaks.


TACTICAL USE

Phosgene was first used in cloud attacks in December, 1915. These
attacks continued for about nine months and were then gradually
replaced, to a large extent, by gas shell attacks. Phosgene was
first found in German projectiles in November, 1916. These shell
were known as the D-shell. Besides pure phosgene, mixtures of
phosgene and chloropicrin, phosgene and superpalite, and phosgene and
diphenylchloroarsine have been found.

[Illustration: FIG. 26.—Interior of a Shell Dump.]

The English introduced the use of projectors in the Spring of 1917.
They have a decided advantage over shell in that they hold a larger
volume of gas and readily lend themselves to surprise attacks. As the
Germans say, “the projector combines the advantages of gas clouds and
gas shell. The density is equal to that of gas clouds and the surprise
effect of shell fire is also obtained.”

Toward the close of the war, the Germans made use of a mixture of
phosgene and pumice stone. A captured projector contained about
13 pounds of phosgene and 5½ pounds of pumice. There seems to be
some question as to the value of such a procedure. Lower initial
concentrations are secured; this is due, in part of course, to the
smaller volume of phosgene in the shell containing pumice. Pumice does
seem to keep the booster from scattering the phosgene so high into the
air, and at the same time does not prevent the phosgene from being
liberated in a gaseous condition. This would indicate that pumice gives
a more even and uniform dispersion and a more economical use of the gas
actually used.

Owing to its non-persistent nature (the odor disappears in from one and
a half to two hours) and to its general properties, phosgene really
forms an ideal gas to produce casualties.


ACTION ON MAN

Phosgene acts both as a direct poison and as a strong lung irritant,
causing rapid filling of the lungs with liquid. The majority of deaths
are ascribed to the filling up of the lungs and consequently to the
suffocation of the patients through lack of air. This filling up of
the lungs is greatly hastened by exercise. Accordingly, all rules
for the treatment of patients gassed with phosgene require that they
immediately lie down and remain in that position. They are not even
allowed to walk to a dressing station. The necessity of absolute quiet
for gassed patients undoubtedly partly accounts for the later habit of
carrying out a prolonged bombardment after a heavy phosgene gas attack.
The high explosive causes confusion, forcing the men to move about more
or less and practically prevents the evacuation of the gassed. In the
early days of phosgene the death rate was unduly high because of lack
of knowledge of this action of the gas. Due to the decreased lung area
for oxygenizing the air, a fearful burden is thrown on the heart, and
accordingly, those with a heart at all weak are apt to expire suddenly
when exercising after being gassed.

As an illustration of the delayed action of phosgene, a large scale
raid made by one of the American divisions during its training is
highly illuminating.

This division decided to make a raid on enemy trenches which were
situated on the opposite slope of a hill across a small valley. Up
stream from both of the lines of trenches was a French village in the
hands of the Germans. When the attack was launched the wind was blowing
probably six or seven miles per hour directly down stream from the
village, i.e., directly toward the trenches to be attacked. The usual
high explosive box barrage was put around the trenches it was intended
to capture.

Three hundred Americans made the attack. During the attack a little
more than three tons of liquid phosgene was thrown into the village in
75- and 155-millimeter shells. The nearest edge of the village shelled
with phosgene was less than 700 yards from the nearest attacking
troops. None of the troops noticed the smell of phosgene, although the
fumes from high explosive were so bad that a few of the men adjusted
their respirators. The attack was made about 3 A.M., the men remaining
about 45 minutes in the vicinity of the German trenches. The men then
returned to their billets, some five or six kilometers back of the
line. Soon after arriving there, that is in the neighborhood of 9
A.M., the men began to drop, and it was soon discovered that they were
suffering from gas poisoning. Out of the 300 men making the attack 236
were gassed, four or five of whom died.

The Medical Department was exceedingly prompt and vigorous in the
treatment of these cases, which probably accounted for the very low
mortality.

This is one of the most interesting cases of the delayed action that
may occur in gassing from phosgene. Here the concentration was slight
and there is no doubt its effectiveness was largely due to the severe
exercise taken by the men during and after the gassing.

It should be remarked in closing that while gas officers were not
consulted in the planning of this attack, a general order was shortly
thereafter issued requiring that gas officers be consulted whenever gas
was to be used.




CHAPTER VII

LACHRYMATORS


Without question the eyes are the most sensitive part of the body so
far as chemical warfare is concerned. Lachrymators are substances which
affect the eyes, causing involuntary weeping. These substances can
produce an intolerable atmosphere in concentrations one thousand times
as dilute as that required for the most effective lethal agent. The
great military value of these gases has already been mentioned and will
be discussed more fully later.

There are a number of compounds which have some value as lachrymators,
though a few are very much better than all the others. Practically all
of them have no lethal properties in the concentrations in which they
are efficient lachrymators, though we must not lose sight of the fact
that many of them have a high lethal value if the concentration is of
the order of the usual poison gas. The lachrymators are used alone when
it is desired to neutralize a given territory or simply to harrass the
enemy. At other times they are used with lethal gases to force the
immediate or to prolong the wearing of the mask.

A large number of the lachrymators contain bromine. In order to
maintain the gas warfare requirements, it was early decided that the
bromine supply would have to be considerably increased. The most
favorable source of bromine is the subterranean basin found in the
vicinity of Midland, Michigan. Because of the extensive experience of
the Dow Chemical Co. in all matters pertaining to the production of
bromine, they were given charge of the sinking of seventeen government
wells, capable of producing 650,000 pounds of bromine per year. While
the plant was not operated during the War, it was later operated to
complete a contract for 500,000 pounds of bromine salts. They will be
held as a future war asset of the United States.

The principal lachrymators used during the War were:

    Bromoacetone,
    Bromomethylethylketone,
    Benzyl bromide,
    Ethyl iodoacetate,
    Bromobenzyl cyanide,
    Phenyl carbylamine chloride.

Chloropicrin is something of a lachrymator, but it has greater value as
a toxic gas.


HALOGENATED KETONES

One of the earliest lachrymators used was bromoacetone. Because of
the difficulty of obtaining pure material, the commercial product,
containing considerable dibromoacetone and probably higher halogenated
bodies, was used. The presence of these higher bromine derivatives
considerably decreased its efficiency as a lachrymator. The preparation
of bromoacetone involved the loss of considerable bromine in the form
of hydrobromic acid. This led the French to study various methods of
preparation, and they finally obtained a product containing 80 per
cent bromoacetone and 20 per cent chloroacetone, which they called
“martonite.” As the war progressed, acetone became scarce, and the
Germans substituted methylethylketone, for which there was little use
in other war activities. This led to the French “homomartonite.”

Various other halogen derivatives of ketones have been studied in the
laboratory, but none have proven of as great value as bromoacetone,
either from the standpoint of toxicity or lachrymatory power.

_Bromoacetone_ may be prepared by the action of bromine (liquid or
vapor) upon acetone (with or without a solvent). Aqueous solutions of
acetone, or potassium bromide solutions of bromine, have also been used.

Pure bromoacetone is a water clear liquid. There are great differences
in the properties ascribed to this body by different investigators.
This probably is due to the fact that the monobromo derivative is mixed
with those containing two or more atoms of bromine. A sample boiling at
126-127° and melting at -54°, had a specific gravity of 1.631 at 0°. It
has a vapor pressure of 9 mm. of mercury at 20°.

While bromoacetone is a good lachrymator, it possesses the disadvantage
that it is not very stable. Special shell linings are necessary, and
even then the material may be decomposed before the shell is fired.
The Germans used a lead-lined shell, while considerable work has been
carried out in this country with enamel lined shell. Glass lined shell
may also be used. It is interesting to note that, while bromoacetone
decomposes upon standing in the shell, it is stable upon detonation.
No decomposition products are found after the explosion, and even
unchanged liquid is found in the shell. It may be considered as having
a low persistency, since the odor entirely disappears from the surface
of the ground in twenty-four hours.

Bromoacetone was also used by the Germans in glass hand grenades
(Hand-a-Stink Kugel) and later in metal grenades. The metal grenades
weighed about two pounds and contained about a pound and a half of the
liquid.

_Martonite_ was prepared by the French in an attempt more completely
to utilize the bromine in the preparation of bromoacetone. They
regenerated the bromine by the use of sodium chlorate:

    NaClO₃ + 6HBr = NaCl + 3Br₂ + 3H₂O

In practice sulfuric acid is used with the sodium chlorate, so that the
final products are sodium acid sulfate and a mixture of 20 per cent
chloroacetone and 80 per cent bromoacetone, according to the reaction:

    5(CH₃)₂CO + 4Br + H₂SO₄ + NaClO₃ =

    4CH₂BrCOCH₃ + CH₂ClCO CH₃ + NaHSO₄ + 3H₂O.

This product is equally as effective as bromoacetone alone and is very
much cheaper to manufacture. In general its properties resemble very
closely those of bromoacetone.


GERMAN MANUFACTURE OF BROMOACETONE AND BROMOMETHYLETHYL KETONE[17]

These two products were prepared by identical methods. About two-thirds
of the product produced by the factory was prepared from methylethyl
ketone which was obtained from the product resulting from the
distillation of wood. The method employed was to treat an aqueous
solution of potassium or sodium chlorate with acetone or methylethyl
ketone, and then add slowly the required amount of bromine. The
equation for the reaction in the case of acetone is as follows:

    CH₃COCH₃ + Br₂ = CH₂BrCOCH₃ + HBr

Ten kg.-mols of acetone or methylethyl ketone were used in a single
operation. About 10 per cent excess of chlorate over that required
to oxidize the hydrobromic acid formed in the reaction was used. The
relation between the water and the ketone was in the proportion of 2
parts by weight of the former to 1 part by weight of the latter. For 1
kg.-mol. wt. of the ketone, 10 per cent excess over 1 kg. atomic-weight
of bromine was used.

[Footnote 17: Norris, J. _Ind. Eng. Chem._, 11, 828 (1919).]

The reaction was carried out either in earthenware vessels or in
iron kettles lined with earthenware. The kettles were furnished with
a stirrer made of wood, and varied in capacity from 4,000 to 5,000
liters. They were set in wooden tanks and cooled by circulating water.
The chlorate was first dissolved in the water and then the ketone
added. Into this mixture the bromine was allowed to run slowly while
the solution was stirred and kept at a temperature of from 30° to 40°
C. The time required for the addition of the bromine was about 48 hrs.
When the reaction was complete, the oil was drawn off into an iron
vessel and stirred with magnesium oxide in the presence of a small
amount of water in order to neutralize the free acid. It was then
separated and dried with calcium chloride. At this point a sample of
the material was taken and tested. The product was distilled to tell
how much of it boiled over below 130° when methylethyl ketone had been
used. If less than 10 per cent distilled over, the bromination was
considered to be satisfactory. If, however, a larger percentage of low
boiling material was obtained, the product was submitted to further
bromination. The material obtained in this way was found on analysis to
contain slightly less than the theoretical amount of monobromoketone.

It was finally transferred by suction or by pressure into tank-wagons.
At first lead-lined tanks were used, but later it was found that tanks
made of iron could be substituted. In order to take care of the small
amount of hydrobromic acid, which is slowly formed, a small amount of
magnesium oxide was added to the material. The amount of the oxide used
was approximately in the proportion of 1 part to 1000 parts of ketone.
When the magnesium oxide was used, it was found that the bromoketone
kept without appreciable decomposition for about 2 months. The yield of
the product from 580 kg. of acetone (10 kg.-mol. wts.) was 1,100 kg.
The yield from 720 kg. of methylethyl ketone (10 kg.-mol. wts.) was
1,250 kg.


HALOGENATED ESTERS

The use of ethyl iodoacetate was advocated at a time when the price of
bromine seemed prohibitive. Because of the relative price of bromine
and iodine under ordinary conditions, it is not likely that it would
be commonly used. However, it is an efficient lachrymator and is more
stable than the halogenated ketones, so that on a smaller scale it
might be advisable to use it.

It is prepared by the reaction of sodium iodide upon an alcoholic
solution of ethyl chloroacetate. It is a colorless oil, boiling at
178-180° C. (69° C. at 12 mm.) and having a density of about 1.8. It is
very much less volatile than bromoacetone, having a vapor pressure of
0.54 mm. of mercury at 20° C. Ethyl iodoacetate is about one-third as
toxic as bromoacetone, but has about the same lachrymatory value.


AROMATIC HALIDES

“Benzyl bromide” was also used during the early part of the war,
usually mixed with bromoacetone. The material was not pure benzyl
bromide, but the reaction product of bromine upon xylene, and should
perhaps be referred to as “xylyl bromide.”

Pure benzyl bromide is a colorless liquid, boiling at 198-199° C., and
having an odor reminiscent of water cress and then of mustard oil.
The war gas is probably a mixture of mono- and dibromo derivatives,
boiling at 210-220° C., and having a density at 20° C. of 1.3. The
mixture of benzyl and xylyl bromides used by the Germans was known as
“T-Stoff,” while the mixture of 88 per cent xylyl bromide and 12 per
cent bromoacetone was called “Green T-Stoff.”

As in the case of the halogenated acetones, it is necessary to use lead
lined shell for these compounds. Enamel and glass lined shell may be
used and give good results. While they are difficult of manufacture,
satisfactory methods were being developed at the close of the war.

“T-Stoff” may be detected by the nose in concentrations of one part in
one hundred million of air, and will cause profuse lachrymation with
one part in a million. It is a highly persistent material and may last,
under favorable circumstances, for several days. While it is relatively
non-toxic, French troops were rendered unconscious by it during certain
bombardments in the Argonne in the summer of 1915.

A number of derivatives of the benzyl halides have been tested and
some have proven to be very good lachrymators. The difficulty of their
preparation on a commercial scale has made it inadvisable to use them,
and especially inasmuch as bromobenzyl cyanide has proven to be such a
valuable compound.


BROMOBENZYL CYANIDE

Bromobenzyl cyanide is, chemically, α-bromo-α-tolunitrile, or
phenyl-bromo-acetonitrile, C₆H₅CHBrCN. It is prepared by the action of
bromine upon benzyl cyanide.

Benzyl cyanide is prepared by the action of sodium cyanide upon a
mixture of equal parts of 95 per cent alcohol and benzyl chloride. The
benzyl chloride in turn is obtained by the chlorination of toluene at
100°. The material must be fairly pure in order that the benzyl cyanide
reaction may proceed smoothly. The cyanide is subjected to a fractional
distillation and that part boiling within 3 degrees (the pure product
boils at 231.7° C.) is treated with bromine vapor mixed with air.
It has been found necessary to catalyze the reaction by sunlight,
artificial light or the addition of a small amount of bromobenzyl
cyanide.

The product obtained from this reaction, if the hydrobromic acid which
is formed is carefully removed by a stream of air, is sufficiently pure
for use as a lachrymator. It melts from 16 to 22° C., while the pure
product melts at 29° C. It cannot be distilled, even in a high vacuum.
It has a low vapor pressure and thus is a highly persistent lachrymator.

Bromobenzyl cyanide is about as toxic as chlorine, but is many times
as effective a lachrymator as any of the halogenated ketones or
aromatic halides studied. It has a pleasant odor and produces a burning
sensation on the mucous membrane.

Like the other halogen containing compounds, lead or enamel lined shell
are necessary for preserving the material any length of time. In all of
this work the United States was at a very marked disadvantage. While
the Allies and the Germans could prepare substances of this nature and
use them in shell within a month, the United States was sure that shell
filled at Edgewood Arsenal probably would not be fired within three
months. This means that much greater precautions were necessary, both
as to the nature of the shell lining and as to the purity of the “war
gas.”

The question of protection against lachrymatory gases was never a
serious one. During the first part of the war this was amply supplied
by goggles. Later, when the Standard Respirator was introduced, it was
found that ample protection was afforded against all the lachrymators.
Their principal value is against unprotected troops and in causing men
to wear their masks for long periods of time.

The comparative value of the various lachrymators mentioned above is
shown in the following table:

    Bromobenzyl cyanide     0.0003
    Martonite               0.0012
    Ethyl iodoacetate       0.0014
    Bromoacetone            0.0015
    Xylyl bromide           0.0018
    Benzyl bromide          0.0040
    Bromo ketone            0.011
    Choroacetone            0.018
    Chloropicrin            0.019

The figures give the concentration (milligram per liter of air)
necessary to produce lachrymation. The method used in obtaining these
figures is given in Chapter XXI.




CHAPTER VIII

CHLOROPICRIN


During the spring of 1917, strange reports came from the Italian front
that the Germans were using a new war gas. This gas, while it did
not seem to be very poisonous, had the combined property of being a
lachrymator and also of causing vomiting. Large number of casualties
resulted through the men being forced to remove their masks in an
atmosphere filled with lethal gases. The gas had the additional and
serious disadvantage of being a very difficult one to remove completely
in the gas mask. The first American masks were very good when chlorine
or phosgene was considered but were of no value when chloropicrin was
used.

One of the interesting facts of chemical warfare is that few if any
new substances were discovered and utilized during the three years of
this form of fighting. Chlorine and phosgene were well known compounds.
And likewise, chloropicrin was an old friend of the organic chemist.
So much so, indeed, that several organic laboratories prepared the
compound in their elementary courses.

Chloropicrin was first prepared by the English chemist, Stenhouse,
in 1848, by the action of bleaching powder upon a solution of picric
acid. This was followed by a careful study of its physical and chemical
properties, few of which have any connection with its use as a poison
gas. The use of picric acid as an explosive made it very desirable that
other raw materials should be used. Chloroform, which is the ideal
source theoretically (since chloropicrin is nitro-chloroform, Cl₃CNO₂),
gave very poor yields. While it may be prepared from acetone, in fair
yields, acetone was about as valuable during the war as was picric
acid. Practically all the chloropicrin used was prepared from this acid
as the raw material.


MANUFACTURE

In the manufacture of chloropicrin the laboratory method was adopted.
This consisted simply in passing live steam through a mixture of picric
acid and bleaching powder. The resulting chloropicrin passes out of the
still with the steam. There was a question at first whether a steam
jacketed reaction vessel should be used, and whether stirrers should be
introduced. Both types were tested, of which the simpler form, without
steam jacket or stirrer, proved the more efficient.

[Illustration: FIG. 27.—Interior of Chloropicrin Plant.]

The early work was undertaken at the plant of the American Synthetic
Color Company at Stamford, Connecticut. Later a large plant was
constructed at Edgewood Arsenal. At the latter place ten stills, 8 by
18 feet, were erected, together with the necessary accessory equipment.
The following method of operation was used:

The bleach is mixed with water and stirred until a cream is formed.
This cream is then pumped into the still along with a solution of
calcium picrate (picric acid neutralized with lime). When the current
of live steam is admitted at the bottom of the still, the temperature
gradually rises, until at 85° C. the reaction begins. The chloropicrin
passes over with the steam and is condensed. Upon standing, the
chloropicrin settles out, and may be drawn off and is then ready for
filling into the shell. The yield was about 1.6 times the weight of
picric acid used.


PROPERTIES

Chloropicrin is a colorless oil, which is insoluble in water, and which
can be removed from the reaction by distillation with steam. It boils
at 112° C. and will solidify at -69° C. At room temperature it has a
density of 1.69 and is thus higher than chloroform (1.5) or carbon
tetrachloride (1.59). At room temperature it has a vapor pressure of
24 mm. of mercury. It thus lies, in persistency, between such gases as
phosgene on the one hand, and mustard gas on the other, but so much
closer to phosgene that it is placed in the phosgene group.

Chloropicrin is a very stable compound and is not decomposed by water,
acids or dilute alkalies. The reaction with potassium or sodium
sulfite, in which all the chlorine is found as potassium or sodium
chloride, has been used as an analytical method for its quantitative
determination. The qualitative test usually used consists in passing
the gas-air mixture through a heated quartz tube, which liberates free
chlorine. The chlorine may be detected by passing through a potassium
iodide solution containing starch, or by the use of a heated copper
wire gauze, when the characteristic green color is obtained.

An interesting physiological test has also been developed. The eye
has been found to be very sensitive to chloropicrin. The gas affects
the eye in such a way that its closing is practically involuntary. A
measurable time elapses between the instant of exposure and the time
when the eye closes. Below 1 or 2 parts per million, the average eye
withstands the gas without being closed, though considerable blinking
may be caused. Above 25 parts, the reaction is so rapid as to render
proper timing out of the question. But with concentrations between 2
and 25 parts, the subject will have an overpowering impulse to close
his eye within 3 to 30 seconds. The time may be recorded by a stop
watch and from the values thus determined a calibration curve may be
plotted, using the concentration in parts per million and the time to
zero eye reaction. Typical figures are given below. It will be noted
that different individuals will vary in their sensitivity, though the
order is the same.

    +--------+---------+---------+
    | Conc.  |    A    |    B    |
    | p.p.m. | Seconds | Seconds |
    +--------+---------+---------+
    |  20.0  |   4.0   |   5.0   |
    |  15.0  |   5.4   |   5.4   |
    |  10.0  |   7.5   |   7.5   |
    |   7.5  |   9.0   |  10.0   |
    |   5.0  |  13.0   |  15.0   |
    |   2.5  |  18.0   |  30.0   |
    +--------+---------+---------+

[Illustration: FIG. 28.—Calibration Curve of Eyes for Chloropicrin.]


PROTECTION

Because of the stability of chloropicrin, the question of protection
resolves itself into finding an absorbent which is very efficient in
removing the gas from air mixtures. Fortunately such an agent was found
in the activated charcoal used in the American gas mask. The removal of
the gas appears to take place in two stages. In the first, the gas is
adsorbed in such a way that the long-continued passage of air does not
remove it. In the second, the gas is absorbed, and this, really excess
gas, is removed by pure air passing over the charcoal. The relation of
these two factors has an important bearing on the quality of charcoal
to be used in gas masks. It appears that up to a certain point an
increase of the quality is desirable: beyond this, it is of doubtful
value.

Unlike phosgene, chloropicrin is absorbed equally well at all
temperatures. Moisture on the other hand has a very decided effect.
It appears that charcoal absorbs roughly equivalent weights of
chloropicrin and of water; the presence of water in the charcoal thus
displaces an approximately equal amount of chloropicrin.

In the study of canisters it has been found that the efficiency
time is approximately inversely proportional to the concentration.
Formulas have been calculated to express the relation existing between
concentration and life of the canister, and also between the rate of
flow of the gas and the life.

While water seems to have a decidedly marked effect upon the life of a
canister, this is not true of other gases, and the efficiency of the
canister for each gas is not decreased when used in a binary mixture.


TACTICAL USES

Because of the high boiling point of chloropicrin it can only be used
in shell. The German shell usually contained a mixture of superpalite
(trichloromethyl chloroformate) and chloropicrin, the relative
proportions being about 75 to 25. These were called Green Cross Shell,
from the peculiar marking on the outside of the shell. Mixtures of
phosgene and chloropicrin (50-50) have also been used.

The Allies have used a mixture of 80 per cent chloropicrin and 20 per
cent stannic chloride (so-called N. C.). This mixture combines the
advantages of a gas shell with those of a smoke shell, since the
percentage of stannic chloride is sufficiently high to form a very good
cloud. In addition to this, it is believed that the presence of the
chloride increases the rate of evaporation of the chloropicrin. It has
been claimed that the chloride decreases the amount of decomposition
of the chloropicrin upon the bursting of the shell, but careful
experiments appear to show that this decomposition is negligible and
that the stannic chloride plays no part in it. This mixture was being
abandoned at the close of the war.

This N. C. mixture has also been used in Liven’s projectors and in
hand grenades. The material is particularly fitted for hand grenades,
owing to the low vapor pressure of the chloropicrin, and the consequent
absence of pressures even on warm days. As a matter of fact, it was the
only filling used for this purpose, though later the stannic chloride
was changed, owing to the shortage of tin, to a mixture of silicon and
titanium chlorides.

While chloropicrin is sufficiently volatile to keep the strata of air
above it thoroughly poisonous, it is still persistent enough to be
dangerous after five or six hours.




CHAPTER IX

DICHLOROETHYLSULFIDE

“MUSTARD GAS”


The early idea of gas warfare was that a material, to be of value as a
war gas, should have a relatively high vapor pressure. This would, of
course, provide a concentration sufficiently high to cause casualties
through inhalation of the gas-ladened air. The introduction of
“mustard gas” (dichloroethylsulfide) was probably the greatest single
development of gas warfare, in that it marked a departure from this
early idea, for mustard gas is a liquid boiling at about 220° C., and
having a very low vapor pressure. But mustard gas has, in addition,
a characteristic property which, combined with its high persistency,
makes it the most valuable war gas known at the present time. This
peculiar property is its blistering effect upon the skin. Very low
concentrations of vapor are capable of “burning” the skin and of
producing casualties which require from three weeks to three months for
recovery. The combination of these properties removed the necessity for
a surprise attack, or the building up of a high concentration in the
first few bursts of fire. A few shell, fired over a given area, were
sufficient to produce casualties hours and even days afterwards.

Mustard gas, chemically, is dichloroethylsulfide (ClCH₂CH₂)₂S. The name
originated with the British Tommy because the crude material first
used by the Germans was suggestive of mustard or garlic. Various other
names were given the compound, such as “Yellow Cross,” from the shell
markings of the Germans; “Yperite,” a name used by the French, because
the compound was first used at Ypres; and “blistering gas,” because of
its peculiar effect upon the skin.


HISTORICAL

It seems probable that an impure form of mustard gas was obtained
by Richie (1854) by the action of chlorine upon ethyl sulfide. The
substance was first described by Guthrie (1860), who recognized its
peculiar and powerful physiological effects. It is interesting in this
connection to note that Guthrie studied the effect of ethylene upon
the sulfur chlorides, since this reaction was the basis of the method
finally adopted by the Allies.

The first careful investigation of mustard gas, which was then only
known as dichloroethylsulfide, was carried out by Victor Meyer (1886).
Meyer used the reaction between ethylene chlorhydrin and sodium
sulfide, with the subsequent treatment with hydrochloric acid. All the
German mustard gas used during 1917 and 1918 was apparently made by
the use of these reactions, and all the early experimental work of the
Allies was in this direction.

Mustard gas was first used as an offensive agent by the Germans on
July 12-13, 1917, at Ypres. According to an English report, the
physiological properties of mustard gas had been tested by them during
the summer of 1916. The Anti-Gas Department put forward the suggestion
that it should be used for chemical warfare, but at that time its
adoption was not approved. This fact enabled the English to quickly and
correctly identify the contents of the first Yellow Cross dud received.
It is not true, as reported by the Germans, that the material was first
diagnosed as diethylsulfide.

The tactical value of mustard gas was immediately recognized by the
Germans and they used tremendous quantities of it. During ten days
of the Fall of 1917, it is calculated that over 1,000,000 shell were
fired, containing about 2,500 tons of mustard gas. Zanetti states that
the British gas casualties during the month following the introduction
of mustard gas were almost as numerous as all gas casualties incurred
during the previous years of the war. Pope says that the effects of
mustard gas as a military weapon were indeed so devastating that by the
early autumn of 1917 the technical advisers of the British, French,
and American Governments were occupied upon large scale installations
for the manufacture of this material.


PREPARATION AND MANUFACTURE

The analysis of the first German shell indicated that the mustard gas
contained therein had been prepared by the method published by Victor
Meyer (1886) and later used by Clark (1912) in England. It was natural,
therefore, that attention should be turned to the large scale operation
of this method.

The following operations are involved: Ethylene is prepared by the
dehydration of ethyl alcohol. The interaction of hypochlorous acid
(HClO) and ethylene yields ethylene chlorhydrin, ClCH₂CH₂OH. When
this is treated with sodium sulfide, dihydroxyethyl sulfide forms,
which, heated with hydrochloric acid, yields dichloroethyl sulfide.
Chemically, the reactions may be written as follows:

               CH₃CH₂OH = CH₂ : CH₂ + H₂O
       CH₂ : CH₂ + HClO = HOCH₂CH₂Cl
     2HOCH₂CH₂Cl + Na₂S = (HOCH₂CH₂)₂S + 2NaCl
    (HOCH₂CH₂)₂S + 2HCl = (ClCH₂CH₂)₂S + 2H₂O

Without going into the chemistry of this reaction, which is thoroughly
discussed by Gomberg[18] (see also German Manufacture), it may be
said that this “procedure proved to be unsuitable for large scale
production” (Dorsey). As Pope remarks, “That he (the German) should
have been able to produce three hundred tons of mustard gas per month
by the large scale installation of the purely academic method (of
Meyer) constitutes indeed ‘a significant tribute to the potentialities
represented by the large German fine chemical factories.’” It is true
that a great deal of experimental work was carried out by the Allies on
this method, but further study was dropped as soon as the Pope method
was discovered.

[Footnote 18: J. Am. Chem. Soc. =41=, 1414 (1919).]

The first step in advance in the manufacture of mustard gas was the
discovery that ethylene would react with sulfur dichloride. While
American chemists were not very successful in their application of this
reaction, either in the laboratory or the plant, it was apparently,
according to Zanetti, the only method used by the French (the only
one of the Allies that manufactured and fired mustard gas). The plant
was that of the Société Chimique des Usines du Rhone and was started
early in March, 1918, with a production of two to three tons a day.
In July it was producing close to twenty tons a day. The plant was
being duplicated at the time of the Armistice, so that probably in
December, 1918, the production of mustard gas by the dichloride process
would have reached about 40 tons. Zanetti points out, however, that
the process involved complicated and costly apparatus and required
considerable quantities of carbon tetrachloride as a solvent. It is for
this reason that the Levinstein process would have been a tremendous
gain, had the war continued.

About the end of January, 1918, Pope and Gibson, in a study of the
reaction originally used by Guthrie, found that the action of ethylene
upon sulfur chloride (S₂Cl₂) at 60° yielded mustard gas and sulfur:

    2CH₂ : CH₂ + S₂Cl₂ = (CH₂ClCH₂)₂S + S

The reaction at this temperature caused the separation of sulfur;
this occurred after the product stood for some time or immediately
if it was treated with moist ammonia gas. While this process was put
into commercial operation, both in England and America, it offered
considerable difficulty from an operating standpoint. The sulfur would
often separate out and block the inlet tubes (ethylene). While it is
comparatively easy to remove the mustard gas from the separated sulfur
by decantation, a certain amount always remains with the sulfur. It is
almost impossible to economically remove this, and its presence adds
to the difficulty of removing the sulfur from the reactors; the men
engaged in this operation almost always become casualties.

[Illustration: FIG. 29.—The Levinstein Reactor as Installed at Edgewood
Arsenal.]

It was especially important, therefore, when Green discovered that, if
the reaction was carried out at 30°, the sulfur did not settle out but
remained in “pseudo solution” in the mustard gas (Pope) or as a loose
chemical combination of the monosulfide (mustard gas) with an atom of
sulfur (Green). This material has all the physiological activity of the
pure monosulfide, while the enormous technical difficulties of handling
separated sulfur are entirely obviated by this method of manufacture.
To carry out the reaction Levinstein, Ltd., devised the Levinstein
“reactor.” The apparatus is shown in Fig. 29. The process consists
essentially in bringing together sulfur chloride and very pure ethylene
gas in the presence of crude mustard gas as a solvent at a temperature
ranging between 30-35° C. A supply of unchanged monochloride is
constantly maintained in the reacting liquid until a sufficiently large
batch is built up. Then the sulfur monochloride feed is discontinued
and the ethylene feed continued until further absorption ceases. By
controlling the ratio of mustard gas to uncombined monochloride, the
reaction velocity is so increased that the lower temperature may be
used.

The product thus obtained is a pale yellow liquid which deposits no
sulfur and requires no further treatment. It is ready for the shell
filling plant at once. The obvious advantage of this method led to its
adoption in all American plants started for the manufacture of mustard
gas (Edgewood, Cleveland and Buffalo).


ETHYLENE

It was known from the work of certain French chemists that in the
presence of such a catalyst as kaolin, ethyl alcohol is dehydrated at
an elevated temperature to ethylene. The process as finally developed
by American chemists consisted essentially in introducing mixtures of
alcohol vapor and steam, in the ratio of one to one by weight, into an
8-inch iron tube with a 3-inch core, in contact with clay at 500-600°
C. The use of steam rendered the temperature control more uniform and
thus each unit had a greater capacity of a higher grade product. The
gaseous products were removed through a water-cooled surface condenser.
One unit of this type had a demonstrated capacity of 400 cubic feet per
hour of ethylene, between 92 and 95 per cent pure, while the conversion
efficiency (alcohol to ethylene) was about 85 per cent. The Edgewood
plant consisted of 40 such units. This would have yielded sufficient
ethylene to make 40 tons of mustard gas per 24-hour day.

The English procedure consisted in the use of phosphoric acid, absorbed
onto coke. An American furnace was designed and built which gave 2,000
cubic feet per hour of ethylene, with a purity of 98 to 99 per cent.
This furnace was not used on a large scale, because of the satisfactory
nature of the kaolin furnaces.

[Illustration: FIG. 30.—Experimental Installation for the Production
of Ethylene by Kaolin Procedure. Capacity 400-600 cu. ft. Ethylene per
hr.]


SULFUR CHLORIDE

Since chlorine was prepared at Edgewood, it was logical that some of
this chlorine should be utilized in the preparation of sulfur chloride.
The plant constructed consisted of 30 tanks (78 inches in diameter and
35 feet long), each capable of producing 20,000 pounds of monochloride
per day. The tanks are partially filled with sulfur and chlorine passed
in. The reaction proceeds rapidly with sufficient heat to keep the
sulfur in a molten condition. If the chlorine is passed in too rapidly,
the heat generated may be sufficient to boil off the sulfur chloride
formed. Hence water pipes are provided so that a supply of cold water
may be sprayed upon the tanks, keeping the temperature within the
proper limits.

[Illustration: FIG. 31.—Row of Furnaces for the Preparation of
Ethylene.]

In the manufacture of one ton of mustard gas, about one ton of sulfur
chloride and a little less than half a ton of ethylene (12,640 cubic
feet) are required.


GERMAN METHOD OF MANUFACTURE[19]

[Illustration: FIG. 32.—Preparation of Ethylene at Badische Anilin und
Soda Fabrik. 60 units.]

[Footnote 19: Norris, _J. Ind. Eng. Chem._, =11=, 821 (Sept., 1919).]

    “PREPARATION OF ETHYLENE—The gas was
    prepared by passing alcohol vapor over aluminum oxide
    at a temperature of 380° to 400°. The details of the
    construction of one of the furnaces are given in Figs.
    32 and 33. The furnaces were very small and sixty units
    were needed to furnish the amount of gas required. The
    tubes containing the catalyzer were made of copper and
    were heated in a bath of molten potassium nitrate. It
    was stated that the catalyzer was made according to the
    directions of Ipatieff, and that its life was from 10
    to 20 days. The gas produced was washed in the usual
    form of scrubber. The yield of ethylene was stated to
    be about 90 per cent of the theoretical.

[Illustration: FIG. 33.—Ethylene Production at Badische Anilin und Soda
Fabrik. 1 unit.]

[Illustration: FIG. 34.—Chlorhydrin reaction kettle at Badische Anilin
und Soda Fabrik. 16 units.]

    “PREPARATION OF ETHYLENE CHLORHYDRIN—The
    reaction was carried out in a cylindrical tank resting
    on its side. The tank was furnished with a stirrer and
    was insulated by means of cork in order to prevent the
    transfer of heat from the atmosphere to the inside.
    Enough chloride of lime was introduced into the tank to
    furnish 500 kg. of available chlorine, together with 5
    cu. m. of water. At first, about 20 cu. m. of carbon
    dioxide were led into the mixture, next ethylene, and
    later carbon dioxide and ethylene simultaneously. The
    rate of absorption of ethylene was noted and when
    it slackened, more carbon dioxide was added. Fuller
    details as to the addition of the two gases were
    not given as it was stated that it was a matter of
    judgment on the part of the workman who was carrying
    out the operation. The reaction should be carried out
    at as low a temperature as possible, but it was found
    impossible to work below 5° with the apparatus employed
    in this factory. The temperature during the reaction
    varied between 5° and 10°. In order to maintain this
    temperature, the solution was constantly pumped from
    the apparatus through a coil which was cooled by brine.
    When ethylene was no longer absorbed and there was an
    excess of carbon dioxide present, the solution was
    tested for hypochlorous acid. The time required for the
    introduction of ethylene was between 2 and 3 hrs.

    “The contents of the apparatus were passed through a
    filter press by means of which the calcium carbonate
    was removed. The solution thus obtained contained from
    10 to 12 per cent of ethylene chlorhydrin. It was next
    distilled with steam and a distillate collected which
    contained between 18 and 20 per cent of chlorhydrin.
    The yield of chlorhydrin was from 60 to 80 per cent of
    that calculated from the ethylene used.

[Illustration: FIG. 35.—Mustard Gas Manufacture at Leverkusen. Layout
for Chlorination of Thiodiglycol.]

    “PREPARATION OF DIHYDROXYETHYLSULFIDE—To
    prepare the hydroxysulfide, the theoretical quantity
    of sodium sulfide, either in the form of the anhydrous
    salt or as crystals, was added to the 18 to 20 per cent
    solution of chlorhydrin. After the addition of the
    sulfide, the mixture was heated to about 90° to 100°.
    It was then pumped to an evaporator, and heated until
    all the water was driven off. The glycol was next
    filtered from the salt which separated, and distilled
    in a vacuum. The yield of glycol was about 90 per cent
    of the theoretical, calculated from the chlorhydrin.

    “PREPARATION OF DICHLORETHYLSULFIDE—The
    thiodiglycol was taken from the rail to two large
    storage tanks and thence drawn by vacuum direct to
    the reaction vessel. Each reaction vessel was placed
    in a separate cubicle ventilated both from above and
    below and fitted with glass windows for inspection. The
    vessels themselves were made of 1¼ in. cast iron and
    lined with 10 mm. lead. They were 2.5 m. high and 2.8
    m. in diameter. These tanks were jacketed so that they
    could be heated by water and steam, and the reaction
    was carried out at 50°. The hydrochloric acid coming
    from the main pipe was passed through sulfuric acid so
    that the rate could be observed, and passed in by means
    of 12 glass tubes of about 2 cm. diameter. The rate of
    flow was maintained at as high a rate as possible to
    procure absorption. The vapors from the reaction were
    led from the vessel through a pipe into a collecting
    room, and then through a scrubber containing charcoal
    and water, through a separator, and then, finally,
    into the chimney. These exhaust gases were drawn off
    by means of a fan which was also connected with the
    lower part of the chamber in which the reaction vessels
    were set, so that all the gases had to pass through
    the scrubber before going to the chimney. When the
    reaction was completed, the oil was removed by means
    of a vacuum, induced by a water pump, into a cast iron
    washing vessel.

    “The hydrochloric acid layer was removed to a stoneware
    receiver, also by vacuum. A glass enabled the operator
    to avoid drawing oil over with the acid. The pan was
    fitted with a thermometer to the interior as well as to
    the jacket. For testing the material during reaction,
    provision was made for drawing some up by vacuum to
    a hydrometer contained in a glass funnel. The final
    test at this point read 126° Tw. Another portion could
    be drawn up to a test glass and hydrochloric acid
    passed through it in full view. A float contained in
    a glass outer tube served to show the level of the
    liquid in the vessel. The pans in which the operation
    is carried on, as well as those employed for washing
    and distilling the product, were of a standard pattern
    employed in many other operations in the works.

    “The washer consisted of a cast iron vessel, lead
    lined, and was 2.5 m. in diameter, 2 m. deep, and
    fitted with a dome cover and stirring gear. Lead
    pipes served for the introduction of sodium carbonate
    solution and water. Similar pipes were fitted for
    drawing these off by means of a vacuum. A manhole on
    the cover, with a flat top, was fitted with light and
    sight glasses to which were fitted a small steam coil
    for keeping them clear. The washed oil is drawn off
    to a distillation still, which is a cast iron vessel
    homogeneously lead coated, 1.5 m. in diameter and 2 m.
    deep, fitted with a lead heating coil and connected
    through a spiral lead condenser and receiver to a
    vacuum pump. The water is distilled from the oil at
    a pressure of from 62 to 70 mm. absolute pressure.
    When dried, the oil is sent by vacuum to a mixing
    vessel, similar in most respects to the washing vessel,
    in which it is mixed with an appointed quantity
    of solvent, which, in this factory, was usually
    chlorobenzene but occasionally carbon tetrachloride.
    The relative quantities varied with the time of year,
    and instructions were sent from Berlin on this point.
    Thence the mixture was passed to a storage tank and
    into tank-wagons.”


AMERICAN METHOD OF MANUFACTURE

The Chemical Warfare Service investigated carefully the three methods
(German, French, and English) and finally adopted the Levinstein
process. The following discussion is taken from a report originally
made during construction, Sept., 1918.

The Levinstein reactor consisted of a jacketed and lead-lined vessel or
steel tank, 8 feet 5 inches in diameter and 14 feet tall. The reactor
contained 1,400 feet of lead pipe (outside diameter 2⅜ inches), made up
into five coils, giving a total cooling surface of 1,200 square feet.
The finished charge of such a reactor is 12 tons.

Ethylene was introduced through lead injectors, of which there were 16,
each suspended from its own opening in the top and hanging so that the
end of the injector tube was 12 inches from the bottom of the reactor.
The nozzle of the injector was ³/₁₆ inch outside diameter and ethylene
was introduced through it at 40 pounds pressure.

In starting the reaction, enough sulfur chloride was introduced into
the reactor to cover the central nozzles. Ethylene was now introduced,
and as the reaction proceeded sulfur chloride was added in sufficient
quantities to give a high rate of reaction. Brine or cold water was
introduced through the cooling coils and jacket to keep the reacting
temperature at 35° C.

When the charge was completed, the ethylene was turned off so that only
a small amount bubbled through the nozzles and the charge syphoned
off to the settling tank. These were constructed of iron, 8 feet in
diameter and 19 feet tall. They were provided with iron coils by which
the liquid may be cooled down, or the sulfur, which precipitates in the
bottom, melted. The tank was large enough to hold six complete charges
of mustard gas and all the sulfur from these charges was allowed to
accumulate before removal of the sulfur. The supernatant mustard gas
was drawn off from above this sulfur to storage tanks.

Among the factors which influence the reaction are the following:

A temperature of over 60° C. in lead will decompose the product slowly
when sulfur chloride is present.

The presence of iron decomposes the product rapidly at a temperature of
50° C. and probably at a considerably lower temperature.

The purity of the product is dependent upon the time of reaction. There
is always a slow reaction between the mustard gas and sulfur chloride,
and because of this the charge should be completed in 8 hours.

In general the more sulfur that comes out of the solution, the better
is the product. Temperature has a marked effect on the separation of
sulfur. In order to entirely remove the sulfur from the product it was
the custom to increase the temperature at the close of the reaction
from 55° to 70° C. This, however, caused plugging of the lines and the
reactor.


PROPERTIES

Dichloroethylsulfide (mustard gas) is a colorless, oily liquid, which
has a faint mustard odor. The pure material is said to have an odor
very suggestive of that of water cress. While the odor is more or less
characteristic, it is possible to have extremely dangerous amounts of
the gas in a neighborhood without being detected through its odors. It
still seems to be an open question whether mustard gas paralyzes the
sense of smell. One can find opinions on both sides.

Mustard gas boils at 215°-217° C. at atmospheric pressure, so that
it is at once seen to be a very persistent gas. It distills without
decomposition at this temperature but is best purified by vacuum
distillation, or by distillation with steam. A still for the vacuum
distillation of mustard gas has been described by Streeter.[20]

[Footnote 20: _J. Ind. Eng. Chem._, 11, 292 (1919).]

Mustard gas melts, when pure, at 13° to 14° C. (The ordinary summer
temperature is 20°-25° C.). The ordinary product, as obtained from
the “reactor,” melts from 9°-10° C. In order that the product in the
shell might be liquid at all temperatures, winter as well as summer,
the Germans added from 10 to 30 per cent of chlorobenzene, later using
a mixture of chlorobenzene and nitrobenzene and still later pure
nitrobenzene. Carbon tetrachloride has also been used as a means of
lowering the melting point. Many other mixtures, such as chloropicrin,
hydrocyanic acid, bromoacetone, etc., were tested, but were not
used. The effect on the melting point of mustard gas is shown in the
following table:


MELTING POINT OF MUSTARD GAS MIXTURES

    ---------+--------------+---------------+---------------
    Per Cent | Chloropicrin | Chlorobenzene |    Carbon
    Added    |              |               | Tetrachloride
    ---------+--------------+---------------+---------------
        0    |   13.4° C.   |   13.4° C.    |   13.4° C.
       10    |    9.8       |    8.4        |    9.8
       20    |    6.3       |    6.4        |    6.6
       30    |    2.6       |   -1.0        |    3.1
    ---------+--------------+---------------+---------------

The mustard gas as finally made by the United States contained about
17 to 18 per cent sulfur in solution. The gas was then put in shell
and fired without the addition of any solvent. In actual practice this
impure product seemed even more powerful in causing casualties than
equal quantities of the pure mustard gas. Accordingly no redistilling
as originally contemplated was actually carried out.

The specific gravity of mustard gas at 20° is 1.2741. The solid
material has a slightly higher value, being 1.338 at 13°. Its vapor
pressure at room temperature is very low; at 20° this value has been
found to be about 0.06 mm. of mercury.

Mustard gas is practically insoluble in water, less than 0.1 per cent
forming a saturated solution. The reports that a 1 per cent solution
could be obtained did not consider the question of hydrolysis. Mustard
gas is freely soluble in all the ordinary organic solvents, such as
ligroin, alcohol, ether, chloroform, acetic acid, chlorobenzene, etc.
In case the solvent is miscible with water, dilution throws out the
product as an oil.


CHEMICAL PROPERTIES

Mustard gas is very slowly decomposed by water, owing to its very
slight solubility. The products are dihydroxyethylsulfide and
hydrochloric acid:

    (ClCH₂CH₂)₂S + 2H₂O = (HOCH₂CH₂)₂S + 2HCl

Certain sulfonated oils accelerate the rate of hydrolysis, both by
increasing the rate of solution and the solubility of the mustard gas.
Alkalies also increase the rate of hydrolysis. Oxidizing agents destroy
mustard gas. This reaction was made use of practically in that solid
bleaching powder was early introduced as a means of destroying mustard
gas in the field. (Fig. 9.)

Chlorinating agents (chlorine, sulfur dichloride, etc.) rapidly
transform mustard gas into an inactive (non-blistering) substance.
Sulfur dichloride was a valuable reagent in both laboratory and works
in “cleaning up” mustard gas. This reaction also explains why the
early attempts to prepare mustard gas by the interaction of ethylene
and sulfur dichloride were unsuccessful. Mustard gas is probably
formed, but is almost immediately chlorinated by the excess of sulfur
dichloride. Sulfur chloride on the other hand has no effect on mustard
gas. Chloramine-T and Dichloramine-T (the valuable therapeutic agents
introduced by Dakin and Carrel for treatment of wounds) also react
with mustard gas. For this reason they were advocated as treatment for
mustard gas burns. But as we will see later, they were not altogether
successful.


DETECTION

At first the only method of detecting mustard gas was through the sense
of smell. It was then believed that concentrations which could not be
detected in this way were harmless. Later this proved not to be the
case, and more delicate methods had to be devised. In the laboratory
and in the field these tests were not very satisfactory, because most
of them depended upon the presence of chlorine, and the majority of the
war gases contained chlorine or one of the other halogens. The Lantern
Test depended upon the accumulation of the halogen upon a copper
gauze and the subsequent heating of the gauze in a Bunsen flame. This
test could be made to detect one part of mustard gas in ten million
parts of air. Another field detector devised by the Chemical Warfare
Service consisted in the use of selenious acid. Here again the lack of
specificity is apparent, for while certain halogen compounds did not
give the test, arsine and organic arsenicals gave a positive reaction
and often in a shorter time than mustard gas.

[Illustration: FIG. 36.—Field Detector for Mustard Gas.]

The Germans are said to have had plates covered with a yellow
composition which had the property of turning black in the presence
of mustard gas. These plates were lowered into the bottom of recently
captured trenches and if, after a few minutes, they turned black, the
presence of mustard gas was suspected. It is also stated that the
characteristic yellow paint on the olive of the mustard gas shell
had the same composition, and was useful in detecting leaky shell.
According to a deserter’s statement, however, reliance upon this test
resulted in casualties in several instances.

A white paint has also been reported which turned red in the presence
of mustard gas. This color change was not characteristic, for tests
made by our Army showed that other oils (aniline, turpentine, linseed)
were found to produce the same effect.

The Chemical Warfare Service was able to develop an enamel and an oil
paint which were very sensitive detectors of mustard gas. Both of these
were yellow and became dark red in contact with mustard gas. The change
was practically instantaneous. The enamel consisted of chrome yellow as
pigment mixed with oil scarlet and another dye, and a lacquer vehicle,
which is essentially a solution of nitrocellulose in amyl acetate.
One gallon of this enamel will cover 946,500 sq. cm., or a surface
equivalent to a band 3 cm. wide on 12,500 seven cm. shell.

The paint was composed of a mixture of 50 per cent raw linseed oil
and 50 per cent Japan drier, with the above dye mixture added to
the required consistency. In contact with liquid mustard gas, this
changes to a deep crimson in 4 seconds. Furthermore, in contact with
arsenicals, this paint changes to a color varying from deep purple
to dark green, the color change being almost instantaneous and very
sensitive, even to the vapors of these compounds. Other substances have
no effect upon the paint.

For field work, however, nothing was found equal to the trained nose,
and it is questionable if any of the mechanical means described will be
used in the field.


PHYSIOLOGICAL ACTION

One of the most interesting phases of mustard gas is its peculiar
physiological action. This has been studied extensively, both as
relates to the toxicity and to the skin or blistering effect.


TOXICITY

When one considers the high boiling point of mustard gas, and its
consequent low vapor pressure, he is likely to conclude that such a
substance would be of comparatively little value as a toxic or poison
gas. While it is true that an important part of the military value
of mustard gas has been because of its vesicant properties, the fact
still remains that it is one of our most toxic war gases. The following
comparison with a few of the other gases indicates this:

    -----------------+----------------------
                     |    Mg. per Liter
                     +---------------+------
                     |     Mice      | Dogs
    -----------------+---------------+------
    Mustard gas      |      0.2      | 0.05
    Phosgene         |      0.3      | ···
    Hydrocyanic acid |      0.2      | 0.1
    Chloropicrin     |      1.5      | 0.8
    Chlorine         |      ···      | 3.0
    -----------------+---------------+------

When an animal is exposed to the vapors of mustard gas in high
concentration, it subsequently shows a complexity of symptoms, which
may be divided into two classes:

(1) The local effects on the eyes, skin and respiratory tract.
These are well recognized and consist mainly of conjunctivitis and
superficial necrosis of the cornea; hyperemia, œdema and later,
necrosis of the skin, leading to a skin lesion of great chronicity; and
congestion and necrosis of the epithelial lining of the trachea and
bronchi.

(2) The systemic effects due to the absorption of the substance into
the blood stream, and its distribution to the various tissues of the
body.

The most striking observation about the symptoms of mustard gas
poisoning is the latent period which elapses after exposure before any
serious objective or subjective effects are noted. The developments of
the effects are then quite slow, unless very high superlethal doses
have been inhaled.

At first it was a very serious question whether or not the temporary
blindness resulting from mustard gas would not be permanent. Later, as
the depth and seriousness of some of the body burns became well known,
it was a seven-day wonder that no permanent blindness occurred.

The reason seems to be largely a mechanical one. The constant winking
of the eyelids apparently washes the mustard gas off the eyeball
and carries it away so that not enough remains to burn to the depth
necessary to cause permanent blindness.

Due to the very slight concentrations ordinarily encountered in the
field, resulting from a very slow rate of evaporation, the death rate
is very low, probably under 1 per cent among the Americans gassed with
mustard during the war.

If, on the other hand, the gas be widely and very finely dispersed by
a heavy charge of explosive in the shell, the gas is very deadly. In
such cases the injured breathe in minute particles of the liquid and
thus get hundreds of times the amount of gas that would be inhaled as
vapor. This so-called “high explosive mustard gas shell” was a German
development in the very last months of the war. Its effects were great
enough to make it certain that in the future large numbers of these
shell will be used.

The similarity of the symptoms and pathological effects after the
inhalation of large amounts of the vapor and those following an
injection of an olive oil or water solution of mustard gas led Marshall
and his associates to conclude that in high concentrations mustard gas
is absorbed through the lungs. A further bit of evidence consists in
the isolation of the hydrolysis product, dihydroxyethylsulfide, in the
urine of animals poisoned by inhalation of mustard gas. This product
is not toxic and is not responsible for the effects of mustard gas.
Hydrochloric acid, however, does produce very definite effects upon the
animal and may cause death.

From these facts Marshall[21] has proposed the following mechanism of
the action of mustard gas:

[Footnote 21: Marshall, Lynch and Smith, _J. Pharmacal_, =12=, 291-301
(1918).]

    “Dichlorethylsulphide is very slightly soluble in water
    and very freely soluble in organic solvents, or has
    a high lipoid solubility or partition coefficient.
    It would, therefore, be expected to penetrate cells
    very readily. Its rapid powers of penetration are
    practically proven by its effects upon the skin.
    Having penetrated within the living cell, it would
    undoubtedly hydrolyze. The liberation of free
    hydrochloric acid _within the cell_ would produce
    serious effects and might account for the actions of
    dichlorethylsulphide. To summarize, then, the mechanism
    of the action of dichlorethylsulphide appears to be as
    follows:

    “1. Rapid penetration of the substance into the cell by
    virtue of its high lipoid solubility.

    2. Hydrolysis by the water within the cell, to form
    hydrochloric acid and dihydroxyethylsulphide.

    3. The destructive effect of hydrochloric acid upon
    some part or mechanism of the cell.

    “Although hydrochloric acid does not penetrate cells
    readily and is easily neutralized by the buffer action
    of the fluids of the body, we might expect by flooding
    the body with large quantities of acid to produce
    some of the characteristic effects of mustard gas.
    Stimulation of the respiratory center is a well known
    effect of acid. Convulsions and salivation may be
    produced by injection of hydrochloric acid and we have
    been able to produce slowing of the heart by rapid
    injection of this acid.

    “The delayed action of mustard gas might be explained
    by the formation of some compound with some constituent
    of the blood. However, blood taken from dogs which had
    been poisoned with mustard gas and were exhibiting
    typical symptoms at the time, injected into normal
    dogs produced no effect. Serum treated in vitro with
    mustard gas and allowed to stand and then injected into
    a dog, produced no effect. The fluid which is formed
    in the vesicle and blebs produced by the application
    of mustard gas to the skin produces no mustard gas
    effects.”

In studying the toxicity of mustard gas for dogs, it was observed that
a concentration of 0.01 mg. per liter could be tolerated indefinitely.
If this value is considered as a threshold value, and subtracted from
the toxicity values for varying periods of time, it is found that there
is a definite relation between the toxic concentration and the time of
exposure. This is expressed by the formula

                           (C - 0.01)_t_ = K
where C is the concentration observed for a given time _t_. K has the
approximate value of 1.7, where _t_ varies between 7.5 and 480 minutes.


VESICANT ACTION

In addition to its toxicity mustard gas is highly important because
of its peculiar irritating effect upon the skin. Its value is seen
when we realize that one part in 14,000,000 is capable of causing
conjunctivitis of the eye and that one part in 3,000,000 and possibly
one part in 5,000,000 will cause a skin burn in a sensitive person
on prolonged exposure. According to Warthin, the lesions produced by
mustard gas are those of a chemical, not unlike hydrochloric acid, but
of much greater intensity. The pathology of these lesions has been
carefully studied and fully described by Warthin and Weller in their
book on The Pathology of Mustard Gas. Our observations will therefore
be confined to certain striking features of the vesicant action of this
substance.


VARIATION IN SUSCEPTIBILITY OF THE SKIN

Every worker who has worked with mustard gas has noticed that some
individuals are much more susceptible to skin burns from this substance
than are others. Marshall made a study of 1282 men at Edgewood Arsenal,
using a 1 per cent and a 0.01 per cent solution of mustard gas in
paraffin oil. A small drop of these solutions was applied to the skin
of the forearm of the subject and the arm allowed to remain uncovered
for about 10 minutes. The presence or absence of a positive reaction is
indicated by the appearance or absence of erythema 24 hours later. The
results were as follows:

       1%         0.01%       % of Total
    Positive     Positive         3.3
    Positive     Negative        55.3
    Negative     Negative        41.4

The test made on 84 negroes gave the following results:

            1%          0.01%     % of Total
        Positive       Positive       0.0
        Positive       Negative      15.0
        Negative       Negative      78.0
        Questionable   Negative       7.0

    “It is seen from the above tables that negroes as a
    race, have a much more resistant skin than white men.
    No negro of the 84 examined reacted to the 0.1 per cent
    solution, and of course none would react to a more
    dilute one. About 10 per cent of white men react to
    the 0.1 per cent solution, while 2 to 3 per cent react
    to the 0.01 per cent solution or are hypersensitive.
    About 78 per cent of the negroes fail to react to the 1
    per cent solution, while only 20 to 40 per cent of the
    white race do not show a reaction.”

[Illustration: FIG. 37.]

The same individual may also show variations in susceptibility and this
has also been studied by Marshall.

    “The effect of exercise and sweating was investigated.
    A number of individuals were given vapor burns (one
    to five minutes exposure) and then exercised until in
    a profuse sweat, and then the same exposure to vapors
    made. In all cases the burn produced after exercising
    was more severe. Sweating produced by having the
    subjects place their feet in hot water, produced the
    same increase in susceptibility. That the moisture
    on the skin produced by sweating is at least partly,
    if not entirely, responsible for the increased
    susceptibility, was shown in the following way: An
    area of the forearm was kept moist for a few minutes
    with wet cotton. The sponge was then removed and two
    vapor tests made, one over the moist area and one over
    normal, dry skin. In all cases the moist burn was the
    more severe, in one, producing a blister where the
    control did not.

    “The skin of different areas of the body is undoubtedly
    somewhat different in its susceptibility. All our
    tests have been applied to the forearm. The hands
    are considerably more resistant than the forearm.
    Tests made by the oil method on the forearm, chest,
    and back, however, indicate very little difference
    in susceptibility of these areas. The skin in the
    neighborhood of old burns has been shown to be more
    susceptible.

    “In general, the same individual does not become more
    susceptible to skin burns from continued exposure
    to the vapor. The great number of tests which have
    been made on the same individual at different times
    and under the same conditions, indicate a remarkable
    constancy in reaction. A series of men who were tested
    at various times during a period of four months,
    revealed slight changes from time to time in some of
    the men. No man who originally reacted to only the
    1 per cent solution ever reacted to the 0.01, and
    likewise, no man who originally reacted to the 0.01
    ever failed to react to the 0.1 per cent.

    “_Susceptibility of skin of animals._ The paraffin
    oil test was used on a number of animals and indicated
    that differences in susceptibility exist in different
    species and in different individuals of the same
    species.”

       -----------+--------+----------------------------
                  |        |    Percentage Positive to
         Species  | Number +-------+---------+----------
                  | Tested | 1 Per | 0.1 Per | 0.01 Per
                  |        | Cent  |  Cent   |  Cent
       -----------+--------+-------+---------+----------
       Horse      |    1   |  100  |   100   |   100
       Dog        |   91   |   83  |    35   |     0
       Goat       |   11   |   55  |    36   |     0
       Rat        |   10   |   30  |    20   |     0
       Mouse      |    7   |   70  |    14   |     0
       Rabbit     |    2   |  100  |     0   |     0
       Guinea-pig |   12   |   33  |     0   |     0
       Monkey     |    9   |   22  |     0   |     0
       -----------+--------+-------+---------+----------

The horse appears to be the most sensitive and the monkey and
guinea-pig the most resistant species, while the dog would seem to have
a sensitivity as near man as any of the species studied. No animal
has yet been found which will give a blister from the application of
mustard gas.

Smith, Clowes and Marshall[22] have studied the mechanism of absorption
by the skin. They find that it is quite evident that the mustard gas
is at first rapidly taken up by some element on, or adjacent to, the
surface of the skin and for two to three minutes it may be completely
removed, and for ten to fifteen minutes partially removed by prolonged
washing With an organic solvent, and to a lesser extent with soap and
water.

[Footnote 22: J. Pharmacol., =13=, 1 (1919).]

An interesting phenomenon is observed when the untreated normal skin
of one subject is impressed for five minutes upon an area of skin
of another subject, which has been exposed previously to the vapors
of mustard gas. Under these circumstances both donor and recipient
may develop burns (due to the transposition of the poison from one
skin to another), the intensity of which will vary according to the
circumstances and the respective sensitiveness of the participants. The
degree of transposition is most strikingly observed in the intensity
of the burn on the donor’s arm. If two similar exposures are made on
the arm of a sensitive man, and one of these burns is treated, so to
speak, by contact for five minutes, with the skin of a resistant man,
the treated burn will be markedly less severe than the control, in some
cases being entirely prevented. If, however, the recipient is equally
sensitive to or more sensitive than the donor, the burns on the latter
will exhibit far less difference. Both treatments may be effected at
once, using two recipients, one more, and the other less, resistant
than the donor. In such a case the burn brought into contact with the
more resistant skin will be the less severe.

Similarly, if a sensitive individual impresses his arm alternately
against burns of the same concentration and exposure on a resistant
and sensitive man, the recipient receives a more severe burn from the
sensitive than from the resistant man.

This indicates that the skin of a resistant individual exhibits a
greater affinity or capacity for mustard gas than that of a sensitive
one. There is an actual partition of the gas between the two skins,
with an evident tendency to establish an equilibrium in which the
larger portion of the gas will remain in that skin which possesses the
greater capacity for it.

    “A tentative explanation of this phenomenon can be
    made as follows. A three phase system is involved—the
    air over the skin surface constitutes the outer phase;
    some fatty or keratinous elements of the skin, the
    central phase; and a cellular portion of the skin the
    inner phase. The central phase is rich in lipoids and
    poor in water, while the inner phase is rich in water
    and poor in lipoids. After exposure to the vapors
    of dichloroethylsulphide the central phase is the
    absorbing agent and tends to establish equilibrium with
    the other two phases. On account of the lipoid nature
    of the central phase no damage is produced here because
    the compound is not hydrolyzed. On its passage from
    the central to the inner phase hydrolysis takes place
    within the cell and damage results when a sufficient
    concentration of hydrochloric acid is attained. The
    outer phase is constantly being freed from vapor by
    diffusion and convection currents, so more and more can
    evaporate from the central phase. The susceptibility
    of an individual depends on the relative power of
    the central phase to hold the poison in an inactive
    form (not hydrolyzed) and prevent its entry into the
    inner phase at a sufficient velocity to result in the
    formation of a toxic concentration. We do not attempt
    to localize the central or inner phases with any
    definite structure of the skin. As mustard is known to
    penetrate the sebaceous ducts the fat here might form
    one phase and the epithelial lining another.”


TACTICAL USE OF MUSTARD GAS

As before stated, mustard gas, like most other materials used in war,
was discovered in peace. Indeed, Victor Meyer in 1886 worked out fairly
completely its dangerous characteristics. Like phosgene and chlorine
used before it, the materials for its production were available in
considerable quantities through the manufacture of components either
for dyes or photographic chemicals.

Mustard gas, besides being highly poisonous, has so many other
important qualities as to have given it the designation during the
war of the “king of gases.” That broad distinction it still holds.
Its introduction at Ypres, on the night of July 12, 1917, changed
completely the whole aspect of gas warfare and to a considerable extent
the whole aspect of warfare of every kind. It is highly poisonous,
being in that respect one of the most useful of all war gases. It
produces no immediate discomfort. It has a considerable delay action.
It burns the body inside or out, wherever there is moisture. Eyes,
lungs and soft parts of the body are readily attacked. It lingers for
two or three days in the warmest weather, while in cold, damp weather
it is dangerous for a week or ten days, and in still colder weather
may be dangerous for a month or longer whenever the weather warms up
sufficient to volatilize the liquid. It is only slowly destroyed in the
earth, making digging around shell holes dangerous for weeks and months
and in some cases possibly a year or more.

The Germans first used it simply to get casualties and interfere with
or break up the threatened heavy attacks by the British on the Ypres
salient. While not stopping the inauguration of these attacks in the
fall of 1917, the German use of mustard gas was so effective as to
delay the beginning of those attacks for at least two weeks and thus
gain valuable time for the Germans, besides causing serious casualties
with consequent partial break up of companies, regiments and divisions
in the English Army.

The German used his mustard gas throughout the fall of 1917 and the
winter of 1917 and 1918, as above stated, to produce casualties, to
destroy morale, to break up units, and to interfere with operations
generally. During that time, however, he developed a more scientific
use and when he started his big offensives in March, April, May and
June, 1918, he used mustard gas _before_ the battles to cause losses,
break up units and destroy morale, and also during the progress of
battles to completely neutralize strong points which he felt he did
not want to attempt to take by direct assault. Perhaps the most noted
case of this was at Armentières in April, when he deluged the city to
such an extent that mustard gas is said to have actually run in the
streets. So effective was this gassing that not only did the British
have to withdraw from the city but the Germans could not enter it for
more than two weeks. It, however, enabled the Germans to take the city
with practically no loss of life. There were numerous other cases on a
smaller scale where mustard gas was used in the same way.

On account of its persistence it has been generally referred to as
a defensive gas and for that purpose it is incomparable. The use of
sufficient quantities of mustard gas will almost certainly stop the
occupation of areas by the enemy and probably even stop his crossing
them. It also enables strong points which it is not desired to attack
to be completely neutralized,—that is, made so unhabitable that the
area must be evacuated.

A use that was proposed toward the end of the war, and that will
undoubtedly be made of the gas in the future, is to have it planted
in drums in the ground and exploded when an enemy is attempting to
advance. This would be a highly economic way to distribute great
quantities of the material at the moment and in the place most heeded.
It has even been proposed, and this would seem entirely feasible, to
sprinkle certain of these areas with mustard gas by means of sprinklers
attached to drums or even tanks mounted on trucks.

Just before the Armistice the German made another development in the
use of mustard gas. Instead of the ordinary amount of explosive, which
only fairly opened up the shell and allowed the liquid to escape, he
filled nearly 30 per cent of the total space of the shell with high
explosive. This completely broke up the shell and distributed the
greater part of the liquid mustard gas in the form of a fine spray.
This spray, when breathed, proved extremely deadly, as might be
expected from the fact that when in the form of minute particles one
can draw into the lungs in a single breath one hundred times or more
the amount that he would get of pure gas.

Since mustard gas has such a delay action and is effective in such
small concentrations it can be used very effectively in small calibre
guns, as the 75 mm. or 3-inch. Furthermore, since it lasts for two
or three days at the very least, a small number of guns can keep a
very large area neutralized with the gas. With phosgene and similar
non-persistent gases that volatilize almost completely upon the
burst of the shell it is necessary to build up a high concentration
immediately. The exact opposite is true of mustard gas. Mustard gas
can be fired very slowly with the certain knowledge that all shells
fired at one moment will be effective when the next is fired, though
twelve hours or more may intervene between the first and last firing.
Thus, while with phosgene a large number of guns are needed for a gas
attack, with mustard gas the number can be reduced to one-tenth or even
less. Mustard gas may be in the future and has been in the past used
safely in hand grenades because of its very low vapor tension, whereby
the pressure at ordinary temperatures is exceedingly low. This has
an important bearing on cylinders and other containers for shipping
mustard gas, that is, they need be only strong enough to be safe
against handling and not to withstand the high pressure encountered
with phosgene or chlorine cylinders.

In the future, mustard gas will be used in all the ways above stated
and undoubtedly in many more. It can be fired in large quantities upon
strong points to force their evacuation. It can be fired on the flank
of attacking armies for protection against counter-attacks. It can be
fired against the enemy artillery at all times to silence them and stop
their firing. It was thus used by the Americans in the Argonne against
the enemy on the east bank of the Meuse River, this river separating
the American and German armies. It was extremely effective in stopping
the enemy’s artillery. The high explosive mustard gas shell, not only
because of its persistency but because of its quick deadliness, can be
fired singly and be depended upon to do its work wherever there be men
or animals. One of the greatest uses will be by simple sprinkling from
aeroplanes.

The future will see mustard gas used at nearly all times with a
certain quantity of a powerful lachrymator or tear gas. This is for
the reasons, as stated in the beginning, that mustard gas causes no
immediate discomfort and has no objectionable smell. Accordingly,
if the battle be critical, men may continue to fight from four to
eight hours in a mustard gas atmosphere without masks. It is true the
casualties will be high with a high death rate. Nevertheless, this
period of time might enable the artillery to do such effective work as
to completely stop an attack. If, however, at the instant mustard gas
firing is begun a number of powerful lachrymatory shells are sent over,
the immediate wearing of the mask is forced. The enemy is then subject
to all the burning effects of mustard gas as well as the discomfort of
long wearing of the mask.

It may confidently be expected that further developments in the use of
mustard gas will be made, as well as further developments in methods of
throwing it upon the enemy or of bursting shell containing it in his
midst.




CHAPTER X

ARSENIC DERIVATIVES


Since arsenic is well known as an insecticide in the form of lead
arsenate, arsenic acid etc., and in pharmacy, specially in the form
of salvarsan and neosalvarsan, it is not surprising that the Germans
should have endeavored to discover an arsenic derivative which would
be of value from the point of view of chemical warfare. Very early in
the war persistent rumors were circulated that the Germans were to
use arsine. These rumors led to the use of sodium permanganate in the
canister, but as far as is known, no arsine was actually used. Another
suggestion which received considerable attention from American workers
was the use of arsenides, which might decompose under the influence of
the atmospheric moisture with the liberation of arsine. Calculation of
the amount of arsenide necessary to establish a lethal concentration
of arsine showed, however, that there was no possibility of using the
material on the field.

Because of the use of arsenic trichloride in the manufacture of organic
arsenic compounds, a method of preparation was developed from arsenic
trioxide and sulfur chloride or hydrogen chloride. It was also shown
experimentally that the phosgene of the tail gas of phosgene plants
might be converted into arsenic trichloride by reaction with arsenic
trioxide. Charcoal is the catalyzer of this reaction.

Arsenic trichloride is also of interest because it was one of the
constituents of the mixture vincennite, early used by the French.
This was a mixture of hydrocyanic acid, stannic chloride, arsenic
trichloride and chloroform. While extensively used at first, it was
gradually replaced by phosgene.

Arsenic triflouride was also prepared by the action of sulfuric acid
upon a mixture of calcium flouride and arsenic trioxide. The compound
is very easily decomposed by the moisture of the air, and furthermore
is not very toxic.

Organic arsenic derivatives are the most important compounds
from the military point of view. The first substance used was
diphylchloroarsine, a white solid, which readily penetrated the
canister and caused sneezing. This was used alone, and in solution in
phenyl dichloroarsine. Later methyl and ethyl dichloroarsines were
introduced.

[Illustration: FIG. 38.—Apparatus for the Manufacture of
Methyldichloroarsine.]


METHYLDICHLOROARSINE

The Germans apparently used ethyldichloroarsine because they had no
suitable method for the preparation of methyl dichloroarsine, which is
a more satisfactory material. The Chemical Warfare Service developed
the following method of preparation of the methyl derivative. Sodium
arsenite (Na₃AsO₃) is prepared by dissolving arsenic trioxide in sodium
hydroxide solution. The action of methyl sulfate at 850 C. gives
disodium methyl arsenite, Na₂CH₃AsO₃. Sulfur dioxide reduces the
arsenite to methyl arsine oxide, CH₃AsO, which is then reacted with
hydrochloric acid to give methyl dichloroarsine. The final product is
distilled from the mixture and condensed. This material costs from two
to two and a half dollars per pound for chemicals (war prices).

Methyldichloroarsine is a colorless liquid of powerful burning odor,
which boils at 132° C. It is somewhat soluble in water and is soluble
in organic solvents. The specific gravity is 1.838 at 20° C. The vapor
pressure at 25° was found to be 10.83 mm. mercury. Not only is the
material toxic but it has remarkable vesicant properties, comparing
favorably with mustard gas in this respect.

Ethyldichloroarsine, which was used by the Germans, was prepared by
the method given above, using ethyl sulfate, but the yield was never
over 20 per cent. In general this has properties similar to the methyl
derivative.


DIPHENYLCHLOROARSINE

The best known of the arsenicals, however, is diphenylchloroarsine or
sneezing gas. Although this is an old compound (having been prepared
by German chemists in 1885), there was no method for its preparation
on a large scale when, first introduced into chemical warfare. It
was finally discovered that the interaction of triphenyl arsine with
arsenic trichloride was fairly satisfactory and a plant was erected for
its manufacture.

When pure, diphenylchloroarsine is a colorless solid, melting at 44°.
Because of this, it was always used in solution in a toxic gas or in
a shell which contained a large amount of explosive so that on the
opening of the shell the material would be finely divided and scattered
over a wide territory.

Its value lay in the fact that the fine particles readily penetrated
the ordinary mask and caused the irritation of the nose and throat,
which resulted in sneezing. This necessitated the perfection of special
smoke filters to remove the particles, after which the other toxic
materials were removed by the absorbent in the canister.

It causes sneezing and severe burning sensations in the nose, throat
and lungs in concentrations as slight as 1 part in 10 million. In
higher concentrations, say 1 in 200 to 500 thousand it causes severe
vomiting. While neither of these effects are dangerous or very lasting,
still higher concentrations are serious, as in equal concentrations
diphenylchloroarsine is more poisonous than phosgene.

Various other arsenical chemicals were developed in the laboratory,
but with one or two exceptions they were not as valuable as
diphenylchloroarsine and methyldichloroarsine and were therefore
discarded.


GERMAN METHODS FOR MANUFACTURING ARSENICALS[23]


DIPHENYLCHLOROARSINE

[Footnote 23: Norris, _J. Ind. Eng. Chem._, =11=, 825 (1919).]

    “This substance (Blue Cross) was a famous gas of the
    Germans and was made in large quantities. The method
    used by the Germans was different from the one worked
    out by the Allies, and on account of the fact that the
    German method could be carried out without specially
    designed apparatus and required as raw materials
    substances readily obtainable, it was probably
    preferable. It is doubtful, however, whether the Allies
    would have made this gas, for as the result of its
    use no fatalities were reported. The German process
    consisted in preparing phenylarsenic acid by condensing
    benzene diazonium chloride with sodium arsenite.
    The acid was next reduced by sulfur dioxide to
    phenylarsenous acid, which was, in turn, condensed with
    the diazonium compound to form diphenylarsenic acid.
    This acid was reduced to diphenylarsenous oxide, which
    with hydrochloric acid yielded diphenylchloroarsine.
    The chemical equations for the reactions will make
    clearer the steps involved.

                C₆H₅N₂Cl + Na₃AsO₃ = C₆H₅AsO₃Na₂ + NaCl + N₂
                C₆H₅AsO₃Na₂ + 2HCl = C₆H₅AsO₃H₂ + 2NaCl
              C₆H₅AsO₃H₂ + SO₂+H₂O = C₆H₅AsO₂H₂ + H₂SO₄
            C₆H₅N₂Cl + C₆H₅AsO₂Na₂ = (C₆H₅)₂AsO₂Na + NaCl + N₂
               (C₆H₅)₂AsO₂Na + HCl = (C₆H₅)₂AsO₂H + NaCl
        2(C₆H₅)₂AsO₂H + 2SO₂ + H₂O = [(C₆H₅)₂As]₂O + 2H₂SO₄
              [(C₆H₅)₂As]₂O + 2HCl = 2(C₆H₅)₂AsCl + H₂O.

    “The entire process was carried out at Höchst. The
    method used at Höchst was as follows: In preparing
    the diazonium solution, 3 kg.-mols of aniline were
    dissolved in 3000 liters of water and the theoretical
    quantity of hydrochloric acid. The temperature of
    the solution was reduced to between 0° and 5° and
    the theoretical amount of sodium nitrite added.
    The reaction was carried out in a wooden tank of
    the usual form for the preparation of diazonium
    compounds. A solution of sodium arsenite was prepared
    which contained 20 per cent excess of oxide over
    that required to react with the aniline used. The
    arsenous oxide was dissolved in sodium carbonate, care
    being taken to have enough of the alkali present to
    neutralize all of the acid present in the solution
    of the diazonium salt. To the solution of the sodium
    arsenite were added 20 kg. of copper sulfate dissolved
    in water, this being the amount required when 3
    kg.-mols of aniline are used. The solution of the
    diazonium compound was allowed to flow slowly into
    the solution of the arsenite while the temperature
    was maintained at 15°. The mixture was constantly
    stirred during the addition which requires about 3
    hrs. After the reaction was complete, the material
    was passed through a filter press in order to remove
    the coupling agent and the tar which had been formed.
    Hydrochloric acid was next added to the clear solution
    to precipitate phenylarsenic acid, the last portions of
    which were removed by the addition of salt.

    “The phenylarsenic acid was next reduced to
    phenylarsenous acid by means of a solution of sodium
    bisulfite, about 20 per cent excess of the latter
    over the theoretical amount being used. For 100 parts
    of arsenic acid, 400 parts of solution were used.
    The reaction was carried out in a wooden vessel and
    the mixture stirred during the entire operation. A
    temperature of 80° was maintained by means of a steam
    coil. Phenylarsenous acid separated as an oil. The
    aqueous solution was decanted from the oil, which was
    dissolved in a solution of sodium hydroxide, 40° Bé.
    The solution of the sodium salt of phenylarsenous
    acid was treated with water so that the resulting
    solution had a volume of 6 cu. m. when 3 kg.-mols of
    the salt were present. Ice was next added to reduce the
    temperature to 15° and a solution of benzene diazonium
    chloride, prepared in the manner described for the
    first operation, was slowly added. After the coupling,
    diphenylarsenic acid was precipitated by means of
    hydrochloric acid. The acid was removed by means of a
    filter press and dissolved in hydrochloric acid, 20°
    Bé. For one part of diphenylarsenic acid, 3 parts of
    hydrochloric acid were used. Into this solution was
    passed 5 per cent excess of sulfur dioxide over that
    required for the reduction. The sulfur dioxide used was
    obtained from cylinders which contained it in liquid
    condition.

    “The reduction was carried out in an iron tank lined
    with tiles and a temperature of 80° was maintained.
    About 8 hrs. were required for the reaction. The
    diphenylarsenic acid on reduction by the sulfur dioxide
    was converted into diphenylarsenous oxide which, in
    the presence of the hydrochloric acid, was converted
    into diphenylchloroarsine, which separated as an oil.
    The oil was next removed and heated in the best vacuum
    obtainable until it was dry and free from hydrochloric
    acid. The compound melted at 34°. It was placed in iron
    tanks for shipment. The yield of diphenylchloroarsine
    calculated from the aniline used was from 25 to 30 per
    cent of the theoretical. No marked trouble was observed
    in handling the materials and no serious poisoning
    cases were reported.

DIPHENYLCYANOARSINE

“This compound was prepared by treating diphenylchloroarsine with a
saturated aqueous solution of potassium or sodium cyanide.

    (C₆H₅)₂AsCl + NaCN = (C₆H₅)₂AsCN + NaCl.

Five per cent excess of the alkaline cyanide was used. The reaction
was carried out at 60° with vigorous stirring. The yield was nearly
theoretical.


ETHYLDICHLOROARSINE

“This compound was prepared at Höchst from ethylarsenous oxide which
was obtained from the Badische Anilin und Soda Fabrik.

“PREPARATION OF ETHYLARSENOUS OXIDE—The compound was prepared by
treating sodium arsenite with ethyl chloride under pressure. The
resulting sodium salt of ethylarsenic acid was converted into the free
acid and reduced by sulfur dioxide. The ethylarsenous acid formed in
this way lost water and was thereby transformed into ethylarsenous
oxide. The reactions involved are as follows:

          C₂H₅Cl + Na₃AsO₃ = C₂H₅AsO₃Na₂ + NaCl
       C₂H₅AsO₃Na₂ + 2 HCl = C₂H₅AsO₃H₂ + 2 NaCl
    C₂H₅AsO₃H₂ + SO₂ + H₂O = C₂H₅AsO₂H₂ + H₂SO₄
               2C₂H₅AsO₂H₂ = (C₂H₅As)₂O + H₂O.

“The ethyl chloride used in the preparation was in part made in this
factory, and in part received from other sources. As ethyl chloride
is an important product used in peace time, it is not, therefore,
essentially a war product and its preparation was not described.

“In preparing the solution of sodium arsenite, one molecular weight
of arsenous oxide was dissolved in a solution containing 8 molecular
weights of sodium hydroxide. The solution of the base was prepared from
a 50 per cent solution of sodium hydroxide to which enough solid alkali
was added to make the solution a 55 per cent one. In one operation 660
kg. of arsenous oxide were used. For 100 parts of arsenous oxide, 130
parts of ethyl chloride were used, this being the theoretical amount of
the latter.

“The reaction was carried out in a steel autoclave of about 300 liters
capacity. The temperature was maintained at between 90° and 95°. The
ethyl chloride was pumped in, in 3 or 4 portions, and the pressure
in the autoclave was kept at from 10 to 15 atmospheres. The several
portions of ethyl chloride were introduced at intervals of about 1½
hrs. During the entire reaction, the contents of the autoclave were
vigorously stirred. After all the ethyl chloride had been added, the
material was stirred from 12 to 16 hrs., at the end of which time
the pressure had fallen to about 6 atmospheres. The excess of ethyl
chloride and the alcohol formed in the reaction were next distilled
off. At this point a sample of the solution was drawn off for testing.
This was done by determining the amount of arsenite present in the
solution. If not more than 20 per cent of sodium arsenite had not
reacted, the preparation was considered satisfactory. Water was then
added to the contents of the autoclave in sufficient amount to dissolve
the solid material. The product was next drawn over into a tank and
neutralized with sulfuric acid. It was then treated with sulfur dioxide
gas until there was an excess of the latter present. The mixture was
then heated to about 70° when the ethylarsenous oxide precipitated as
a heavy oil. This was readily separated and shipped without further
purification. The yield of ethylarsenous oxide, from arsenic oxide, was
from 80 to 82 per cent of a product which contained about 93 per cent
of pure ethylarsenous oxide.

“PREPARATION OF ETHYLDICHLOROARSINE—The compound was prepared by
treating ethylarsenous oxide with hydrochloric acid. The reaction is as
follows:

    C₂H₅AsO + 2HCl = C₂H₅AsCl + H₂O.

The operation was carried out in an iron kettle lined with lead, which
was cooled externally by means of water and which was furnished with
a lead covered stirrer. To the kettle, which contained from 500 to
1000 kg. of hydrochloric acid left over from the previous operation,
were added 4000 kg. of ethylarsenous oxide. The gaseous hydrochloric
acid was next led in. The kettle was kept under slightly diminished
pressure in order to assist in the introduction of hydrochloric acid.
The temperature during the reaction must not rise above 95°. When
the hydrochloric acid was no longer absorbed and was contained in
appreciable quantities in the issuing gases, the operation was stopped.
This usually occurred at the end of from one to two days. The product
of the reaction was drawn off by means of a water pump and heated in a
vacuum until drops of oil passed over. The residue was passed over to
a measuring tank and finally to tank-wagons made of iron. The yield of
the product was practically the theoretical.

On account of the volatility of the compound and its poisonous
character, the apparatus in which it was prepared was surrounded by
an octagonal box, the sides of which were fitted with glass windows.
Through this chamber a constant supply of air was drawn. This was led
into a chimney where the poisonous vapors were burned. The gases given
off during the distillation of the product were passed through a water
scrubber.”


“LEWISITE”

The one arsenical which created the most discussion during the War, and
about which many wild stories were circulated, was “Lewisite,” or as
the press called it, “Methyl.” Its discovery and perfection illustrate
the possibilities of research as applied to Chemical Warfare, and
points to the need of a permanent organization to carry on such work
when the pressure of the situation does not demand such immediate
results.

The reaction of ethylene and sulfur chloride, which led to the
preparation of mustard gas, naturally led the organic chemists
to investigate the reaction of this gas and other unsaturated
hydrocarbons, such as acetylene, upon other inorganic chlorides, such
as arsenic, antimony and tin. There was little absorption of the
gas, either at atmospheric or higher pressures, and upon distilling
the reaction product, most of the gas was evolved, showing that no
chemical reaction had taken place. However, when a catalyser, in the
form of aluminium chloride, was added, Capt. Lewis found that there
was a vigorous reaction and that a highly vesicant product was formed.
The possibilities of this compound were immediately recognized and
the greatest secrecy was maintained regarding all the details of
preparation and of the properties of this new product. At the close
of the War, this was considered one of the most valuable of Chemical
Warfare secrets, and therefore publication of the reactions involved
were withheld. Unfortunately or otherwise, the British later decided
to release the material for publication, and details may be found in
an article by Green and Price in the _Journal of the Chemical Society_
for April, 1921. It must be emphasized that the credit for this work
belongs, not to these authors, but to Capt. W. Lee Lewis and the men
who worked with him at the Catholic University branch of the American
University Division (the Research Division of the C. W. S.).

On a laboratory scale, acetylene is bubbled through a mixture of 440
grams of anhydrous arsenic trichloride and 300 grams of anhydrous
aluminium chloride. Absorption is rapid and much heat is developed.
After six hours, about 100 grams of acetylene is absorbed. The reaction
product was dark colored and viscid, and had developed a very powerful
odor, suggestive of pelargoniums. Attempts to distill this product
always led to violent explosions. (It may be stated here that Lewis was
able to perfect a method of distillation and separation of the products
formed, so that pure materials could be obtained, with little or no
danger of explosion.) The English chemists therefore decomposed the
product with ice-cold hydrochloric acid solution of constant boiling
point (this suggestion was the result of work done by Lewis). The
resulting oil was then distilled in a current of vapor obtained from
constant boiling hydrochloric acid and finally fractionated into three
parts.

The first product obtained consist in the addition of one
acetylene to the arsenic trichloride molecule, and, chemically, is
chlorovinyldichloroarsine, CHCl: CH·AsCl₂, a colorless or faintly
yellow liquid, boiling at 93° at a pressure of 26 mm. A small quantity,
even in very dilute solution, applied to the skin causes painful
blistering, its virulence in this respect approaching that of mustard
gas. It is more valuable than mustard gas, however, in that it is
absorbed through the skin, and as stated on page 23, three drops,
placed on the abdomen of a rat, will cause death in from one to three
hours. It is also a very powerful respiratory irritant, the mucous
membrane of the nose being attacked and violent sneezing induced. More
prolonged exposure leads to severe pain in the throat and chest.

The second fraction (β, β′-dichlorodivinylchloroarsine) is a product
resulting from the addition of two acetylene molecules to one arsenic
trichloride, and boils at 130° to 133° at 26 mm. It is much less
powerful as a vesicant than chlorovinyldichloroarsine, but its irritant
properties on the respiratory system are much more intense.

The third fraction, β, β′, β″-trichlorotrivinylarsine, (CHCl: CH)₃As,
is a colorless liquid, boiling at 151° to 155° at 28 mm., which
solidifies at 3° to 4°. It is neither a strong vesicating agent nor a
powerful respiratory irritant. At the same time, its odor is pungent
and most unpleasant and it induces violent sneezing.




CHAPTER XI

CARBON MONOXIDE


Carbon monoxide, because of its cheapness, accessibility and ease of
manufacture, has been frequently considered as a possible war gas.
Actually, it appears never to have been used intentionally for such
purposes. There are several reasons for this. First, its temperature of
liquefaction at atmospheric pressure is -139° C. This means too high a
pressure in the bomb or shell at ordinary temperatures. Secondly, the
weight of carbon monoxide is only slightly less than that of air, which
keeps it from rolling into depressions, dugouts and trenches, as in
the case of ordinary gases, and also permits of its rather rapid rise
and dissipation into the surrounding atmosphere. A third reason is its
comparatively low toxic value, which is only about one-fifth that of
phosgene. However, as it can be breathed without any discomfort, and as
it has some delay action, its lack of poisonous properties would not
seriously militate against its use were it not for the other reasons
given.

It is, nevertheless, a source of serious danger both in marine and
land warfare. Defective ventilation in the boiler rooms of ships
and fires below decks, both in and out of action, are especially
dangerous because of the carbon monoxide which is produced. In one of
the naval engagements between the Germans and the English, defective
high explosive shell, after penetrating into enclosed portions of the
ship, evolved large quantities of carbon monoxide and thus killed some
hundreds of men. On shore, machine gun fire in enclosed spaces, such
as pill boxes, and in tanks, liberates relatively large quantities of
carbon monoxide. Similarly, in mining and sapping work, the carbon
monoxide liberated by the detonation of high explosives constitutes one
of the most serious of the difficulties connected with this work and
necessitated elaborate equipment and extensive military training in
mine rescue work.

The removal of carbon monoxide from the air is difficult because of its
physical and chemical properties. Its low boiling point and critical
temperature makes adequate adsorption at ordinary temperatures by the
use of an active absorbent out of the question. Its known insolubility
in all solvents similarly precludes its removal by physical absorption.

After extensive investigation two absorbents have been found.[24] The
first of these consists in a mixture of iodine pentoxide and fuming
sulfuric acid, with pumice stone as a carrier. Using a layer 10 cm.
deep and passing a 1 per cent carbon monoxide air mixture at the rate
of 500 cc. per minute per sq. cm. cross section, a 100%-90% removal
of the gas could be secured for two hours at room temperature and
almost as long at 0° C. The reaction is not instantaneous, and a brief
induction period always occurs. This may be reduced to a minimum by the
addition of a little iodine to the original mixture.

[Footnote 24: Complete details of this work may be found in _J. Ind.
Eng. Chem._, =12=, 213 (1920).]

The sulfur trioxide given off is very irritating to the lungs, but
by the use of a layer of active charcoal beyond the carbon monoxide
absorbent, this disadvantage was almost completely eliminated. However,
sulfur dioxide is slowly formed as a result of this adsorption and
after prolonged standing or long-continued use of the canister at a
high rate of gas flow gives serious trouble.

Considerable heat is given off in the reaction and a cooling attachment
was required. The most satisfactory device was a metal box filled
with fused sodium thiosulfate pentahydrate, which absorbed a very
considerable amount of the heat.

Still a further disadvantage was the fact that the adsorbents became
spent by use, even in the absence of carbon monoxide, since it absorbed
enough moisture from the air of average humidity in several hours, to
destroy its activity.

The difficulties mentioned were so troublesome that this absorbent was
finally supplanted by the more satisfactory oxide absorbent described
below.

[Illustration: FIG. 39.—Diagram of Carbon Monoxide Canister, CMA3.]

The metallic oxide mixture was the direct result of an observation that
specially precipitated copper oxide with 1 per cent silver oxide was an
efficient catalyst for the oxidation of arsine by oxygen. After a study
of various oxide mixtures, it was found that a mixture of manganese
dioxide and silver oxide, or a three component system containing
cobaltic oxide, manganese dioxide and silver oxide in the proportion of
20:34:46 catalyzed the reaction of carbon monoxide at room temperature.
The studies were extended and it was soon found that the best catalysts
contained active manganese dioxide as the chief constituent. This was
prepared by the reaction between potassium permanganate and anhydrous
manganese sulfate in the presence of fairly concentrated sulfuric acid.
It also developed that the minimum silver oxide content decreased
progressively as the number of components increased from 2 to 4. The
standard catalyst (Hopcalite) finally adopted for production consisted
of 50 per cent manganese dioxide, 30 per cent copper oxide, 15 per cent
cobaltic oxide and 5 per cent silver oxide. The mixture was prepared
by precipitating and washing the first three oxides separately, and
then precipitating the silver oxide in the mixed sludge. After washing,
this sludge was run through a filter press, kneaded in a machine, the
cake dried and ground to size. While it is not difficult to obtain a
product which is catalytically active, it requires a vigorous control
of all the conditions and operations to assure a product at once
active, hard, dense and resistant as possible to the deleterious action
of water vapor.

[Illustration: FIG. 40.—Tanks and Press for Small Scale Manufacture of
Carbon Monoxide Absorbent.]

Hopcalite acts catalytically and therefore only a layer sufficiently
deep to insure close contact of all the air with the catalyst is
needed. One and a half inches (310 gm.) were found ample for this
purpose.

The normal activity of Hopcalite requires a dry gas mixture. This was
secured by placing a three-inch layer of dry granular calcium chloride
at the inlet side of the canister.

Because of the evolution of heat, a cooling arrangement was also used
in the Hopcalite canisters.

The life of this canister was the same irrespective of whether its use
was continuous or intermittent. The higher the temperature the longer
the life because Hopcalite is less sensitive to water vapors at higher
temperatures. Since, if the effluent air was sufficiently dried, the
Hopcalite should function indefinitely against any concentration of
carbon monoxide, the life of the canister is limited solely by the life
of the drier. Therefore the net gain in weight is a sure criterion of
its condition. After many tests it was determined that any canister
which had gained more than 35 grams above its original weight should
be withdrawn. The canisters, at the time of breakdown, showed a gain
in weight varying between 42 and 71 grams, with a average of 54 grams.
It is really, therefore, the actual humidity of the air in which the
canister is used that determines its life.

[Illustration: FIG. 41.—Navy Head Mask and Canister.]




CHAPTER XII

DEVELOPMENT OF THE GAS MASK


While in ordinary warfare the best defense against any implement of
war is a vigorous offense with the same weapon, Chemical Warfare
presents a new point of view. Here it is very important to make use of
all defensive measures against attack. Because of the nature of the
materials used, it has been found possible to furnish, not only general
protection, but also continuous protection during the time the gas is
present.

The first consideration in the protection of troops against a gas
attack is the provision of an efficient individual protective appliance
for each soldier. The gas attack of April 22, 1915 found the Allies
entirely unprepared and unprotected against poisonous gas. While a few
of the men had the presence of mind to protect themselves by covering
their faces with wet cloths, the majority of them became casualties.
Immediately steps were taken to improvise protective devices among
which were gags, made with rags soaked in water or washing soda
solution, handkerchiefs filled with moist earth, etc. One suggestion
was to use bottles with the bottom knocked off and filled with moist
earth. The breath was to be taken in through the bottle and let out
through the nose; but as bottles were scarce and few of them survived
the attempt to get the bottom broken off, the idea was of no value.

The first masks were made by the women of England in response to the
appeal by Lord Kitchener; they consisted of cotton wool wrapped in
muslin or veiling and were to be kept moist with water, soda solution
or hypo.


ENGLISH MASKS

=The Black Veiling Respirator.= The first form of the English mask is
known as the Black Veiling respirator and consisted of cotton waste
enclosed in a length of black veiling. The waste was soaked in a
solution of:

    Sodium thiosulphate     10   lbs.
    Washing soda             2.5 lbs.
    Glycerine                2   lbs.
    Water                    2   gals.

The glycerine was put in to keep the respirator moist, thus obviating
the need for dipping before use.

[Illustration: FIG. 42.—Early Gas Protection.]

The respirator was adjusted over the mouth and nose, the cotton waste
being molded to the shape of the face and the upper edge of the veiling
pulled up so as to protect the eyes. These respirators were used in
the attacks of May 10th and 12th, 1915 and were reasonably efficient
against the low concentration of chlorine then used; they were
difficult to fit exactly to the face, which resulted in leakage. The
cotton waste often became lumpy and had to be shredded out or discarded.

=The Hypo Helmet.= The next development of the British protection was
the so-called Hypo helmet. This is said to have resulted from the
suggestion of a Canadian sergeant that he had seen a German pulling a
bag over his head during a gas attack. It consisted of a flannel bag
soaked in the same solution as was used for the veiling respirator and
was fitted with a pane of mica as a window. The helmet was tucked down
inside the jacket which was then buttoned up tightly around the neck.
As may be seen from Figure 43, this would not prove very satisfactory
with the American type of uniform.

This helmet had many advantages over the veiling respirator but the
window often became cracked or broken from the rough treatment in the
trenches. Later the mica was replaced by celluloid and still later by
glass eyepieces set in metal rings. These were very effective against
chlorine in the field.

=The P and PH Helmets.= During the summer of 1915 it became evident
that phosgene-chlorine mixtures would be used in gas attacks and it
was therefore necessary to provide protection against this. The hypo
helmet, which offered no protection against phosgene, was soaked in
an alkaline solution of sodium phenolate (carbolic acid) containing
glycerine, and with this new form of impregnation was called the P
helmet. It protected against 300 parts of phosgene in a million of air.
Since this solution attacks flannel, two layers of flannelette were
used. The helmet was further improved by the addition of an expiratory
valve, partly to prevent the man from breathing any of his own breath
over again and partly to prevent the deterioration of the alkali of the
mask by the carbon dioxide of the expired air.

The protection was later further increased by the addition of
hexamethylenetetramine, and this mask is known as the PH helmet. This
increased the protection to 1,000 p.p.m.

The early types of helmet offered no protection against lachrymators.
For this purpose goggles were used, the later types of which had glass
eyepieces and were fitted around the eyes by means of rubber sponge.
While intended for use only after a lachrymatory bombardment, the
troops frequently used them during and after an ordinary gas attack
when the mask should have been worn. Consequently they were withdrawn.

The PH helmet was unsatisfactory because of the following reasons:

    (1) It was warm and stuffy in summer;
    (2) It deteriorated upon exposure to air;
    (3) It was incapable of further development;
    (4) It had a peculiar odor and, when wet, frequently
        burned the foreheads of the men;
    (5) It offered practically no protection against
        lachrymators.

[Illustration: FIG. 43.—Method of Wearing the P. H. Helmet.]

[Illustration: FIG. 44.—Early Type of Standard (British) Box Respirator
(S. B. R.)]

=Box Respirator.= The increasing concentration of gas from cylinder
attacks and the introduction of shell, with such gases as chloropicrin
and superpalite, led, early in 1916, to very definite and constructive
efforts on the part of the British to increase the protection offered
by the mask. The result was a “polyvalent” respirator of the canister
type (the Standard Box Respirator). This mask was probably the result
of experience with oxygen apparatus in mine rescue work. The lines on
which this canister was modeled involved the use of a canister filled
with highly sensitive absorbent charcoal mixed with or alternating
in layers with oxidizing granules of alkaline permanganate. It was
the result of innumerable experiments, partly conducted in France
but mostly in England under the direction of the late Lieut. Col.
Harrison, who was almost entirely responsible for the wonderful
production of this respirator.

The respirator (Figure 44) consisted of the canister mentioned above,
which is attached by a flexible tube to a facepiece or mask. The
facepiece is made of rubberized fabric and fits the face so that there
is little or no leakage. This is secured by means of tape and elastic
bands which fit over the head. The nose is closed by means of clips,
which are wire springs with rubbered jaws covered with gauze (Fig.
45). Breathing is done through a mouthpiece of rubber; the teeth close
on the rubber tabs and the rubber flange lies between the teeth and
the lips. The expired air finds exit through a rubber flutter valve
in an angle tube just outside the mask. This arrangement furnishes a
double line of protection; if the face piece is punctured or torn,
gas-containing air cannot be breathed as long as the noseclip and
mouthpiece are in position.

The early English canister was packed with 675 cc. of 8-14 mesh war gas
mixture, 40 per cent of which was wood charcoal and 60 per cent reddish
brown soda-lime granules. The metal dome at the bottom of the can was
covered with a thin film of cotton. At two-thirds of the distance to
the top was placed a paper filter and a heavy wire screen which differs
from our heavy screen in that it is more loosely woven. The mixture
was covered with a cotton filter pad and a wire screen, over which was
placed the wire spring.

The use of this mask ensures that all the air breathed must enter the
lungs through the canister. This air passage is entirely independent
of leaks in the facepiece, due either to a poor fit about the face
or to actual leakage (from a cut or tear) of the fabric itself. The
facepiece is readily cleared of poison gases which may leak in. This is
accomplished by taking a full inspiration, releasing the noseclip, and
exhaling through the nose, which forces the air out around the edges of
the facepiece.

On the other hand, this type of mask possesses a number of very obvious
disadvantages, particularly from a military point of view:

The extreme discomfort of the facepiece. This discomfort arises from a
number of causes certain of which are inherent in this type of mask,
among them being: (_a_) the noseclip, (_b_) the mouthpiece, and (_c_)
the lack of ventilation within the facepiece chamber.

Aside from the actual physical discomfort of the noseclip and
mouthpiece, which becomes intense after long periods of wearing, this
combination forces upon the wearer an unnatural method of respiration
to which it is not only difficult to become accustomed, but which also
causes extreme dryness of the throat. The mouthpiece greatly increases
salivation and as swallowing is rather more difficult with the nose
closed, this adds another extremely objectionable feature.

[Illustration: FIG. 45.—Interior of S. B. R., Showing Cotton Wrapped
Noseclips.]

[Illustration: FIG. 46.—French M-2 Mask.]

The lack of ventilation in the facepiece chamber entraps the heat
radiating from the face and retains the moisture which is constantly
evaporating from the skin. This moisture condenses on the eyepieces,
and even if cleared away by the use of a so-called anti-dimming paste,
usually makes vision nearly impossible.


FRENCH MASKS

=M-2 Mask.= The early protection of the French Army was obtained from a
mask of the type M-2 (Fig. 46).

This mask consists of a number of layers of muslin impregnated with
various absorbent chemicals. A typical mask was made up of 20 layers of
cheesecloth impregnated with _Greasene_ and 20 layers impregnated with
_Complexene_. These solutions were made up as follows:

    Complexene:  39.0 lbs.  Hexamethylenetetramine
                 37.5 lbs.  Glycerine
                 27.5 lbs.  Nickel sulfate (NiSO₄.7 H₂O)
                 11.8 lbs.  Sodium carbonate (Na₂CO₃)
                            Water

    Greasene:   107.0 lbs.  Castor oil
                 81.0 lbs.  Alcohol (95%)
                 10.7 lbs.  Glycerine (90%)
                  3.1 lbs.  Sodium hydroxide (NaOH)

This mask fits the face tightly and as a consequence the inhaled air
can be obtained only by drawing it through the pores of the impregnated
fabric. There is no outlet valve. The exhaled air makes its escape
through the fabric. The eyepieces are made of a special non-dimming
celluloid. The mask is protected from rain by a flap of weather proof
fabric, which also protects the absorbent chemicals from deterioration.

At the beginning of the war the United States experimented considerably
with the French mask. Several modifications of the impregnating
solutions were suggested, as well as methods of application. One of
these was to separate the components of the complexene solution and
impregnate two separate layers of cloth; this would make a three-layer
mask. In view of the phosgene which was in use at that time, the
following arrangement was suggested:

    20 layers of hexamethylenetetramine,
    10 layers of nickel sulfate-sodium carbonate,
    10 layers of greasene.

This arrangement was more effective than the original French mask and
offered the following protection when tested against the following
gases (concentration 1 to 1,000, rate 30 liters per minute):

    Phosgene           65 minutes
    Hydrocyanic acid   60 minutes
    Chlorine           60 minutes

[Illustration: FIG. 47.—Interior View of M-2 Mask.]

[Illustration: FIG. 48.—French Artillery Mask, Tissot Type.]

=Tissot Mask.= The French deserve great credit for their development of
the Tissot type mask. This was first issued to artillerymen, stretcher
bearers, and certain other special classes of soldiers to furnish them
with protection and yet enable them to work with greater efficiency
because of the decrease in resistance to breathing. The mask (Fig.
48) resembles the British box respirator in that it consists of a
canister and rubber facepiece, but differs in that the mouthpiece and
noseclip are lacking. The inhaled air enters the mask from two tubes
which open directly under the eyepieces and allow the air to sweep
across them. This removes, by evaporation, the condensed moisture of
the breath from the eyepieces, which otherwise would obstruct the
vision. The circulation of the fresh air in the mask also removes and
dilutes lachrymatory gases which may filter through the mask. The
exhaled air escapes through a simple outlet valve. This type of mask is
advantageous because:

    (1) The facepiece is tight and comfortable.
    (2) The eyepieces do not become dimmed.
    (3) There is no difficulty in speaking.
    (4) Salivation is eliminated because of the absence of the
        mouthpiece.
    (5) It is generally more comfortable than the box respirator.

This mask, however, was made of thin rubber of great flexibility which,
while affording a perfect fit, did not possess sufficient durability to
recommend it as the sole defense of the wearer.

The canister is markedly different from all other canisters described
in this chapter in that a highly hygroscopic chemical absorbent is
used. An approximate determination showed about 70 per cent sodium
hydroxide. The use of caustic soda in the canister is made possible by
the intermixing of steel wool with the granules of caustic. A layer of
absorbent having the appearance of vegetable charcoal is placed at the
top of the canister.

The canister has the shape of a rectangular prism 8 × 6½ × 2½ inches;
and, owing to the use of steel wool, is large in proportion to the
weight of absorbent contained. Valves are supplied which prevent
exhalation through the canister. When not in use the opening in the
bottom of the canister is plugged with a rubber stopper to protect the
absorbents from moisture. The canister is carried against the body and
is connected to the facepiece with a flexible rubber-fabric tube.

=A. R. S. Mask (Appareil Respiratoire Special).= One of the latest
types of French mask is the so-called A. R. S. mask, which is based
upon, or at least resembles closely, the German mask. This is a frame
mask made from well rubberized balloon material, provided on the inside
with a lining of oiled or waxed linen and fitted with a drum which
is screwed on. The mask is provided with eyepieces of cellophane,
fastened by metal rings into rubber goggles, which are sewed in the
mask. A metal mouth-ring is tied in the mask with tape. This ring is
placed somewhat higher than in the German mask, in this way reducing
the harmful space under the mask. An inlet and outlet valve is placed
in the mouth-ring; the first is of mica while the other, which is in
direct communication with the interior of the mask, is of rubber. On
the inside of the mask, in front of the valves, a baffle is sewed in,
whereby the inhaled air is forced to pass in front of the eyepieces to
prevent dimming and, at the same time, condensed vapor is prevented
from entering the valves.

[Illustration: FIG. 49.—French A. R. S. Mask.]

The mask or head straps are arranged in the same way as on the latest
M-2 mask, i.e., one elastic band is placed across the top of the head
and the other across the back; the two are joined by an elastic. Below
these two straps is an adjustable elastic neck band. The drum is made
of metal similar in shape to the German drum and fits in the mouth-ring
by means of a thread. It is made tight by a rubber ring as in the
German mask. The thread differs from that on the German mask, making
an interchange of canisters impossible. The canister or drum includes
a bottom screen, springs and wire screens between the layers. It is
closed by a perforated bottom. There are three layers. On the top is
a thin layer of absorbent cotton. Beneath this is a central layer of
charcoal, which is a little finer than the German charcoal. The lower
layer consists of soda-lime, mixed with charcoal and zinc oxide and
moistened with glycerine.


GERMAN MASK

The early type of German mask probably served as the model for the
French A. R. S. mask. The facepiece was made of rubber, which was later
replaced by leather because of the shortage of rubber. The following is
a good description of a typical German facepiece:

“The facepiece of the German mask was made of one piece of leather,
with seams at the chin and at the temples, giving it roughly the shape
of the face. The leather was treated with oil to make it soft and
pliable, also to render it impervious to gases. The dressed surface
was toward the inside of the mask. A circular steel plate, 3 inches
in diameter, was set into the facepiece just opposite the wearer’s
nose and mouth, with a threaded socket into which the drum containing
the absorbents screwed. A rubber gasket (synthetic?) held in place by
a sort of pitch cement, secured a gas-tight joint between the drum
and the facepiece. There were no valves, both inhaled and exhaled air
passing through the canister. The eyepieces were inserted by means
of metal rims with leather washers, and were in two parts: (_a_) a
permanent exterior sheet of transparent material (‘cellon’) resembling
celluloid, and (_b_) an inner removable disc which functioned as an
anti-dimming device. This latter appeared to be of ‘cellon’ coated on
the side toward the eye with gelatin, and was held in position by a
‘wheel’ stamped from thin sheet metal, which screwed into the metal
rim of the eyepiece from the inside. The gelatin prevented dimming by
absorbing the moisture, but wrinkled and blistered and became opaque
after a few hours’ use, and could not be changed without removing the
mask. The edge of the facepiece all around was provided with a bearing
surface consisting of a welt of finely woven cloth about one inch wide
sewed to the leather. In some instances this welt was of leather of an
inferior grade. The edge of the facepiece was smoothed over by a coat
of flexible transparent gum, probably a synthetic compound.”

[Illustration: FIG. 50.—German Respirator.]

[Illustration: FIG. 51.—The German Respirator.]

     1. Smoke Filter Extension.
     2. Canister.
     3. Ring for Protecting Eye Piece.
     4. Anti-dimming Disc Envelope.
     5. Carrying Case.
     6. Cloth Wallet for Extra Canister (1918).
     7. Can for Extra Canister (1916).
     8. Assembled Respirator.
     9. Face Piece.
    10. Anti-dimming disc.

=German Canister.= The general appearance of the canister (Sept., 1916
Type) is that of a short thick cylinder slightly tapered and having at
the smaller end a threaded protrusion or neck by which it is screwed
onto the facepiece. The cylinder is about 10 cm. in diameter and about
5 cm. in length. In the canister are three layers of absorbents of
unequal thickness separated by disks of fine mesh metal screen. The
canister is shipped in a light sheet iron can 10 cm. in diameter and 8
cm. high. The can is shellacked and is lined with paper packing board.
The container is made air-tight by sealing with a strip of adhesive
tape.

[Illustration: FIG. 52.—Cross Section of 1917 and 1918 German
Canisters.]

                      ABSORBENTS.

     Absorbent.       Composition.       Weight.  Volume.
    1917. No. 1.  Chemical Absorbent.    66 gr.   105 cc.
          No. 2.  Impregnated Charcoal.  36 gr.    85 cc.
          No. 3.  Chemical Absorbent.    15 gr.    45 cc.
    1918. No. 1.  Impregnated Charcoal.  58 gr.   185 cc.
          No. 2.  Chemical Absorbent.    29 gr.    45 cc.

    Total Volume of Absorbents, 1917, 235 cc. = 14.3 cu. in.
                                1918, 230 cc. = 14.0 cu. in.
    Total Weight of Absorbents, 1917, 117 gr.
                                1918, 87 gr.
    Volume of Air Space above Absorbents = 50 cc. = 3.1 cu. in.

=Body.= The body of the canister is made of sheet metal (probably
iron), which is protected on the outside with a coat of dark gray
paint and on the inside with a japan varnish. For ease in assembling
the sides of the canister have a gentle taper, and are formed so as to
supply a seat for each of the follower rings. The protrusion or neck
has about six threads to the inch, the pitch of the screw being 4 mm.
The lower part of the body is rolled so as to give a finished edge, and
the upper part of the cylinder is grooved to receive the top support.

The first screen is double, consisting of a coarse top screen five to
six mesh, per linear inch, and immediately below, a finer screen of
30-40 mesh, per linear inch. The top support is a rigid ring of metal
with two cross arms, which give added, strength to the ring and support
to the screens. It springs into a groove at the top of the body and
forms the support for the contents of the canister. Both screens are
made of iron wire and the top support is made of iron (probably lightly
tinned).

The second screen, which separates the second and third absorbents, is
double, consisting of two disks of 30-40 mesh iron screen. Both screens
are held in place by a follower ring.

The third screen is single, but otherwise it is exactly similar to the
second screen. It serves to keep separate the layers of absorbents No.
1 and No. 2.

The fourth screen (30-40 mesh) is made of iron wire and is held to the
bottom support by six cleats which are punched from the body of the
support. The bottom support is simply a flanged iron cover for the
bottom of the canister. It is punched with 79 circular holes each 4
mm. in diameter and is painted on the outside to match the body of the
canister. The screen and the inside of the bottom support or cover are
coated with a red paint.


AMERICAN MASK

At the entrance of the United States into the war, three types of masks
were available: the PH helmet, the British S. B. R. and the French
M-2 masks. Experiments were made on all three of these types, and it
was soon found that the S. B. R. offered the greatest possibilities,
both as regards immediate protection and future development. During
the eighteen months which were devoted to improvement of the American
mask, the facepiece underwent a gradual evolution and the canister
passed through types _A_ to _L_, with many special modifications
for experimental purposes. The latest development consisted in an
adaptation of the fighting mask to industrial purposes. For this
reason a rather detailed description of the construction of the
facepiece and of the canister of the respirator in use at the close of
the war (R. F. K. type) may not be out of place. The mask now adopted
as standard for the U. S. Army and Navy is known as the Model 1919
American mask, with 1920 model carrier, and will be described on page
225.

[Illustration: FIG. 53.—Diagrammatic Sketch of Box Respirator Type
Mask.]

=Facepiece.= The facepiece of the R. F. K. type Box Respirator is made
from a light weight cotton fabric coated with pure gum rubber, the
finished fabric having a total thickness of approximately ¹/₁₆ inch.
The fit of the facepiece is along two lines—first, across the forehead,
approximately from temple to temple; second, from the same temporal
points down the sides of the face just in front of the ears and under
the chin as far back as does not interfere with the Adam’s apple. In
securing this fit, the piece of stock for the facepiece is died out
of the felt and pleated up around the edges to conform to this line.
After this pleating operation, the edges of the fabric are stitched to
a binding frame similar to a hat-band made up of felt or velveteen
covered with rubberized fabric. All the stitching and joints in the
facepiece are rendered gas-tight by cementing with rubber cement. This
facepiece is made in five sizes ranging from No. 1 to No. 5, with a
large majority of faces fitted by the three intermediate sizes, 2, 3, 4.

=Harness.= The function of the harness is to hold the mask on the face
in such a way as to insure a gas-tight fit at all points. Because of
the great variations in the conformation of different heads, this
problem is not a simple one. Probably, the simplest type of harness, as
well as the one which is theoretically correct, consists of a harness
in which the line of fit across the forehead is extended into an
elastic band passing around the back of the head, while the line of fit
around the side of the face and chin is similarly extended into another
elastic tape passing over the top of the head; these should be held in
place by a third tape, preferably non-elastic, attached to the mask at
the middle of the forehead and to the middle points of the other tapes
at a suitable distance to hold them in their proper positions.

The discomfort of the earlier types of harness has been remedied, in
a large measure, by the development of a specially woven elastic web
which, for a given change in tension, allowed more than double the
stretch of the commercial weaves. There is still much room for valuable
work in developing a harness which will combine greater comfort and
safety. The following points should always be observed in harness
design:

(1) The straps should pull in such a direction that as large a
component as possible of the tension of the strap should be available
in actually holding the mask against the face.

(2) The number of straps should be kept to a minimum in order to
avoid tangling and improper positioning when put on in a hurry by an
inexperienced wearer.

=Eyepieces.= One of the most important parts of the gas mask, from the
military point of view, is the eyepiece. The primary requirement of a
good eyepiece is that it shall provide a minimum reduction in clarity
of vision with a maximum degree of safety to the wearer. The clarity
of vision may be affected in one of several ways: (1) by abrasion of
the eyepieces under service conditions; (2) irregularities in the
surface and thickness of the eyepiece, causing optical dispersion;
(3) absorption of light by the eyepiece itself; (4) dimming of the
eyepieces due to condensation of moisture radiating from the face or in
the exhaled air.

Three types of eyepieces were used but by the end of the war the first
two types had been abandoned.

(1) Ordinary celluloid.

(2) Various hygroscopic forms of celluloid, known as non-dimming
eyepieces.

(3) Various combinations of glass and celluloid, known as non-breakable
eyepieces.

Celluloid was used first, due to its freedom from breakage. It is not
satisfactory because it is rapidly abraded in use, turns yellow, thus
increasing its light absorption, has relatively uneven optical surfaces
and becomes brittle after service.

The various forms of non-dimming lenses function by absorbing the water
which condenses on their surfaces, either by combining individual drops
into a film which does not seriously impair vision, by transmitting
it through the surface and giving it off on the exterior or by a
combination of these mechanisms. With the exception that they are
non-dimming, they are open to all the objections of the celluloid
eyepiece and, as a matter of fact, were never tried out in the field.

The so-called non-breakable eyepieces are formed by cementing together
a layer of celluloid between two layers of glass.[25] This results in
an almost perfect eyepiece. Any ordinary blow falling upon such an
eyepiece does no more than crack the glass, which remains attached to
the celluloid coating. Except in extreme cases, the celluloid remains
unbroken and there is relatively slight danger of a cracked eyepiece of
this sort leaking gas.

[Footnote 25: So-called “Triplex” glass.]

In the matter of flying fragments, the type of eyepiece consisting of
a single layer of celluloid and glass with the celluloid placed next
to the eye, has probably a slight advantage over the type in which
there is glass on both sides. However, the superior optical surface of
the latter type, coupled with its greater freedom from abrasion of the
surface led to the adoption of this type known as “triplexin” in the
mask produced in the later part of the American manufacturing program.
It should be pointed out in connection with this type of eyepiece that
it is possible to make it as perfect optically as desired by using the
better grades of glass. While the optical properties of these eyepieces
undoubtedly suffer somewhat with age, due to the discoloration of
the celluloid, it can be safely said that this material, located as
it is between the layers of glass and relatively little exposed to
atmospheric conditions, will probably be far less affected in this way
than is the ordinary celluloid eyepiece.

[Illustration: FIG. 54.—American Box Respirator, Showing Improved
Rubber Noseclip.]

The position of the eyepiece is very important; the total and the
binocular fields of vision should be kept at a maximum.

=noseclip.= The noseclip is probably the most uncomfortable feature
of the types of mask used during the War. While a really comfortable
nose pad is probably impossible, the comfort of the clip was greatly
improved by using pads of soft rubber and springs giving the minimum
tension necessary to close the nostrils.

=Mouthpiece.= The design of the mouthpiece should consider the size
and shape of the flange which goes between the lips and teeth; this
should be such as to prevent leakage of gas into the mouth and should
reduce to a minimum any chafing of the gums. The opening through the
mouthpiece is held distended at its inner end by a metallic bushing
to prevent its collapse, if, under stress of excitement, the jaws
are forced over the flange and closed. Rubber has proved a very
satisfactory material for this part of the facepiece.

=Flexible Hose.= The flexible hose leads from the angle tube to the
canister. This should combine flexibility, freedom from collapse, and
extreme physical ruggedness. These specifications are met successfully
by the stockinette-covered corrugated rubber hose. The angular
corrugations not only give a high degree of flexibility but are
extremely effective in preventing collapse. The flexibility gained by
this construction is not only lateral but also longitudinal; a hose
having a nominal length of 10 inches functions successfully between
lengths of 8 and 12 inches. The covering of stockinette, which is
vulcanized to the rubber in the manufacturing process, adds materially
to the mechanical strength by preventing incipient tears and breaks.

=Exhalation Valve.= The exhalation valve allows the exhaled air to pass
directly to the outside atmosphere. (This valve is not found on the
German mask.) This valve has the following advantages:

(1) It tends to reduce very materially the dead air space in the mask.

(2) It prevents deterioration of the absorbent on account of moisture
and carbon dioxide of the expired air.

(3) It reduces the back pressure against expiration, since it is
unnecessary to breathe out against the resistance of the canister.

The disadvantage, which may under certain conditions be very serious,
is that, if for any reason the valve fails to function properly,
inspiration will take place through the valve. It can be readily seen
that any failure of this nature will allow the poisonous atmosphere to
be drawn directly into the lungs of the wearer.

The type of valve generally used is shown in Fig. 55, which shows one
of these valves mounted and unmounted. While it is rather difficult
to give a clear description of its construction, the valve may be
considered as a flattened triangular sack of rubber, whose altitude
is two or three times the base and from which all three corners have
been clipped, each giving openings into the interior of the sack. The
opening at the top is slipped over the exhalation passage of the angle
tube, and the air passes out through the other two corners. Closure is
obtained by the combination of two factors,—first, the difference in
atmospheric pressure, and second, the tension due to mounting a section
which has been cured in the flat over an elliptical opening.

[Illustration: FIG. 55.—American Type Exhale Valve, Mounted and
Unmounted.]

In order to protect the flutter valve from injury and from contact with
objects which might interfere with its proper functioning, the later
types of valve were provided with a guard of stamped sheet metal.


CANISTERS

During the development of the facepiece, as discussed above, the
American canister underwent changes in design which have been
designated as _A_ to _L_. These changes were noted by the different
colored paints applied to the exterior of the canister.

Type _A_ canister was exactly like the British model then in use,
except that it was made one inch longer because it was realized that
the early absorbents were of poor quality. The canister was made of
beaded tin plate and was 18 cm. high. The area of the flattened oval
section was 65 sq. cm. In the bottom was a fine wire dome 3.4 cm. high.
The valve in the bottom was integral with the bottom of the container,
there being no removable plug for the insertion of the check valve. The
absorbents were held in place by a heavy wire screen on top and by two
rectangular springs.

[Illustration: FIG. 56.—American Canister, Type _A_.]

Inhaled air entered through the circular valve at the bottom of the
canister, passed through the absorbents and through a small nipple at
the top.

The filling consisted of 60 per cent by volume of wood charcoal,
developed by the National Carbon Co., and 40 per cent of green soda
lime, developed and manufactured by the General Chemical Company,
Easton, Pa. The entire volume amounted to 660 cc. The early experiments
with this volume of absorbent showed that ⅖ soda-lime was the minimum
amount that could be used and still furnish adequate protection against
the then known war gases. It was, therefore, decided to use ⅖ soda-lime
and ⅗ charcoal by volume and this proportion has been adhered to in all
of the later types of canisters. It is interesting to note that these
figures have been fully substantiated by the later experimental work on
canister filling.

The charcoal and soda-lime were not mixed but arranged in five layers
of equal volume, each layer, therefore, containing 20 per cent of the
total volume. The layers were separated by screens of crinoline. At the
top was inserted a layer of terry cloth, a layer of gray flannel, and
two steel wire screens. The cloth kept the fine particles of chemicals
from being drawn into the throat of the person wearing the mask.

This canister furnished very good protection against chlorine and
hydrocyanic acid and was fairly efficient against phosgene, but it was
useless against chloropicrin. These canisters were never used at the
front, but served a very useful purpose as experimental canisters and
in training troops.

It was soon found that better protection was obtained if the absorbents
were mixed before packing in the canister. This procedure also
simplified the method of packing and was used in canister _B_ and
following types. Among other changes introduced in later types were:
The integral valve was replaced by a removable check valve plug which
enabled the men in the field to adjust the valve in case it did not
function properly. The mixture of charcoal and soda-lime was divided
into three separate layers and these separated by cotton pads. The pads
offered protection against stannic chloride smokes but not against
smokes of the type of sneezing gas. The green soda-lime was replaced
by the pink granules. In April, 1918, the mesh of the absorbent was
changed to 8 to 14 in place of 6 to 14.

About July 1, 1918, the authorities were convinced by the field forces
of the Chemical Warfare Service that the length of life of the chemical
protection of the standard _H_ canister (the type then in use) was
excessive and that the resistance was much too high. Type _J_ was
therefore adopted, July 27, 1918. In this the volume of the absorbent
was reduced from 450 cc. to 300 cc. It was packed in two layers, ⅔ in
the bottom and ⅓ in the top. One pad was placed between the layers and
one on top. This change gave a lowering of the resistance of 27 per
cent (to 2.5 inches) at a sacrifice of 50 per cent of the length of
life of the canister, but not of protection during the shortened life.
Type _L_ differed from this only in having 325 cc. of absorbent, a
change made to decrease leakage about the top cotton pad.

[Illustration: FIG. 57.—U. S. Army Canister, Type _J_.]

The following table shows the relative efficiency of various canisters:

    -----------------+----------+----------+----------+----------+------
                     |          |  U. S.,  | British, | French,  |German
                     | p. p. m. | Type _H_ | S. B. R. | A. R. S. |
    -----------------+----------+----------+----------+----------+------
    Chloropicrin     |   1000   |    770   |    17    |     2    |   43
    Phosgene         |   2500   |     85   |    54    |     5    |   16
    Hydrocyanic acid |    500   |     70   |    90    |          |   10
    Mustard gas      |    100   |   1800   |          |    35    |  195
    -----------------+----------+----------+----------+----------+------

The figures represent time in minutes till the first traces of gas
begin to come through.

[Illustration: FIG. 58.—Type _J_ Canister and Contents]


MANUFACTURE

The following description of the manufacture of the gas mask at the
Long Island plant is taken from an article by Col. Bradley Dewey[26]:

[Footnote 26: _J. Ind. Eng. Chem._, =11=, 185 (1919).]

“INCOMING INSPECTION—A thorough 100 per cent inspection was made of
each part before sending it to the Assembly Department. The inspectors
were carefully chosen and were sent to a school for training before
they were assigned to this important work. Every feature found to
be essential to the manufacture of a perfect gas mask was carefully
checked.

“The incoming inspection of the flexible rubber hose leading from the
canister to the facepiece can be taken as an illustration. Each piece
of hose was given a visual inspection for buckles or blisters in the
ends or in the corrugations; for cuts, air pockets, or other defects
on the interior; for loose seams where fabric covering was cemented
to the rubber tube; for weaving defects in the fabric itself; and for
careless application of the cement. Special tests were conducted for
flexibility, as a stiff hose would produce a strain on the soldier’s
mouth; for permanent set to insure that the hose was properly cured;
for the adhesion of the fabric covering to the hose; and for kinking
when the hose was doubled on the fingers. Finally each piece was
subjected to a test for leaks under water with a pressure of 5 lbs. per
sq in.

“Each eyepiece and the three-way metal connection to the facepiece
were subjected to a vacuum test for leakage. The delicate exhalation
valve was carefully examined for defects which would be liable to cause
leakage. Fabric for the facepiece was given a high-tension electrical
test on a special machine developed at the plant to overcome the
difficulty met in the inspection of this most important material. It
was of course necessary that the facepiece fabric be free from defects
but just what constituted a defect was the source of much discussion.
The electrical test eliminated all personal views and gave an impartial
test of the fabric. The machine consisted of two steel rolls between
which a potential difference of 4,000 volts was maintained; the fabric
was led through the rolls and wherever there was a pinhole or flaw the
current arced through and burned a clearly visible hole.

“PRELIMINARY FACEPIECE OPERATIONS—Blanks were died out from the
facepiece fabric in hydraulic presses. Each face blank was swabbed to
remove bloom and the eye washers were cemented about the eyeholes. The
pockets for holding the noseclips were also cemented to the blanks. The
bands which formed a gas-tight seal of the mask about the face were
died out from rubberized fabric to which a felt backing was attached.
The harness consisting of elastic and cotton tapes was also sewed
together at this point.

“FACEPIECE OPERATIONS—The sewing machine operations were next
performed. First the died out blanks were pleated to form the
facepiece. The operator had to register the various notches in the
blank to an accuracy of ¹/₃₂ in. and to locate the stitches in some
cases as closely as ¹/₆₄ in. The band was next sewed to the periphery
of the facepiece after which the harness was attached. The stitches
on the outside of the facepiece were covered with liquid dope, which
filled the needle holes and made the seams gas-tight.

“In addition to the inspection of each operation, the completed
facepiece was submitted to a control inspection to discover any defects
that might escape the attention of the inspectors on the various
operations.

“ASSEMBLY OPERATIONS—The facepieces were now ready for assembly and
were sent for insertion of the eyepieces, which was done in specially
designed automatic presses. The eyepieces had to be carefully inserted
so that the facepiece fabric extended evenly around the entire
circumference.

“Before manufacture began on a large scale, the most satisfactory
method of conducting each assembly operation was worked out and
the details standardized, so that operators could be quickly and
efficiently trained. No detail was considered too small if it improved
the quality of the mask. The assembly operations proceeded as follows:

“The exhalation valve was first joined to the three-way metal tube
which formed the connection between the facepiece, flexible hose, and
mouthpiece. Each valve was then tested for leakage under a pressure
difference of a one inch head of water. No valve was accepted which
showed leakage in excess of 10 cc. per min. under these conditions.

“The metal guard to protect the exhalation valve was next assembled,
followed by the flexible hose. The three-way tube was then assembled
to the facepiece by means of a threaded connection and the rubber
mouthpiece attached. To illustrate the attention to details the
following operation may be cited:

    “The contact surfaces between each rubber and metal
    part were coated with rubber cement before the parts
    were assembled. The connection was then tightly wired,
    care being taken that none of the turns of wire should
    cross and finally the wire was covered with adhesive
    tape so that no sharp edges would be exposed.

    “The masks, completely assembled except for the
    canisters, were inspected and hung on racks on
    specially designed trucks which prevented injury in
    transit, and were delivered to the Finishing Department.

“CANISTER FILLING—Meanwhile the canisters were being filled, in another
building.

“The chemicals were first screened in such a way that the fine and
coarse materials were separated from the correctly sized materials.
They were then carried on a belt conveyor to the storage bins, whence
they were fed by gravity through pipes to various mixing machines. A
special mixing machine was developed to mix the carbon and granules in
the proper proportions for use in the canister. The mixed chemicals
were then led to the canister-filling machines. There was a separate
mixing machine for each filling machine, of which there were eighteen
in all.

“The can-filling department was laid out in six units. Each unit had a
capacity of 20,000 cans per day. A system of double belt conveyors was
installed to conduct empty canisters to the machines and carry away the
filled ones.

“Each filling operation was carefully inspected and special stops were
placed on the belt conveyors so that a canister could not go to the
next operation without having been inspected. Operators and inspectors
were stationed on opposite sides of the belt. The chemicals were placed
in the canister in three equal layers which were separated by pads of
cotton wadding. The first layer was introduced from the filling machine
(which delivered automatically the proper volume of chemicals), the
canister was shaken to pack the chemicals tightly, the cotton baffle
inserted, the second layer of chemicals introduced and so forth. On top
of the top layer of chemicals were placed a wire screen and a specially
designed spring which held the contents of the canister securely in
place. The metal top was then fitted and securely soldered.

“Each canister was tested under water for possible leaks in joints or
soldering, with an air pressure of 5 lbs. per sq. in. A test was also
made for the resistance which it offered to breathing, a rate of flow
of air through the canister of 85 liters per min. being maintained and
the resistance being measured in inches of water.

“The filled canisters were then painted a distinctive color to indicate
the type of filling.

“FINISHING DEPARTMENT—In the finishing department, the filled
canisters, were conducted down the middle of the finishing tables and
assembled to masks.

[Illustration: FIG. 59.]

“The finished masks were then inspected, placed in unit boxes, ten to a
box, and returned for the final inspection.

“FINAL INSPECTION—Final inspection of the completely assembled masks
was as rigid as could be devised, and was closely supervised by army
representatives. Only the most painstaking, and careful women were
selected for this work and the masks were examined in every detail
to discover any defect that might have escaped previous inspection.
Finally, each mask was inspected over a bright light in a dark booth
for small pinholes which the ordinary visual inspection might not have
detected.

“As a check on the quality on the final inspectors’ work a reinspection
of 5 per cent of the passed masks was conducted. Where it was found
that a particular inspector was making numerous mistakes, her eyes were
examined to see whether it was due to faulty eyesight or careless work.
Masks containing known defects were purposely sent to these inspectors
to determine whether they were capable of continuing the inspection
work. In this way the desired standard was maintained.

“A daily report of the final inspection was sent back to each of the
assembly departments involved so that defects might be eliminated
immediately and the percentage of rejects kept as low as possible.

“After the final inspection the masks were numbered, packed in
knapsacks, and the filled knapsacks placed in packing cases,
twenty-four to a case.”


TISSOT MASK

The French, as has already been pointed out, early recognized that
certain classes of fighting men, as the artillerymen, needed the
maximum of protection with the minimum decrease in efficiency. The
result of this was the Tissot Mask. Before the United States entered
the war, the British standard box respirator had reached a greater
degree of perfection, with far greater ruggedness and portability. It
was therefore adopted as the American standard. At the time of the
invention of the British box respirator and practically up to the time
the United States entered the war, masks were worn only during the
sporadic gas attacks then occurring and only for a brief period at a
time. As the war progressed, the men were compelled to wear their masks
for much longer periods (eight hours was not uncommon). It was then
seen that more comfort was needed, even at the expense of a little
safety.

The principle of the Tissot mask was correct so far as comfort was
concerned, since it did away with the irritating mouthpiece and
noseclip, but the chief danger in the French mask arose from the fact
that the facepiece was made of thin, pure gum rubber. The Research
Division, together with the Gas Defense Division, developed two
distinct types of Tissot masks. The first of these was the Akron
Tissot, the second the Kops Tissot. The best features of these have
been combined in the 1919 Model.

[Illustration: FIG. 60.—American Tissot Mask, Early Type.]

[Illustration: FIG. 61.—American Tissot Mask, Interior View.]


1919 MODEL AMERICAN MASK

=Facepiece.= This facepiece is made of rubberized stockinet about
one-tenth inch in thickness. The stockinet is on the outside only and
is for the purpose of strengthening and protecting the rubber which is
of very high grade. The facepiece is died out as a single flat piece
from the stockinet which is furnished in long rolls. The die is of such
shape that when the facepiece is sewed there is but one seam, and that
between the angle tube opening and the edge under the chin. This seam
is sewed with a zigzag stitch with the stockinet sides flat together.
The seam is then stretched over a jig, so as to form a flat butt joint.
This seam is then cemented with rubber cement and taped, inside and
out, to make it thoroughly gas-proof.

The eyepiece openings are of oval shape with the longer axes horizontal
and considerably smaller than the finished eyepieces. The eyepieces
being circular, the cloth is stretched to accommodate them, giving the
necessary bulge to keep the cloth and metal of the eyepieces away from
the face. The harness has three straps on each side. Instead of the
single strap over the top of the head, two straps lead from directly
over the eyes, both being made of elastic the same as the other straps.
All six straps are brought together around a pad of felt and cloth
about 2½ × 3½ inches at the back of the head. This pad makes the
harness much more comfortable.

The rubberized stockinet is reinforced on the inner or rubber side with
thin bits of cloth at all points where the straps are sewed on. The
strap across the temples just above the ears is sewed at two points,
one about one-half inch from the edge and the other about two inches
from the edge. This is for the purpose of helping press the cloth
against the temples, thereby adding to the gas-tightness for those
heads that have a tendency to be hollow at the temples. The lower strap
is just above the chin and is for the purpose of giving gas-tightness
in that vicinity. All of the straps except the two over the top of the
head are attached to the pad with buckles, and are thus capable of
exact adjustment.

The eyepieces are of triplex glass in metal rings with rubber gaskets.
In pressing the rings home, the rubberized stockinet is turned and held
securely so that there is no possibility of pulling them out. The angle
tube containing the outlet valve and the connection to the corrugated
tube connecting with the canister is the same as with the latest model
R. F. K. mask. The only difference as regards the corrugated tube is
that a greater length is needed with the new carrier under the left
shoulder. The total length of the tube for this model is about 24
inches. On the inside of the facepiece and connected to the angle tube
inlet is a butterfly baffle of rubber, so arranged that the incoming
air is thrown upward and over the eyepieces, thus keeping them clear no
matter how much the exertion or what the temperature, except in certain
rare cases when the temperature is down at zero F. or below.

[Illustration: FIG. 62.—1919 Model American Mask.]


CANISTER

The canister is radically different from the canisters used in the
R. F. K. and earlier types. In the first place, it is longer, the
total length finished being 8 inches. It has two inlet valves at the
top end protected by a tin cover instead of the single inlet valve
at the bottom of the earlier types. The two inlet valves are each ⅝
inch in diameter and are made up of square flat valves on the end of a
short rubber tube. The rubber tube is fitted over a short metal tube.
Gas-tightness is obtained both by the pressing of the valve against
the round edge of the metal tube and by the pressure of the edges
against each other. These valves, while delicate, are proving very
satisfactory, and being simply check valves to prevent the air going
back through the canister, they are not vital. In case of failure, the
eyepieces would fog somewhat and the dead air space be increased by
that held in the inlet tube.

The canister consists really of two parts—an outer casing that is
solid and an inner perforated tin casing. Around the perforated tin is
fitted a filter of wool felt ³/₁₆ of an inch in thickness. This wool
felt is very securely fastened by turning operations to solid pieces
of tin, top and bottom, so that no air can get into the chemicals
without passing through the filter. Thus the air coming through the
inlet valves at the top circulates around the loosely fitting outside
corrugated case to all parts of the filter and after passing through
the filter continues through the perforations of the tin into the
charcoal and soda-lime granules.

The chemicals are packed around a central wedge-shaped tube extending
about two-thirds the length of the can. The wedge is enlarged at the
top and made circular where it passes through the top of the can to
connect with the corrugated tube. The wedge-shaped inner piece is made
of perforated tin and is covered with thin cloth to prevent dust from
the chemicals passing into the tube and thus into the lungs. The cans
are filled from the bottom and are subjected to two mechanical jarring
operations in order to settle the chemicals thoroughly before the
spring which holds them in place is added. The outer tin cap protecting
the inlet valves has two openings on each side but none at the ends of
the canister.

[Illustration: FIG. 63.—1919 Model American Mask after Adjustment.]

The carrier is a simple canvas case nearly rectangular, about one foot
wide and 15 inches in length. The width is just sufficient at the back
to hold the canister and the front part to hold the extra length of
corrugated tube and the facepiece. There are two straps, one passing
over the right shoulder and the other around the body. The one passing
over the right shoulder has two “V” shaped seams at the top so as to
change the direction of the strap over the shoulder in order that it
will pull directly downward instead of against the neck. The flap
closing the case opens outward.

It has the usual automobile curtain fasteners. A secondary fastener at
the top of the opening is arranged so that when the tube is adjusted to
the proper length and the mask is adjusted to the face of the wearer,
the flap can be buttoned tightly over the corrugated tube and held
tightly. This prevents water from entering the case.

Figures 62 and 63 show the position of the carrier both with the
facepiece in the carrier and after adjustment. It will be noted that
the carrier does not interfere with the pack nor with anything on the
front of the body. The left arm hangs almost entirely natural over
the case. It has been thoroughly tried out by the Infantry, Cavalry,
Artillery and Special Gas Troops and adopted as eminently satisfactory.


SPECIAL CANISTERS

=Navy.= The early Navy canister is a drum much like the German
canister. The container is a slightly tapered metal cylinder, 9 cm.
in diameter at the bottom. The most satisfactory filling for this
drum consists of two layers, 98 cc. in each, of a standard mixture of
charcoal and soda-lime, separated by cotton wadding pad. The filling is
6-20 mesh, instead of 8-14 mesh. A later type is shown in Figure 41.

=Carbon Monoxide.= This canister is discussed in Chapter XI.

=Ammonia.= Ammonia respirators were needed by the Navy and also by
the workmen in refrigeration plants. Early protection was obtained by
the use of pumice stone impregnated with sulfuric acid. This had many
disadvantages, such as the amount of heat evolved, the caustic fumes
produced, high resistance and corrosion of the canister. To overcome
these, the “Kupramite” canister was developed. The filling consists of
pumice stone impregnated with copper sulfate. Pumice stone, 8 to 14
mesh, and technical copper sulfate are placed in an evaporating pan
in the ratio of one part by weight CuSO₄·5H₂O to 1.5 parts pumice,
and the whole is covered with sufficient water to dissolve the salt
at boiling temperature. The mixture is then boiled down with constant
stirring until crystallization takes place on the pumice and the
crystals are nearly dry. The pumice thus treated is then removed from
the dish, spread out and allowed to dry in the air. The fines are then
screened out on a 14-mesh sieve. Care must be taken in the evaporating
process that the absorbent is still slightly moist when taken from the
pan.

[Illustration: FIG. 64.—Early Type Navy Mask. Contains noseclip and
mouthpiece.]

In packing the standard Army canister with kupramite a layer of
toweling is placed on top of the absorbent to filter out any fine
particles which might be drawn up from the absorbent, and the whole is
held in place by the usual heavy wire screen and spring. This method of
packing is to be used with the present mouthpiece type of army mask.
If the new Tissot type mask is used, a modification of the packing is
desirable in order to eliminate the trouble due to moisture given off
by the absorbent during service condensing on the eyepieces of the mask
and thus impairing the vision of the wearer. To remedy this defect a
1-in. layer of kupramite at the top of the canister is replaced by
activated charcoal or silica gel, preferably silica gel. This decreases
the humidity of the effluent air sufficiently to prevent dimming of the
eyepieces. If charcoal is used, a 2-8 cotton pad (Eastern Star Furrier
Co., Pawtucket, R. I.) is substituted for the toweling in order to
remove charcoal dust. The canister complete weighs about 1.7 lbs.

[Illustration: FIG. 65.—Ammonia Canister—“Kupramite.”]

A canister containing 45 cu. in. of this material will protect a man
breathing at rest for at least 5 hours against 2 per cent ammonia and
for 2½ hours against 5 per cent ammonia. Its advantages are large
capacity and activity, negligible heat of absorption, and cheapness.


PHYSIOLOGICAL FEATURES OF THE MASK

For some time after the introduction of gas warfare, the gases used
were of the so-called non-persistent type. Under these conditions it
was necessary to wear the mask for only relatively short periods,
after which the cloud dissipated. With the increasing use of gas and
the introduction of the more persistent gases, particularly mustard
gas, it not only became necessary to wear the mask for long periods of
time but also to do relatively heavy physical work, such as serving
artillery, when wearing the mask.

[Illustration: FIG. 66.—Ammonia Mask, Showing Relative Size of
Canister.]

Under these conditions, it became evident that the wearing of the
mask caused a very great reduction in the military efficiency of
the soldier. The reasons for this reduction in efficiency have been
made the subject of extensive research by a group of the foremost
physiologists and psychologists of the country. As a result of their
work, the causes contributing to this reduction in efficiency may be
grouped about the following main factors:

(1) The physical discomfort of the mask arising from causes such as
pressure on the head and face, due to improperly fitting facepieces and
harness, the noseclip, and the mouthpiece.

(2) Abnormal conditions of vision, due to poor optical qualities in eye
pieces and restrictions of vision, both as to total field and binocular
field.

(3) Abnormal conditions of respiration, among them being (_a_) the
unnatural channels of respiration caused by wearing the box respirator,
(_b_) increase in dead air space in respiratory circuit, and (_c_) the
increase in resistance to both inhalation and exhalation, the last two
mentioned being present to a greater or less degree in all types of
mask.

Of these general subdivisions the various phases of the first two are
so evident that no further discussion will be given. The effects of
the changed conditions of respiration are, however, less obvious, and
it may be of interest to present in a general way the results of the
research along this line, particularly as regards the harmful effects
of increasing the resistance and dead air space in the respiratory
tract above the normal.

The function of respiration is to supply oxygen to and remove carbon
dioxide from the blood as it passes through the lungs. This interchange
of gases takes place in the alveoli, a myriad of thin-walled air sacs
at the end of the respiratory tract where the air is separated by a
very thin membrane through which the gases readily pass. The volume
and rate, or in other words, the minute-volume, of respiration is
automatically controlled by the nerve centers in such a way that a
sufficient amount of air is supplied to the lungs to maintain by means
of this interchange a uniform percentage of its various constituents
as it leaves the lungs. It will be readily seen therefore, that
anything which causes a change in the composition of the air presented
to the blood in the alveoli will bring about abnormal conditions of
respiration.

Inasmuch as the gaseous interchange between the lungs and the blood
takes place only in the terminal air sacs it follows that, at the end
of each respiration, the rest of the respiratory tract is filled with
air low in oxygen and high in carbon dioxide, which on inspiration
is drawn back into the lungs, diluting the fresh air. The volume of
these passages holding air which must be re-breathed is known as the
anatomical dead air space.

Similarly, when a mask is worn the facepiece chamber and any other
parts of the air passage common to inspiration and expiration become
additional dead air space contributing a further dilution of oxygen
content and contamination by carbon dioxide of the inspired air in
addition to that occasioned by the anatomical dead space, which of
course, is always present and is taken care of by the functions
normally controlling respiration.

Major R. G. Pearce who directed a large amount of the research along
this line, sums up the harmful effects of thus increasing the dead air
space as follows:

1. Interpretation from the physiological standpoint:

(_a_) A larger minute-volume of air is required when breathing through
dead air space. This, interpreted on physiological grounds, means that
the carbon dioxide content of the arterial blood is higher than normal.
The level to which the content of carbon dioxide in the arterial blood
may rise is limited. Anything which wastefully increases the carbon
dioxide level of the blood decreases the reserve so necessary to a
soldier when he is asked to respond to the demand for exercise which is
a part of his daily life.

(_b_) A larger minute-volume of air must be pulled through the
canister, which offers resistance proportional to the volume of air
passing through it. If resistance is a factor of harm, dead air space
increases that harm, since dead air space increases the volume of air
passing through the canister.

(_c_) As will be noted below, the effect of resistance is a tendency to
decrease the minute-volume of air breathed. Dead air space increases
the minute-volume. Accordingly, if breathing is accomplished against
resistance and through a large volume of dead air space, the volume
of air breathed is reduced more in proportion to the actual needs of
the body than when breathing against resistance without the additional
factor of dead space; this, again, causes the level of carbon dioxide
in the blood and tissues to be raised to a higher level than normal,
and thus again there is some reserve power wasted.

2. Interpretation from the standpoint of the canister.

The life of the canister depends on the volume of the gas-laden air
passed through it. The dead space increases the minute-volume of air
passed through the canister and, therefore, shortens its life.

Physiologically, the reason for the harmful effects of breathing
resistance is more involved:

    “The importance of resistance to breathing lies in: (1)
    the effect on the circulation of the blood, and (2) the
    changes in the lung tissue, which seriously interfere
    with the gas exchange between the outside air and the
    blood. Data have been presented to draw attention to
    the seriousness of resistance to inspiration. In these
    reports, it was suggested that the deleterious effects
    on the body consist in changes in the blood pressure,
    increased work of the right side of the heart, and an
    increase in the blood and lymph content of the lungs.
    Resistance also decreases the minute-volume of air
    breathed and thereby increases the percentage of carbon
    dioxide in the expired air. The foregoing changes are
    all deleterious.

    “Although the chief problem of resistance in gas mask
    design concerns inspiration, nevertheless _resistance
    to expiration_ is an important factor. The expired
    air of the lungs contains carbon dioxide for which
    means of escape must be provided. The expiratory act is
    more passive than the inspiratory act, and resistance
    to expiration is, therefore, more keenly felt than
    resistance to inspiration. It is then imperative that
    the exhale valve be so arranged as to allow for the
    escape of the entire amount of air during the time of
    expiration with the least possible resistance. The data
    of the laboratory indicate that seldom, if ever, do
    expiratory rates rise above a velocity of 150 to 175
    per minute. The effect of resistance to exhalation upon
    the vital organs of the body is not dissimilar to that
    of inspiration.”




CHAPTER XIII

ABSORBENTS[27]


The absorbents used in both the British and American gas mask canister,
which afforded a degree of protection far superior to that of any
other allied or enemy nation except Germany, consisted of a mixture
of charcoal and soda-lime, as described in the preceding chapter. In
general, a gas mask absorbent must have certain requirements. These
are: absorptive activity, absorptive capacity, versatility, mechanical
strength, chemical stability, low breathing resistance, ease of
manufacture and availability of raw materials.

[Footnote 27: The basis of this chapter is the series of articles by
Lamb and co-workers which appeared in the _J. Ind. Eng. Chem._ for
1919.]

_Absorptive activity_, or a very high rate of absorption, is one of
the more important properties of a satisfactory absorbent. A normal
man when exercising violently breathes about 60 liters of air per
minute, and since inhalation occupies but slightly more than half of
the breathing cycle, the actual rate at which gas passes through the
canister during inhalation is about 100 liters per minute. Calculated
on the basis of the regular army canister, this corresponds to an
average linear air velocity of about 80 cm. per second. On the average,
therefore, a given small portion of the air remains in contact with
the gas absorbent for only about 0.1 second. Besides this, the removal
of the toxic material must be surprisingly complete. Though the
concentration entering the canister may occasionally be as high as one
half per cent, even the momentary leakage of 0.001 per cent (ten parts
per million) would cause serious discomfort and the prolonged leakage
of smaller amounts would have serious results in the case of some
gases. The activity of the present gas mask charcoal is shown by the
fact that it will reduce a concentration of 7000 parts per million of
chloropicrin to less than 0.5 part per million in less than 0.03 second.

Of equal importance is the _absorptive capacity_. That is, the
absorbent must be able to absorb and hold large amounts of gas per
unit weight of absorbent. Its life must be measured in days against
ordinary concentrations of gas. It is further necessary that the gas
be held firmly and not in any loose combination which might give up
minute traces of gas when air is, for long periods of time, breathed in
through a canister which has previously been exposed to gas.

The absorbents used must be of a type which can be relied upon to
give adequate protection against practically any kind of toxic gas
(_versatility_). The need of this is apparent when the difficulty of
having separate canisters for various gases is considered, as well
as the difficulty in rapidly and accurately identifying the gases
and the possible introduction of new and unknown gases. Fortunately,
practically all of the toxic gases are very reactive chemically or have
relatively high boiling points and can therefore be absorbed in large
amounts by charcoal.

Absorbents must be _mechanically strong_ in order to retain their
structure and porosity under conditions of transport and field use.
Further, they must not be subject to abrasion for the production of a
relatively small amount of fines would tend to plug the canister or to
cause channels through which the gas would pass without being absorbed.

Since the canister is filled several months before it is first used
in the trenches, and since the canister may be used over a period of
months before it is discarded, it is obviously the ultimate activity
and capacity (not the initial efficiency) which determines the value
of an absorbent. It must therefore have a very considerable degree of
_chemical stability_. By this is meant that the absorbent itself is
not subject to chemical deterioration, that it does not react with
carbon dioxide, that it does not disintegrate or become deliquescent
even after being used and that it has no corrosive action on the metal
container.

In a good general absorbent there must be a proper balance between its
various essential qualities, and hence the most suitable mixture will
probably always be a compromise.


CHARCOAL

The fact that charcoal would condense in its pores or adsorb certain
gases, holding them firmly, had been known for a long time.[28] In
general, it was known that so-called animal charcoal was the best
for decolorizing sugar solutions, that wood charcoal was the best
for adsorbing gases and that coke had very little adsorbing or
decolorizing power. No one knew the reason for these facts and no one
could write a specification for charcoal. The ordinary charcoal used
in the scientific laboratory was cocoanut charcoal, since Hunter had
discovered more than fifty years ago that this was the best charcoal
for adsorbing gases.


RAW MATERIALS[29]

The first charcoal designed to offer protection against chlorine and
phosgene was made by carbonizing red cedar. Since this had little value
against chloropicrin, attention was turned to cocoanut shell as the
source of raw material. This charcoal fulfilled the above conditions
for a satisfactory absorbent better than any other form tested. It must
not be supposed, however, that investigation of carbon stopped with
these experiments. In the search for the ideal carbon, practically
almost every hard vegetable substance known was tested. Next to
cocoanut shells, the fruit pits, several common varieties of nuts
abundant in the United States, and several tropical nuts (especially
cohune nuts), were found to make the best carbon. Pecan nuts, and all
woods ranging in hardness from iron wood down to ordinary pine and
fir, were found to be in the second class of efficiency. Among other
substances tested were almonds, Arabian acorns, grape seeds, Brazil
nut husks, balsa, osage orange, Chinese velvet bean, synthetic carbons
(from coal, lamp-black, etc.), cocoa bean shell, coffee grounds, flint
corn, corn cobs, cotton seed husks, peanut shells and oil shale. While
many of these substances might have been used in an emergency, none of
them would produce carbon as efficient, volume for volume, as that of
the cocoanut shell and other hard nuts.

[Footnote 28: Bancroft (_J. Phys. Chem._ =24=, 127, 201, 342 [1920])
gives a comprehensive review of “Charcoal before the War.”]

[Footnote 29: Part of this section is quoted from “Armies of Industry,”
by Crowell and Wilson, Yale Univ. Press.]

Some idea of the scale of charcoal production may be seen from the
requirement for cocoanut shells. When we first began to build masks our
demands for carboniferous materials ranged from 40 to 50 tons a day
of raw material; by the end of the war, we were in need of a supply
of 400 tons of cocoanut shells per day. This demand would absorb the
entire cocoanut production of tropical America five times over. (The
total production of cocoanuts in Central America, the West Indies and
the Caribbean Coast of South America amounted to 131,000,000 nuts
annually, equal to a supply of 75 tons of shells daily.) It was equal
to one-tenth of the total production of the Orient, which amounted to
7,450,200,000 nuts annually. This large demand always made a reserve
supply of charcoal material practically impossible. The “Eat More
Cocoanut” campaign started by the Gas Defense more than doubled the
American consumption of cocoanut in a brief space of time and in
October, 1918, with the help of importation of shell, we averaged about
150 tons of shells per day, exclusive of the Orient.

The first heating of cocoanut shells to make charcoal reduces
their weight 75 per cent. It was evident, therefore, that we could
more economically ship our oriental supply in the form of charcoal
produced on the other side of the Pacific Ocean. A charcoal plant was
established in the Philippine Islands and agents were sent to all parts
of the Oriental countries to purchase enormous supplies of shells.
While the work was only gaining momentum when the Armistice was signed,
the plant actually shipped 300 tons of cocoanut shell carbon to the
United States and had over 1000 tons on hand November 11, 1918.

In the search for other tropical nuts, it was found that the cohune
or corozo nut was the best. These nuts are the fruit of the manaca
palm tree. They grow in clusters, like bananas or dates, one to four
clusters to a tree, each cluster yielding from 60 to 75 pounds of
nuts. They grow principally on the west coast of Central America in
low, swampy regions from Mexico to Panama but are also found along the
Caribbean coast. The chief virtue of the cohune nut from the charcoal
point of view was its extreme thickness of shell; this nut is 3 inches
or more in length and nearly 2 inches in diameter but the kernel is
very small. Four thousand tons per month were being imported at the
time of the Armistice. A disadvantage in the use of cohune nuts was
that their husks contained a considerable amount of acid which rotted
the jute bags and also caused the heaps of nuts to heat in storage.

A third source of tropical material was in the ivory nuts used in
considerable quantities in this country by the makers of buttons.
There is a waste of 400-500 tons per month of this material, which was
used after screening out the dust. This material is rather expensive,
because it is normally used in the manufacture of lactic acid.

Another great branch of activity in securing carbon supplies was
concerned with the apricot, peach and cherry pits and walnut shells of
the Pacific Coast. A nation-wide campaign on the part of the American
Red Cross was started on September 13, 1918. Between this time and the
Armistice some 4,000 tons of material were collected. Thus the slogan
“Help us to give him the best gas mask” made its appeal to every person
in the United States.


A THEORY OF CHARCOAL ACTION

It has been pointed out that the first charcoal was made from red
cedar. While this was very satisfactory when tested against chlorine,
it was of no value against chloropicrin. In order to improve the
charcoal still further it was desirable to have some theory as to
the way charcoal acted. It was generally agreed that fine pores were
essential. The functioning of charcoal depends upon its adsorptive
power and this in turn upon its porosity. The greater the ratio of
its surface to its mass, that is, the more highly developed and
fine grained its porosity, the greater its value. Another factor,
however, seemed to play a rôle. As a pure hypothesis, at first, Chaney
assumed that an active charcoal could only be secured by removing the
hydrocarbon which he assumed to be present after carbonization. Being
difficultly volatile, these hydrocarbons prevent the adsorption of
other gases or vapors on the active material. To prove this, red cedar
charcoal was heated in a bomb connected with a pump which drew air
through the bomb. Although the charcoal had been carbonized at 800°,
various gases and vapor began to come off at 300°, and when cooled,
condensed to crystalline plates.

This experiment not only proved the existence of components containing
hydrogen in the charcoal, but also showed that one way of removing the
hydrocarbon film on the active carbon was to treat with an oxidizing
agent.

In the light of the later experimental work Chaney feels that there are
two forms of elementary carbon—“active” and “inactive”; the active form
is characterized by a high specific adsorptive capacity for gas while
the inactive form lacks this property. In general the temperature of
formation of the active form is below 500-600° C. The form is easily
attacked by oxidizing agents—while the latter is relatively stable.
The combination of active carbon with an adsorbed layer or layers of
hydrocarbon is known as “primary” carbon. Anthracite and bituminous
coal are native primary carbons, while coke contains a considerable
amount of inactive carbon, resulting from the decomposition of
hydrocarbon during its preparation.


PREPARATION OF ACTIVE CHARCOAL

“On the basis of the above discussion, the preparation of active
charcoal will evidently involve two steps:

“First.—The formation of a porous, amorphous base carbon at a
relatively low temperature.

“Second.—The removal of the adsorbed hydrocarbons from the primary
carbon, and the increase of its porosity.

“The first step presents no very serious difficulties. It involves,
in the case of woods and similar materials, a process of destructive
distillation at relatively low temperatures. The deposition of
inactive carbon, resulting from the cracking of hydrocarbons at high
temperatures, must be avoided. The material is therefore charged into
the retorts in thin layers, so that the contact of the hydrocarbon
vapors with hot charcoal is avoided as much as possible. Furthermore,
most of the hydrocarbon is removed before dangerous temperatures are
reached. A slight suction is maintained to prevent outward leaks,
but no activation by oxidation is attempted, as this can be carried
on under better control and with less loss of material in a separate
treatment.

[Illustration: FIG. 67. Dorsey Reactor for Activating Cocoanut Charcoal
with Steam.]

“The second step, that is, the removal of the absorbed hydrocarbons
from the primary carbon, is a much more difficult matter. Prolonged
heating, at sufficiently high temperatures, is required to remove or
break up the hydrocarbon residues. On the other hand, volatilization
and cracking of the hydrocarbons at high temperatures is certain to
produce an inactive form of carbon more or less like graphite in its
visible characteristics, which is not only inert and non-adsorbent,
but is also highly resistant to oxidation. The general method of
procedure which has yielded the best results, is to remove the
adsorbed hydrocarbons by various processes of combined oxidation
and distillation, whereby the hydrocarbons of high boiling points
are broken down into more volatile substances and removed at lower
temperatures, or under conditions less likely to result in subsequent
deposition of inactive carbon. Thin layers of charcoal and rapid gas
currents are used so that contact between the volatilized hydrocarbons
and the hot active charcoal may be as brief as possible. In this way
cracking of the hydrocarbons at high temperature, with consequent
deposition of inactive carbon, is largely avoided.

“While the removal of the hydrocarbons by oxidation and distillation
is the main object of the activation process, another important
action goes on at the same time, namely, the oxidation of the primary
carbon itself. This oxidation is doubtless advantageous, up to a
certain point, for it probably at first enlarges, at the expense of
the walls of solid carbon, cavities already present in the charcoal,
thus increasing the total surface exposed. Moreover, the outer ends
of the capillary pores and fissures must be somewhat enlarged by this
action and a readier access thus provided to the inner portions of the
charcoal. However, as soon as the eating away of the carbon wall begins
to unite cavities, it decreases, rather than increases, the surface of
the charcoal, and a consequent drop in volume activity, that is in the
service time, of the charcoal, is found to result.

“It is obvious, therefore, that conditions of activation must be so
chosen and regulated as to oxidize the hydrocarbons rapidly and the
primary carbon slowly. Such a differential oxidation is not easy
to secure since the hydrocarbons involved have a very low hydrogen
content, and are not much more easily oxidized than the primary
carbon itself. Furthermore, most of the hydrocarbons to be removed
are shut up in the interior of the granule. On the one hand, a high
enough temperature must be maintained to oxidize the hydrocarbons
with reasonable speed; on the other hand, too high a temperature must
not be employed, else the primary carbon will be unduly consumed. The
permissible range is a relatively narrow one, only about 50 to 75°.
The location of the optimum activating temperature depends upon the
oxidizing agent employed and upon other variables as well; for air, it
has been found to lie somewhere between 350 and 450°, and for steam
between 800 and 1000°.

“The air activation process has the advantage of operating at a
conveniently low temperature. It has the disadvantage, that local
heating and an excessive consumption of primary carbon occur, so that a
drop in volume activity results from that cause before the hydrocarbons
have been completely eliminated. As a consequence, charcoal of the
highest activity cannot be obtained by the air activation process.”

The steam activation process has the disadvantage that it operates
at so high a temperature that the regulation of temperature becomes
difficult and other technical difficulties are introduced. It has the
advantage that local heating is eliminated. The hydrocarbons can,
therefore, be largely removed without a disproportionate consumption of
primary carbon. This permits the production of a very active charcoal.

It has the further advantage that it worked well with all kinds of
charcoal. Inferior material, when treated with steam, gave charcoal
nearly as good as the best steam-treated cocoanut charcoal. Because of
the shortage of cocoanut, this was a very important consideration.

[Illustration: FIG. 68.—Section of Raw Cocoanut Shell. Magnified 146½
diameters.]

The air, steam and also carbon dioxide-steam activation processes have
all been employed on a large scale by the Chemical Warfare Service for
the manufacture of gas mask carbon.

[Illustration: FIG. 69.—Section of Carbonized Cocoanut Charcoal.
Magnified 146½ Diameters.]

[Illustration: FIG. 70.—Two-Minute Charcoal not Activated. Magnified
732 Diameters.]

    “The above considerations are illustrated fairly well
    by the photo-micrographs shown in Figs. 68 to 71. Fig.
    68 shows a section of the original untreated cocoanut
    shell crosswise to the long axis of the shell. In it
    can be seen the closely packed, thick-walled so-called
    ‘stone-cells’ characteristic of all hard and dense nut
    shells. Fig. 69 is a photograph of a similar section
    through the same cocoanut shell after it has been
    carbonized. As these photographs are all taken with
    vertical illumination against a dark background, the
    cavities, or voids, and depressions all appear black,
    while the charcoal itself appears white. It is clear
    from this photograph that much of the original grosser
    structure of the shell persists in the carbonized
    products. Figs. 70 and 71 are more highly magnified
    photographs of a carbonized charcoal before and after
    activation, respectively. As before, all the dark
    areas represent voids of little or no importance in
    the adsorptive activity of the charcoal, while the
    white areas represent the charcoal itself. In Fig. 70
    (unactivated) the charcoal itself between the voids
    it seen to be relatively compact, while in Fig. 71
    (activated) it is decidedly granular. This granular
    structure, just visible at this high magnification
    (1000 diameters), probably represents the grosser
    porous structure on which the adsorption really
    depends. These photographs, therefore, show how the
    porosity is increased by activation.”

[Illustration: FIG. 71.—31-Minute Steam Activated Charcoal. Magnified
732 Diameters.]

The great demand for charcoal, and the need for activating other than
cocoanut charcoal led to the development of the Dressler tunnel kiln,
which seemed to offer many advantages over the Dorsey type of treater.

[Illustration: FIG. 72.—Sectional View of Dressler Tunnel Kiln, Adapted
to Activation of Charcoal.]

    “The Dressler tunnel kiln is a type used in general
    ceramic work. The furnace consists essentially of a
    brick kiln about 190 ft. long, 12 ft. broad, and 9
    ft. high, lined with fire brick. Charcoal is loaded
    in shallow, refractory trays in small tram cars,
    about 120 trays to the car. The cars enter the kiln
    through a double door and the charcoal remains in the
    hot zone at a temperature of about 850° C. for about
    4 hrs., depending upon the nature of the material
    charged. Water is atomized into this kiln, and a
    positive pressure maintained in order to exclude
    entrance of air. The kiln is gas-fired and the charcoal
    is activated by the steam in the presence of the
    combustion gases.

    “Under such treatment the charcoal is given a high
    degree of activation without the usual accompanying
    high losses. Seemingly the oxidizing medium used,
    together with the operating conditions, produce a
    deep penetration of the charcoal particles without
    increasing the extensive surface combustion experienced
    in the steam activators. The capacity of such a type
    furnace is limited only by the size of the installation.

“The advantages of this type furnace may be tabulated as follows:

    1—High quality of product.
    2—Small weight and volume losses.
    3—Large capacity per unit.
    4—Minimum initial cost and maintenance of installation.
    5—Simplicity and cheapness of operation.
    6—Adaptability to activation of all carbon materials.
    7—Availability of furnaces of this general type already constructed.”


SUBSTITUTES FOR NUT CHARCOAL

The first experiments were made with a special anthracite coal
(non-laminated and having conchoidal fracture). This had a life of 560
minutes as against 360 minutes for air treated cocoanut charcoal and
800-900 minutes for steam-treated charcoal.

When the Gas Defense Service tried to activate anthracite on a large
scale in vertical gas retorts at Derby, Connecticut, the attempt was
a failure. They carbonized at 900° and then turned on the steam with
the result that the steam-treated coal had a slightly greater density
than the untreated, which was wrong, and had a shiny appearance in
parts with roughened deposits in other parts. When the hydrocarbons
are decomposed at high temperatures, the resulting carbon is somewhat
graphitic, is itself inactive, is not readily oxidized, and impairs
or prevents the activation of the normal carbon upon which it is
deposited. This discovery made it possible to treat anthracite
successfully. The conditions must be such as to minimize high
temperature cracking, to carry off or oxidize the hydrocarbons as fast
as formed, and especially to prevent the gases from cooler portions of
the treater coming in contact with carbon at a much higher temperature.
With these facts in mind, a plant was built at Springfield which
produced 10 tons a day of 150-300 minute charcoal from raw anthracite.
This was one-third of the total production at that time and was mixed
with the nut charcoal made at Astoria, thereby preventing an absolute
shortage of canister-filling material in October, 1918.

It was next shown that the cocoanut charcoal fines resulting from
grinding and screening losses and amounting to 50 per cent of the
product, could be very finely ground, mixed with a binder, and baked
like ordinary carbon products. By avoiding gas-treating in the bake,
the resulting charcoal is nearly as good as that from the original
shell. A recovery plant for treating the cocoanut fines was built at
Astoria. The product was called “Coalite.”

The great advantage of cocoanut shell as a source of charcoal is that
it is very dense and consequently it is possible to convert it into a
mass having a large number of fine pores, whereas a less dense wood,
like cedar, will necessarily give more larger pores, which are of
relatively little value. The cocoanut charcoal is also pretty resistant
to oxidation which seems to make selective oxidation a more simple
matter. By briquetting different woods, it is possible to make charcoal
from them which is nearly equal to that from cocoanut shell.

By heating lamp-black with sulfur and briquetting, it was possible to
make a charcoal having approximately the same service time as cocoanut
charcoal. A charcoal was made by emulsifying carbon black with soft
pitch, which gave the equivalent of 400 minutes against chloropicrin
before it had been steam-treated. This looked so good that the plans
were drawn for making a thousand pounds or more of this product at
Washington to give it a thorough test. This was not done on account
of the cessation of all research work. The possible advantage of this
product was the more uniform distribution of binder.

Instead of steam-treating anthracite coal direct, it was also
pulverized, mixed with a binder, and baked into rods which were then
ground and activated with steam. The resulting material, which was
known as Carbonite, had somewhat less activity than the lamp-black
mixes but was very much cheaper. A plant was built to bake 40 tons a
day of this material, which would yield 10 tons a day of active carbon
after allowing for grinding losses and steam treatment. The plant was
guaranteed to furnish an absorbent having a life of 600 minutes against
chloropicrin.


GERMAN CHARCOAL

After the Armistice was signed, Chaney took up the question of how
the Germans made their charcoal. The German charcoal was made from
coniferous wood and was reported to be as good as ours, in spite of
the fact that they were using inferior materials. Inside of a month
Chaney had found out how the German charcoal was made, had duplicated
their material, and had shown that it was nothing like as good as
our charcoal. The Germans impregnated the wood with zinc chloride,
carbonized at red heat, and washed out most of the zinc chloride. When
this zinc chloride was found in the German charcoal, it was assumed
that it had been added after the charcoal had been made. It was
therefore dissolved out with hydrochloric acid, thereby improving the
charcoal against chloropicrin. The German charcoal was then tested as
it stood, including the fines, against American charcoal, 8 to 14 mesh.
The most serious error, however, was in testing only against a high
concentration of chloropicrin. The German charcoal contains relatively
coarse pores which condense gases at high concentrations very well but
which do not absorb gases strongly at low concentrations. The result
was that the German charcoal was rated as being four or five times as
good as it really was.

[Illustration: German Charcoal. ×200.]

[Illustration: FIG. 73.—Charcoal from Spruce Wood.]


COMPARISON OF CHARCOAL

The following table shows a comparison of charcoals from different
sources. The method of activation was identical and the times of
treatment were those approximately giving the highest service time. The
results against chloropicrin, therefore, represent roughly the relative
excellence of the charcoal obtainable from various raw materials, using
this method of activation:

       COMPARISON OF VARIOUS ACTIVE CHARCOALS ACTIVATED IN LABORATORY
    -----------------+-----------------+---------------+----------------
                     |                 |               |  Accelerated
                     |    Apparent     |Steam Treatment|  Chloropicrin
                     |     Density     |   at 900°     |  Test Results
      Base Material  +-------+---------+----+----------+--------+-------
                     |Primary|Activated|Time|  Weight  | Weight |Service
                     |Carbon | Carbon  |Min.|   Loss   |Absorbed| Time
                     |       |         |    | Per Cent |Per Cent| Min.
    -----------------+-------+---------+----+----------+--------+-------
    Sycamore         | 0.158 |  0.080  |  18|    53    |   41   |  7.3
    Cedar            | 0.223 |  0.097  |  60|    88    |   78   | 16.0
    Mountain mahogany| 0.420 |  0.236  |  60|    44    |   32   | 16.3
    Ironwood         | 0.465 |  0.331  |  60|    44    |   31   | 20.8
    Brazil nut       | 0.520 |  0.316  | 120|    71    |   46   | 32.2
    Ivory nut        | 0.700 |  0.460  | 120|    70    |   48   | 47.0
    Cohune nut       | 0.659 |  0.502  | 120|    48    |   51   | 53.4
    Babassu nut      | 0.540 |  0.322  | 210|    68    |   85   | 58.7
    Cocoanut         | 0.710 |  0.445  | 120|    60    |   61   | 58.4
    Cocoanut         | 0.710 |  0.417  | 180|    75    |   72   | 64.4
    -----------------+-------+---------+----+----------+--------+-------

                         BRIQUETTED MATERIALS
    -----------------+-------+---------+----+----------+--------+-------
    Sawdust          | 0.542 |  0.365  | 120|    66    |   53   | 40.0
    Carbon black     | 0.769 |  0.444  | 240|    64.3  |   53   | 50.5
    Bituminous coal  | 0.789 |  0.430  | 165|    61    |   58.3 | 46.8
    Anthracite coal  | 0.830 |  0.371  | 480|    81    |   53   | 40.7
    -----------------+-------+---------+----+----------+--------+-------

    “In conclusion, it will be of interest to compare
    the charcoals manufactured and used by the principal
    belligerent nations, both with one another and with the
    above mentioned laboratory preparations. Data on these
    charcoals are given in the following table:

    COMPARISON OF TYPICAL PRODUCTION CHARCOALS OF THE PRINCIPAL
                        BELLIGERENT NATIONS
    --------+----------+-------------+--------+-------+-----------------
            |          |             |Apparent|Service|
    Country |   Date   |Raw Material |Density | Time  |     Remarks
            |          |             |        | Corr. |
            |          |             |        |to 8-14|
            |          |             |        | Mesh  |
    --------+----------+-------------+--------+-------+-----------------
    U. S. A.|Nov. 1917 |Cocoanut     |  0.60  |  10   |Air activated
    U. S. A.|June, 1918|Mixed nuts,  |  0.58  |  18   |Steam activated
            |          |   etc.      |        |       |
    U. S. A.|Nov. 1918 |Cocoanut     |  0.51  |  34   |Steam activated
    England |   1917   |Wood         |  0.27  |   6   |Long distillation
    England |Aug. 1918 |Peach stones,|  0.54  |  16   |
            |          |   etc.      |        |       |
    France  | 1917-18  |Wood         |  0.23  |   2   |
    Germany |  Early   |Wood         |    ?   |   3   |Chemical and
            |          |             |        |       | steam treatment
    Germany |June, 1917|Wood         |  0.25  |  33   |Chemical and
            |          |             |        |       | steam treatment
    Germany |June, 1918|Wood         |  0.24  |  42   |Chemical and
            |          |             |        |       | steam treatment
    --------+----------+-------------+--------+-------+-----------------

    “It is at once evident that the service time of most
    of these charcoals is very much less than was obtained
    with the laboratory samples. However, in the emergency
    production of this material on a large scale, quantity
    and speed were far more important than the absolute
    excellence of the product. It will be noted, for
    instance, that the cocoanut charcoal manufactured by
    the United States, even in November, 1918, was still
    very much inferior to the laboratory samples made from
    the same raw material. This was not because a very
    active charcoal could not be produced on a large scale,
    for even in May, 1918, the possibility of manufacturing
    a 50-min. charcoal on a large scale had been
    conclusively demonstrated, but this activation would
    have required two or three times as much raw material
    and five times as much apparatus as was then available,
    due to the much longer time of heating, and the greater
    losses of carbon occasioned thereby.

    “It should furthermore be pointed out that the increase
    in the chloropicrin service time of charcoal from
    18 to 50 min. does not represent anything like a
    proportionate increase in its value under field service
    conditions. This is partly due to the fact that the
    increased absorption on the high concentration tests
    is in reality due to condensation in the capillaries,
    which, as has been pointed out, is not of much real
    value. More important than this, however, is the fact
    that most of the important gases used in warfare are
    not held by adsorption only, but by combined adsorption
    and chemical reaction, for which purpose an 18-min.
    charcoal is, in general, almost as good as a 50-min.
    charcoal.”


TYPICAL ABSORPTIVE VALUES OF DIFFERENT CHARCOALS AGAINST VARIOUS GASES

    LEGEND:
    (A) = H₂O Content, (%)
    (B) = Accel. Chloropicrin Service Time, (Min.)
    (C) = Chloropicrin
    (D) = Phosgene
    (E) = Hydrocyanic Acid
    (F) = Arsine
    (G) = Cyanogen Chloride
    (H) = Trichloromethylchloroformate
    (I) = Chlorine
    ---+-----------------+--------+---+-----+---------------------------
       |                 |        |   |     |   Service Time, Minutes
       |                 |        |   |     |    Standard Conditions
    No.|     Charcoal    | Nation |   |     +---+---+---+---+---+---+---
       |                 |        |(A)| (B) |(C)|(D)|(E)|(F)|(G)|(H)|(I)
    ---+-----------------+--------+---+-----+---+---+---+---+---+---+---
     1 |Poor cocoanut    |U. S. A.| 0 |  10 |120|175| 20| 18| 55| 50|270
     2 |Medium cocoanut  |U. S. A.| 0 |  30 |350|260| 25| 25| 65| 65|370
     3 |Good cocoanut    |U. S. A.| 0 |  60 |620|310| 27| 30| 75| 70|420
     4 |Same as No. 2    |        |   |     |   |   |   |   |   |   |
       |   but wet       |U. S. A.|12 | 18  |320|330| 35| 16| 35| 95|
     5 |No. 2 impregnated|U. S. A.| 0 | 35  |400|700| 70|400| 70|190|510
     6 |Wood             |French  | 0 |  2.5| 25| 75|  9|  0|  1| 20|
     7 |Wood             |British | 0 |  6  | 70| 90| 18|  4|  5| 30|
     8 |Peach stone      |British | 0 | 16  |190|135| 30| 25| 65| 60|
     9 |Treated wood     |German  | 0 | 42  |230|105| 20| 20| 22| 25|
    10 |No. 9 impregnated|German  |30 |  9  | 90|320| 16|  1|110|120|
    ---+-----------------+--------+---+-----+---+---+---+---+---+---+---

                 STANDARD CONDITIONS OF TESTS
      Mesh of absorbent                   8-14
      Depth of absorbent layer            10 cm.
      Rate of flow per sq. cm. per min.   500 cc.
      Concentration of toxic gas          0.1 per cent
      Relative humidity                   50 per cent
      Temperature                         20°

    Results expressed in minutes to the 99 per cent efficiency points.
    Results corrected to uniform concentrations and size of particles.


SODA-LIME

Charcoal is not a satisfactory all-round absorbent because it has
too little capacity for certain highly volatile acid gases, such
as phosgene and hydrocyanic acid, and because oxidizing agents are
needed for certain gases. To overcome these deficiencies the use of
an alkali oxidizing agent in combination with the charcoal has been
found advisable. The material actually used for this purpose has been
granules of soda-lime containing sodium permanganate. Its principal
function may be said to be to act as a reservoir of large capacity for
the permanent fixation of the more volatile acid and oxidizable gases.

The development of a satisfactory soda-lime was a difficult problem.
The principal requirements follow: Its _activity_ is not of vital
importance, as the charcoal is able to take up gas with extreme
rapidity and then later give it off more slowly to the soda-lime.
_Absorptive capacity_ is of the greatest importance, since the
soda-lime is relied upon to hold in chemical combination a very
large amount of toxic gas. Both _chemical stability_ and _mechanical
strength_ are difficult to attain. The latter had never been solved
until the war made some solution absolutely imperative.


COMPOSITION OF REGULAR ARMY SODA-LIME

The exact composition of the army soda-lime has undergone considerable
modification from time to time as it has been found desirable to change
the raw materials or the method of manufacture. A rough average formula
which will serve to bring out the interrelation between the different
constituents is as follows:

     COMPOSITION OF WET MIX
                                 Per Cent
    Hydrated lime                45
    Cement                       14
    Kieselguhr                    6
    Sodium hydroxide              1
    Water                        33 (approx.)

        AFTER DRYING
    Moisture content              8 (approx.)

        AFTER SPRAYING
    Moisture content             13 (approx.)
    Sodium permanganate content   3 (approx.)

Within limits, the method of manufacture is more important than the
composition or other variables, and has been the subject of a great
deal of research work even on apparently minor details. The process
finally adopted consists essentially in making a plastic mass of lime,
cement, kieselguhr, caustic soda, and water, spreading in slabs on
wire-bottomed trays, allowing to set for 2 or 3 days under carefully
controlled conditions, drying, grinding, and screening to 8-14 mesh,
and finally spraying with a strong solution of sodium permanganate with
a specially designed spray nozzle. The spraying process is a recent
development, most of the soda-lime having been made by putting the
sodium permanganate into the original wet mix. Many difficulties had to
be overcome in developing the spraying process, but it eventually gave
a better final product, and resulted in a large saving of permanganate
which was formerly lost during drying, in fines, etc.


FUNCTION OF DIFFERENT COMPONENTS

=Lime.= The hydrated lime furnishes the backbone of the absorptive
properties of the soda-lime. It constitutes over 50 per cent of the
finished dry granule and is responsible in a chemical sense for
practically all the gas absorption.

=Cement.= Cement furnishes a degree of hardness adequate to withstand
service conditions. It interferes somewhat with the absorptive
properties of the soda-lime and it is an open question whether the gain
in hardness produced by its use is valuable enough to compensate for
the decreased absorption which results.

=Kieselguhr.= The loss in absorptive capacity due to the presence of
cement is in part counterbalanced by the simultaneous introduction of
a relatively small weight though considerable bulk, of kieselguhr.
In some cases, there seems to be a reaction between the lime and the
kieselguhr, which results in some increase in hardness.

=Sodium Hydroxide.= Sodium hydroxide has two primary functions in
the soda-lime granule. In the first place, a small amount serves to
give the granule considerable more activity. The second function is
to maintain roughly the proper moisture content. This water content
(roughly 13-14 per cent after spraying) is very important, in order
that the maximum gas absorption may be secured.

=Sodium Permanganate.= The function of the sodium permanganate is to
oxidize certain gases, such as arsine,[30] and to act as an assurance
of protection against possible new gases. The purity of the sodium
permanganate solution used was found to be one of the most important
factors in making stable soda-lime. It was, therefore, necessary to
work out special methods for its manufacture. Two such methods were
developed, and successfully put into operation.

[Footnote 30: Which, however, was never used on the battlefield.]

Careful selection of other material is also necessary, and this phase
of the work contributed greatly to the final development of the form of
soda-lime.




CHAPTER XIV

TESTING ABSORBENTS AND GAS MASKS


One of the first necessities in the development of absorbents and gas
masks was a method of testing them and comparing their deficiencies.
While the ultimate test of the value of an absorbent, canister or
facepiece is, of course, the actual man test of the complete mask, the
time consumed in these tests is so great that more rapid tests were
devised for the control of these factors and the man test used as a
check of the purely mechanical methods.


TESTING OF ABSORBENTS[31]

Absorbents should be tested for moisture, hardness, uniformity of
sample and efficiency against various gases.

[Footnote 31: See Fieldner and others, _J. Ind. Eng. Chem._, =11=, 519
(1919).]

_Moisture_ is simply determined by drying for two hours at 150°. The
loss in weight is called moisture.

The _hardness_ or _resistance to abrasion_ is determined by shaking
a 50-gram sample with steel ball bearings for 30 minutes on a Ro-tap
shaking machine. The material is then screened and the hardness number
is determined by multiplying the weight of absorbent remaining on the
screen by two.

The _efficiency_ of an absorbent against various gases depends upon a
variety of factors. Because of this, it is necessary to select standard
conditions for the test. These were chosen as follows:

The absorbent under test is filled into a sample tube of specified
diameter (2 cm.) to a depth of 10 cm. by the standard method for
filling tubes, and a standard concentration (usually 1,000 or 10,000
p.p.m. by volume) of the gas in air of definite (50 per cent) humidity
is passed through the absorbent at a rate of 500 cc. per sq. cm. per
min. The concentration of the entering gas is determined by analysis.
The length of time is noted from the instant the gas-air mixture is
started through the absorbent to the time the gas or some toxic or
irritating reaction product of the gas begins to come through the
absorbent, as determined by some qualitative test. Quantitative samples
of the outflowing gas are then taken at known intervals and from the
amount of gas found in the sample the per cent efficiency of the
absorbent at the corresponding time is calculated.

    Per cent efficiency =
                   p.p.m. entering gas - p.p.m. effluent gas
                   -----------------------------------------  × 100.
                          p.p.m. entering gas

These efficiencies are plotted against the minutes elapsed from
the beginning of the test to the middle of the sampling period
corresponding to that efficiency point. A smooth curve is drawn through
these points and the efficiency of the absorbent is reported as so many
minutes to the 100, 99, 95, 90, 80, etc., per cent efficiency points.

The apparatus used in carrying out this test is shown in Fig. 74.
Descriptive details may be found in the article by Fieldner in _The
Journal of Industrial and Engineering Chemistry_ for June, 1919.
With modifications for high and low boiling materials, the apparatus
is adapted to such a variety of gases as chlorine, phosgene,
carbon dioxide, sulfur dioxide, hydrocyanic acid, benzyl bromide,
chloropicrin, superpalite, etc.

As the quality of the charcoal increased, the so-called standard test
required so long a period that an accelerated test was devised. In this
the rate was increased to 1,000 cc. per minute, the relative humidity
of the gas-air mixture was decreased to zero, and the concentration
was about 7,000 p.p.m. The rate is obtained by using a tube with an
internal diameter of 1.41 cm. instead of 2.0 cm.


CANISTERS

After an absorbent has been developed to a given point, and is
considered of sufficient value to be used in a canister, the materials
are assembled as described in Chapter XII. While the final test is
the actual use of the canister, machine tests have been devised which
give valuable information regarding the value of the absorbent in the
canister and the method of filling.

[Illustration: FIG. 74.—Standard Two-tube Apparatus for Testing
Absorbents, Showing Arrangement for Gases Stored in Cylinders.]

The first test must be that for _leakage_. The canister must show no
signs of leaking when submitted to an air pressure of 15 inches of
mercury (about half of the normal atmospheric pressure).

The second factor tested is the _resistance to air flow_. This is
determined at a flow of 85 liters per minute and should not exceed 3
inches. The latest canister design has a much lower resistance (from 2
to 2½ inches).

The third test is the _efficiency_ of the canister against various
gases. For routine work, phosgene, chloropicrin and hydrocyanic acid
are used against the standard mixture of charcoal and soda-lime:
Chloropicrin is usually used against straight charcoal fillings, while
phosgene and hydrocyanic acid are used against soda-lime.

[Illustration: FIG. 75.—Apparatus for Testing Canisters Against
Chloropicrin.]

Different types of apparatus are required for these gases. They are
very complicated, as may be seen from the sketch in Fig. 75, and
yet a man very quickly learns the procedure necessary to carry out
a test of this kind. The gas is passed through the canister under
given conditions, until at the end of the apparatus a test paper or
solution indicates that the gas is no longer absorbed but is passing
through unchanged. This point is called the “break point,” and the time
required to reach this point is known as the life of the canister. This
time is also the time to 100 per cent efficiency. Other points, such
as 99, 95, 90 and 80 per cent efficiency are determined. These are
used in comparing canisters.

The canister tests were of two general classes: continuous and
intermittent. In the first the air-gas mixture was drawn through
continuously until the break point was reached. The results obtained
in this way, however, did not give the time measure of the value of
a canister in actual use. The intermittent test differs only in that
the flow of air-gas mixture is intermittent, corresponding to regular
breathing. Special valves were adapted to this work.

Canisters must also be tested as to the protection they offer against
smoke. These methods are discussed in Chapter XVIII.


MAN TESTS

The final test of the canister is always carried out by means of the
so-called “man test.” Special man-test laboratories were built at
Washington, Philadelphia and Long Island. These are so constructed
that, if necessary, a man may enter the chamber containing the gas and
thus test the efficiency of the completed gas mask. In most cases,
however, the canister is placed inside or outside the gas-chamber and
the men breathe through the canister, detecting the break point by
throat and lung irritation.

The following brief description of the man test laboratory at the
American University will give a good idea of the plan and procedure.[32]

[Footnote 32: Taken from Fieldner’s article mentioned above.]

The man test laboratory is a one-story building, 56 ft. in length and
25 ft. in width. The main part is occupied by three gas chambers,
laboratory tables, and various devices for putting up and controlling
gas concentrations in the chambers. A small part at one end is used as
an office and storeroom.

Good ventilation is of great importance in a laboratory of this nature.
This is secured by means of a 6 ft. fan connected to suitable ducts.
The fan is mounted on a heavy framework outside and at one end of the
building. The fan is driven at a speed of about 250 r.p.m. by a 10 h.p.
motor. The main duct is 33 in. square, extending to all parts of the
building. A connection is also made to a small hood used when making
chemical analyses.

The gases, fumes, etc., drawn out by the fan, are forced up and out of
a stack 30 in. in diameter, extending upward 55 ft. above the ground
level.

The main features of each of the three gas chambers are identical.
Auxiliary pieces of apparatus are used with each chamber, the type of
apparatus being determined by the characteristics of the gas employed.

[Illustration: FIG. 76.—Man Test Laboratory, American University.]

Each chamber is 10 ft. long, 8 ft. wide and 8½ ft. high, having,
therefore, a capacity of 680 cu. ft. or 19,257 liters. The floor is
concrete, and the walls and ceiling are constructed on a framework
of 2 × 4 in. scantling, finished on the outside with wainscoting and
on the inside with two layers of Upson board (laid with the joints
lapped) covered with a ½ in. layer of special cement plaster laid upon
expanded metal lath. The interior finish is completed by two coats of
acid-proof white paint. The single entrance to the chamber is from
outside the laboratory, and is closed by two doors, with a 36 × 40 in.
lock between them. These doors are solid, of 3-ply construction, 2½ in.
thick, with refrigerator handles, which may be operated from either
inside or outside the chamber. The door jambs are lined with ³/₁₆ in.
heavy rubber tubing to secure a tight seal.

At the end of the chamber opposite the doors, a pane of ¼ in. wire
plate glass, 36 × 48 in., is set into the wall, and additional
illumination may be secured by 2 headlights, 12 in. square, set into
the ceiling of the chamber and of the air-lock, respectively, and
provided with 200 watt Mazda lamps and Holophane reflectors. Openings
into the chamber, five in number, are spaced across this end beneath
the window and 9 in. above the table top.

Fans are installed for keeping the concentration uniform.

[Illustration: FIG. 77.—Details of Canister Holder.]

Various devices have been installed for attaching the canister to be
tested (Fig. 77). This arrangement allows the canister to be changed at
will without any necessity for disturbing the concentration of gas by
entering the chamber.

Arrangements for removing the gas from the chamber consist of a small
“bleeder” which allows a continuous escape of small amounts and a large
blower for rapidly exhausting the entire contents of the chamber.

Other general features of the equipment deal with the determination
of the physical condition surrounding the tests, often a matter of
considerable importance. The temperature of the gas inside the chamber
is easily ascertained by means of a thermometer suspended inside the
window in such a position as to be read from the outside. The relative
humidity of the mixture of air and gas in the chamber is determined by
means of a somewhat modified Regnault dew point apparatus mounted on
the built-in table.


PRESSURE DROP AND LEAK DETECTING APPARATUS

Another piece of apparatus consists of a combined pressure drop machine
and leak tester (Fig. 78) for measuring the resistance of canisters
and testing them for faulty construction. This is mounted on a small
table, with the motor and air pump installed on a shelf underneath.
The resistance, or pressure drop, of canisters is measured by the
flow meter _A_ and the water manometer _B_. Air is drawn through the
canister and the flow meter _A_ at the rate of 85 liters per min.,
the flow being adjusted by the needle valve. The pressure drop across
the canister is read on the water manometer _B_, one end of which is
connected to the suction line, the other open to the air. The reading
is generally made in inches, correction being made for the resistance
of the connecting hose and the apparatus itself.

Canisters are tested for leaks by the apparatus shown at _D_ in Fig.
78. The canister is clamped down tightly by wing nuts against a piece
of heavy ¼-in. sheet rubber large enough to cover completely the bottom
of the canister and prevent any inflow of air through the valve.
Suction is then applied, and a leak is indicated by a steady flow of
air bubbles through the liquid in the gas-washing cylinder _E_. A
second gas-washing cylinder, empty, is inserted in the line between _E_
and the canister as a trap for any liquid drawn back when the suction
is shut off. If a leak is shown, it can be located by applying air
pressure to the canister and then immersing it in water.

[Illustration: FIG. 78.—Apparatus for Determining Pressure Drop and for
Detecting Leaks in Canisters.]


METHODS OF CONDUCTING TESTS

Three general methods of conducting man tests are followed:

(1) Canisters are placed in the brackets outside the chamber or
fastened to the wall tubes within the chamber. The subjects of the
test remain outside the chamber, and the facepieces of the masks are
connected directly to the canisters, in the first case, and to the
wall tubes connecting with the canisters, in the second case. The
concentration is established and the time noted. Then the men put on
the masks and breathe until they can detect the gas coming through
the canisters. Reading matter is provided for the men during the test
period. When gas is detected, the time is again noted and the time
required for the gas to penetrate the canister is reported as the “time
to break down” or “service time” of the canister. Ten canisters are
tested at one time, and the average of the results for the 10 canisters
is taken for that type of canister. Much less accurate results are
obtained when the final figure is based on a small number of canisters.
This is largely due to the various breathing rates and sensitiveness of
different men.

(2) The canisters are placed as in (1), but it is only necessary
to know if they will give perfect protection for a given length of
time. The procedure is the same as in (1), except that the test is
arbitrarily stopped at the end of the indicated time, and the number of
canisters and the service times of the same noted.

(3) When the canisters are of such a type that they cannot be properly
tested as in (1), or when it is desired to test the penetrability of
the facepiece, the men wear the complete mask and enter the chamber.
They remain until gas penetrates the canister or the facepiece, as
the case may be, or until it is determined that the desired degree of
protection is afforded. The service time is computed as in (1).

(4) Maximum-breathing-rate tests are made either by men in the chamber
or by the men outside, in which they do vigorous work on a bicycle
ergometer. In this test the average man will run his breathing rate up
to 60 or 70 liters per min.

The concentration of the gas is followed throughout the test by
aspirating samples and analyzing them.

=Type of Masks Used.= In the future the 1919 model will be used for
all tests. In general, during the War, the following procedure held,
although variations occurred in special cases:

When men entered a gas-chamber, the full facepiece was, of course,
required. The type of facepiece was determined by the nature of the
gas. If the gas was most easily detected by odor or eye irritation, a
modified Tissot mask was used. If it was most easily detected by throat
irritation, a mouth-breathing mask was employed.

When men were outside the chamber, the choice was made in the
same manner, except in the case of detection of the gas by throat
irritation. In this case the mouthpiece was attached to two or three
lengths of breathing tubes and a separate noseclip was used. The
facepiece was not needed and the men were much more comfortable without
it.

=Disinfection of Masks.= Mouthpieces are disinfected after use by
first holding them under a stream of running water and brushing out
thoroughly with a test tube brush; then the latter is dipped into a 2
per cent solution of lysol, and the inner parts of the mouthpiece are
brushed out well; finally the mouthpiece and exhaling valve are dipped
bodily into the lysol solution and allowed to dry without rinsing.
Tissot masks are wiped out with a cloth moistened in alcohol, followed
by another cloth moistened in 2 per cent lysol solution. The flexible
tubes are given periodic rinsings with 95 per cent alcohol.

=Applicability of Man Tests.= Man tests are applicable to all gases
which can be detected by the subject of the test before he breathes a
dangerous amount.

The man test laboratory described above provides facilities for
obtaining information concerning the efficiency of canisters,
facepieces, etc., within very short periods of time, without waiting
for the construction of special apparatus required for machine tests.
To get satisfactory results from machine tests, a delicate qualitative
chemical test for the gas is essential. Man tests can be made when such
a qualitative test is not known. Further, man tests can be made with
higher concentrations of some gases than is practicable with machines.
Evolution of excessive amounts of moisture when high concentrations of
some gases are used causes much more trouble with machine tests than
with man tests.

On the other hand, man tests are adversely affected by the varying
sensitiveness and lung capacities of the men, and the humidity of the
air-gas mixture is not subject to as exact control as is the case with
machine tests.


FIELD TESTS

It will be observed that all of the above tests are concerned only
with the efficiency of the absorbent and its packing in the canister.
No attempt was made to determine the comfort and general “feel” of the
mask. For this purpose field tests were devised, covering periods from
two to five hours. The first test was a five-hour continuous wearing
test. It was assumed that any mask which could be worn for five hours
without developing any marked features of discomfort could, if the
occasion demanded it, be worn for a much longer period of time. A
typical test follows:

     8:00 to  8:30  Instruction and adjustment of gas mask.
                        Gas-chamber tests
     8:30 to  9:30  Games involving mental and physical activity
     9:30 to 11:30  Cross-country hike with suitable periods of rest
    11:30 to 12:00  Tests of vision
    12:00 to 12:30  Games to test mental condition of subjects
    12:30 to  1:00  Gas-chamber fit test

[Illustration: FIG. 79.—Hemispherical Vision Chart.]

Vision was tested by means of a hemispherical chart (Fig. 79). This
chart was 6 ft. in diameter and was constructed of heavy paper laid
over a wire frame. A hinged head rest was provided for holding the
subject’s head firmly in position with the center directly between the
eyes. The subject wearing the mask took up his position, and with one
eye closed at a time, indicated how far along the meridian of longitude
he could see with the other eye. The observer sketched in the limit of
vision by outlining the perimeter of the roughly circular field allowed
by each eyepiece. The intersection of the two fields gave the extent of
binocular vision possible with the mask.

Various other tests were also used, in order that the extent and nature
of the vision could be accurately determined.

Aside from the problems of comfort, protection, vision and other
important features of gas mask efficiency, the question arose as to
whether certain designs of masks or canisters were mechanically able
to withstand the rough treatment they were certain to receive in
actual field service. A test was, therefore, developed to simulate
such service as transportation of masks from base depots to the front,
carrying of supplies and munitions by men wearing masks in the “alert”
position, exposure to rain and mud, hasty adjustment of masks during
gas alarms and typical mistreatment of masks by the soldiers.

All these tests were of great value in the development of a good gas
mask.




CHAPTER XV

OTHER DEFENSIVE MEASURES


PROTECTIVE CLOTHING

Protective clothing was an additional feature of the general program
of protection. As far as factory protection is concerned, the use of
protective garments was more or less of a temporary expedient and they
were abandoned as fast as automatic machinery and standard practice
made their use less necessary. It is likewise a question regarding
their value at the front. It is very certain that the garments
developed needed to be made lighter and more comfortable to be of much
value to the fighting unit.

The first development of protective clothing was along the lines of
factory protection. The large number of casualties in connection with
the manufacture of mustard gas made it imperative that the workmen
be protected not only from splashes of the liquid mustard gas, but
also from its vapors. The first suit developed provided protection to
the entire body. The ordinary clothing materials and even rubberized
fabrics offered little protection but it was found that certain
oilcloths were practically impermeable to mustard gas. The suit was a
single garment, buttoning in the back, with no openings in the front,
no pockets and with tie-strings at wrists and ankles. The head was
protected by means of an aluminium helmet, supported by means of a head
band resting on the head like a cap and slung from the inside of the
helmet; this permitted slight head motions independent of the helmet.
In order to provide cooling and ventilating and pure air breathing, the
suit was inflated by pumping a considerable volume of air into the suit
through a flexible hose long enough to permit considerable freedom of
movement.

This suit had the very great disadvantage of limiting the range of
motion to the length of the hose. Because of this, a Tissot type mask
was used in place of the helmet and hose connections. The hood was made
of the same special oilcloth as the suit, enveloped the head and neck
and extended a short distance down the back and over the chest. The
canister was slung on the left hip by an oilcloth harness and was kept
from swinging by an oilcloth belt around the waist. The canister was
much larger than the standard box respirator, had a much longer life
with lower resistance and weighed about 3.5 lbs.

[Illustration: FIG. 80.—Impervious Overall Suit for Mustard Gas.]

Another type of impervious overall suit was developed which protected
against mustard gas for over 100 minutes. The material was a cotton
sheeting which was impregnated with linseed oil containing a suitable
non-drying material, which was thoroughly oxidized in the fabric. These
suits proved to be very uncomfortable, especially in warm weather,
because they entirely prevented the escape of perspiration from the
body.

Semi-permeable suits were then prepared, in which the cotton sheeting
was impregnated or coated with a solution of gelatin and glycerine. The
fabric was then “tanned” to render the gelatin insoluble in water. Such
a suit is valuable for factory wear, but the impregnating material is
easily leached out and the suit is therefore not recommended for field
service.

This was built with an inside layer of dry cloth together with an
outside layer of treated cloth to afford the necessary chemical
protection against mustard gas. Work of fabrication consisted in
treating the cloth with simplexene, cutting the suits to design and
size, and sewing them together.

Treatment consisted in passing the fabric through a dye machine, then
through the wringer rolls where the excess oil was expressed. The
inner layer of dry cloth was found necessary, since the cloth was cut
as soon as treated. Simplexene does not attain the maximum degree of
“tackiness” for two or three days, owing to the presence in the oil of
a small amount of volatile spirits. However, by allowing the cloth to
air for 48 hours before cutting, the inner lining could probably be
dispensed with.

The fighting suits were distributed among various detachments using
mustard gas in field tests, and in other places where protection
against vapor was needed and where field conditions were approximated.
The tests showed that the suit gave satisfactory protection for
considerable periods against mustard gas vapors. No other suit, equal
both in porosity and protection, has yet been submitted, although
samples furnishing better protection with much higher resistance have
been examined. The protection of the simplexene suit is about 30
minutes against saturated gas. A large number of these suits were made
and taken abroad for field tests at the front.


PROTECTIVE GLOVES

Protective gloves have been made with a variety of impregnating agents.
The one which was selected for large scale production was impregnated
with a solution of cellulose nitrate because of the availability of
materials and the protection offered by the finished product. The
material is impregnated after being made up. The one finger type of
glove is used. The gloves are placed on wooden forms and dipped into
the impregnating solution. After draining a few minutes, the gloves
are turned upside down on racks and run through a drying oven. Finally
they are removed from the forms and conditioned by drying at a moderate
temperature for several hours. After being properly cured they are
fitted with two straps on the gauntlet of each glove. They should offer
protection to chloropicrin (standard method of test) for 30 minutes.
When subjected to rough work they will last from one to two weeks.

[Illustration: FIG. 81.—Coated Gloves for Protection against Mustard
Gas.]


PROTECTIVE OINTMENTS

The extensive use of mustard gas on the field caused the men to be
exposed to low concentrations of the vapors for extended periods of
time. Since it did not seem feasible to furnish the men with special
fighting suits, which would protect them against these vapors, it was
desirable to provide protection in the form of an ointment which could
be applied to the body. In order to be satisfactory an ointment should
have the following properties:

    (_a_) It should protect against saturated mustard
       gas during the longest possible exposure.

    (_b_) Its protective action should last as long
       as possible after the application of the ointment.
       It was felt that the ointment should give protection
       for 24 hours after it is applied, even if the body is
       perspiring freely.

    (_c_) The material should not be easily rubbed off
       under the clothing.

    (_d_) It should be non-irritating to the membranes
       of the body.

    (_e_) There should be no likelihood of toxic
       after-effects on long use.

    (_f_) It should be of a good consistency under a
       fairly wide temperature range and give a good coating
       at the temperature of the body.

    (_g_) Its method of manufacture should be simple
       and rapid, and the raw materials required should be
       abundant.

    (_h_) The cost should not be excessive.

An extensive study of this question was made both in the laboratories
and on the field. At first it was believed that successful results
could be obtained by the use of such ointments. Careful investigation
showed, however, that while these ointments really did protect against
rather high concentrations of vapor for short times of exposure, they
were probably not so valuable when used against low concentrations
over an extended period of time. It was further demonstrated that the
protection furnished by a coating of linseed oil is practically equal
to the best ointment which has been developed. About 150 ointments were
prepared and tested. These consisted of two parts or components, the
metallic soap or other solid material and the oil or liquid part which
bound and held the solid. The latter is called the base. The best base
is lanolin, containing 30 per cent of water. A solution of wax in olive
oil was next best. Of the metallic soaps the oleates and linoleates are
better than the stearates. A satisfactory ointment has the following
composition:

    Zinc oxide                  40
    Linseed oil (raw)           20
    Lard                        20
    Lanolin                     20

A modification of this formula is:

    Zinc oxide                  45
    Linseed oil                 30
    Lard                        10
    Lanolin                     15

The physical properties of this ointment are very good. It forms a
smooth, even coating on the skin, sticks well enough not to rub off
easily on the clothing and yet is not sticky. Its consistency is
such that it can be readily pressed from an ointment tube. A. E. F.
reports indicate that sag paste (zinc stearate and vegetable oil) is as
satisfactory as any of the preparations tried.

The great difficulties of such preparation from a field point of view
are: Extra weight to be carried by the soldiers, necessity for keeping
in tight boxes or tubes, thereby adding to the difficulty of carrying,
and finally, the difficulty encountered when applying it properly to
the body in the field, where gas contaminated hands may cause harm.

The paste was too late a development for thorough field trial. It was
used just enough to cause severe partisan controversies between its
advocates and those opposed to it. Unquestionably, it proved of decided
value in preventing mustard gas burns when properly applied. There are
many authentic cases where men alongside each other were similarly
gassed except as to burns. The difference in burns arose from the use
or non-use of the paste, and in some cases of poor application. Fries
is of the opinion that had the war lasted another year the use of
pastes would have become universal unless some thoroughly successful
substance for impregnating the uniform or underclothing had been
developed. This is likewise his belief for the future.


PROTECTION OF ANIMALS

=Horse Mask.= The need of protection for animals (horses and dogs),
although not as great as in the case of men, was of sufficient
importance so that masks and boots were developed for the horse and a
mask for the dog.

The German horse mask was the first produced. It was of the nose bag
type, enveloping the mouth and nose of the animal. It was fitted with a
complicated drawstring and with snap hooks fastening it to the harness.
The interior contains a plate of stiff material to prevent the collapse
of the bag. The mask itself was apparently not impregnated, but was
used wet or with a filling of wet straw or rags to act as the absorbent.

[Illustration: FIG. 82.—German Respirator for Horses.]

The French had two types of horse masks impregnated with a
glycerine-nickel hydroxide mixture. One type had a closed bottom, while
in the other, the bottom was open.

The British horse mask has a two-layer flannelette bag, with a canvas
mouth pad and elastic drawstring. It was impregnated with a mixture of
phenol, formaldehyde, ammonia, canister soda and glycerine.

The first type of American horse mask was modelled after
the British and was impregnated with the Komplexene mixture
(hexamethylenetetramine, glycerine, nickel sulfate mixture). This mask
had too high a resistance and caused complete exhaustion in running
horses. The second mask was made of a large number of layers of very
open cheesecloth. It consists of two bags, impregnated with different
mixtures (Komplexene and Simplexene). Horses can run two miles with
this mask without showing evidences of exhaustion.

Dewey gives the following method of manufacture:

The chemical employed consisted of a mixture of hexamethylenetetramine
(to give protection against phosgene), nickel sulfate (to protect
against the possible use of hydrocyanic acid), sodium carbonate and
glycerine. This solution was mixed in a heavy steam jacketed mixing
kettle with heavy geared stirrers. The mixture was conducted by pipes
to the impregnating apparatus which consisted of a rotary laundry
washing machine. The masks were treated in this machine for 15 minutes,
and then placed in a power operated wringer and the solution driven off
to a given weight. Following this operation, they were suspended on
wire supports and conducted through a hot air drying machine and dried
to a definite weight. 378,000 horse masks were produced at the rate of
5,000 per day.

[Illustration: FIG. 83.—Horse Mask—American Type.]

Theoretically, horse masks and horse boots are very
valuable,—practically, they did very little actual good in the field,
not that they would not protect or that animals would not wear them.
The trouble was with the riders and drivers. Gas attacks, coming
usually at night, made adjustment of horse masks difficult at best,
while in the confusion of bursting shell and smoke, the drivers
absolutely forgot the horse masks or after putting on their own masks
feared to try putting masks on the animals. This last was natural as
most animals fight the adjustment of the mask and in so doing there is
great risk that the man’s mask may be torn off and the man gassed. In
the future, such masks will have even more importance than in the past,
for the present methods of manufacture of mustard gas coupled with its
all-round effectiveness will cause a use of it ten-fold greater than at
any time in the World War. In such cases, operations will necessarily
be frequently carried on over large areas thoroughly poisoned with
mustard gas. Here the animals will be masked and booted before entering
the gassed area, and remain so until they leave it. In the torn and
broken ground around the front line there will always be need for
animal transportation,—wagon, cart and horse—as in such places it is
far better in nearly all cases than motor transport.

=Dog Mask.= The use of dogs in messenger service and in Red Cross work,
in which gassed areas must be passed, led to the designing of a mask
to give the animals suitable protection. The same materials and method
of impregnation were used as in the horse mask. With eight layers of
cheesecloth, adequate protection against mustard gas was secured with
practically no pressure drop.

The eyepieces were made of thin sheets of cellulose acetate bound
around the edge with adhesive tape and sewed directly over openings
cut through the mask fabric. The ear pockets were made round and full
enough to fit pointed or lop-eared animals. The mask is continued to
form a wide neck band which may be drawn up by two adjustable straps.
It is made sufficiently full to allow a free movement of the dog’s jaws
and yet tight enough around the neck to avoid the possibility of being
pawed off. The dog apparently soon became accustomed to wearing the
mask.

=Horse Boots.= The increasing amount of mustard gas used on the Western
front made it seem necessary to develop some form of protection for the
horse’s hoof and fore-leg. It has been found that mustard gas vapors
attack the fleshy portion of the leg, especially around the coronary
band and causes inflammation of the frog of the foot. The problem was
solved by devising a special hoof pad and a boot. The pad was made of
sheet iron imbedded in a hoof protector (composition rubber) to which
the shoe is applied. The shoe just overlaps the metal plate on the
inside and provides a solid metal surface for the bottom of the foot.
Such a pad not only offers protection against gas but against shell
splinters, barbed wire, etc., and would be useful at all times on the
front.

[Illustration: FIG. 84.—Impervious Boots and Pads to Protect Horses’
Legs and Hoofs against Mustard Gas.]

[Illustration: FIG. 85.—Protective Gas Outfit—Gas Mask, Gas Suit,
Gloves, Boots, Horse Mask, Horse Boots, Horse Pads.]

The boot was made of satin, treated so as to be impervious to mustard
gas. It covers all of the foot except the bottom and extends to just
below the knee. The boot is held in contact with the hoof by a sewed
cloth strap, which passes around the bottom of the hoof and is held in
position by projections extending from the spur or toe clip. Special
care is taken to insure a perfect joint at the rear of the boot since
the small cavity in the back of the hoof is one of the most sensitive
parts. The boot is wrapped about one and a half times around the leg
and is clipped with five loops through which passes a ¾-inch strap.

=Dugout Blankets.= Dugout protection is intended to prevent entrance of
any gases, lethal, lachrymatory or irritant, into the enclosed space.
This has been most efficiently accomplished by means of curtains hung
upon wooden frames and fitting closely against all edges of the opening
to be closed. These curtains have usually been of heavy material and
have generally been spoken of as dugout blankets. Since they were
designed to exclude all toxic gases, they had to be devised upon
general mechanical principles rather than upon principles of chemical
action with specific gases. Permeability to air has not been considered
a necessity, it being held that sufficient ventilation is secured by
means of the air entering through the soil. For large dugouts and
extended use large air filters were designed to draw pure air into the
dugout with a fan.

The qualities aimed at, to which both fabric and treatment should
contribute, are the following:

    (_a_) Impermeability to gas.
    (_b_) Flexibility, especially at low temperatures.
    (_c_) Non-inflammability.
    (_d_) Freedom from stickiness and from tendency to lose
                    material by drainage under action of gravity.
    (_e_) Mechanical strength.
    (_f_) Simplicity of manufacture and treatment.
    (_g_) Low cost.

Army blankets, both those for men and those for horses, proved suitable
materials for curtains, but the scarcity of wool made it desirable to
select an all cotton fabric.

A large number of oils were studied as impregnating agents. The most
satisfactory mixture consisted of 85 per cent of a heavy steam refined
cylinder oil and 15 per cent of linseed oil. This is taken up to the
extent of about 300 per cent increase in weight of the blanket during
impregnation. It becomes oxidized to some extent upon the surface of
the blanket, which becomes less oily than the soft, central core.
The finished blanket possessed the following properties: It resists
penetration of 400-600 p.p.m. of chloropicrin for 8 hours (dugout test)
and mustard gas for 100-400 minutes (machine test). It is sufficiently
flexible after standing for 2 hours at 18° F. to unroll of its own
weight, and may be unrolled by applying a slight force at 6° F.; it is
not ignited by lighted matches and shows but little loss by drainage.

Two types of machines were designed for impregnation, one for use on
large scale behind the line, and a field apparatus for use at the
front.




CHAPTER XVI

SCREENING SMOKES


The intelligent use of screening smokes in modern infantry tactics
offers innumerable advantages through concealment and deception. It
confers upon daylight operations many of the advantages which were
gained by conducting operations at night with few of the disadvantages
of the latter.

Smoke screens have been frequently used by the Navy and by Merchantmen;
a common method of escape was to shut off the air from the fire with
consequent incomplete combustion of the fuel, thus causing a cloud of
dense black smoke. This is often mentioned in the blockade runners of
the days in the Civil War, where wood, high in pitch and rosin, was
freely introduced into the furnaces, in order that they might escape
under cover of this smoke.

Early in the present war it was found that black smoke had a low
obscuring power, showed frequent rents or holes and were difficult
to standardize. Their production also caused a considerable loss in
the speed of the vessel. They therefore fell into disuse except for
emergency purposes and today the standard smoke for screening purposes
of all kinds is, without exception, white.[33]

[Footnote 33: While it is a well known fact that black smoke is not as
efficient as white smoke for screening purposes, the reason for this
fact is not clear.]


PROPERTIES OF SMOKE CLOUD

The properties most desired in a screening smoke, apart from low cost,
are: (_a_) _Maximum screening power_, which refers to the question of
density, i.e., a relatively thin layer must completely obscure any
object behind it, and (_b_) _Stability_, which implies, among other
things, a low rate of settling or dissipation. There is little reason
to doubt that, within limits, the smaller the particles of a smoke
cloud, the more completely will the smoke possess these qualities.
The screening power of a smoke cloud depends very largely upon the
scattering of the light coming through it, and by analogy with those
peculiar solutions which we call colloidal, we should expect the
scattering to increase as the degree of subdivision increases, within
limits. The rate of settling is unquestionably an inverse function
of the size of the particles. The chief aim, therefore, in smoke
production is to attain as high a degree of subdivision as possible.
Methods may be classified as good or bad, in so far as they satisfy or
fail to satisfy this criterion.


RAW MATERIALS FOR SMOKE CLOUDS

It is obvious that only gases or substances capable of being brought
into the vapor state or into a very fine state of subdivision can be
used for producing smoke clouds. The reaction product, of which the
smoke particles consist, should preferably be:

(_a_) _Solid._ Otherwise the particles will tend to grow in size by
condensation of the liquid particles present in the cloud.

(_b_) _Non-volatile._ If volatile, the particles will disappear by
evaporation as the cloud is diluted by air currents. Larger particles
will also form at the expense of the smaller ones.

(_c_) _Non-deliquescent._ If the particles are deliquescent, they will
tend to grow by condensation of water vapor upon them.

(_d_) _Stable_ towards the usual components of the atmosphere,
especially moisture.

While it might seem that it would be difficult to fulfill these
conditions, there are several chemical compounds which have been
successfully used as smoke producers. This does not mean that they
fulfill all the conditions, but they represent a compromise between the
various requirements.

=Phosphorus.= One of the earliest materials to be used in smoke clouds
was phosphorus. This is prepared on a commercial scale by heating
phosphate rock (which contains calcium phosphate) with sand and coke
in an electric furnace. Phosphorus occurs in two forms, white and red.
_White phosphorus_, which is formed when the vapor of the substance
is quickly cooled, is, in the pure state, almost colorless, melts at
44° C., boils at 287° C., is readily soluble in various solvents, and
is luminous in the air, at the same time emitting fumes (the oxidation
product, phosphorus pentoxide). On gentle warming in the air, it takes
fire and burns with a brightly luminous flame. _Red phosphorus_ is
obtained by heating white phosphorus out of contact with the air, to a
temperature of 250° to 300° C. Red crusts then separate out from the
colorless liquid phosphorus, and almost the entire amount is gradually
converted into a red, solid mass. If this is freed by suitable solvents
from the small amounts of unchanged white phosphorus, a dark red powder
is obtained, which remains unchanged for a long time in the air, does
not appreciably dissolve in the solvents for white phosphorus, does
not become luminous, and can be heated to a fairly high temperature
without igniting. Further, red phosphorus is not poisonous, while white
phosphorus is highly so.

Either form burns to phosphorus pentoxide, which is converted by the
moisture of the air to phosphoric acid,

        4P + 5O₂ = 2 P₂O₅
    2P₂O₅ + 6H₂O = 4H₃PO₄

Since one pound of phosphorus takes up 1.33 pounds of oxygen and 0.9
pound of water, it is not surprising that phosphorus is one of the best
smoke producers per pound of material. Comparison of the value of the
two forms for shell purposes have invariably pointed to the superiority
of the white variety.

In addition to its use as a smoke producer, it is used in incendiary
shell and in tracer bullets. For incendiary purposes a mixture of red
and white phosphorus is superior.

=Chlorosulfonic Acid.= Chlorosulfonic acid, ClSO₂OH, was first
employed by the Germans to produce white clouds, both on land and on
sea. For this purpose, they sprayed or dropped it onto quicklime, the
reaction between it and the lime furnishing the heat necessary for
volatilization, though in this way about 30 per cent of the acid is
wasted.

Chlorosulfonic acid is obtained from sulfur trioxide and hydrogen
chloride, which combine when gently heated:

    SO₃ + HCl = ClSO₂OH

[Illustration: FIG. 86.—75 mm. White Phosphorus Shell. 2 seconds after
bursting.]

On a commercial scale, hydrogen chloride is passed into 20 per cent
oleum, until saturation is reached. This is heated in a nitric acid
still, when the chlorosulfonic acid distills over between 150°-160° C.
With 30 per cent oleum, the conversion factor is about 42 per cent. The
residue in the still is about 98 per cent sulfuric acid.

It forms a colorless liquid, boiling at 152° C., and having a density
of 1.7.

Chlorosulfonic acid fumes in the air, because reaction with water forms
sulfuric acid and hydrochloric acid.

    ClSO₂OH + H₂O = H₂SO₄ + HCl

This material was not used by the United States since oleum was found
superior.

=Oleum.= Oleum is a solution of 20 to 30 per cent sulfur trioxide
(SO₃) in concentrated sulfuric acid. It has been used by the Germans
to produce clouds on land and sea, by its contact with quicklime, and
by the Americans for screening tanks and aeroplanes. Sulfur trioxide
has been found to be superior as a shell filling. It is believed that
the smoke producing power of oleum is due solely to its sulfur trioxide
content, the sulfuric acid itself acting only as a solvent. The rather
high freezing point of the oleum containing high percentages of sulfur
trioxide is a disadvantage.

=Sulfur Trioxide.= Sulfur trioxide, SO₃, is a colorless mobile liquid,
which boils at 46° C. and solidifies to a transparent ice-like mass,
melting at 15° C. It is prepared by passing a mixture of sulfur dioxide
and oxygen over finely divided platinum or other catalysts at a
temperature between 400 and 450° C. Sulfur trioxide can only be used as
a filler for shell and bombs, and is probably the best substitute for
phosphorus.

=Tin Tetrachloride.= Tin tetrachloride, SnCl₄, is obtained by the
action of chlorine on metallic tin. It is a liquid, boiling at 114° C.,
and having a density of 2.2. It fumes in the air, because it hydrolyzes
to stannic hydroxide:

    SnCl₄ + H₂O = Sn(OH)₄ + 4 HCl

It makes a better and more irritating smoke for shell and hand
grenades, than either silicon or titanium tetrachlorides. Since there
is practically no tin in this country, the other tetrachlorides were
developed as substitutes.

=Silicon Tetrachloride.= Silicon tetrachloride, SiCl₄, is prepared from
silicon or from impure silicon carbide by heating it with chlorine in
an electric furnace. The raw material (silicon carbide) is a by-product
in the manufacture of carborundum. It is a colorless liquid, boiling at
about 58° C., and fumes in moist air, owing to hydrolysis:

    SiCl₄ + 4 H₂O = Si(OH)₄ + 4 HCl

It is not very valuable in shell, though it is more effective on moist,
cool days than on warm, dry ones. Its greatest use is found in the
smoke cylinder, combined with ammonia. By the action of the moisture of
the air, the following reaction takes place:

    SiCl₄ + 4 NH₃ + 4 H₂O = Si(OH)₄ + 4NH₄Cl

The addition of a lachrymator gives a mixture which works well in hand
grenades for mopping up trenches.

=Titanium Tetrachloride.= Titanium tetrachloride, TiCl₄, is made from
rutile, TiO₂, by mixing with 30 per cent carbon and heating in an
electric furnace. A carbonitride is formed, which is said to have the
composition Ti₅C₄N₄, but the actual composition may vary from this to
the carbide TiC. This product is heated to 600-650° C., and chlorine
passed through, giving the tetrachloride. It is a colorless, highly
refractive liquid, which boils at about 136° C., is stable in dry air
and fumes in moist air. The best smoke is produced by using 5 parts of
water to one of the tetrachloride, instead of the theoretical 4 parts
[which would form Ti(OH)₄.] Since it is more expensive to manufacture
and not as effective as silicon or tin tetrachloride, it is used only
as an emergency material.

=Berger Mixture.= One of the most important smoke materials was the
zinc-containing mixture, which was used in the smoke box, the smoke
candle, certain of the smoke grenades and in various forms of colored
smokes. The basis of this was the _Berger Mixture_, which had the
composition:

    Zinc                   25
    Carbon tetrachloride   50
    Zinc oxide             20
    Kieselguhr              5

This formula produced a light gray carbon smoke, with much carbon in
the residue. In this mixture the zinc and carbon tetrachloride react to
form zinc chloride and carbon; the kieselguhr keeps the mixture solid
by absorbing the tetrachloride, while the zinc oxide is practically
useless, as its absorbing power is small.

In order to accelerate the reaction and to oxidize the carbon, thereby
changing the color of the smoke from gray to white, an oxidizing
agent was added. Sodium chlorate was chosen for economic reasons. The
reaction now proved to be too violent, and the zinc oxide was replaced
by ammonium chloride. This cooled the smoke, retarded the rate of
burning and added to the density of the smoke, since the obscuring
power of the ammonium chloride is high. The kieselguhr was replaced by
precipitated magnesium carbonate, which is as good an absorbent, gives
a much smoother burning mixture, and also adds somewhat to the density
of the smoke by virtue of the magnesium mechanically expelled. The
mixture then had the composition:

    Zinc                    34.6
    Carbon tetrachloride    40.8
    Sodium chlorate          9.3
    Ammonium chloride        7.0
    Magnesium carbonate      8.3


SIZE OF SMOKE PARTICLES

In the problem of smoke production, the size of the particle is of
great importance. Being a physical quantity it can easily be correlated
with such physical properties as settling, diffusion, coagulation, and
evaporation. These factors are more important in connection with toxic
smokes, since there the penetration factor must be considered.

Smoke appears to consist of particles of all sizes from 10⁻³ cm.,
which may just be resolved by the unaided eye, to molecular
dimensions, 10⁻⁸ cm. The larger particles settle out most rapidly and
so do not remain long in suspension.


MEASUREMENT

Wells and Gerke have developed a form of ultra-microscope which is
well adapted to the measurement of the size of smoke particles. The
ultra-microscope is a low power microscope using intense dark ground
illumination for viewing particles which are too small to be seen
by transmitted light. They are rendered visible in this way, since
any object, no matter how small, which emits enough light to affect
the retina is visible, provided the background is sufficiently dark.
Thus stars are visible at night and dust particles are easily seen
in a sunbeam in a darkened room. The larger particles, viewed in
this way, do not appear larger but brighter. The apparent size of
the particles is determined by the diffraction pattern and is thus
dependent only on the optical system used to view them. The more
intense the incident light, the brighter the particles appear. In the
ultra-microscope described, the image of an intense source, such as a
concentrated filament lamp, or an arc, is focused upon the particles in
the microscopic field, but the axis of the illuminating beam, instead
of coinciding with the axis of the microscope, as ordinarily used,
is perpendicular to it. The beam itself, therefore, never enters the
microscope at all, but passes under the objective into a blackened
chamber where it is absorbed. The field of the microscope is made dark
by placing underneath the objective another “black hole” or blackened
chamber with an opening just a little larger than the field.[34]

[Footnote 34: This ultra-microscope is described in _J. Am. Chem. Soc._
=41=, 312 (1919).]

The method used for measuring the velocity consisted in causing the
particle to describe a definite stroke many times in succession in an
electric field. This was accomplished by reversing the direction of the
field with a rotating commutator. The convection due to the source of
light is perpendicular to this motion so that a zigzag line is obtained
(see Fig. 88). The amplitude of this oscillation is an accurate measure
of the distance traversed by the particle under the electric force for
a definite small interval of time. The speed of the rotating commutator
and the electric field are both susceptible of precise measurement, so
that the size of a single particle is precisely determined.

[Illustration: FIG. 87.—Ultramicroscope for Measuring Size of Smoke
Particles.]

[Illustration: FIG. 88.—Measurement of Smoke Particles by Use of
Ultramicroscope.]

When a sample of smoke is viewed in the ultra-microscope, it appears
like the starry heavens, except that the stars are dancing violently
about. At first little distinction is made between the particles, as
there seems to be no order in their motion, but soon it becomes evident
that the brighter particles are more sluggish than the dim ones. This
is due to the greater mass of the bright particles, for they are
larger. The particles are all moving slowly away from the source of
light and eventually diffuse to the walls of the cell.

When the electric field is turned on, about one-third of the particles
immediately migrate, about equally in both directions, to the two
electrodes. If the field is reversed, the direction of migration
is reversed and if the commutator is used the particles oscillate
regularly. Sometimes the particles may be seen to combine and become
neutral, in which case oscillation ceases.


CONCENTRATION OF SMOKE

In measuring the concentration of smokes, the following terms are
useful:

=Density.= The density of a smoke is defined as the reciprocal of the
thickness of the smoke layer in feet necessary to obscure a given
filament. Thus six inches of a smoke of density 2.0 is required to
obscure an electric light filament, whereas one requiring four feet
would have a density of 4. Another way to show the significance of this
definition is to point out that if a definite weight of a stable smoke
is diluted with air after it is formed, the product of the volume by
the density always remains constant. Any marked variation in this rule
may be taken as evidence that the particles of smoke are undergoing a
change, in most cases due to evaporation.

=Total Obscuring Power.= The volume of smoke produced per unit weight
of material used is the second factor in determining the value of a
smoke. The product of this volume per unit weight by the density of the
smoke is the real measure of effectiveness, and is called the total
obscuring power (T. O. P.) of the smoke. If the volume is expressed in
cubic feet per pound and the density in reciprocal feet, the unit of T.
O. P. is square feet per pound. That is, it expresses the square feet
of a smoke wall, thick enough to completely obscure a light filament
behind it, which could be produced from a pound of the reacting
substances. The total obscuring power of some typical smokes are as
follows:

    Phosphorus                   4600
    NH₄Cl(NH₃ + HCl)             2500
    SnCl₄ + NH₃ + H₂O            1590
    Berger Mixture               1250
    SnCl₄ + NH₃                   900
    SO₂ + NH₃                     375

In all measurements of density, and therefore of T. O. P., the _rate
of burning_ must be considered. If a slow burning material be compared
with a rapid one, the former will not reach its true maximum density,
as a great deal of the smoke may settle out during the time of burning.
Comparisons of T. O. P. are significant only when made on smoke
mixtures of the same type and in about the same quantities.


MEASUREMENT

Two methods of measuring the effectiveness of a smoke cloud have
been devised, one, the smoke box, which measures the obscuring power
directly by observing at what distance a lamp filament is obscured by
intervening smoke, the other, the Tyndall meter, which measures the
intensity of the scattering of the light.

The earliest measurements of smoke intensity are perhaps those of
Ringelmann (_Revue Technique_, =19=, 286), who devised the well known
chart of that name, intended mainly for measuring intensities of black
smoke issuing from a chimney at a distance. The first measurements
for military purposes are probably due to Bertrand, who made numerous
comparative studies with his “salle opacimetrique.” This was a room
23 × 14 × 3.6 meters, with 7 windows. Two doors, one provided with
3 oculars 2 cm. in diameter, gave access to the room. On the other
door, opposite the first, were hung several black signs. Six pairs
of columns were spaced along the room at measured distances. When a
smoke is produced in the room, the black paper signs first become
invisible, then the door itself, and finally the columns, pair by
pair. They reappear in the reverse order, and as a measure of relative
opacity Bertrand took the time elapsing between the detonation and the
reappearance of the farther door.

[Illustration: FIG. 89.—Tyndall Meter.]

[Illustration: FIG. 90.—Cottrell Precipitation Tube.]

=Smoke Box.= The smoke box, used by the C. W. S., was constructed of
wood with tight joints, and had a moveable brass rod running through it
to which was attached a small size 25-Watt Mazda lamp. The density of
each smoke introduced in the box is determined by moving this lamp back
and forth until a point is reached when the pattern of the filament
can just be distinguished by the observer looking in at the glass
window, external light being excluded by a black cloth. The thickness
of the smoke layer between the glass window and the light is recorded
as the measure of the smoke density. For field tests, a larger box, 6
× 8 × 8 feet (288 cubic feet) was constructed. The observation light
was moveable in a line connecting the mid-points of opposite sides of
the box. To insure uniform distribution of smoke, a fan with 18-inch
blade revolved at any desired speed between 60 and 250 r.p.m. With
this, results are obtained indicating both the original density and its
stability.

=Tyndall Meter.= The Tyndall meter was first devised for studying
smokes and mists. Tolman and Vliet adapted it to Chemical Warfare
purposes, and used it in studying the properties of smokes.

The apparatus (Fig. 89) consists eventually of an electric light bulb,
a condensing lens giving a beam of parallel light which passes through
the diaphragm, and a Macbeth illuminometer for measuring the strength
of the Tyndall beam. In case the material is a liquid suspension or
solution, it is introduced into a cylindrical glass tube, while smokes
and mists are premixed directly through the apparatus. The long closed
tubes are provided, respectively, for absorbing the beam after it has
passed through the disperse system and for giving a dark background for
observing the Tyndall beam. Methods of standardization are given in the
_Journal of the American Chemical Society_, =41=, 299.

A third method for analyzing smokes consists in the use of an
electrical precipitator. This apparatus consists essentially of
a modified Cottrell Precipitator, with a central wire as cathode
surrounded by a cylindrical foil as anode (Fig. 90). The smoke to
be analyzed is drawn through the apparatus at a known rate, and the
particles of smoke precipitated on the foil by means of a high voltage,
direct current. The determination of concentration is made by weighing
the foil before and after precipitation.


APPARATUS FOR SMOKE PRODUCTION


SMOKE BOX

The smoke box was developed for the Navy for use when it was desirable
to have the smoke screen generated away from the ship. (The smoke
funnel, described later, was operated on board ship). The float
consists of an iron container (holding the smoke mixture) surrounded
by an iron float to support the apparatus when it is thrown into the
water (Fig. 91). The iron container consists of a cylinder 22 inches
high and 10 inches in diameter. One inch holes are bored 1½ inches
from the top of this cylinder, from which the smoke is emitted. The
iron float is about 2 feet in diameter and 8 inches deep. This box
holds approximately 100 pounds of smoke mixture, and is so constructed
that it will float one hour. When ignited, the mixture burns 9 to 9½
minutes. The smoke produced has a T. O. P. of about 1900. Fig. 92 shows
the Navy Smoke Box in action.

[Illustration: FIG. 91.—Navy Smoke Box.]

[Illustration: FIG. 92.—Navy Smoke Box in Action.]


SMOKE CANDLE

Smoke candles are used for producing a cloud of smoke for screening
purposes in or behind the lines. They are made by packing about
three pounds of the modified Berger Mixture in a container (Fig. 93)
(galvanized can 5¼ inches by 3½ inches) and are lighted by means of the
match head type of ignition. Smoke is given off at a uniform rate for
about 4 minutes, forming a dense, fog-like cloud which hangs low (Fig.
94). This smoke is absolutely harmless, and can be breathed without
discomfort. The obscuring power is high and, with a favorable wind, a
small number of the candles will produce a screen sufficiently dense to
allow operations to be carried out unseen by the enemy.

[Illustration: FIG. 93.—B. M. Smoke Candle.]


SMOKE GRENADE

The smoke grenade is also designed for use in trench and field warfare,
where it is desired to produce a dense smoke screen. It is made by
packing 340 grams of the standard smoke mixture in an ordinary light
metal gas grenade. Around the top of the grenade are vents closed by
a zinc strip. The ignition is caused by the standard bouchon when the
grenade is thrown. The heat of the reaction burns through the zinc
strip and a dense cloud of smoke is evolved for 45 seconds.

[Illustration: FIG. 94.—Smoke Cloud from B. M. Candle.]

Stannic chloride has also been used extensively in hand grenades, as
it gives a very disagreeable cloud of smoke upon detonation. Due to
the high prices and urgent need of tin for other purposes, silicon
tetrachloride was substituted for tin tetrachloride towards the close
of the war. A mixture of silicon tetrachloride and chloropicrin was
also used. This not only gives a very good smoke cloud, but combines
with it the toxic properties of the chloropicrin cloud.

The method of firing the smoke grenade is the same as that of any
grenade using the same type of bouchon. Usually the grenade is grasped
in the hand for throwing in such a manner that the handle of the
bouchon is under the fingers. The safety clip is pulled out with the
other hand and the grenade is thrown with an overhand motion. When the
grenade leaves the hand, the handle of the bouchon flies off, allowing
the trigger to hit the cap which ignites the fuse.

The white phosphorus combined hand and rifle grenade became the
standard smoke grenade by the end of the war. Stannic chloride was used
to clear out dugouts, but not as a smoke producer.


STOKES’ SMOKE SHELL

[Illustration: FIG. 95.—Stokes’ Smoke Shell.]

The Stokes’ smoke shell was perfected to furnish a means of maintaining
the best possible smoke screen at long ranges by means of an easily
portable gun. The 3-inch Stokes shell, as adapted for combustion
smokes, weighs about 13 pounds and contains about 4 pounds of standard
smoke mixture. This shell is designed to produce a continuous screen
over a period of 3 to 4 minutes.


LIVENS SMOKE DRUM

The Livens smoke drum was designed for use with the 8-inch Livens
projector, so as to produce a smoke screen of large volume and long
duration at long ranges. The drum, as adapted for combustion smokes,
weighs 17.5 pounds empty and 49 pounds loaded. The smoke-gas mixture
was specially adapted for use in the Livens drum.

[Illustration: FIG. 96.—Livens Smoke Bomb.]

Smoke mixtures in Livens were never used to any considerable extent
in the war and it is questionable if they ever will be. A Livens can
usually only be fired once before resetting, hence Stokes mortars are
used whenever possible.


SMOKE FUNNEL

The smoke funnel was developed for the production of a white smoke
cloud from the stern of a vessel. The smoke producing materials are
liquid ammonia and silicon tetrachloride, with carbon dioxide as a
compressing medium. This is the most satisfactory compressing medium,
because: (1) The silicon tetrachloride is forced out at nearly constant
pressure. (2) The carbon dioxide is easily compressed to a liquid and
can be handled in this form. Further, it has a vapor pressure of 800
pounds at 60° F., and a cylinder can be nearly emptied without loss
in efficiency. (3) Carbon dioxide is sufficiently soluble in silicon
tetrachloride to cause the latter to effervesce and thus materially aid
in its evaporation on spraying. (4) Liquid carbon dioxide, behaving in
a manner similar to liquid ammonia, affords a means for the silicon
tetrachloride to “keep pace” with the ammonia, under changes in
temperature, and thus ensures a more nearly neutral, and therefore the
most effective, smoke.

[Illustration: FIG. 97.—Navy Smoke Funnel.]

The smoke funnel proper consists of an open end cylinder, about 2 feet
in diameter and 7 feet long, mounted in a horizontal position on an
angle iron frame. At one end is an 18-inch fan securely fastened to the
cross supports. This fan is operated by hand, through gears giving a
ratio of about 30 to 1. The silicon tetrachloride enters the cylinder
through a pipe, which terminates in four spray nozzles, while the
ammonia enters through a single nozzle. The air forced into the funnel
serves to hydrolyze the silicon tetrachloride and mixes the vapors. The
resulting reaction evolves a dense white cloud of very large volume and
high obscuring power. One set of cylinders is capable of maintaining
this cloud for over 30 minutes. Under normal conditions the discharge
is at the rate of 2 pounds of silicon tetrachloride to 1 pound of
ammonia. To stop the smoke, the silicon tetrachloride is closed first,
the ammonia allowed to run about half a minute, and the fan is shut off
last.

[Illustration: FIG. 98.—Navy Smoke Funnel in Operation.]


SMOKE KNAPSACK

The smoke knapsack furnishes a portable apparatus for smoke production.
The gross weight is about 70 pounds; when in operation it gives a dense
white smoke for about 15 minutes. The operation may be intermittent
or continuous and the quantity of smoke is sufficient to completely
hide one platoon of men in skirmish formation with a 5-mile per hour
enfilade wind. The apparatus consists of two steel tanks about 26
inches in height and 6 inches in diameter. From the side of each tank,
but near the bottom, extends a short pipe on which is placed a suitable
valve. A flexible armored hose connects the valve to a short length of
pipe which is equipped with spray nozzle. The cylinders are charged
with silicon tetrachloride and ammonia under pressure. The valves may
be operated with the left hand, while the sprayer apparatus is held in
the right. The release buckles are within easy reach of both hands.


SHELL

While many special devices have been developed by means of which the
gas troops and infantry are able to set up smoke clouds on short
notice, the smoke shell, fired by the artillery, always played an
important part in this work. In the same way that a large number of the
poison gases were adapted to artillery use, so were most of the smoke
producing substances.

As a filler for smoke shell, phosphorus easily ranks first, and is
approached only by sulfur trioxide in very humid weather. A rough
approximation to the relative values of some of its rivals is given in
the following table:

    White phosphorus      100
    Sulfur trioxide        60-75
    Stannic chloride       40
    Titanium chloride      25-35
    Arsenic chloride       10

Comparison of the value of different forms of phosphorus for shell
purposes has invariably pointed to the superiority of the white
variety. Mixtures of white and red (2 to 1) have also proved effective.

A complete barrage over a front of 200 yards can be established in from
40 seconds to 1 minute and maintained by firing a salvo followed by
battery fire of 3 seconds. Four 4.5-inch howitzers could maintain an
effective barrage over a front of 1000 yards. The influence of sunshine
is very marked, as in moist, cool weather one shell every 15 seconds is
sufficient.

[Illustration: FIG. 99.—Smoke Screen for Tanks.]


SCREENING TANKS

Tests have demonstrated (see Fig. 99) that successful smoke screens for
tanks may be produced by spraying oleum into the exhaust. On a 7-ton
tank of the Renault type (40 H. P.) 110 cc. per minute produced a large
volume of smoke, which had excellent covering power, and which could be
made intermittent or continuous at will.

The same method may be applied to aeroplanes, and to ships. It is
calculated that a cylinder containing 300 pounds of 20 per cent oleum
will maintain a smoke screen on a ship for a period of 15 minutes,
if oleum is used at the rate of 23.6 pounds per minute. Since the
cylinders may be arranged in batteries, the screen may be continued
for any period of time. The Tank Corps rather favor phosphorus rifle
grenades for producing a smoke screen at a distance from the tank.


PURPOSE OF SMOKE SCREEN

Smoke screens may be employed with one or more of the following objects
in view:

(1) To mask known enemy observation posts and machine gun nests; to
conceal the front and flanks of attacking troops, concentration of guns
and tanks, roads and concentration points; to blind the flashes of
batteries in action and to hamper aerial observations.

(2) As a feint to draw the enemy’s attention to a front on which no
attack is being made, so as to hold his troops to their trenches, or to
induce him to expend ammunition needlessly and to put down a barrage in
the wrong place.

(3) To simulate gas and force the enemy to wear his mask. Gas should
occasionally be mixed with smoke, to impress upon him the belief that
it is never safe to remain in a smoke cloud without wearing his mask.

(4) In rolling or mountainous country, to fill valleys with smoke and
thereby conceal the advance from all observation, including aerial.

(5) To cover the construction of bridges, trenches, etc., in the face
of the enemy.


THE TACTICAL VALUE OF SMOKE

The pall of smoke that hung over every battlefield of the Civil
War made a profound impression upon Fries when, as a boy, he first
read of those battles. However, practically every reference made
to smoke treated it as a nuisance. It obscured the field of vision
and interfered with troop movements as well as with the aiming and
firing of rifles and cannon, though due to their short range this
was not so serious as it would be nowadays. Nevertheless so deeply
was this interference appreciated that the most earnest efforts were
made to discover a smokeless powder. This, as the world well knows,
was developed with great efficiency during the latter part of the
nineteenth century. With the development of the smokeless powders
came also a better understanding of the action of powder, whereby the
velocity of projectiles, and consequently the range and accuracy, were
greatly increased. This increased range and accuracy of guns forced a
consideration of protection,—and concealment is one form of protection.

The Navy would appear to have been the first branch of the American
forces to realize how valuable a smoke screen may be. Thus Fries, in
August, 1913, had the interesting experience of witnessing a week’s
maneuvers at the eastern entrance to Long Island Sound between the
Navy and the Coast Artillery. During that week the Navy carried out
extensive experiments with smoke screens both by day and by night. The
smoke in all cases was generated by smothering the fires on destroyers
or other ships, thus causing dense clouds of black smoke to be given
out from the funnels.

After the World War had been in progress some time and particularly
about the time the United States entered it, a determined search was
begun for more efficient smokes and more efficient smoke producers.

In the Navy, smoke screens were expected to be established by small
craft behind which larger vessels could maneuver for position and
range. These screens were also established for the purpose of cutting
off the view of enemy submarines or other vessels, thus allowing
merchant ships or even warships when injured or outclassed to escape.

The Army was much slower to appreciate the value of smoke. In fact,
apparently no army really realized the value of a smoke screen until
after gas warfare became an accomplished fact. As is well known, the
evaporation of the large quantity of liquid used in wave attacks
caused a cloud of condensed moisture. This is what gave rise to the
designation “cloud attack.”

English regulations for defense against gas in the early days called
for every man and animal to stand fast upon the approach of a gas cloud
and remain quiet until the cloud had passed. Thus casualties were
reduced to a minimum and the English were fresh to receive the attack
that was frequently launched immediately after the cloud had passed.
The Germans finally thought of the plan of sending over a fake gas
attack. In that way they simply produced a smoke cloud that looked like
a gas attack. Naturally the English stood fast as before. The Germans
attacking in the fake cloud naturally caught the British at a complete
disadvantage with consequent disastrous results to the latter.

But that was a game at which two could play. About this time the
value of white phosphorus for producing a smoke screen was taken up
by the British and large numbers of 4-inch Stokes mortar shells were
filled for that purpose. All armies then began to experiment with
smoke producing materials. Most of these were liquid. Of them all, as
has been stated before, white phosphorus, a solid, proved the best.
Toward the close of the war these smoke screens began to be used to
a considerable extent for the purposes given above. No one who has
engaged in target practice and encountered a fog, or who has hunted
ducks and geese in a fog needs to be told of the difficulty of hitting
an object he cannot see.

The First Gas Regiment proved its worth and won everlasting glory by
using the Stokes’ mortars of the British with their phosphorus bombs
for attacking machine gun nests. The white phosphorus in that case had
a double effect. It made a perfect smoke screen, thereby making the
German machine gun shots simply shots in the dark, while at the same
time the burning phosphorus forced the gunners to abandon their guns
and surrender. Thus phosphorus played and will play in the future the
double rôle of forming a defensive screen and of viciously attacking
enemy troops. This phosphorus, which catches fire spontaneously, burns
wet or dry, total immersion in water alone sufficing to put it out.
This means of extinguishing the flames being almost totally absent on
the battlefield, it can be truthfully said that burning phosphorus is
unquenchable. The burns are severe and difficult to heal. For these
reasons white phosphorus will be used in enormous quantities in any
future war.

All armies have begun to realize this value of smoke. In the future it
will be the infantryman’s defense against all forms of weapons and it
will be used on every field of battle, by every arm of the service and
at all times, day or night. It is even more effective in shutting out
the light from searchlights, star bombs and similar illuminants for
use in night attacks than it is in daylight. With this straight use of
smoke for protection will go its use along with poisonous gases. Every
smoke cloud will be poisonous or non-poisonous at the will of the one
producing the cloud, and this will be true whether it is produced from
artillery shell, mortar bombs, hand grenades, smoke candles or other
apparatus. Thus smoke and gas together will afford a field for the
exercise of ingenuity greater than that of all other forms of warfare.
The only limitation to the use of smoke and gas will be the lack of
vision of commanders and the ignorance of armies.

Proper recognition and aid given to chemical warfare development
and instruction in peace are the only methods of overcoming these
limitations. In this, as in all other development work, the most
serious obstacle comes from the man who will not see, whether it be
from a lack of intelligence, laziness or inbred opposition to all forms
of advancement.




CHAPTER XVII

TOXIC SMOKES


The introduction of diphenylchloroarsine as a poison gas really
introduced the question of toxic smokes. This material, as has
already been pointed out, is a solid, melting at about 30°. In order
to secure efficient distribution, the material was mixed with a
considerable amount of high explosive. When the shell burst, the
diphenylchloroarsine was finely divided or atomized and produced a
cloud of toxic particles. Since smoke particles are only slightly
removed by the ordinary mask, this formed a very effective means of
chemical warfare.

An analogous result was obtained by the use of poison gases, such
as chloropicrin, in a smoke cloud produced from silicon or stannic
chloride. Here, however, the toxic material was a real gas, and so the
real result attained consisted in forcing the men to wear their masks
in all kinds of clouds. The true toxic smoke went further in that the
ordinary mask offered little protection and thus compelled the warring
nations to develop a special type of smoke filter.

These smoke clouds consist of very small particles, which may be
considered as a _dispersed_ phase, distributed in the air, which we may
call the _dispersing medium_. The dispersed phase may be produced by
_mechanical_, _thermal_, or _chemical_ methods.

_Mechanical dispersion_ consists in the tearing apart of the material
into a fine state of subdivision. It may be called a hammer and anvil
action. The more powerful the mechanical force, the smaller the
resulting particles. This may be accomplished by the use of a high
explosive, such as the Germans used in the case of diphenylchloroarsine.

The production of smoke by _thermal dispersion_ depends essentially
upon the fact that when a substance of sufficiently low vapor pressure
is volatilized, and the vapors are passed into the air, they
recondense on the nuclei of the air to form a smoke. Vaporization from
an open container, permitting the vapors to pass directly to the air
without being quickly carried away from the surface of evaporation,
produces smoke having larger particles, because each particle formed
remains for an appreciable period of time in contact with air saturated
with vapor, and hence grows very rapidly.

The easiest way to produce small smoke particles is to mix the toxic
material directly with some fuel which will produce a large amount of
heat and gas upon burning. When this mixture is enclosed in a container
having a small orifice, upon burning, the toxic vapor and gas will pass
through this orifice at high velocity; it has been demonstrated by Lord
Rayleigh that the size of the particles depends upon the velocity of
emission of the gas from a given orifice.

The product of _chemical combination_ may include a super-saturated
vapor, which condenses into small particles.

_Explosive dispersion_ is really a combination of _mechanical
dispersion_ followed by _thermal dispersion_.


PENETRATION

The fundamental idea underlying all the work on toxic smokes is to
obtain a smoke that has marked penetrating power. Screening power is
not important here. In addition to penetration, a smoke should be
highly toxic and have a slow rate of settling.

Penetration may be tested by the use of a standard filter; a suitable
filter for this purpose is one which does not remove the smoke to such
an extent that measurement of its concentration becomes difficult,
and one which does not become clogged quickly by the smoke. A filter
consisting of two pads of felt, placed side by side and arranged so
that the smoke first comes in contact with the thinner and less dense
pad has been found very satisfactory.

In testing penetration, smoke is produced by dispersing one gram of the
toxic substance in a sheet iron box of 1000 liters capacity. After 5
minutes a steady concentration is usually attained and the smoke is
then forced through a Tyndall meter, (see page 299) after dilution with
air, where the initial concentration is determined. It then passes
through the standard filter, and through a second Tyndall meter, where
the final concentration is measured. The difference of the two readings
gives the amount of smoke retained by the filter. The penetration is
ordinarily represented by a series of figures, which decrease from a
maximum value at the beginning of the test to a minimum at a point
where the filter permits the passage of so little smoke that it cannot
be measured. This decrease is due to decrease in penetrating power and
concentration of the smoke, and to increase in filtering power of the
filter as a result of plugging. Usually five degrees of penetration are
recognized, excellent, good, fair, poor and very poor.

[Illustration: FIG. 100.—Penetration Apparatus Used to Test Toxic
Smokes.]

A portable penetration apparatus is shown in Fig. 100. In using the
apparatus, the smoke producing material is so placed with reference to
the apparatus that the sample is taken about 20 feet down the wind, so
that the smoke is appreciably diluted. One man is stationed at each
Tyndall meter and takes readings as fast as his recorder can write
them, so that the smoke density, before and after the filter, can be
followed very closely.


PHYSIOLOGICAL ACTION

In addition to a high penetrating power a smoke should also possess
great toxic, irritant, sternutatory, or lachrymatory power. These
properties are tested by exposing mice to the smoke in the chamber.
They are placed in the chamber at the beginning of the run, and exposed
for 10 minutes to the smoke from 1 gram of the material. While these
tests are only qualitative in character, they give a fairly good notion
of the relative value of different materials.


QUANTITATIVE RELATIONSHIPS

It has been found that, if the optical readings from the Tyndall meter
are plotted as ordinates against the time _t_ (the time elapsed after
detonation) as abcissas, and that portion of the curve between _t_ =
0 and _t_ = 30 considered, the curve generally descends sharply at
first, from a high point representing the density immediately after the
production of the smoke, to a point in the neighborhood of _t_ = 8,
where it flattens out and descends much more slowly with a slope that
changes little. The area under the significant portion of the curve,
that is, the area circumscribed by the curve from the point _t_₃₀ to
_t_₀, the vertical axis from this point to the origin, the horizontal
axis from the origin to _t_₃₀ and the line perpendicular to this
axis, cutting the curve at _t_₃₀, is a rough measure of the relative
values of different smokes. This area is calculated as the sum of two
rectangles, from _t_₀ to _t_₈ and from _t_₈ to _t_₃₀.

Some results are as follows:

                                Area 30
    Phenyldichloroarsine          181
    Triphenyldichloroarsine       178
    Diphenylcyanoarsine           137
    Diphenylchloroarsine          101
    Cyanogen bromide               94
    Methyl dichloroarsine          70
    Phenylimidophosgene            69
    Mustard gas                    38

The curves in Fig. 101 show the way in which the readings fall off with
time. Each substance of course has its characteristic curves.

[Illustration: FIG. 101.—Typical Curves Showing the Decrease in
Concentration of Smoke Cloud with Time.]


TOXIC MATERIALS

The selection of materials for the production of toxic smokes can only
be carried out experimentally. A number of very toxic substances have
been shown to be valueless as toxic smokes because of low penetration,
decomposition during the process of smoke production, or for other
reasons.

Arsenic compounds produce smokes distinctly better than the average.
Inorganic compounds which have high melting and boiling points are very
poor smoke producers. The only exception to this is magnesium arsenide,
which may suffer decomposition. Compounds like mercuric chloride
and arsenic tribromide, which boil or sublime at comparatively low
temperatures, produce good smokes. Most materials which boil below 130°
C. produce no smoke as they evaporate on dispersion. It is difficult
to set any upper limit for the boiling point beyond which materials do
not produce good smokes, but in all probability 500° C. is not far from
the maximum. Liquids and solids are, on the whole, almost equally good
as smoke producers. The physical condition of the material has no great
effect upon the amount of smoke which it will produce. This seems to
depend only upon the physical and chemical properties of the material.


TOXIC SMOKE APPARATUS

It has been mentioned above that the Germans used a shell, containing
solid diphenylchloroarsine and a high explosive. A 10.5 cm. shell
(Blue Cross) was about two-thirds filled with cast trinitrotoluene
and contained a glass bottle with 300-400 grams of toxic material.
Diphenylchloroarsine was also used in shell, in solution, a mixture of
phosgene and diphosgene (superpalite) being the ordinary solvent (Green
Cross). Mixtures of diphenylchloroarsine and phenyldichloroarsine were
also used.

In the case of high explosive shell, the use of a separate container
appears to be desirable, because a mixture with the explosive seriously
decreases its sensitiveness and even its destructive power. There is
also a question as to the stability of such a mixture. However, 75 mm.
shell containing 30 per cent diphenylchloroarsine mixed with T. N. T.
gave good clouds of toxic smoke.


TOXIC SMOKE CANDLE

Two toxic smoke candles were developed by the Chemical Warfare Service,
known as the B-M Toxic Smoke Candle, perfected by the Pyrotechnic
Section of the Research Division, and the Dispersoid Smoke Candle,
developed by the Dispersoid Section.

The B-M Toxic Smoke Candle consists of a bottle-shaped sheet steel
toxic container set into a can, containing smoke mixture. The heat from
the burning mixture causes the distillation of the toxic material.
The toxic vapor is discharged through a nipple, screwed into the neck
of the container and extending over the top of the smoke can. Steel
wool is used in the toxic container to reduce the violent boiling and
spattering of the material. A small amount of steel wool, held in place
by a wire screen, is also used in the nipple for the same purpose. The
toxic container is sealed by a fusible metal plug, melting at 90° C.,
cast into a retainer at the base of the nipple. The fusible plug melts
upon the first application of heat and allows free passage of the vapor
into the smoke cloud. The ignition of the apparatus is effected by
means of a simple match head and an accompanying scratcher.

[Illustration: FIG. 102.—Toxic Smoke Cloud from 500 D. M. Candles.]

    The candles were placed in 5 parallel rows which were
        2 yards apart, each row containing 100 candles on
        a 100 yard front. The total time of active smoke
        emission was 23 minutes.

The first evolution of smoke occurs about 10 seconds after the first
appearance of flame. About one minute after ignition the toxic
material will begin to distill into the smoke cloud and this will
continue for about four minutes. The burning of the candle should be
complete in about six minutes.

[Illustration: Dispersoid Candle British Candle

FIG. 103.—Comparison of Dispersoid and British D. M. Candles.]

The Dispersoid Toxic Smoke Candle differs from the B-M candle in that
the toxic container is not used. A mixture of smokeless powder and the
toxic material (diphenylchloroarsine or D. M., an arsenical obtained
from arsenic trichloride and diphenylamine) is filled directly into
the container, a cylindrical can 3.5 inches in diameter and 9 inches
high made from 27 gauge sheet metal, and packed under a total pressure
of 2,500 pounds. The top of the candle is a metal cover, containing
the match head scratcher, which is separated from the match head by a
Manila paper disc. These are the same as those used in the B-M candle.
The candle has a total weight of about 4.25 pounds, of which 3.6 pounds
are the smoke mixture, containing about 1.3 pounds of toxic material.

In operating the candles, the cover is removed and the match head
ignited by friction with the scratcher. The match head burns through
the cardboard and ignites the powder. The heat and gas produced by the
combustion of the powder vaporizes the particles of the toxic material
and carries the vapors out through the orifices at a high velocity
whereupon they recondense to form a smoke. The rapid emission of the
vapors through the orifice prevents any possibility of their ignition.

The time before good emission of smoke takes place after the ignition
of the match tip of a candle is 30 seconds. The average time of
vigorous smoke emission is from four to five minutes. The result
of a field test with the dispersoid candle is shown in Fig. 102. A
comparison of a British and a Dispersoid candle is shown in Fig. 103.
It should be stated that this may not have been a fair test as only one
British candle was available for the comparative test.




CHAPTER XVIII

SMOKE FILTERS


The first types of the Standard Box Respirator contained cotton pads,
which sufficed to remove the ordinary smoke of the battlefield and even
that from the earlier toxic materials. Improved methods of producing
toxic smokes, by means of which smaller particles were obtained, led,
early in 1918, to the recognition of the need of improved protection
against these smokes. The first attempts to meet this need consisted
in improving the filtering qualities of these pads. It was soon found,
however, that to make better filter pads would greatly increase the
total resistance of the canister. This was highly undesirable, since
the resistance of the ordinary canister was already so high as to be
very uncomfortable. To overcome this objection, some of the early
designs of filter canisters were provided with a mechanical valve,
which could be operated by hand, to by-pass the air around the filter
when the canister was used against gas alone, or so set as to make the
air pass through the filter when smoke was feared. This introduced a
factor of uncertainty among the men during a gas attack, since each man
must decide for himself whether smoke was present. This reason alone
was sufficient for discarding this design.

A preliminary study of the situation indicated that any filter for fine
smoke particles must have a high resistance per unit of area, but that
the total resistance must be comparatively low. In order to secure
the large area necessary to bring the total resistance within reason,
the experimental work was developed along three lines: The formation
of a filter into a bag, cup, or jacket to surround the outside of
the canister; the use of an arrangement sufficiently compact to go
inside the canister; and the use of a filter as a separate unit, to be
attached to the canister by an air connection.

A survey of the possible filtering materials indicated that only two
offered promise, namely, paper and felt.


PAPER FILTERS

Reports that the British had developed thin, creped, sulfite-cellulose
wood pulp paper for filters led to an intensive study of this material
by the Chemical Warfare Service.

[Illustration: FIG. 104.—Crepe Paper Doughnut Filter Canister.]

In general we may say that the development of paper filters (in sheet
form) met with little success. Papers affording the required protection
did not live up to the resistance specifications. The reason for this
probably is in the method of making paper. The pulp is fed onto the
screen of a Fourdrinier machine under conditions that do not permit of
uniformity in the distribution of the fibers and consequently there is
no uniformity in the size of pores. In order to eliminate the large
holes, which allow the smoke to pass readily, the paper must be pressed
to reduce these pores to the proper magnitude. This naturally results
in an approximately equal decrease in the size of the small pores, with
a consequent increase in the final resistance out of all proportion to
the protection gained. A very satisfactory paper was finally produced,
but the resistance was too high and it was necessary to increase the
total available filtering area, which resulted in the accordion type
of filter. This filter was incapable of development on a large scale
because of the large amount of hand work required in assembling. The
lack of uniformity in a single sheet has been overcome with some
success by making up a filter from 40 to 80 layers of tissue or crepe
paper, trusting that the law of chance would bring the large pores in
some successive layer. Such a filter was adopted by the British, but
since it did not give protection comparable with that afforded by felt
filters, it was rejected in the United States.

In the so-called “doughnut” filter use was made of tissue paper.
Instead of seeking for uniformity in a vertical direction through a
block of tissues, it was sought along the axis horizontal with the
sheet. The effectiveness of such a filter was less than that of felt.
In addition, serious difficulty was met in cutting the pile of tissue
paper into the proper shape so that eventually it was abandoned as a
production possibility.


FELT FILTERS

Work on the felt filters started about June, 1918. Great difficulties
were met in the beginning, as a felt satisfactory for this purpose must
be made under carefully controlled conditions and production conditions
during the war did not readily lend themselves to such control.
However, the opportunities afforded in felt making for uniform packing
and arranging of the fibers (the whole process of making a felt, is
one of gradual packing of fibers into a relatively small volume) are
such as to assure a greater degree of success than is the case in paper
making.

Very successful filters have been obtained with the use of felt. There
are two serious objections to its use, however. The first is the
great cost of the filter (this was above one dollar per filter at the
close of the War); the second is that felt is a valuable industrial
commodity. It is thus very desirable that a cheaper and a less
important industrial material be found.


THE 1919 CANISTER

Just before the Armistice, the Gas Defense Long Island Laboratory
brought out the so-called “1919 Canister,” which consisted of an oval
section, perforated metal, war gas material container with a central,
flat, perforated breathing tube connected to a nozzle at one end. (See
also page 228.) After this inner container is packed with the war gas
chemicals, a filter jacket is slipped over it and the top edge sealed
to the inner container.

[Illustration: FIG. 105.—1919 Felt Filter Canister.]

Attempts were made to put paper filters on this canister by wrapping
it with layers of paper. In some cases, layers of coarse burlap or
mosquito netting were applied between the layers of paper to give
mechanical strength and air space. The fact that many filters gave good
protection showed that a filter of this type and material is possible,
but the operations of wrapping and sealing require careful work in
production and inspection and even with the greatest skill and care,
imperfections are almost impossible to avoid. This chance of defects,
together with the labor involved, makes the process undesirable.


A THEORY OF SMOKE FILTERS

Tolman, Wells and Gerke, during the course of their work on toxic
smokes, developed the following theory of smoke filters.

The phenomena occurring in the filtration of smoke are exceedingly
complicated, but the general nature of the process may be simply
described in terms of the kinetic properties of the small particles
comprising the smoke.

A filter may be regarded as a series of minute capillaries through
which the smoke slowly flows. In order that filtration may take place,
it is not necessary to assume that the capillaries of the filter are
smaller than the particle, for the particles may diffuse to the walls
of the capillaries and it is believed that with typical filters this is
the actual method of smoke removal for particles less than 10⁻⁴ cm. in
diameter.

In accordance with this view as to the nature of smoke filtration,
the important factors involved are (1) the Brownian motion of the
smoke particles, (2) the area and arrangement of the internal surface
presented by the filter, (3) the flow of the smoke as a whole, and
(4) the attractive forces between the filter surfaces and the smoke
particles. The first three of these factors determine how many
particles come within the range of the mutual forces of the particle
and filter surface, and the fourth factor determines the chance or
expectation that the particle will permanently adhere to the surface of
the filter.


TESTING SMOKE FILTERS

All the early tests made on smoke filters used diphenylchloroarsine,
because it was felt that the filter must be tested against a toxic
smoke. A man test was developed as representative as possible of actual
conditions in the field, and the time necessary for a man to detect
diphenylchloroarsine smoke in the effluent stream when breathing at
a normal rate, using a carefully controlled concentration of smoke
produced by detonation, was used as the criterion of the protection
offered by the canister. This test was subject to extensive individual
variations, due to the varying physiological resistances of different
men to diphenylchloroarsine smoke. Further, it was quite inadequate for
rapid testing on a large scale. A testing machine was then developed,
which gave results comparable with those obtained in the man test. The
method used in detecting the gas was physiological, that is, by smell
or by its irritating action towards the membranes of the eye. While
these are purely qualitative tests, they are much more sensitive than
any possible chemical tests.

Because of the desirability of having a method which could be
controlled chemically, other methods were developed.

Ammonium chloride is a solid smoke, consisting of particles of quite
variable sizes. It is sensitive to dilution and clogs the pores of the
filtering medium quite rapidly. For this reason it was used in the
study of the rate of plugging or clogging of the filter (the closing of
the pores of the fabric or other material to the passage of air).

The smoke is produced by the reaction of ammonia and hydrogen
chloride-air streams. The smoke thus generated is passed from the
mixing chamber to a larger distribution box and from there through
the filter, at a standard rate. The concentration of the smoke may
be accurately determined by chemical means or photometrically, using
a Hess-Ives Tint Photometer, the Marten Photometer, or a special
photometer developed by the Chemical Warfare Service.

A comparison of a large number of tests with those of other smokes
would indicate that ammonium chloride smoke offers accurate information
as to protection sought, but is hardly a desirable smoke for testing on
a large scale.

The third method developed was the sulfuric acid smoke. This smoke was
produced by passing dry air through a tower of solid pieces of sulfur
trioxide and then mixing the vapor with a large volume of air at 50 per
cent relative humidity. It is not a clogging smoke and the filtering
efficiency does not change materially in the time of exposure required
for a test. The smoke lends itself easily to chemical analysis and
offers data as to exact particulate cloud concentrations which will
penetrate canisters; photometric measurements are also applicable.

[Illustration: FIG. 106.—Tobacco Smoke Apparatus for Testing Canisters.]

The fourth method consists in the use of tobacco smoke. This is
generated by passing air over ignited sticks of a mixture of tobacco
(63 per cent), rosin (30 per cent) and potassium nitrate (7 per cent).
This smoke is composed of particles of extreme uniformity in size;
chemically it is relatively inert. It is not a clogging smoke and is
not sensitive to moisture and dilution. The density of the effluent
smoke is compared with that of the entering smoke in a Tyndall beam,
and the filtering capacity of the material determined in terms of
the amount of air necessary to dilute the entering air to the same
concentration of the effluent air. The method is simple in manipulation
and the test is a rapid one (50 canisters per day). Because of
the apparent superiority of tobacco smoke as a testing smoke, the
accompanying disadvantages are possibly outweighed.

From the standpoint of inherent chemical properties, the general
desirability of a suitable testing smoke would decrease in the
following order: tobacco, sulfuric acid, ammonium chloride.




CHAPTER XIX

SIGNAL SMOKES


The success of pyrotechnics in night signalling led, during the
World War, to considerable attention being paid to the development
of pyrotechnic signals for day use. This was mainly directed to the
production of distinctive smokes, which should have the same long range
visibility under varying light conditions. Since a gray or white smoke
might be confused with the smoke produced accidentally by the explosion
of shell, it was necessary to use smoke of definite and unmistakable
colors, and red, blue, yellow, green and purple smokes were developed.
During the early part of the war, only a yellow smoke was in use,
though others were added later.


PRODUCTION OF COLORED SMOKES

There are three possible ways of obtaining signal smokes.

      I. Mechanically dispersing solids.
     II. Chemical Reaction.
    III. Volatilization of colored materials.

I. The first method, while possible, can never be an efficient method
of producing signals. Some success was met with in dispersing certain
inorganic materials, as rouge, and ultramarine, in projectiles fired
from a 3-inch mortar and exploded by a time fuse arrangement at the
height of their flight. Various mixtures were also tried, such as
antimony oxysulfide and aluminum powder (red), arsenic and antimony
trichlorides with sodium thiosulfate (yellow), etc., but these
compositions have the disadvantages of being liable to catch fire if
dispersed by a black powder explosion.

II. While colored smokes may be produced by chemical reaction, such
as the combination of hydrogen iodide (HI), chlorine and ammonia, the
clouds are not satisfactory as signals. In this particular case, the
purple cloud (to the operator in the aeroplane) appeared white to the
observers on the ground.

High temperature combustion smokes have also been studied. These are
used in the so-called smoke torches. The _yellow_ arsenic sulfide
smoke is the most widely used. Most formulas call for some sulfide of
arsenic (usually the native realgar, known commercially as “Red Saxony
Arsenic”), sulfur, potassium nitrate, and in some cases, a diluent like
ground glass or sand. A typical mixture consists of:

    Red arsenic sulfide   55%
    Sulfur                15%
    Potassium nitrate     30%

A very similar smoke may be obtained from the following mixture:

    Sulfur              28.6%
    White arsenic       32.0%
    Potassium nitrate   33.8%
    Powdered glass       6.6%

These smokes are not as satisfactory in color as the smoke produced
by a dye smoke mixture, especially when viewed from a distance, with
the sky as a background. They fade out rather quickly to a very nearly
white smoke.

A _black_ smoke upon first thought might seem to be the easiest of all
smokes to produce, but actually the production of a black smoke that
would be satisfactory for signalling purposes was rather a difficult
matter.

Starting with the standard smoke mixture, which gives a white or gray
smoke, hexachloroethane, which is solid, was substituted for the carbon
tetrachloride, in order to avoid a liquid constituent. Naphthalene was
first used, until it was found that the mixture of naphthalene and
hexachloroethane melted at temperatures below that of either of the
constituents. Anthracene was then substituted. The principal reaction
is between the magnesium and the chlorine-containing compound, whereby
magnesium chloride and carbon are formed. The reaction is very violent,
and a white smoke is produced. The anthracene slows down the reaction
and at the same time colors the smoke black. The speed of the reaction
may be controlled by varying the anthracene content.

In burning this type of smoke mixture in a cylinder, it is essential
that free burning be allowed. It has been found that if combustion
is at all smothered, and the smoke forced to escape through a
comparatively small opening, it will be gray instead of dense black.

III. Various attempts have been made to utilize the heat evolved when
the Berger type smoke mixture reacts to volatilize or mechanically
disperse various colored inorganic substances, and especially iodine.
These were unsuccessful. Modifications, such as

    Strontium nitrate   1 part
    Powdered iron       2 parts
    Iodine              3 parts

were also tried, but while such mixtures ignited easily, burned freely
and evenly, and gave a continuous heavy purple cloud, they were very
sensitive to moisture and capable of spontaneous ignition.

The most satisfactory and successful colored smokes are those produced
by the volatilization of organic dye materials. This practice seems
to have originated with the British, who produced such smokes by
volatilizing or vaporizing special dyes by igniting mixtures of the
dye, lactose and potassium chlorate and smothering the combustion.

In selecting dyestuffs for this purpose it was at once recognized that
only those compounds can be used which are volatilized or vaporized
without decomposition by the heat generated when the mixture is ignited
and the combustion smothered. It was also found that the boiling point
and melting or volatilization point of the colored compound must be
close enough together so that there is never much liquid dye present.
Since all colored organic compounds are destroyed if subjected to
sufficient heat, the mixture must be so prepared and the ignition
so arranged that the heat generated is not sufficient to cause this
destruction.

The oxidizing agents used in the combustion mixture may be either
potassium or sodium chlorate. The nitrate is not satisfactory. Lactose
has proven the best combustible. Powdered orange shellac is fairly
satisfactory but offers no advantage over lactose.

The following dyes have been found to give the best smokes:

    Red        “Paratoner”
    Yellow     Chrysoidine + Auramine
    Blue       Indigo
    Purple     Indulin (?)
    Green      Auramine Yellow + Indigo

At the beginning of the war, the only colored smoke used by the United
States Army was a yellow smoke. The smoke mixture used in all signals,
excepting the smoke torch, was the old arsenic sulfide mixture. The
following smoke signals were adopted during the World War:

    Signal Parachute Rocket             Yellow and Red
    V. B. Parachute Cartridge           Yellow
    25 mm. Very Parachute Cartridge     Yellow
    35 mm. Signal Cartridge             Yellow
    35 mm. Signal Cartridge             Red
    35 mm. Signal Pistol
    25 mm. Very Signal Pistol
    V. B. Rifle Discharger Cut


THE TACTICAL USE OF SIGNAL SMOKES

From the days when Horatius kept the bridge, down through the centuries
to the World War, all leaders in battle were pictured at the front
and with flaming sword, mounted on magnificent chargers, or otherwise
so prominently dressed that all the world knew they were the leaders.
During all these hundreds of years commands on the field of battle
were by the voice, by the bugle, or by short range signals with arms,
flags, and swords. Even where quite large forces were involved they
were massed close enough ordinarily so that signalling by such means
sufficed to cover the front of battle. In those cases where they did
not, reliance was put upon swift couriers on horseback or on foot.

With the invention of smokeless powder and the rifled gun battles were
begun and carried on at greater and greater ranges. Artillery fired
not only 2,000 to 3,000 yards but up to 5,000 and 10,000 yards, or
even, as in the World War, at 20,000 yards and more. It was then that
other means of signalling became essential. Distant signalling with
flags is known to have been practiced to a certain extent on land for
a long time. The extension of the telegraph and telephone through
insulated wires laid by the Signal Service was the next great step
in advance, and in the World War there came in addition the wireless
telephone both on land and in aeroplanes and balloons.

Along with this development, as mentioned under Screening Smokes, came
the development of the use of smoke for protection and for cutting off
the view of observers, thus making observation more and more difficult.
This use of smoke, coupled with the deadly fire of machine guns and
high explosives, forced men to take shelter in deep shell holes, in
deep trenches and other places that were safe, but which made it nearly
impossible to see signals along the front of battle.

Every man can readily be taught to read a few signals when clearly
indicated by definite, sharply defined colored smokes. At first these
were designed for use on the ground and will be used to a certain
extent in the future for that purpose, particularly when it is desired
to attract the attention of observers in aeroplanes or balloons. In
such cases a considerable volume of smoke is desired. For the man in
the trench or shell hole some means of getting the signal above the
dust and smoke of the battlefield is needed. It is there that signal
smokes carried by small parachutes, contained in rockets or bombs, have
proven their worth. These signals floating high above the battlefield
for a minute or more, giving off brilliantly colored smokes, afford a
means of sending signals to soldiers in the dust and smoke of battle
not afforded by any other method so far invented. As before stated,
every man can be taught these simple signals, where but very few men
can be taught to handle even the simplest of wireless telephones.

Thus, smoke has already begun to complicate, and in the future will
complicate still more, every phase of fighting. It will be used for
deception, for concealment, for obscuring vision, for signalling and
to hide deadly gases. The signal rocket will be used to start battles,
change fronts, order up reserves, and finally to stop fighting.

The signal smokes by day will be displaced at night by brilliantly
colored lights which will have the same meaning as similarly colored
smokes during the day. Thus, literally, smoke in the future will be the
cloud by day and the pillar of fire by night to guide the bewildered
soldier on the field of battle with all its terrors and amidst the
confusion, gas, smoke and dust that will never be absent while battles
last.




CHAPTER XX

INCENDIARY MATERIALS


Since it is generally known that white phosphorus, when exposed to
the air, takes fire spontaneously, it logically follows that numerous
suggestions should have been made for using this material in incendiary
devices. Practice, however, has shown that, while phosphorus is
undoubtedly of value against very easily ignitable materials, such as
hydrogen in Zeppelins, or the gasoline tanks of aeroplanes and dry
brush or grass, it is of much less value when wood and other materials
are considered. This is partly because of the low temperature of
burning, and partly because the product of combustion (phosphoric
anhydride) is really an excellent fireproofing substance. In view of
this, phosphorus was used primarily for smoke production.

A superior incendiary material is found in thermit, a mixture of
aluminum and iron oxide. When ignited, it produces an enormous amount
of heat very quickly, and the molten slag that results from the
reaction will prolong the incendiary action upon inflammable materials.
When used alone, however, it has the disadvantages that the incendiary
action is confined to a small area and that the heat energy is wasted
because of the fact that it is so rapid in its action.

For this reason it is customary to add a highly inflammable material,
which will become ignited by the thermit and will continue the
conflagration. Petroleum oils, carbon disulfide, wood distillation
products and other inflammable liquids were thoroughly tested for this
purpose. The final conclusion was reached that oil, solidified with
soap (sodium salts of the higher fatty acids) by a special method
developed by the Chemical Warfare Service, was by far the best material
to be used. In certain tests, using a combination of thermit and solid
oil, flames fifteen feet high were obtained, which would be very useful
against walls, ceilings, etc.

In addition to this type of incendiary material, it was desirable to
have a spontaneously inflammable mixture of oils, which could be used
in Livens’ shell, Stokes’ shell or aeroplane bombs. The basis of these
mixtures is fuel oil and phosphorus. By varying the proportions of
the constituents it is possible to obtain a mixture that will ignite
immediately upon exposure to the air, or one that will have a delayed
action of from 30 seconds to two minutes.

The incorporation of metallic sodium gives a mixture that will ignite
when spread upon water surfaces.


INCENDIARY DEVICES

The incendiary devices used during the late war included: bombs, shell,
tracer shell and bullets, grenades, and flame throwers.


BOMBS

Incendiary bombs were used almost exclusively by aircraft. The value
of bombs which would cause destruction by starting conflagrations was
early recognized but their development was rather slow. While the
designs were constantly changing, two stand out as the most favored:
a small unit, such as the Baby Incendiary Bomb of the English, and a
large bomb, such as the French Chenard bomb or the American Mark II
bomb.

In general bombs which, when they function upon impact, scatter small
burning units over a considerable area, are not favored. Small unit
bombs can be more effectively used because the scatter can be better
regulated and the incendiary units can be more advantageously placed.

=German Bombs.= Incendiary bombs were used by the Germans in their
airplane raids, usually in connection with high explosive bombs. A
typical armament of the later series of German naval airships consisted
of the following:

     2 660-pound bombs
    10 220-pound bombs
    15 110-pound bombs
    20 Incendiary bombs

making a total weight of about 2½ tons.

[Illustration: FIG. 107.—Incendiary Devices.

(From Left to Right). Mark II Bomb, B. I. Bomb, Mark I Dart, Mark II
Dart, Mark I Dart, Grenade, Mark I Bomb.]

A typical German bomb is shown in Fig. 108. It consists essentially of
a receiver of white iron (R) composed of a casing and a central tube
of zinc, joined together in such a fashion that, when the whole was
complete, it had the appearance of an elongated vessel with a hollow
center. Within this central hollow is placed a priming tube (T) of thin
sheet iron, pierced by a number of circular openings. The receiver is
about 445 mm. (17.5 in.) high and 110 mm. (4.3 in.) at its maximum
diameter. It is wrapped with strands of tarred cord over nearly its
entire length. The empennage (270 mm. or 10.6 in.—in height) consisted
of three inclined balancing fins, which assured the rotation of the
projectile during its fall.

In the body of the bomb was a viscous mass of benzine hydrocarbons,
while the lower part of the receiver contained a mixture of potassium
perchlorate and paraffin. The central tube apparently contained a
mixture of aluminum and sulfur.

[Illustration: FIG. 108.—Aerial Incendiary Bomb, November, 1916.]

[Illustration: FIG. 109.—German Incendiary Bomb, Scatter Type.]

Later the Germans used a scatter type of bomb (Fig. 109) which was
designed to give 46 points of conflagration. Each of these 46 small
cylinders contained 50 grams of an air incendiary material. They were
arranged in layers, packed in with very fine gun powder. The bomb
is ignited by a friction lighter which is pulled automatically when
the bomb is released from the aeroplane. The bomb is constructed to
burst in the air and not on striking the ground. The upper part of the
projectile consists of a cast iron nose riveted to the sheet iron body
of the bomb. When the explosion occurs, the nose is blown away and the
small incendiary cylinders are scattered in the air.

The incendiary material appears to be a mixture of barium nitrate and
tar. Its incendiary power is very low because combustion takes the form
of a small flame of very short duration. It should, however, be very
valuable for firing inflammable materials.

=British Bombs.= The early British bombs were petrol bombs, which were
used without great success for crop burning. Phosphorus bombs were
then used for attacking aircraft. But the most successful incendiary
is the so-called “Baby Incendiary Bomb.” This is a 6.5-ounce bomb with
an incendiary charge of special thermit. These small bombs are carried
in containers holding either 144 or 272 bombs. The former container
approximates in size and weight one 50-pound H.E. bomb and the latter
one 120-pound H.E. bomb. The bomb contains a cartridge very much like a
shot gun shell which, on impact, sets down on the striker point in the
base of the body, and causes the ignition of the charge. It is claimed
that the cartridge of the B.I. bomb burns when totally immersed in any
liquid (water included) and in depths up to two feet the flame breaks
through the surface.

=French Bombs.= The French used three types of incendiary bombs, a
special thermit (calonite), the Chenard and the Davidsen. The Chenard
bomb is a true intensive type and is thought to be very successful.
It functions by means of a time fuse operated by the unscrewing of
a propeller, before striking the ground, and reaches its target in
flames. Its chief disadvantage is the small amount of incendiary
material which it carries. The Davidsen bomb expels its charge as a
single unit and is not considered as valuable or as successful as the
Chenard.

=American Bombs.= The program of the Chemical Warfare Service included
three types of bombs:

    Mark  II  Incendiary drop bomb
    Mark III  Incendiary drop bomb
    Mark   I  Scatter bomb

=Mark II Bomb.= The incendiary Mark II drop bomb is designed to be
dropped from an aeroplane and is intended for use against buildings,
etc., when penetrating effect followed by an intensive incendiary
action is sought.

The bomb case consists of two parts: a body and a nose. The body is a
tapering zinc shell which carries the firing mechanism and stabilizing
tail fin at the small end and at the large end a threaded ring which
screws into the nose. The nose is of drawn steel of such shape as to
have low end-on resistance and is sufficiently strong to penetrate
frame structures.

[Illustration: FIG. 110.—Loading Bombs with “Solid” Oil.]

The incendiary effect is produced by a thermit charge carried in the
nose of the bomb. This charge is ignited by a booster of “Thermit
Igniter” fired by black powder. The latter is ignited by a flash from
the discharge of a standard 0.30 caliber service cartridge contained in
the body of the bomb, and exploded by a firing mechanism of the impact
type. This method of firing has proven wholly unsatisfactory and will
be superseded by some more direct-acting mechanism. The body of the
bomb is filled with solidified oil. The molten thermit burns through
the case of the bomb and liberates the oil which has been partially
liquefied by the heat of the thermit reaction. Additional incendiary
effect is afforded by the sodium nitrate contained in the nose below
the thermit, and by two sheet lead cylinders filled with sodium and
imbedded in the solid oil. The sodium increases the difficulty of
extinguishing the fire with water.

=Mark III Bomb.= This bomb is simply a larger size of the Mark II bomb,
its weight being approximately 100 pounds as compared with 40 pounds
for the Mark II bomb. It is designed to be dropped from an aeroplane
and is intended for use against buildings when marked penetrating
effect is desired. The method of functioning is the same as the Mark II
bomb and it has the same defects in the firing mechanism.

=Mark I Bomb (Scatter Type).= The Mark I incendiary drop bomb is also
designed to be dropped from aeroplanes and is intended for use against
grain fields, ammunition dumps, light structures or similar objectives
when only a low degree of ignition is required. It is of the so-called
scatter type, due to the action of the exploding charge which casts
out incendiary material within a radius of 20 feet from the point of
contact.

The incendiary action is due to the ejection of the various incendiary
units in the bomb by the explosion of the black powder in the nose. The
flash of this explosion serves to ignite the units. A powder charge in
the rear of the bomb acts simultaneously with the nose charge, opening
the bomb casing, and aiding materially in the scatter of the units.
The bomb is so arranged as to function close to the ground, which is a
further factor in the scatter of the units.

The incendiary units are waste balls about 2.5 in. in diameter and
having an average weight of 2.5 ounces, tied securely with strong
twine. These are soaked in a special oil mixture. Carbon disulfide and
crude turpentine, or carbon disulfide, benzene heads and crude kerosene
gave satisfactory results. A later development attempted to replace
the waste balls by solid oil, but the difficulties of manufacture and
questions of transportation argued against its adoption.

These bombs were not used at the front. Nearly all of the American
incendiary bombs proved too light on the nose and lower half, generally
resulting in deformation upon impact and very poor results. New ones
will be made stronger.


INCENDIARY DARTS

The British early recognized the value of a small bomb, and
consequently adopted their B.I.B. (Baby Incendiary Bomb), weighing
about 6.5 ounces. These are capable of being dropped in lots of 100
or more and thus literally shower a given territory with fire. The
intensity of fire at any given point is much less than that obtained
with the larger bombs, but the increased area under bombardment more
than counter balances this disadvantage. While the British aimed at
the perfection of a universal bomb, the American service felt that two
classes should be developed, one to be used against grain fields and
forests, the other against buildings.

The first class was called the Mark I Dart. This consisted of an
elongated 12-gauge shot gun shell, filled with incendiary material
and provided with a firing mechanism to ignite the primer as the dart
strikes the ground. The flash of the primer sets fire to the booster,
which, in turn, ignites the main incendiary charge. The latter burns
several minutes, with a long flame. A retarding stabilizer attached
to the tail of the dart serves the two-fold purpose of insuring the
functioning of the firing mechanism and, by retarding the final
velocity of the dart, preventing the collapse of the dart body when
dropped from very high altitudes.

The incendiary mixture is one which gives a long hot flame, burns for
several minutes and leaves very little ash. In general it consists
of an oxidizing agent (barium or sodium chlorate), a reducing agent
(aluminum, or a mixture of iron, aluminum and magnesium), a filler
(rosin, powdered asphaltum or naphthalene) and in some cases a binder
(asphaltum, varnish or boiled linseed oil).

The Mark II Dart was developed to furnish a small size penetrating
agent. It consists of a two-inch (diameter) zinc case filled with
thermit and solid oil as the incendiary materials and provided with
a cast iron nose for penetration. During the first half minute after
firing, a pool of molten iron is formed by the thermit, which is very
penetrating and affords a good combustible surface for the oil, which
burns for an additional ten minutes.

It has an advantage over the Mark I dart in that it penetrates, and
over the Mark II bomb in that it is smaller and lighter in weight.


INCENDIARY SHELL

Incendiary shell have been successfully used against aircraft and
to some extent in bombardments of inflammable ground targets.
Anti-aircraft shell are of small caliber and are usually
tracer-incendiary. Such shell are filled with pyrotechnic mixtures
which ignite at the moment of firing, or by time fuse, and are
effective against highly inflammable material. Shell filled with
thermit which explode and scatter the molten iron have been used
against aircraft and ground targets, but with rather poor results.
Large shell, which burst upon impact and scatter units of burning
materials, have been used with some success against ground targets.

Tracer shell contain such mixtures as barium nitrate, magnesium and
shellac, or red lead and magnesium.


INCENDIARY BULLETS

Incendiary bullets are only effective against highly inflammable
material, and are therefore used principally in aerial warfare against
aircraft, either for the purpose of igniting the hydrogen of the gas
bag, or the gasoline. The present tendency is towards the use of the
large size (11 mm.) bullet, because of its greater incendiary action.

The incendiary material is either white phosphorus or a special
incendiary mixture consisting of an oxidizing agent and some
combustible or mixture of combustibles. The white tracer bullet
contains a mixture of barium peroxide and magnesium. A red bullet
contained in addition, strontium nitrate and chloride, or peroxide.


INCENDIARY HAND GRENADE

While the use of incendiary grenades and other small incendiary devices
is limited, such armament is considered very valuable in trench
warfare. They can be used to set fire to inflammable material, either
in offensive or defensive operations.

Phosphorus grenades, while used principally for producing smoke (see
page 302), have considerable value as an incendiary weapon.

Thermit grenades are very useful in rendering unserviceable guns
and other metallic equipment which must be abandoned. They permit
aviators to destroy planes which motor troubles oblige to land in enemy
territory. They are also used to ignite inflammable liquids, thrown
into a dugout, or sprayed over an objective by a flame projector.

The Mark I hand grenade was developed for burning enemy ammunition
dumps, for clearing away brush or other material in front of trenches
and for use in dugouts. The standard H.E. grenade body was half-filled
with thermit and half with a celluloid container filled with a
solidified fuel oil. The grenade is fired by the spit of the fuse of
the bouchon firing mechanism. This, through the booster, lights the
thermit igniter, which in turn fires the main charge of thermit. The
resulting molten iron readily penetrates the grenade case, at the same
time igniting the celluloid case and its contents. The oil burns for
about 3.5 minutes. This grenade was never used since it was considered
that an all thermit grenade would be of more value.


TRENCH MORTAR EQUIPMENT

Special projectiles were designed for use with the Stokes mortar and
the Livens’ projector. Thermit was used only in Stokes’ projectiles.
The Livens’ projectile was filled with inflammable units (chlorated
jute) immersed in a light oil mixture. Thrown from a projector into
the enemy’s trench, it explodes, giving a large flash and scattering
the burning units over an area of forty yards. The Mark II projectile,
designed for general incendiary effect against readily inflammable
material, consists of an altered 8-inch Livens’ gas projectile filled
with chlorated jute units impregnated with solid oil and immersed in
a spontaneously inflammable oil. After a short delay, these units
burst into flame and burn vigorously for several minutes. It is almost
impossible to extinguish them without large quantities of water. Such
bombs have only a very limited use, so that it is questionable if they
are really worth while.

[Illustration: FIG. 111.—German 8" Incendiary Bullet.]

[Illustration: FIG. 112.—German Incendiary Blue Pencil.]


GERMAN BLUE PENCIL

A very interesting and curious device was developed by the Germans in
the form of an incendiary pencil. Similar in appearance to a common
blue pencil, sharpened at one end, they are distinguished only by a
small, almost imperceptible, point placed on the outside 11 mm. from
the unsharpened end. They are 175 mm. long, 11.1 mm. in diameter and
weigh 12 to 13 grams. The interior of the pencil contains a glass
bulb, with two compartments filled with sulfuric acid and a celluloid
tube filled with potassium chlorate. The glass bulb ends in a slender
point; when this is broken the acid comes into contact with the
chlorate and causes an explosion. The two materials are separated by a
layer of clay, which causes a delayed action of about 30 minutes. The
operator breaks the point of bulb, buries the pencil vertically in the
inflammable material and then has half an hour in which to get away,
before any possibility of a fire. He cuts the pencil with a knife 2
cm. from the point, so that if caught he has the appearance of simply
sharpening a pencil.


FLAMING GUN

Among the unsuccessful weapons of the late war, the liquid fire gun
or Flammenwerfer, as the German called it, is probably the most
interesting. Its origin, according to a German story, was due to a
mere accident. A certain officer, during peace maneuvers, was ordered
to hold a fort at all cost. During the sham fight, having employed all
the means at his disposal, he finally called out the fire brigade and
directed streams of water upon the attacking force. Afterwards, during
the criticism of the operations in the presence of the Kaiser, he
claimed that he had subjected the attackers to streams of burning oil.
The Kaiser immediately inquired whether such a thing would be possible,
and was assured that it was entirely feasible.

[Illustration: Copyright by Kadel and Herbert, N. Y.

FIG. 113.—Liquid Fire Attack.]

Long series of experiments were necessary before a satisfactory
combination of oils was produced, which could be projected as a
flame on the enemy, but they were finally successful. Unlike the
use of poison gas, however, the flaming liquid gun did not prove to
be a successful weapon of warfare. True, at first they were rather
successful, but this was before the men learned their real nature. In
the first attack, the Allies were completely surprised and the troops
were routed by the flames. Auld tells of one of the early attacks (July
29, 1915) when, without warning, the front line troops were enveloped
in flames. Where the flames came from could not be seen. All that the
men knew was that they seemed surrounded by fierce, curling flames,
which were accompanied by a loud roaring noise, and dense clouds of
black smoke. Here and there a big blob of burning oil would fall into
a trench or saphead. Shouts and yells rent the air as individual men,
rising up in the trenches or attempting to move in the open, felt the
force of the flames. The only way to safety appeared to be to the rear.
This direction the men that were left took. For a short space the
flames pursued them and the local retirement became a local rout. After
the bombardment which followed, only one man is known to have returned.

After a study of the pictures of the liquid fire gun in operation, it
is evident that the men could not be blamed for this retirement. One
has only to imagine being faced by a spread of flame similar to that
used for the oil burners under the largest boiler, but with a jet
nearly 60 feet in length and capable of being sprayed round as one
might spray water with a fire hose.

Later, when the device was better known it was different, though even
then it was a pretty good test of a man’s nerve. It was found that
the flames could not follow one to the bottom of a trench as the gas
did, and that, if a man crouched to the bottom of his trench, his head
might be very warm for a minute or so but that the danger was soon past
and he then could pick off the man who had so recently made things
uncomfortable for him.

While it is said that Major R., who invented the Flammenwerfer, enjoyed
a great popularity among his men, and is familiarly known as the Prince
of Hades, there is no doubt that this was not shared by the Allies.
Their rule was: “Shoot the man carrying the apparatus before he gets
in his shot, if possible. If this cannot be done, take cover from the
flames and shoot him afterwards.”

The German had several types, which may be grouped into the _small_ or
_portable_ and the _large_ Flammenwerfers.

The portable Flammenwerfer consisted of a sheet steel cylinder of two
compartments, one to hold compressed nitrogen, the other to hold the
oil. The nitrogen furnished the pressure which forces the oil out
through the flexible tube. Air cannot be used, because the oxygen would
form an explosive mixture with the vapors of the oil, and any heating
on compression, or back flash from the flame or fuse might make things
very unpleasant for the operator. A pressure of about 23 atmospheres
is reached when the cylinder is charged. The nitrogen appeared to
be carried on the field in large containers and the flame projectors
actually charged in the trenches.

The oil used in the flame projectors varied from time to time, but
always contained a mixture of light or easily volatile and heavy and
less volatile fractions of petroleum or mineral oil, very carefully
mixed. In some cases even ordinary commercial ether has been found in
the cylinders.

[Illustration: FIG. 114.—Small Flammenwerfer.]

The most interesting part about the flame projector is the lighting
device. This is so made that the oil ignites spontaneously the minute
the jet is turned on, and is kept alight by a fiercely burning mixture
which lasts throughout the discharge. This mixture is composed of
barium nitrate, potassium nitrate, metallic magnesium and charcoal,
with some resinous material. The priming consists of black powder and
metallic magnesium.

When the oil rushes out of the jet, it forces up the plunger of a
friction lighter and ignites this core of fiercely burning mixture.

The range of these small projectors is from 14 to 17 meters (17 to 20
yards) but the duration of the flame is rather less than a minute.

In a later pattern, it was designed that one nozzle should be issued
to three reservoirs. After the discharge of one, the jet is attached
to the others in succession. This is called the “Wx” Flammenwerfer
(interchangeable). In this way a squad of three men could carry 58
pints of inflammable oil. It is a question, though, whether the third
man would live to use his reservoir.

[Illustration: FIG. 115.—Boyd Flame Projector.]

The fact that the trenches were often very close together during the
early part of the war, made possible the use of large or stationary
Flammenwerfer. These consisted of a steel reservoir 3⅓ feet in height
and 1⅔ feet in diameter, weighing about 250 pounds, which could be
connected to two steel cylinders, containing nitrogen under pressure.
These carried 180 liters (40 gallons) of liquid and operated under a
pressure of 15 atmospheres. The discharge nozzle was at the end of a
metal tube three feet long, and its orifice was about ⁵/₁₆ of an inch
in diameter. The range of this apparatus was from 33 to 40 yards and
the duration of the flame from one to two minutes. Because of the
comparatively short range of these guns and the ease with which they
could be destroyed, if located by the enemy, their use was very limited.

Even with the portable flammenwerfer, the most difficult thing to do
is to get near enough the target to make the shoot effective. Another
serious disadvantage is its very short duration. It is impossible to
charge up again on the spot, and the result is that once the flame
stops, the whole game is finished and the operators are at the mercy of
the enemy.

With these facts in mind it is easy to see how service in the flaming
gun regiments is apparently a form of punishment. Men convicted of
offenses in other regiments were transferred either for a time or
permanently and were forced under threat of death in the most hazardous
enterprises and to carry out the most dangerous work. Taken all in
all the flame thrower was one of the greatest failures among the many
promising devices tried out on a large scale in the war.




CHAPTER XXI

THE PHARMACOLOGY OF WAR GASES


The pharmacology of war gases plays such an important part in chemical
warfare that a brief discussion may well be given of the methods
used in the testing of gases for toxicity and other pharmacological
properties.

War gases may be divided into two groups: persistent and
non-persistent, each of which may include several classes:

      I. Lethal
     II. Lachrymatory
    III. Sternutatory
     IV. Special

Each class necessitates special tests in order to determine whether or
not it is suitable for further development.


TOXICITY

One of the first points which must be carefully determined in
investigating a substance is its toxicity. It is important that this be
determined for numerous reasons:

1. To determine what concentrations are dangerous in the field.

2. To ascertain how effective protective devices have to be to furnish
sufficient protection against the gas.

3. To furnish a basis for accurate experimental work on the treatment
of gassed cases.

4. To decide whether or not the material is worthy of further
development in the laboratory or in the plant.

These considerations necessitate the determination of the toxicity in
the form of a vapor and not by the ordinary method of administration
by mouth, through the skin (subcutaneously) or through the blood
(intravenously). The simplest method of determining the toxicity of
a substance as a vapor would be to place animals in a gas-tight box
and introduce a known amount of the substance in the form of vapor.
But by this method the concentration is not accurately known unless
chemical analyses of the air are made, and then it is found to be much
less than that calculated from the amount of substance introduced,
because of condensation on the walls of the chamber, or absorption of
the substance by the skin and hair of the animal and in some cases, of
decomposition of the substance by moisture in the air. Moreover, it is
found that the concentration decreases markedly with time. Because of
these factors, the figures used for the concentration are more or less
guess work. To overcome these difficulties, a chamber is used through
which a continuous current of air, containing a known and constant
amount of the poisonous vapor, is passed. Such an apparatus is shown in
Fig. 116.

[Illustration: FIG. 116.—Continuous Flow Gassing Chamber for Animals.]

The flask _E_ is a 300 cc. Erlenmeyer flask, with a ground glass
stopper. The liquid to be tested is placed in this flask together
with a sufficient quantity of glass wool to prevent splashing and the
carrying over mechanically of droplets of the liquid. Air is passed
through _A_ and _C_ (calcium chloride drying tubes) and the rate
measured by the flow meter _D_. The air and gas are mixed in _F_ before
passing into the chamber _G_. This chamber is made of plate glass, is
of about 100 liters capacity, and is air-tight. The entire flow of air
and gas through the box, kept constant at 250 liters per minute, is
measured at _H_. The gas is removed through _K_, which is filled with
charcoal and soda-lime, in order that little gas may pass into the pump.

By weighing the flask _E_, and its contents before and after passing
air through it, and knowing the total volume of the mixture passing
through the chamber during the same period, the concentration of the
substance can readily be calculated. This concentration, as determined
by the “loss in weight” method, can be checked by chemical analysis
(samples taken at _M_—_M_). The method has been found to give accurate
values.

The concentration in the chamber reaches its constant level within 30
to 40 seconds after the apparatus is started.

With the flow of 250 liters per minute, the difficulties mentioned
above are reduced to a point where they are practically negligible.

All toxicity tests on mice were made with an exposure of ten minutes,
while dogs were exposed for thirty minutes. In case death did not occur
during exposure, the animals were kept under observation for several
days. Toxicity and all other figures are expressed in milligrams per
liter of air, though parts per million (p.p.m.) was frequently used
during the early work.

Another point of difficulty is the great individual variation in the
susceptibility of animals. This is probably greater than when the
poison is administered subcutaneously or intravenously. It necessitates
the use of a large number of animals in making a determination of the
toxicity of a gas. Again, the toxicity for different species may vary,
and as the ultimate aim is a knowledge of the toxicity for man, a
great many different species must be used. If the toxicity is widely
different for different animal species, it is hard to arrive at a
definite conclusion as to the toxicity for man.

With longer exposures than thirty minutes the lethal concentration
is usually less, there being a cumulative effect. This is not true
for hydrocyanic acid. If the concentration is not enough to kill at
once, an animal can stand it almost indefinitely. Whether the action
is cumulative or not depends on the rate at which the system destroys
or eliminates the poison. If the poison is being eliminated as fast
as received the concentration in the tissues cannot increase. It is
stated, for example, that the amount of nicotine in a cigar would
kill a man if taken in one dose. If it is spread over twenty minutes,
the destruction or elimination of the nicotine is so rapid that no
obviously bad effects are noted.

Another interesting thing about the work on poison gases is that in
most cases a preliminary exposure to less than the lethal concentration
does not seem to make the animal either more or less sensitive on a
later exposure. This is quite unexpected, because we know that with
irritating gases, especially lachrymators, men adapt themselves to
much higher concentrations than they could stand at first. In view
of the experiences of arsenic eaters, it is quite possible that the
experiments, which showed no accustoming to toxic gases, were not
continued long enough to give positive results.

Not only does the susceptibility of different animals of the same
species vary greatly for a particular gas, but the susceptibility of
different species varies greatly with different gases. Thus while the
effects of certain gases on mice are quite comparable to the effects on
man, it is very far from being true with other gases.


LACHRYMATORS

While one cannot determine the lethal concentrations of poison gases
for men, it is possible to determine the concentration that will
produce lachrymation. The threshold value is that at which two-thirds
of the observers experience irritation. The lachrymatory value is
considerably higher than the threshold value.

[Illustration: FIG. 117.—Aeration Apparatus for Testing Lachrymators.]

A very satisfactory method for determining lachrymatory values is
shown in Fig. 117. Air is measured at _A_ and bubbled through the
lachrymatory substance in _B_. The air and gas are mixed in _D_ and
pass into _E_, a gas-tight, glass-walled chamber of about 150 liters
capacity. The gas is removed through _Ef_, by suction and the volume of
the air-gas mixture measured by the flow meter, _F_.

After the apparatus has run a few minutes, and the concentration of
the gas has become constant, the subject is instructed to adjust the
mask, attached at _H_, and to tell whatever he notices just as soon
as he notices it. The operator stands in such a position that he can
manipulate the stopcock _H_ without being observed by the subject.
After breathing air for a time (_H_ is a two-way cock, connected with
the air through _J_, and to the chamber through _Eg_) both to become
accustomed to the mask and to eliminate, as far as possible, any
“psychological symptoms,” the subject is allowed to breathe the gas
mixture for a maximum of three minutes. If the expected symptoms are
produced in less than this time, the test is discontinued as soon as
they develop.

[Illustration: FIG. 118.—Type of Spray Nozzles.]

For accurate work, it is necessary to work with a pure sample which is
at least fairly volatile. Mixtures cannot be run by this method. In
this case it is necessary to volatilize each separately, passing the
vapors simultaneously into the mixing chamber _E_.

A spray method may also be used with satisfactory results. Types of
sprays are shown in Fig. 118.


ODORS

Because of the great value in detecting low concentrations of gases in
the field, it is important to know the smallest amount of a gas that
can be detected by odor. In some cases, this test is more delicate than
any chemical test yet devised.

Odors may be divided into two classes, true odors, and mild irritation.
By true odor is meant a definite stimulation of the olfactory nerve,
giving rise to a sensation which is more or less characteristic for
each substance producing the stimulation. Mild irritation defines
the sensation which is confused with the sense of smell by untrained
observers, but which is really a gentle stimulation of the sensory
nerve endings of the nose. This so-called odor of substances producing
this effect is not characteristic. Higher concentrations of these
compounds almost invariably cause a definite irritation of the nose.

Examples of true odors are the mercaptans, mustard gas, bromoacetone,
acrolein, chlorine and ammonia. Substances which cause mild irritation
are chloroacetone, methyl dichloroarsine, ethyl iodoacetate and
chloropicrin.

In making the test for odor, the same apparatus is used as for
lachrymators. The time of exposure is shortened to 30 seconds, as the
subject always detects the odor at the first or second inhalation.

In this connection the recent work of Allison and Katz (_J. Ind.
Eng. Chem._ =11=, 336, [1919]) is of interest. They have designed an
instrument, “the odorometer,” for measuring the intensity of odors
in varying concentrations in air. It is based on the principle given
above. A measured volume of air is passed through the liquid and
then diluted to a given concentration. The mixture is then passed
through a rubber tube with a glass funnel at the open end. Only one
inhalation of the mixture is used to determine the intensity of
the odor. The position of any strength of odor on the scale depends
upon the sensitiveness and judgment of the operator, but with one
person conducting the entire test, the results have been found quite
satisfactory. (See tables on pages 360 and 361.)


SKIN IRRITANTS

Substances which seem useful for producing skin burns are studied both
on animals and on man. Dichloroethyl sulfide (mustard gas) is used as a
basis of comparison. Several methods are available.

=Direct Application.= This method consists of the direct application of
the compound itself to the skin, using a definite quantity (0.005 cc.
or 0.005 mg.) over a definite area (5 square centimeters) of the skin.
With such a quantity of mustard gas a rather severe burn on animals is
produced. No precautions are taken to prevent evaporation from the skin
since it is believed that in this way the test will approximate fairly
closely the field conditions.

=Vapor Tests.= Preliminary tests with vapors of volatile compounds are
best made by placing a small amount of the material on a plug of cotton
in the bottom of a test tube enclosed in a larger test tube which acts
as an air jacket. After about an hour at room temperature the mouth of
the test tube is applied to the skin. The concentration is not known,
but one is dealing practically with saturated vapor. If an exposure
of from 30 to 60 minutes produces no effect, one is safe to assume
that the compound is not sufficiently active to be of value as a skin
irritant.

If quantitative results are desired, the apparatus shown in Fig. 119
is used. Dry air is blown through the bubbler, which is connected with
a series of glass skin applicators. The concentration is determined
in the usual way. The skin applicator consists of a small cylinder
about 1.5 to 2 cm. in diameter and about 4 cm. long with a small
glass handle attached on top. The opening is 1 cm. in diameter. When
the concentration of the gas is constant, the exposure to the skin
is made directly for any desired length of time. The skin irritant
efficiency is judged by comparing the per cent of positive responses to
approximately equal concentrations of the vapors, using mustard gas as
a standard.

           TABLE I—PHYSICAL AND PHYSIOLOGICAL PROPERTIES OF CHEMICALS USED
                        AS STENCHES
    ----------------+-------+--------+-----------------+-------------+------------
                    |Boiling|Freezing|                 |Physiological|
          Chemical  | Point,| Point, |   Character     | Properties  | Remarks
                    |  °C.  |  °C.   |    of Odor      |  of Vapor   |
    ----------------+-------+--------+-----------------+-------------+------------
    Amyl acetate    | 148   |  -75   |Banana oil       |Harmless     |Pleasant to
                    |       |(thick) |                 |             |most people;
                    |       |        |                 |             |disagreeable
                    |       |        |                 |             |to some
    Ethyl acetate   |  77.4 |  -83.8 |Fruity, pleasant |Harmless     |
    Amyl alcohol    | 137.8 |        |Alcoholic        |Harmless     |
    Butyric acid    | 162.3 |   -7.9 |Very disagreeable|Harmless     |
    Valeric acid    | 186.4 |  -58.5 |Very disagreeable|Harmless     |
    Ethyl ether     |  35   | -112.6 |Pungent          |Soporific    |
    Phenyl          | 165   |        |Very disagreeable|Unknown      |
       isocyanide   |       |        |                 |             |
    Allyl           | 151   |        |Mustard oil,     |Lachrymatory |
     isothiocyanate |       |        |  disagreeable   | and toxic   |
    Methyl          | 119   |   34   |Mustard oil,     |Lachrymatory |
      isothiocyanate|       |        |  disagreeable   | and toxic   |
    Amyl isovalerate| 190   |        |Very disagreeable|Harmless     |
    Butyl mercaptan |  97   |        |Very disagreeable|Harmless     |
    Isobutyl        |  88   |        |Very disagreeable|Unknown      |Probably
       mercaptan    |       |        |                 |             | harmless
    Ethyl mercaptan |  37   | -144.4 |Very disagreeable|Harmless     |
    Propyl mercaptan|  67   |        |Very disagreeable|Unknown      |Probably
                    |       |        |                 |             | harmless
    Methyl          | 222.2 |   -8.3 |Oil of           |Harmless     |
       salicylate   |       |        |  wintergreen,   |             |
                    |       |        |  pleasant       |             |
    Amyl thioether  | 95-98 |        |Very disagreeable|Unknown      |Probably
                    |       |        |                 |             | harmless
    Ethyl thioether |  92   |  -99.5 |Very disagreeable|Unknown      |Probably
                    |       |        |                 |             | harmless
    Carbon          | 76.74 |  -19.5 |Sweet, unpleasant|Harmless     |
     tetrachloride  |       |        |                 |             |
    Chloroform      |  62   |  -63.2 |Sweet, agreeable |Soporific    |
    Iodoform        | Decom-|  119   |Unpleasant       |Harmless     |
                    | poses |        |                 |             |
    Artificial musk |       |        |Pleasant         |Harmless     |Unpleasant
                    |       |        |                 |             |in higher
                    |       |        |                 |             |concentration
    Nitrobenzene    | 209.4 |    5.71|Almonds, pleasant|Toxic        |
    Oil of          |       |        |Pleasant         |Harmless     |
       peppermint   |       |        |                 |             |
    Pyridine        | 115.2 |  -42   |Very disagreeable|Toxic        |
    ----------------+-------+--------+-----------------+-------------+-------------

   TABLE II—RESULTS OF MEASUREMENT OF THE INTENSITY OF VARIOUS STENCHES
     ---------------------+---------------------------------------------
                         |    Volumes of the Chemical, as a Perfect
                         |       Gas, per Million Volumes of Air,
                         |              Intensity of Odor
                         +------------+------+----------+--------+------
    Chemical             |            |      |  Quite   |        | Very
                         | Detectable |Faint |Noticeable| Strong  Strong
    ---------------------+---------- -+------+----------+--------+------
    Amyl acetate         |     7      |   10 |    13    |   90   |  246
    Ethyl acetate        |   190      |  339 |   615    | 1236   | 1753
    Amyl alcohol         |    63      |   83 |   123    |  439   |  601
    Butyric acid         |     2.4    |    6 |    18    |   91   |  161
    Valeric acid         |     7      |   29 |   125    |  332   |  962
    Ethyl ether          |  1923      | 3352 |  4927    | 5825   |19982
    Butyl mercaptan      |     6      |   12 |    18    |   38   |   56
    Isobutyl mercaptan   |     3.5    |    5 |     7    |   11   |   16
    Ethyl mercaptan      |    18      |   35 |    73    |  141   |  198
    Propyl mercaptan     |     2      |    7 |     9    |   14   |   17
    Amyl thioether       |     0.2    |    1 |     1.6  |    1.7 |   2.2
    Ethyl thioether      |     3      |   12 |    29    |   61   |   74
    Allyl isothiocyanate |    ?2      |    3 |     6    |    8   |   50
    Methyl isothiocyanate|     5      |   13 |    23    |   36   |   48
    Amyl isovalerate     |     1.7    |    3 |     6    |   10   |   12
    Carbon tetrachloride |   718      | 1461 |  1588    | 4964   |6091
    Chloroform           |   674      | 1389 |  2600    | 5887   |9528
    Iodoform             |     1.1[35]|      |          |        |
    Artificial musk      |            |      |          |        |
    Nitrobenzene         |    29      |   36 |    44    |  114   | 296
    Phenyl isocyanide    |     0.5    |    1 |     3    |   10   |  25
    Pyridine             |    10      |   45 |    93    |  700   | 1764
    Methyl salicylate    |    16.1    |   23 |    29    |  244[36]|
    Oil of peppermint    |            |      |          |        |
    ---------------------+------------+------+----------+--------+------
    ---------------------+----------------------------------------------
                         |        Milligrams of Chemical per
                         |              Cu. Ft. of Air,
                         |             Intensity of Odor
                         +-----------+-------+----------+--------+------
    Chemical             |           |       |  Quite   |        |  Very
                         | Detectable| Faint |Noticeable| Strong |Strong
    ---------------------+-----------+-------+----------+--------+------
    Amyl acetate         |   1.1     |   1.5 |     2    |  14    |   38
    Ethyl acetate        |  19.4     |  34.6 |    63    | 126    |  191
    Amyl alcohol         |   6.4     |   8.5 |    13    |  45    |   61
    Butyric acid         |   0.3     |   0.6 |     2    |   9    |   16
    Valeric acid         |   0.8     |   3.4 |    15    |  39    |  114
    Ethyl ether          | 165.1     | 287.7 |   423    | 500    | 1715
    Butyl mercaptan      |   0.5     |   1.0 |     2    |   3    |    5
    Isobutyl mercaptan   |   0.2     |   0.5 |     0.7  |   1    |    2
    Ethyl mercaptan      |   1.3     |   2.5 |     5    |  10    |   14
    Propyl mercaptan     |   0.2     |   0.6 |     0.8  |   1.2  |   1.6
    Amyl thioether       |   0.04    |   0.2 |     0.3  |   0.4  |   0.5
    Ethyl thioether      |   0.3     |   1.2 |     3    |   6    |    8
    Allyl isothiocyanate |   0.2     |   0.3 |     0.7  |   0.9  |    6
    Methyl isothiocyanate|   0.4     |   1.1 |     2    |   3    |    4
    Amyl isovalerate     |   0.4     |   0.5 |     1    |   2    |   2.3
    Carbon tetrachloride | 128       | 260   |   283    | 886    | 1087
    Chloroform           |  93       | 192   |   360    | 816    | 1321
    Iodoform             |  0.5[37   |       |          |        |
    Artificial musk      |  0.001[38]|       |          |        |
    Nitrobenzene         |   4       |   5   |     6    |  16    |   42
    Phenyl isocyanide    |   0.06    |   0.1 |     0.4  |   1    |    3
    Pyridine             |   0.9     |   4   |     9    |  64    |  162
    Methyl salicylate    |   2.8     |   4   |     5    |  43[39 |
    Oil of peppermint    |   0.68    |   0.9 |     3    |   9.5  |   9.9
    ---------------------+-----------+-------+----------+--------+-------
    ---------------------+-----------------------------------------------
                         |           Milligrams of Chemical per
                         |                 Liter of Air,
                         |               Intensity of Odor
                         +-----------+------+----------+---------+------
    Chemical             |           |      |  Quite   |         | Very
                         | Detectable| Faint|Noticeable| Strong  |Strong
    ---------------------+-----------+------+----------+---------+------
    Amyl acetate         | 0.039     | 0.053|   0.067  | 0.478   | 1.326
    Ethyl acetate        | 0.686     | 1.224|   2.219  | 4.457   | 6.733
    Amyl alcohol         | 0.225     | 0.300|   0.442  | 1.581   | 2.167
    Butyric acid         | 0.009     | 0.021|   0.066  | 0.329   | 0.580
    Valeric acid         | 0.029     | 0.119|   0.523  | 1.394   | 4.036
    Ethyl ether          | 5.833     |10.167|  14.944  |17.6667  |60.600
    Butyl mercaptan      | 0.018     | 0.037|   0.055  | 0.120   | 0.177
    Isobutyl mercaptan   | 0.008     | 0.018|   0.025  | 0.041   | 0.060
    Ethyl mercaptan      | 0.046     | 0.088|   0.186  | 0.357   | 0.501
    Propyl mercaptan     | 0.006     | 0.020|   0.028  | 0.043   | 0.054
    Amyl thioether       | 0.001     | 0.007|   0.0115 | 0.012   | 0.015
    Ethyl thioether      | 0.012     | 0.042|   0.107  | 0.223   | 0.271
    Allyl isothiocyanate | 0.008     | 0.012|   0.024  | 0.030   | 0.201
    Methyl isothiocyanate| 0.015     | 0.039|   0.067  | 0.108   | 0.144
    Amyl isovalerate     | 0.012     | 0.018|   0.039  | 0.072   | 0.082
    Carbon tetrachloride | 4.533     | 9.222|  10.024  |31.333   |38.444
    Chloroform           | 3.300     | 6.800|  12.733  |28.833   |46.666
    Iodoform             | 0.018[40] |      |          |         |
    Artificial musk      |0.00004[41]|      |          |         |
    Nitrobenzene         | 0.146     | 0.178|   0.222  | 0.563   | 1.493
    Phenyl isocyanide    | 0.002     | 0.005|   0.013  | 0.042   | 0.105
    Pyridine             | 0.032     | 0.146|   0.301  | 2.265   | 5.710
    Methyl salicylate    | 0.100     | 0.145|   0.179  | 1.526[42]|
    Oil of peppermint    | 0.024     | 0.032|   0.109  | 0.332   | 0.348
    ---------------------+-----------+------+----------+---------+------

[Footnote 35: Maximum concentration obtainable.]

[Footnote 36: Maximum concentration obtainable.]

[Footnote 37: Maximum concentration obtainable.]

[Footnote 38: Maximum concentration obtainable.]

[Footnote 39: Maximum concentration obtainable.]

[Footnote 40: Maximum concentration obtainable.]

[Footnote 41: Maximum concentration obtainable.]

[Footnote 42: Maximum concentration obtainable.]

=Touch Method.= This method consists of dipping a small glass rod drawn
to a needle-like end to the depth of 1 mm. in the compound and then
quickly touching the skin. The method is qualitative only.

[Illustration: FIG. 119.—Skin Irritant Vapor Apparatus.]

=Use of Solutions.= Alcohol, kerosene, olive oil, carbon tetrachloride
and other solvents may be used for the purpose of determining
the lowest effective concentration of a substance, and for the
determination of the relative skin irritant efficiencies of various
compounds. Since the skin irritants were scarcely ever used in
this form in the field, that is, in solution, the method is not as
satisfactory as the vapor method.




CHAPTER XXII

CHEMICAL WARFARE IN RELATION TO STRATEGY AND TACTICS[43]


=Fundamentals of War.= The underlying fundamental principles of
Chemical Warfare are the same as for all other arms. Because of this,
it is worth while, and even necessary, to understand the applications
of Chemical Warfare, for us to go back and study the work of the
masters in war from the dawn of history down to the present. When we
do that we find that the underlying fundamental principles of war
remain unchanged. They are the same today as they were in the time of
Demosthenes, and as they will be 10,000 years from now. It is an axiom
that the basis of success in war is the ability to have at the decisive
point at the decisive moment a more effective force than that of the
enemy. This involves men and materials. It involves courage, fighting
ability, and the discrimination and energy of the opposing commanders.

[Footnote 43: This material is adapted from a lecture by Gen. Fries
before the students of the General Staff College, in Washington, May
11, 1921.]

Another fundamental is that no success is achieved without positive
action; passive resistance never wins. These are really unchanging
fundamentals. We may also say that the vigor of attack, the speed of
movement of men and supplies, and the thorough training of men in the
use of the weapons of war are unchanging requirements, but outside of
these everything is subject to the universal law of change.

=Grecian Phalanx and Roman Legion.= The last word in the development
of human strength as a battle weapon was illustrated by the Grecian
phalanx with its sixteen rows of men, the spears of each row being so
adjusted that all reached to the front line. That phalanx could not
be stopped by any other human formation that met it face to face. To
overcome it required a Roman legion that could open up and take the
phalanx in the flank and rear. In the same way, the elephants of the
Africans and the chariots of the Romans with their great swords swept
all in front of them, until the Roman Legion, opening up into smaller
groups allowed the elephants and chariots to pass through only to close
in on them from the rear. Then and then only did those engines of war
disappear forever.

=Frederick the Great.= Frederick the Great, realizing that rapidity of
fire would win on the fields of battle where he fought, trained his
men to a precision of movement in close order probably never achieved
by any other troops in the world and then added to their efficiency by
teaching them to load and fire muskets at double the rate of that of
his adversaries. He was thus enabled to concentrate at the decisive
points a preponderance of power, which swept all his enemies before him.

=Napoleon.= Napoleon achieved the same decisive power in a different
way. Realizing that his French troops could not stand the rigorous
training that the Prussians underwent, he trained them to fight with
great enthusiasm, to travel long distances with unheard of swiftness,
and to strike the enemy where least expected. He added to that a
concentration of artillery until then not thought of as possible on the
field of battle. He, of course, had also a genius for organizing and
keeping up his supply.

=Grant and Jackson.= Grant at Vicksburg and Stonewall Jackson in
the Shenandoah Valley and at Chancellorsville, achieved the same
results in different ways. In every case the fundamental principle of
concentrating the greatest force at the decisive point at the vital
moment in the battle remained the same. The methods for achieving that
end change with every age, and every commander of world-wide renown
developed something new or used an old method in a new way. And that
is the fundamental requirement for a successful general. Hannibal,
Hasdrubal, Cæsar, Napoleon, Frederick the Great, Scott, Grant, and
Jackson were all independent thinkers. Each and every one dared to
do something that every other general and statesman of his time told
him could not be done or that would bring about disaster. They had
the courage of their convictions. They had the courage to think out
new ideas and to develop them, and then they had the courage to carry
through those convictions, not alone against the opposition of the
enemy, but against the opposition of their own people, both in the
field and at home. And we may be perfectly sure that in each case had
these men not done the things they did, they would have gone down to
oblivion just as has been the case with millions of others who tried
the usual methods in the usual way.

=Chemical Warfare Latest Development.= Chemical Warfare is the latest
development of war. So far as the United States is concerned, it is
considerably less than four years old. It is the most scientific of all
methods of fighting and also the most universally applicable to all
other methods of making war. The use of poisonous and irritating gases
in war is just as fundamental as the introduction of gunpowder. In
fact, they have an even wider application to war than powder itself.

=Necessity for New Methods.= The idea that has been expressed above
is that the General Staff and the Army commander who sticks to old
and tried methods and who is unwilling to try with all his might new
developments, will never achieve any first class success. The General
Staffs and the generals of the future that win wars will be the ones
who make the most vigorous and efficient use of Chemical Warfare
materials. They cannot confine this use to the artillery, to Aviation,
to Special Gas Troops, or to any other single branch of the war
machine. They must make use of it in every way.

=What Is Meant by Gas.= It must be understood that by gases we refer
to materials that injure by being carried to the victim in the air.
The word “gas” has nothing whatever to do with the condition of the
material when in the shell, or the bombs, or the cylinders before
released. In every case, the gases are liquids or solids. When the
containers are broken open the liquids are volatilized either by the
gas pressure or by the force of the explosion of the bomb.

=Groups of Gases.= Chemical Warfare gases are divided into three great
groups. So far as their actual tactical use on the field of battle is
concerned, there are only two groups—persistent and non-persistent. The
third is the irritant group. This group affects the eyes and the lungs
so as to make the victim very uncomfortable if not completely incapable
of action in quantities so small as to cause no injury that lasts more
than a few hours. The quantities of such gases needed to force the
wearing of the mask is ¹/₁₀₀₀ that needed to cause the same discomfort
by the really poisonous gases, such as phosgene. They, therefore, have
a very great economic value in harassing the enemy by forcing him to
wear masks and to take other precautions against gas. And no matter how
perfect gas masks and gas-proof clothing become, their long-continued
use will cut down physical vigor in an ever increasing ratio until in
two or three days an army may be totally incapacitated.

=Smoke.= In Chemical Warfare materials we have another great group
which will probably be equal in the future to the three groups just
mentioned. That is common smoke. Smoke has a variety of uses. By
the simple term “smoke” is meant smokes that are not poisonous or
irritating. Such smokes offer a perfect screen against enemy vision,
whether it is the man who sights the machine gun, the observer in the
lookout station, the cannoneer or even the aeroplane observer. Every
shot through impenetrable smoke is a shot in the dark and has a tenth
or even less chance of hitting its mark. Smoke affords a means of
decreasing the accuracy of firing, much the same as night decreases it,
without the inherent difficulties of night action.

=Peace Strategy.= The strategy of successful war involves the strategy
of peace. This has been true from the days when David with his
sling-shot slew Goliath, down to the present moment. We don’t always
think of it in connection with war, but back of every successful
war has been preparation during peace. It may have been incidental
preparation such as the training of men in fighting Indians, and in
creating public sentiment favorable to an independent nation that
preceded the Revolutionary War. It may, on the other hand, have been a
deeply studied policy such as that of the Germans prior to the World
War. They tried and generally quite successfully, to coördinate all
peace activities toward the day when a war should come that would
decide the future destiny of the German Empire, and it was only because
of that study in peace that Germany almost single-handed was able to
stand out for more than four years against the world. The Allies came
near losing that war because they did not appreciate that the strategy
of efficient war had to be preceded by the strategy of peace.

=Chemical Warfare an Example.= Chemical warfare is a particularly good
example of this fact. Prior to the World War we had acknowledged, and
without any misgivings, that Germany led the world in chemistry, that
it produced most of the dyes in the world, and to a large extent the
medicines of the world. We felt that when American needs showed it to
be advisable we could take up chemistry and chemical production and
soon excel the Germans. We had not reckoned on the suddenness of war.

We were just getting ready with chemicals, and that included powders
and high explosives, when the war closed. And yet we had had not only
eighteen months’ intensive preparation after our own entry into the
World War, but also the preparation of great steel institutions and
powder factories for nearly three years in manufacturing supplies for
the Allies who preceded us in the war.

=Coal Tar.= The World War opened the eyes of England, France and Japan
as well as the United States. Each of them today is struggling to build
up a great chemical industry as the very foundation of successful war.
Few of us realized prior to the World War that in the black, sticky
mess called coal tar from the coking of coal or the manufacture of gas
from coal and oil, was stored up most of the high explosives used in
war, the majority of the poison gases, a great deal of the medicines of
the world, and nearly all the dyes of the world. The Germans realized
it and in their control over methods of using this material, together
with the great commercial plants developed to manufacture it, as well
as with the trained personnel that must go with such plants, were
enabled, when blockaded on land and sea, to furnish the munitions, the
clothing and the food needed for four and one-half years of war.

=Great Chemical Industries.= Thus it is that our Government today is
giving most serious heed to the need of building up a great chemical
industry in the United States. We have the raw materials. We need
only the factories and the trained men that go with them. We need, of
course, in addition to the development of the coal tar industry, a
production of heavy chemicals such as chlorine, sulfuric acid and the
like, all of which, however, are bound together by community interest
in peace as well as in war.

=Reserves of Chemists.= A part of the strategy of peace is the
card-indexing of the manpower of a nation divided into special groups.
In one great group must come those who have a knowledge of chemistry
and the chemical industries. That must be so worked out that if war
should come on a moment’s notice, within twenty-four hours thereafter
every chemist could be given his job, jobs extending from the firing
line to the research laboratory. And that is the task of the Chemical
Warfare Service. And right here it is well to know that Congress, among
the other features of its Army Reorganization Act of June 4, 1920,
provided for a separate Chemical Warfare Service with these powers:


CHEMICAL WARFARE POWERS

    The Chief of the Chemical Warfare Service under the
    authority of the Secretary of War shall be charged
    with the investigation, development, manufacture,
    or procurement and supply to the Army of all smoke
    and incendiary materials, all toxic gases, and all
    gas defense appliances; the research, design, and
    experimentation connected with chemical warfare and its
    material; and chemical projectile filling plants and
    proving grounds; the supervision of the training of the
    Army in chemical warfare, both offensive and defensive,
    including the necessary schools of instruction; the
    organization, equipment, training, and operation of
    special gas troops, and such other duties as the
    President may from time to time prescribe.

=Why Power Is Needed.= These rather broad powers indicate that Congress
realized the unity of effort that must be made from the research
laboratory to the firing line if America was to keep pace with Germany
or any other nation in chemical warfare. Some have raised the question
as to whether a service should be both supply and combat. Perhaps the
best answer to that question is that so organized Chemical Warfare
was a success in the World War. It was a success notwithstanding it
had to be developed in the field six months after our entry into
the war and with no precedents, no materials, no literature and no
personnel. Through its officers on the staffs of commanding generals
of armies, corps and divisions, and through its fighting gas troops in
the front line, it was enabled to direct its research, development and
manufacture more quickly along lines shown to be necessary by every
change in battle conditions, than any other service.

=Chemical Warfare Troops.= And why should there not be fighting
Chemical Warfare troops? They fight under exactly the same orders as
all other troops. They conform to the same general plan of battle. They
bring, however, to that battle experts in a line that it takes a long
time to master. And where has there been any live commander in the
world’s history who refused aid from any class of troops that might
help him win?

=Specialists in War.= The wars of the future will become more and more
wars of the specialists. Your Infantry may remain the backbone of the
fighting force, but if it has not the Artillery, the Aviation, the
Chemical Warfare, the Engineers, the tanks and other specialists to
back it up, it will be overcome by the army which has such specialists.
Indeed the specialist goes into the very organization of the Infantry
itself with its machine gun battalions, its tank battalions, and as now
proposed, the Infantry light howitzer companies.

=Duties of Chemical Warfare Staff Officers.= The Chemical Warfare
officers on the staff of armies, corps and divisions are there for
the purpose of giving expert advice as to the quantities of chemical
materials available, the best conditions for using them, and the best
way of avoiding the effects of enemy gas upon our own troops. The
conditions that must be kept in mind are so many that no other officer
can be expected to master and keep them if he does his own work well.
The general staff officers and commanding generals will not have the
time to even try to remember the actual effects of clouds, wind, rain,
trees, valleys, villages and plains upon each and every gas. They must
depend upon the Chemical Warfare officer for accurate information
along those lines, and if he cannot furnish it they will have to
secure some one who can. The history of war is filled with the names
of generals who failed because they could not forget how to command a
company. These Chemical Warfare officers will also furnish all data
as to supply of chemical warfare materials, and will furnish the best
information along lines of training, whether for defensive or offensive
use of gas.

=Gas Used by all Arms.= As before stated, we cannot confine the use
of gas to any one arm. We may then ask why, if it is applicable to
all arms, it should need special gas troops. Special gas troops are
for the purpose of putting off great quantities of chemical warfare
materials by special methods that are not applicable to any other
branch now organized or that any other branch has the time to master.
Long-range firing of gas by the artillery can be done just as well by
the artillery as by gas troops. Why? Because in the mechanics of firing
chemical ammunition there is no difference whatever from the mechanics
of firing high explosives or shrapnel. The same will be true of gas
rifle grenades and smoke candles in use by the Infantry. The same will
be true of the dropping of gas bombs and the sprinkling of gas by the
aeroplanes. In this connection just remember that all of the army is
trained in first aid, but in addition we have our ambulance companies,
our hospitals, and our trained medical personnel.

=Arguments Against Use of Gas.= It has been many times suggested
since the Armistice that the use of poisonous gas in war may be done
away with by agreement among nations. The arguments against the use
of gas are that it is inhumane and that it might be used against
non-combatants, especially women and children. The inhumanity of it is
absolutely disproven by the results of its use in the World War. The
death rate from gas alone was less than one-twelfth that from bullets,
high explosives and other methods of warfare. The disability rate for
gas patients discharged was only about one-fourth that for the wounded
discharged for other causes. The permanently injured is likewise
apparently very much less than from other causes.

=Humanity.= No reliable statistics that we can get show that gas in
any way causes tuberculosis any more than a severe attack of bronchitis
or pneumonia causes tuberculosis. Since its principal effects are
upon the lungs and, therefore, hidden from sight, every impostor is
beginning to claim gassing as the reason for his wanting War Risk
benefits from the Government. We do not claim there may not be some
who are suffering permanent injuries from gas, and we are trying very
hard to find out from the manufacturers of poisonous gases and allied
chemicals if they have any authentic records of such cases. So far the
results indicate that permanent after-effects are very rare.

As to non-combatants, certainly we do not contemplate using poisonous
gas against them, no more at least than we propose to use high
explosives in long-range guns or aeroplanes against them. The use of
the one against non-combatants is just as damnable as the other and it
is just as easy to refrain from using one as the other.

=Gas Cannot be Abolished.= As to the abandonment of poison gas, it must
be remembered that no powerful weapon of war has ever been abandoned
once it proved its power unless a more powerful weapon was discovered.
Poisonous gas in the World War proved to be one of the most powerful of
all weapons of war. For that reason alone it will never be abandoned.
It cannot be stopped by agreement, because if you can stop the use
of any one powerful weapon of war by agreement you can stop all war
by agreement. To prepare to use it only in case it is used against
you is on the same plane as an order that was once upon a time issued
to troops in the Philippine Islands. That order stated in substance
that no officer or soldier should shoot a savage Moro, even were he
approaching the said officer or soldier with drawn kriss (sword),
unless actually first struck by such savage. Every officer preferred,
if necessary, to face a court-martial for disobedience of such an order
rather than allow a savage Moro with a drawn kriss to get anywhere
_near_, let alone wait until actually struck.

Let the world know that we propose to use gas against all troops that
may be engaged against us, and that we propose to use it to the fullest
extent of our ability. We believe that such a proposition will do more
to head off war than all the peace propaganda since time began. It has
been said that we should not use gas against those not equipped with
gas. Then why did we use repeating rifles and machine guns against
Negritos and Moros armed only with bows and arrows or poor muskets and
knives. Let us apply the same common sense to the use of gas that we
apply to all other weapons of war.

=Effect on World War Tactics.= A very brief study of the effects of
chemical warfare materials on the strategy of the World War will
indicate its future. It began with clouds of chlorine let loose from
heavy cylinders buried under the firing trench. These took a long time
to install and then a wait, sometimes long, sometimes brief, for a
favorable wind, but even at that these cloud gas attacks created a new
method of fighting and forced new methods of protection. Gas at once
added a tremendous burden to supply in the field, to manufacture, and
to transportation, and in a short time even made some decided changes
in the tactics of the battle field itself.

=Cloud Gas.= The fact that the gas cloud looked like smoke is
responsible for the name “cloud gas.” Really all gases are nearly or
wholly invisible, but those which volatilize suddenly from the liquid
state so cool the air as to cause clouds of condensed water vapor.
The cloud obscured everything behind and in front of it. It led the
German to put off fake smoke clouds and attack through them, thus
taking the British at a tremendous disadvantage. Then and there began a
realization of the value of smoke. Cloud gas was also the real cause of
the highly organized raid that became common in every army during the
World War. The real purpose in the first raids, carried out by means
of the box barrage, was to find out whether or not gas cylinders were
being installed in trenches.

These raids finally became responsible, in a large measure, for driving
the old cloud gas off the field of battle. It did not, however, stop
the British from putting off cloud gas attacks in 1918 by installing
their gas cylinders on their light railway cars and then letting the
gas loose from the cylinders while still on the cars. This enabled them
to move their materials to the front and put off gas attacks on a few
hours’ notice when the wind was right.

=Toxic Smoke Candles.= To-day we have poisonous smokes that exist
in solid form and that are perfectly safe to handle until a fuse is
lighted. The so-called candles will be light enough so that one man can
carry them. With these, cloud gas can be put off on an hour’s notice
when wind and weather conditions are right, no matter how fast the army
may be moving and whether on the advance or in retreat. Cloud gas will
usually be put off at night because the cloud cannot be seen, because
then men are tired and sleepy, and all but the most highly trained
become panicky. Under those conditions the greatest casualties result.
The steadiness of wind currents also aids cloud gas attacks at night.

=Value of Training in Peace.= And this brings up the value of training
in peace. We are frequently asked, “Why do you need training with masks
in peace; why do you need training with actual gas in peace; cannot
these things be taught on short notice in war?” The answer is, “No!”
Nothing will take the place of training in peace.

All of us recall that early in the war the Germans spread broadcast
charges that the Allies were using unfair and inhumane methods of
fighting because they brought the Ghurka with his terrible knife from
Asia and the Moroccan from Africa. And we all know that after a time
the Germans ceased saying anything about these troops. What was the
cause? They were not efficient. Just as the Negro will follow a white
officer over the top in daylight and fight with as much energy and
courage and many times as much efficiency as the white man, he cannot
stand the terrors of the night, and the same was true of the Ghurka and
the Moroccan.

All the Allies soon recognized that fact as shown by their drawing
those troops almost entirely away from the fighting lines. In some
cases dark-skinned troops were kept only as shock troops to be replaced
by the more highly developed Caucasian when the line had to be held for
days under the deadly fire of the counter attack. The German idea, and
our own idea prior to the World War, was that semi-savages could stand
the rigors and terrors of war better than the highly sensitive white
man. War proved that to be utterly false.

=Familiarity with Gas Necessary.= The same training that makes for
advancement in science, and success in manufacture in peace, gives the
control of the body that holds the white man to the firing line no
matter what its terrors. A great deal of this comes because the white
man has had trained out of him nearly all superstition. He has had
drilled into him for hundreds of years that powder and high explosive
can do certain things and no more. If the soldier is not to be afraid
of gas we must give him an equal knowledge of it, its dangers, and its
limitations. The old adage says, “Familiarity breeds contempt.” Perhaps
that is not quite true, but we all know that it breeds callousness
and forgetfulness; that the man manufacturing dynamite or other more
dangerous explosives takes chances that we who do not engage in such
manufacture shudder at.

=Edgewood Chemists Not Afraid.= All of this has direct application
to training with chemical warfare materials in peace. _We believe
that all opposition to chemical warfare today can be divided into
two classes—those who do not understand it and those who are afraid
of it—ignorance and cowardice._ Our chemists at Edgewood Arsenal are
every day toying with the most powerful chemical compounds; toying with
mixtures they know nothing of, not knowing what instant they may induce
an explosion of some fearful poisonous gas. But they have learned how
to protect themselves. They have learned that if they stop breathing
and get out of that place and on the windward side they are safe. They
have been at that work long enough to do that automatically.

=Staff Officers Must Think of Gas in Every Problem.= The staff officer
must train the army man in peace with all chemical warfare materials
or he will lose his head in war and become a casualty. The general
staff officers and commanding generals must so familiarize themselves
with these gases and their general use that they will think them in
all their problems just exactly as they think of the Infantry, or of
the Cavalry, or of the tanks or of the Artillery in every problem. On
them rests the responsibility that these gases are used properly in
battle. If plans before the battle do not include these materials for
every arm and in the proper quantities of the proper kinds they will
not be used properly on the field of battle and on them will rest the
responsibility.

They are not expected to know all the details of gases and their uses,
but they will be expected to consider the use of gas in every phase of
preparing plans and orders and then to appeal to the chemical warfare
officers for the details that will enable them to use the proper gases
and the proper quantities. They cannot go into those details any more
than they can go into the details of each company of infantry. If they
try to do that they are a failure as staff officers.

=Effect of Masks on Troops.= The very best of masks cause a little
decrease in vision, a little increase in breathing resistance, and a
little added discomfort in warm weather, and hence the soldier must
learn to use them under all conditions. But above all in the future
he must be so accustomed to the use of the mask that he will put it
on automatically—almost in his sleep as it were. We have tear gases,
today, so powerful and so sudden in their action that it is doubtful if
one man out of five who has had only a little training can get his mask
on if subject to the tear gas alone—that is, with tear gas striking him
with full force before he is aware of it.

=Effectiveness of Gas in World War.= In the past war more than 27 out
of every 100 Americans killed and wounded suffered from gas alone. You
may say that many of the wounds were light. That is true; but those men
were put out of the battle line for from one to four months—divisions,
corps and armies almost broken up—and yet the use of gas in that war
was a child’s game compared to what it will be in the future.

It is even said that many of them were malingerers. Perhaps they were,
but do you not suppose that there were at least as many malingerers
among the enemy as there were in our own ranks? Furthermore, if you can
induce malingering it is a proper method of waging war, and unless our
boasted ability is all a myth we should have fewer malingerers under
conditions of battle than any other nation.

=Strategy of Gas at Picardy Plains.= Let us go back now to the strategy
of gas in war. Following the cloud gas came tear gases and poisonous
gases in shells and bombs. A little advance in tactics here and a
little there, the idea, though, in the early days being only to produce
casualties. As usual the Germans awoke first to the fact that gas
might be used strategically and on a large scale. And thus we find that
ten days before he began the battle of Picardy Plains he deluged many
sections of the front with mustard gas. He secured casualties by the
thousands, but he secured something of greater importance. He wore out
the physical vigor and lowered the morale of division after division,
thus paving the way for the break in the British Army which almost let
him through to the sea.

He used non-persistent gases up to the very moment when his own men
reached the British lines, thereby reducing the efficiency of British
rifle and artillery fire and saving his own men. And this is just a
guide to the future. A recent writer in the _Field Artillery Journal_
states that gas will probably not be used in the barrage because of its
probable interference with the movement of our own troops. In making
that statement he forgot the enemy and you cannot do that if you expect
to win a war.

=Gas in Barrages.= In the future we must expect the enemy to be in a
measure as well prepared in chemical warfare as we are. Let us consider
the special case of our own men advancing to the attack behind a
rolling barrage. We will consider also that the wind is blowing toward
our own troops. Obviously under those conditions the wind will blow
our own gas back onto our troops. Will we use gas in that barrage? We
certainly will! Because with the wind blowing toward our own troops
we have the exact ideal condition that the enemy wants for his use of
gas. He will then be deluging our advancing troops with all the gas he
can fire, in addition to high explosives and shrapnel. Our men must
wear masks and take every precaution against enemy gas. How foolish
it would be not to fire gas at the enemy under those conditions. If
we did not fire gas we would leave him entirely free from wearing
masks, and entirely free from taking every other precaution against
gas while our own troops were subject to all the difficulties of gas.
No, we will fire gas at him in just as great quantities as we consider
efficient. And that is just a sample of what is coming on every field
of battle—gas used on both sides by every method of putting it over
that can be devised.

=World War Lessons Only Guide Posts. Example of Book Worms.= Every
lesson taught by the World War must be taken as a guide-post on the
road to future success in war. No use of gas or other materials in the
past war must be taken as an exact pattern for use in any battle of
the future. Too much study, too much attention to the past, may cause
that very thing to happen. A certain general commanding a brigade in
the Argonne told me just recently that while the battle was going on a
general staff officer called him on the telephone and asked him what
the situation was. He gave it to him. The staff officer then asked,
“What are you doing?” and he told him. The staff officer replied, “Why,
the book doesn’t say to do it that way under such conditions.” There
you have the absurd side of too much study and too close reliance on
details of the past.

The battle field is a perfect kaleidoscope. The best we can hope to get
out of books is a guide—something that we will keep in our minds to
help us decide the best way to meet certain situations. He who tries
to remember a particular position taught in his school with the idea
of applying that to actual use in battle is laying the foundation for
absolute failure. Your expert rifleman never thinks back when he goes
to fire a shot as to just what his instructor told him or what the book
said. He just concentrates his mind on the object to be attained, using
so far as comes to him facts he has learned from books or teachers.
Your general and your staff must do the same.

=Infantry Use of Gas.= A few words about how we will use gas in the
future. We will start with the Infantry. The Infantry as such will
use gas in only two or three ways. They will use some gas in rifle
grenades, and a great deal more smoke. We speak of the rifle grenade
because in our opinion the hand grenade is a thing of the past. We do
not believe there will ever be used in the future any grenade that is
not applicable to the rifle. The Infantry will probably often carry
large quantities of gas in the shape of the toxic smoke candle. These
materials being solids may be shot up by rifles or artillery fire, run
over by trucks or tractors, or trampled and still be harmless. It is
only when the fuses are lighted and the material driven off by heat
that they are dangerous. In using these candles under these conditions
you must have sufficient chemical warfare officers and soldiers to get
the necessary control indicated by the sun, wind, woods, fogs, ravines
and the like.

=Cavalry Use of Gas.= Next consider the Cavalry. The Cavalry will use
gas practically the same as the Infantry. The chemical warfare troops
will accompany the Cavalry with Stokes’ mortars or other materials
to fire gases into small enemy strongholds that may be encountered
whether machine gun nests, mountain tops, woods or villages. They will
do this either against savages or civilized people. Methods of making
these materials mobile for that purpose are already well under way. If
against savages and one does not want to kill them, use tear gases—no
better method of searching out hidden snipers in mountain tops, among
rocks, or villages, in ravines, or in forests was ever invented.

=Use of Gas by Tanks.= The tanks will employ gas in the same way as
the Infantry with the possibility, however, that they may be used to
carry large quantities of gas on caterpillar tractors where otherwise
it would be difficult to move the gas. This is not a certainty, but is
a situation promising enough to warrant further study.

=Artillery Use of Gas.= Your Artillery will fire gas and smoke in every
caliber of gun. There is a tendency now to limit gas to certain guns
and howitzers and to limit smoke to even a smaller number of guns. This
is a mistake that we are going to recognize. A very careful study of
the records of the war show that more casualties were produced several
times over by a thousand gas shells than by a thousand high explosive
or shrapnel. And that is because gas has an inherent permanence that no
other weapon of war has.

=Permanency of Gas.= The bullet whistles through the air and does its
work or misses. The high explosive shell bursts, hurling its fragments
that in a few seconds settle to earth, and its work is done. The
shrapnel acts in the same way, but when one turns loose a shell of gas
it will kill and injure the same as the high explosive shell and in the
same length of time and in addition for some minutes thereafter. Even
with the non-persistent gases, it will continue on its way, causing
death or injury to every unprotected animal, man or beast in its path.
With the persistent gases, the materials from each shell may persist
for days.

=Variety of Uses of Gas.= This brings up the point of the great variety
of uses to which gas can be put. The non-persistent gas may be used
at all times where one wants to get rid of it in a few moments—the
persistent gas wherever one wants to keep the enemy under gas for days
at a time. We will use mustard gas on strong points in the advance,
on flanks, on distant areas one will not expect to be reached, and as
our own protection of masks and clothing increases toward perfection
we will use it on the very fields you expect to cross. Why? Because we
will be firing it at the enemy for days before hand and we will cause
him trouble all those days while we ourselves will encounter it for a
few hours at the most. So do not think that mustard gas is only going
to be used in defense in the future.

=Solid Mustard Gas and Long-Range Guns.= We will come to use chemical
warfare materials just as high explosives and bullets are used today,
even though at times we do suffer an occasional loss from our own
weapons. Our Artillery in long-range guns where we want destruction
will fill each shell with say 15 per cent gas and 85 per cent high
explosive. We have a solid mustard gas that may be so used. We have
tremendously powerful tear gases and irritating gases that may be so
used. Being solids they do not affect the ballistic qualities of the
shell. And what an added danger will mustard gas from every shell bring
against railroad centers, rest villages, cantonments, cross-roads and
the like. The results will be too great for any force to overlook such
use.

=Tear Gases in Shrapnel.= We will probably use tear gas in most, if
not all, of our shrapnel. The general idea now is that we should not
put tear gas in all shrapnel because under certain conditions it will
be blown back and harass our own troops. But as was said before, we
must remember that the enemy will be using gas at all times as well
as ourselves, and hence if we limit ourselves in any line we give the
enemy an advantage. This use of gas by the Artillery will extend to all
classes of guns—seacoast, field, turret and what not.

=Use of Gas by Air Service.= _Bombs._ Let us next consider the Air
Service. We naturally think of dropping gas in bombs when we speak of
the use of gas by the Air Service. Gas will so be used and it will be
used in bombs of perhaps a thousand pounds or even a ton in weight,
at least 50 per cent of which will be gas. Such gases, however, will
be of the non-persistent type—phosgene or similar ones. They will be
used against concentration camps and cross-roads, on troops on the road
in columns; against railroad centers and rest areas; in other words,
against groups of men or animals.

_Sprinkling._ But that is not even the beginning of the use of gas by
aeroplanes. Mustard gas, which is one-third again as heavy as water,
and which volatilizes far slower than water, may be sprinkled through
a small opening such as a bung hole in a tank that simply lets liquid
float out. The speed of the aeroplane will atomize it. In this way,
gas can be sprinkled over whole areas that must be crossed in battle.
The Lewisite, of which we have heard considerable, will be used. It is
less persistent than the mustard gas, but like mustard gas it produces
casualties by burning. Unlike mustard gas, however, the burns from a
quantity equal to three drops will usually cause death. The material
can be made up by hundreds, even thousands, of tons per month.

We are working on clothing that will keep it out just as we have been
and are working on clothing that will protect against mustard gas.
But these gases are so powerful that if any opening be left in the
clothing the gas will get through, so that even if we get clothing that
will protect, it must cover every inch of the skin from head to foot.
Besides the mask must be worn at all times.

Consider the burden put on any army in the field that would have
to continually wear such complete protection. What a strain on the
mentality of the men! As before said, to endure it at all we must train
our men to think of such conditions, to face them in peace, and in
order to do so we must actually use gas. Just as in the World War the
highly trained Caucasian outdistanced the savage in endurance, just so
will the most highly trained men in the future outdistance all others
in endurance.

=Navy.= We now come to the consideration of the Navy. The Navy will use
gas both in its guns and in smoke clouds, and in some form of candle
that will float. The toxic smokes that in high enough concentrations
will kill are extraordinarily irritating in minute quantities—so minute
they cannot be seen or felt for a few moments. Every human being on a
ship must breathe every minute just as every human being everywhere
must breathe every minute or die. A gas that gets into the ventilating
system of a ship will go all through it and the Navy realizes it.

The Navy is studying how to keep the gas out of their own ships, and
how to get it into the enemy’s ships. The toxic smokes may be dropped
from aeroplanes or turned loose from under water by submarines. In
either case they will give off smokes over wide areas through which
ships must pass. Any defects will let these toxic smokes in and will
force every man to wear a mask. Aeroplane bombs will come raining
down on the ship or alongside of it either with toxic smokes or other
terrible gases. White phosphorus that burns and cannot be put out wet
or dry will be rained on ships. Yes, chemical warfare materials will be
used by the Navy.

=Gas Against Landing Parties.= The use of gas against landing parties
or to aid landing parties has come up in many ways. Our studies to date
indicate that gas is a greater advantage to the defense against landing
parties than to the offense. Mustard gas and the like may be sprinkled
from aeroplanes, and while it will not float long on the water, it
will float long enough to smear any small boats attempting to land. It
can be sprinkled over all the areas that landing parties must occupy.
Mustard gas may be placed in bombs or drums around all areas that are
apt to be used as landing places and exploded in the face of advancing
troops.

=Storing Reserve Gases in Peace.= And a word here about how long gases
may be stored. One of the statements made by opponents of chemical
warfare was that gas is a purely war time project and could not be
stored up in peace. We have today at Edgewood Arsenal some 1,400 tons
of poisonous gases not including chlorine. Those gases have been
manufactured, practically every ounce of them, for three years, and
are yet in almost perfect condition. Our chemists believe they can be
kept in the future for ten years and perhaps longer. Our gas shells
then will have the life almost of a modern battleship, while the cost
of a million will be but a fraction of the cost of a battleship. What I
have just said applies particularly to liquid gases such as phosgene,
chlorpicrin, and mustard gas. We know that many of the solids may be
kept for far longer periods.

=Storing Gas Masks.= Our masks, too, we believe can be kept for at
least ten years. Experience to date indicates that rubber deteriorates
mainly through the action of sunlight and moisture that cause oxidation
or other change in the crystalline structure of cured rubber.
Accordingly, we are putting up masks today in hermetically sealed
boxes. It is thus evident that we can store a reserve of masks and
gases in peace the same as other war materials.

=Use of Gas by Gas Troops.= Now we come to the use of gas by special
gas troops. In the war, Gas Troops used 4-inch Stokes’ mortars and
8-inch Livens’ projectors and in a very short time would have used a
new portable cylinder for setting off cloud gas, using liquid gases,
such as phosgene. They will use these same weapons in future wars.
All of these are short-range weapons, but since the Livens’ bomb or
drum contains 50 per cent of its weight in gas while the artillery
shell contains 10 per cent, they have an efficiency away beyond that
of artillery or any other method of discharging gas except cloud gas.
They will, therefore, produce more casualties than any other method
known for the amount of material taken to the front. These short-range
weapons were developed by the British for trench use and not for open
warfare, and yet our troops developed methods with the Stokes’ mortars
that enabled them to keep up with many of the Infantry divisions.

=Phosphorus and Thermit Against Machine Gun Nests.= The use of
phosphorus and thermit against German machine gun nests by the Gas
Troops is well known. How effective it was is not known to so many.
Phosphorus and thermit were so used from the early days of the Marne
fight in the latter part of July, 1918, to the very close of the war.
There is no recorded instance where the Gas Troops failed to silence
machine gun nests once the machine guns were located. In the future Gas
Troops will put off the majority of all cloud gas attacks even with
toxic smoke candles.

=Necessity for Training in Peace.= This is an outline of the subject
of chemical warfare. As stated in the beginning, the fundamental
underlying principles for the successful use of poisonous gas is
necessarily the same as for any other war materials. The necessity
for continuous training in peace is just the same with chemical
warfare as with the rifle, the machine gun, with field artillery or
any other weapon of war. Indeed it is more so because the use of gas
is so perfectly adaptable to night work. Men must be taught to take
precautionary measures when so sleepy, tired and worn out that they
will sleep through the roar of artillery.

=How Chemical Warfare Should be Considered.= We ask you only to look
at the use of chemical warfare materials as you look at the use of
the artillery, infantry, cavalry, tanks or aeroplanes. Measure its
possible future use; not simply by its use in the World War, but by
considering all possible developments of the future. Remember that its
use was barely four years old when the war closed, while the machine
gun, the latest type of infantry weapon, had been known for more than
one-third of a century. Chemical warfare developments are in the infant
stage. Even those on the inside of chemical warfare when the Armistice
was signed can see today things that are certain to come that were
undreamed of at that time. This is bound to be so with a new weapon.

To sum up, gas is a universal weapon, applicable to every arm and every
sort of action. Since we can choose gases that are either liquid or
solid, that are irritating only or highly poisonous, that are visible
or invisible, that persist for days or that pass with the wind, we have
a weapon applicable to every act of war and for that matter, to every
act of peace. But we must _plan_ its use, remembering there is no
middle ground in war, it is success or failure, life or death. Remember
also that training outruns production in a great war, that 5,000,000
men can be raised and trained before they can be equipped unless we
with proper foresight build up our essential industries, keep up our
reserve of supplies, and above all, keep such perfect plans that we
can turn all the wheels of peace into the wings of war on a moment’s
notice.




CHAPTER XXIII

THE OFFENSIVE USE OF GAS


WHAT CHEMICAL WARFARE INCLUDES

Chemical Warfare includes all gas, smoke and incendiary materials and
all defensive appliances, of which the mask is the principal item, used
by the Army. Some of the items or materials in both offense and defense
are used by the entire Army, while a few are used only by Chemical
Warfare troops.


THE TERM “GAS”

The term “gas” is now taken to include all materials that are carried
to the enemy by the air, after their liberation from cylinders, bombs
or shell. It is necessary that this broad use of the term “gas” be
thoroughly understood, because some of these materials are solids,
while all others are liquids, until liberated from the containers at
the time of the attack. These containers may be special cylinders for
cloud gas attacks, special bombs for Livens’ projectors and mortars,
or artillery shell, and even aviation bombs. Some of the liquids which
have a very low boiling point volatilize quickly upon exposure to air,
and hence require only enough explosive to open the shell and allow the
liquid to escape. Practically all solids have to be pulverized by a
large amount of high explosive, or driven off as smoke by some heating
mixture.


TECHNICAL NATURE

Chemical warfare, besides being the newest, is the most technical and
most highly specialized Service under the War Department. There is
no class of people in civil life, and no officers or men in the War
Department, who can take up chemical warfare successfully until they
have received training in its use. This applies not only to the use of
materials in attack, but to the use of materials for defense. Ten years
from now perhaps this will not be true. It is certainly hoped that it
will not be. By that time the entire Army should be pretty thoroughly
trained in the general principles and many of the special features
of chemical warfare. If not, chemical warfare cannot be used in the
field with the efficiency and success with which it deserves to be
used. Furthermore, it is believed that within ten years the knowledge
of the gases used in chemical warfare will be so common through the
development of the use of these same materials in civil life, that it
will not be so difficult, as at the present date, to get civilians who
are acquainted with Chemical Warfare Service materials.


EFFECTIVENESS OF GAS

Chemical warfare materials were used during the war by Chemical Warfare
Service troops, by the Artillery and by the Infantry. In the future
the Air Service and Navy will be added to the above list. Chemical
warfare, even under the inelastic methods of the Germans, proved one
of the most powerful means of offense with which the American troops
had to contend. To realize its effectiveness we need only remember
that more than 27 out of every 100 casualties on the field of battle
were from gas alone. Unquestionably many of those who died on the
battlefield from other causes suffered also from gas. No other single
element of war, unless you call powder a basic element, accounted for
so many casualties among the American troops. Indeed, it is believed
that a greater number of casualties was not inflicted by any other arm
of the Service, unless possibly the Infantry, and even in that case it
would be necessary to account for all injured by bullets, the bayonet,
machine guns and hand grenades. This is true, in spite of the fact
that the German was so nearly completely out of gas when the Americans
began their offensive at St. Mihiel and the Argonne, that practically
no gas casualties occurred during the St. Mihiel offensive, and only a
very few until after a week of the Argonne fighting. Furthermore, the
Germans knew that an extensive use of mustard gas against the American
lines on the day the attack was made, and also on the line that marked
the end of the first advance a few days later, would have produced
tremendous casualties. Judging from the results achieved at other times
by an extensive use of mustard gas, it is believed that had the German
possessed this gas and used it as he had used it a few other times,
American casualties in the Argonne would have been doubled. In fact,
the advance might even have been entirely stopped, thus prolonging the
war into the year 1919.


HUMANITY OF GAS

A few words right here about the humanity of gas are not out of
place, notwithstanding the Army and the general public have now so
completely indorsed chemical warfare that it is believed the argument
of inhumanity has no weight whatever. There were three great reasons
why chemical warfare was first widely advertised throughout the world
as inhumane and horrible. These reasons may be summed up as follows:

In the first place, the original gas used at Ypres in 1915 was
chlorine, and chlorine is one of a group of gases known as
suffocants—gases that cause death generally by suffocating the patient
through spasms of the epiglottis and throat. That is the most agonizing
effect produced by any gas.

The second reason was unpreparedness. The English had no masks, no
gas-proof dugouts, nor any of the other paraphernalia that was later
employed to protect against poisonous gas. Consequently, the death rate
in the first gas attack at Ypres was very high, probably 35 per cent.
As a matter of fact, every man who was close to the front line died.
The only ones who escaped were those on the edges of the cloud of gas
or so far to the rear that the concentration had decreased below the
deadly point.

The third great reason was simply propaganda. It was good war
propaganda to impress upon everybody the fact that the German was
capable of using any means that he could develop in order to win a
victory. He had no respect for previous agreements or ideas concerning
warfare. This propaganda kept up the morale and fighting spirit of the
Allies, and was thoroughly justifiable upon that score, even when it
led to wild exaggeration.

The chlorine used in the first attack by the German is the least
poisonous of the gases now used. Those later introduced, such as
phosgene, mustard gas and diphenylchloroarsine are from five to ten
times as effective.

The measure of humanity for any form of warfare is the percentage of
deaths to the total number injured by the particular method of warfare
under consideration.

=American Gas Casualties.= The official list of casualties in battle as
compiled by the Surgeon General’s office covering all cases reported up
to September 1, 1919, is 258,338. Of these 70,752, or 27.4 per cent,
were gas casualties. Also of the above casualties 46,519 resulted in
death, of whom about 1,400 only were due to gas. From these figures it
is readily deduced that while 24.85 per cent of all casualties from
bullets and high explosives resulted in death, only 2 per cent of those
wounded by gas resulted in death. That is, a man wounded on the battle
field with gas had twelve times as many chances of recovery as the man
who was wounded with bullets and high explosives.


FUNDAMENTALS OF CHEMICAL WARFARE

Before taking up in some detail the methods of projecting gas upon the
enemy, it is very desirable to understand the fundamentals of chemical
warfare, in so far as they pertain to poisonous gases. Following the
first use of pure chlorine all the principal nations engaged in the
war began investigations into a wide range of substances in the hope
of finding others more poisonous, more easily produced, and more
readily projected upon the enemy. These investigations led to the use
of a large number of gases which seriously complicated manufacture,
supply, and the actual use of the gases in the field. Gradually a more
rational conception of chemical warfare led both the Allies and the
enemy to restrict the numbers of gases to a comparative few, and still
later to divide all gases into three groups. Thus the German divided
his into three groups known as (1) Green Cross, the highly poisonous
non-persistent gases, (2) Blue Cross, or diphenylchloroarsine,
popularly known as sneezing gas, and (3) Yellow Cross, highly
persistent gases, such as mustard gas. In the American Chemical Warfare
Service we have finally divided all gases into two primary groups.
These groups are known as “Non-persistent” and “Persistent.” The
“Non-persistent” gases are those quickly volatilizing upon exposure
to the air, and hence those that are carried away at once by air
currents, or that in a dead calm will be completely dissipated into
the surrounding air in a few hours. If sufficient high explosive be
used to pulverize solids, they may be used in the same way, and to a
large extent certain highly persistent liquid gases may have their
persistency greatly reduced by using a large amount of high explosive,
which divides the liquid into a fine spray. The “Persistent” group
constitutes those gases that are very slowly volatilized upon exposure
to the atmosphere. The principal ones of these now used or proposed are
mustard gas and bromobenzylcyanide. For purposes of economy, and hence
efficiency, certain gases, both persistent and non-persistent, are
placed in a third group known as the “Irritant Group.” These gases are
effective in extremely low concentrations against the lungs and other
air passages, or the eyes. Diphenylchloroarsine, and some other solids
when divided into minute particles by high explosive or heat, irritate
the nose, throat and lungs to such an extent in a concentration of
one part in ten millions of air as to be unbearable in a few minutes.
The tear gases are equally powerful in their effects on the eyes. The
irritating gases are used to force the wearing of the mask, which in
turn reduces the physical vigor and efficiency of the troops. This
reduction in efficiency, even with the best masks, is probably 25 per
cent for short periods, and much more if prolonged wearing of the mask
is forced.


EFFICIENCY OF IRRITANT GASES

One pound of the irritant gases is equal to 500 to 1,000 pounds of
other gases when forcing the wearing of the mask alone is desired. The
great economy resulting from their use is thus apparent. Due to the
rapid evaporation of the non-persistent gases they are used generally
only in dense clouds, whether those clouds be produced from cylinders
or from bombs. These gases are used only for producing immediate
casualties, as the necessary amount of gas to force the enemy to
constantly wear his mask by the use of non-persistent gases alone could
not possibly be taken to the front.

Mustard gas, which is highly persistent and also attacks the lungs,
eyes and skin of the body, may and will be used to force the wearing
of the mask. It has one disadvantage when it is desired to force
immediately the wearing of the mask, and that is its delayed action
and the fact that it acts so slowly, and is usually encountered in
such slight concentrations that several hours’ exposure are necessary
to produce a severe casualty. For these reasons the enemy may often
take chances in the heat of battle with mustard gas, and while himself
becoming a casualty, inflict quite heavy casualties upon opposing
troops by continuing to operate his guns or rifles without masks. A
powerful tear gas on the other hand forces the immediate wearing of the
mask.


MATERIAL OF CHEMICAL WARFARE USED BY C. W. S. TROOPS

Chemical warfare troops, in making gas attacks, use cylinders for the
cloud or wave attack, and the Livens’ projector and the 4-inch Stokes’
mortar for attacks with heavy concentrations of gas projected by bombs
with ranges up to a mile. This distance will in the future probably
be increased to 1½ or 1¾ miles. The original cylinders used in wave
attacks were heavy, cumbersome and very laborious to install, and
notwithstanding the wave attack was known to be the deadliest form of
gas attack used in the war, fell into disrepute after the use of gas
became general in artillery shells and in special bombs.

=Cloud Gas.= The Americans at once concluded that since cloud gas
attacks were so effective, efforts should be made to make these attacks
of frequent occurrence by decreasing the weight of the cylinders, and
by increasing the portability and methods of discharging the cylinders.
As early as March, 1918, specifications for cylinders weighing not more
than 65 pounds, filled and completely equipped for firing, were cabled
to the United States. They would have been used in large numbers in
the campaign of 1919 had the enemy not quit when he did. Toxic smoke
candles that are filled with solids driven off by heat will probably
be the actual method in the future for putting off cloud attacks. The
toxic smoke candle is perfectly safe under all conditions and can
be made in any size desired. Cloud gas attacks will be common in
the future, and all plans of defense must be made accordingly. They
will usually be made at night, when, due to fatigue and the natural
sleepiness which comes at that time, men are careless, lose their way,
or neglect their masks, and are thus caught unprepared. Experience in
the war proved that a wave attack always produced casualties even, as
several times occurred, when the enemy or the Allied troops knew some
hours beforehand that the attack was coming. The English estimated
these casualties to be 10 or 11 per cent of the troops exposed.

=Livens’ Projectors.= The second most effective weapon for using gas
by gas troops was and will be the Livens’ projector. This projector is
nothing less than the simplest form of mortar, consisting of a straight
drawn steel tube and a steel base plate. As used during the World War
by the Allies it did not even have a firing pin or other mechanism in
the base, the electric wires for firing passing out through the muzzle
and alongside the drum or projectile which was small enough to permit
that method of firing. These were set by the hundreds, very close
behind or even in front of the front line trenches. They were all fired
at the same instant, or as nearly at the same instant as watches could
be synchronized, and firing batteries operated. As discussed on page 18
these mortars were emplaced deep enough in the ground to bring their
muzzles practically level with the surface. It usually took several
days to prepare the attack, and consequently allowed an opportunity
for the enemy to detect the work by aeroplane photographs or by raids,
and destroy the emplacements by artillery fire. It should be added,
however, that notwithstanding this apparent great difficulty, very
few attacks were broken up in that way. Nevertheless, in line with
the general policy of the American troops to get away from anything
that savored of trench warfare, and to make the fighting as nearly
continuous as possible with every means available, the American
Chemical Warfare Service set at work at once to develop an easy method
of making projector attacks.

It was early found, that, if the excavation was made just deep enough
so that the base plate could be set at the proper angle, the drums or
projectiles were fired as accurately as when the projectors or mortars
were set so that the muzzles were level with the surface. The time
required to emplace a given number of mortars in this way was only
about one-fifth of that required for digging them completely in.

Coupled of course with these proposed improvements in methods, studies
were being made and are still being made to produce lighter mortars,
better powder charges, and better gas checks in order to develop the
full force of the powder. Many improvements along this line can be
made, all of which will result in greater mobility, more frequent
attacks, and hence greater efficiency.

=4-Inch Stokes’ Mortar.= The Stokes’ mortar is not different from that
used by the Infantry, except that it is 4-inch, while the Infantry
Stokes’ is 3-inch. The 4-inch was chosen by the British for gas, as
it was the largest caliber that could be fired rapidly and yet be
moderately mobile. Its range of only about 1,100 yards handicapped
it considerably. The poor design of the bomb was partly responsible
for this. The powder charges also were neither well chosen nor well
designed. It is believed that great improvements can be made in the
shape of the bomb and in the powder charge, which will result in much
longer range and high efficiency, while in no way increasing the weight
of the bomb or decreasing the rate of fire. These last two weapons
were used during the World War, and will be very extensively used in
the future for firing high explosive, phosphorus, thermit and similar
materials that non-technical troops might handle.

Since gas has proven without the shadow of a doubt, that it will
produce more casualties for an equal amount of material transported to
the front than any other substance yet devised, all troops using short
range guns or mortars should be trained to fire gas whenever weather
conditions are right. When weather conditions are not right, they
should fire the other substances mentioned. The Livens’ projector with
its 60 pound bomb, of which 30 pounds will be gas or high explosive,
is a wonderful gun up to the limit of its range. The bomb, not being
pointed, does not sink into the ground, and hence upon exploding exerts
the full force of high explosive upon the surroundings, whether bombs,
pill boxes, barbed wire or trenches, to say nothing of personnel.

=High Explosive in Projectors.= When these are burst by the hundreds on
a small area everything movable is blotted out. Thus concrete machine
gun emplacements, lookout stations, bomb-proofs and wire entanglements
are destroyed, trenches filled up, and the personnel annihilated. This
was amply demonstrated on the few occasions when it was actually used
at the front. The American Infantry, wherever they saw it tried out,
were wild to have more of it used. The German was apparently equally
anxious to have the use stopped. It is, however, one of the things
that must be reckoned with in the future. It means practically that No
Man’s Land in the future will be just as wide as the extreme range of
these crude mortars—and here a word of caution. While efforts have been
made to increase the range of these mortars, whether of the Livens’
projector or Stokes’ variety, no further increase will be attempted
when that increase reduces the speed of firing or the efficiency of
the projectile. In other words results depend upon large quantities of
material delivered at the same instant on the point attacked, and if
this cannot be obtained the method is useless. For this reason these
mortars will never be a competitor of the artillery. The artillery will
have all that it can do to cover the field within its range—beyond that
reached by the mortars.

=Phosphorus in 4-Inch Stokes.= Phosphorus will be used largely by gas
troops, but only in the 4-inch or other Stokes’ mortar that may be
finally adopted as best. The Livens’ projector carries too great a
quantity, and being essentially a single shot gun, is not adapted to
keeping up a smoke screen by slow and continued firing, or of being
transported so as to keep up with the Infantry. Phosphorus has also
very great value for attacking personnel itself. Any one who has been
burned with phosphorus or has witnessed the ease with which it burns
when exposed to air, wet or dry, has a most wholesome fear of it. The
result of it in the war showed that the enemy machine gunners or other
troops would not stand up under a bombardment of phosphorus fired from
the 4-inch Stokes’ mortar—each bomb containing about seven pounds.

=Thermit.= Thermit is used in the same way, and while the idea of
molten metal, falling upon men and burning through clothing and even
helmets, is attractive in theory, it proved absolutely worthless for
those purposes on the field of battle. It was found impossible to throw
sufficiently large quantities of molten metal on a given spot to cause
any considerable burn. In other words, the rapid spreading out and
cooling of the metal almost entirely ruined its effectiveness, except
its effect on the morale. This latter, however, was considerable, as
one might judge from seeing the thermit shells burst in air. For this
reason thermit may find a limited use in the future.


THE SPREAD OF GAS

=Height of Gas Cloud.= The height to which gas rises in a gas cloud
is not exactly known, but it is believed to be not much more than
fifty feet, and then only at a considerable distance from the point of
discharge. Moving pictures taken of gas clouds show this to be true. It
is also indicated by the fact that pigeons, which are very susceptible
to poisonous gas, practically always return to their cages safely when
liberated in a gas cloud. This was a good deal of a mystery until it
was realized that the pigeon escaped through his rising so quickly
above the gas. This of course would be expected when it is known that
practically all gases successfully used were two or more times as heavy
as air. Such gases rise only by slow diffusion, or when carried upwards
by rising currents. The absence of these upward currents at night is
one of the reasons why gas attacks are more effective at night than
during the day.

=Horizontal Spread of Gas.= Another important thing to know in regard
to the behavior of the wave of gas is the horizontal spread of a cloud.
If gas be emitted from a cylinder the total spread in both directions
from that point is from 20° to 30° or an average of 25°. This varies,
of course, with the wind. The higher the wind the less the angle,
though the variation due to wind is not as great as might be expected.
This horizontal spread of the gas cloud was measured experimentally,
and the results checked by aeroplane pictures of heavy wave attacks
over the enemy line. In the latter case the path of the gas was very
closely indicated by the dead vegetation. This vegetation was killed
and bleached so that it readily showed up in aeroplane photographs.
The visibility of a gas cloud arises from the fact that when a large
amount of liquid is suddenly evaporated, the air is cooled and moisture
condensed, thereby creating a fog. With gases such as mustard gas
and others of slight volatility, a visible cloud is not formed. For
purposes of identification of points struck by shell, smoke substances
are occasionally added, or a few smoke shell fired with the gas shell.
As future battle fields will be dotted everywhere with smoke clouds, a
point that will be discussed more fully later, the firing of smoke with
gas shell will probably be the rule and not the exception.


REQUIREMENTS OF SUCCESSFUL GAS

If we succeed in getting a poisonous gas that has no odor it will be
highly desirable to fire it so that it will not be visible. In that
case no smoke will be used. Carbon monoxide is such a gas, but there
are several important reasons why it has not been used in war. (See
page 190). These considerations indicate the general requirements
for a successful poisonous gas. If non-persistent it must be quickly
volatilized, or must be capable of being driven off by heat or by other
means, which can be readily and safely produced in the field. It must
be highly poisonous, producing deaths in high concentrations, and more
or less serious injuries when taken into the system in quantities as
small as one-tenth of that necessary to produce death. If it has a
slightly delayed action with no intervening discomfort, it is still
better than one that produces immediate discomfort and more or less
immediate action. It must be readily compressed into a liquid and
remain so at ordinary temperatures, with the pressure not much above 25
or 30 pounds per square inch.

As a persistent gas it must be effective in extremely low
concentrations, in addition to having the other qualities mentioned
above.

These general characteristics concerning gases apply whether used by
Chemical Warfare troops, the Artillery, the Air Service, the Navy,
or the Infantry. In speaking of these substances being used by the
Infantry, it is understood that an ample number of Chemical Warfare
officers will be present to insure that the gases may not be turned
loose when weather conditions are such that the gas might drift back
and become a menace to our own troops. This is absolutely essential
since no troops who have as varied duties to perform as the Infantry,
can be sufficiently trained in the technical side of chemical warfare
to know when to put it off on a large scale with safety and efficiency.


ARTILLERY USE OF GAS

The Artillery of the future will probably fire more gas than any other
one branch of the Army. There are two reasons for this—first, the large
number of guns now accompanying every Army, and second, the long range
of many of these guns. As before indicated, the gases are adaptable to
various uses, and hence to guns differing both in caliber and range.
The gas will be fired by practically all guns—from the 75 mm. to the
very largest in use. It is even possible that if guns smaller than the
75 mm. become generally useful that certain gases will be fired by them.

=Efficiency of Artillery Gas Shell.= It is well to remember in the
beginning that all artillery shell so far designed and used, contain
only about 10 per cent gas, i.e., 10 per cent of the total weight of
shell and gas. It is hoped that gas shell may later be so designed
that a somewhat greater proportion of the total weight of the shell
will be gas than is now true. This is very desirable from the point of
efficiency. As stated above the bombs used by Chemical Warfare troops
contain nearly 50 per cent of their total weight in gas, and hence are
nearly five times as efficient as artillery shell within the limit of
range of these bombs. This fact alone is enough to warrant the use of
gas troops to their full maximum capacity in order that the artillery
may not fire gas at the ranges covered.


GUNS FIRING PERSISTENT AND NON-PERSISTENT GASES

Considering the firing of non-persistent and persistent gases, it may
be said generally that non-persistent gases will be fired only by the
medium caliber guns which are available in large numbers. In fact, the
firing of non-persistent gases will be confined mainly to the 6-inch or
155 mm. Howitzer and gun.

As our Army was organized in France, and as it is organized at present,
the number of 155 mm. guns will be greater than all others put
together, except the 75 mm. In order that a non-persistent gas may be
most effective a high concentration must be built up very quickly. This
necessitates the use of the largest caliber shell that are available
in large numbers. Of course, a certain percentage of the gas shell of
other calibers may consist of non-persistent gases in order to help out
the 155 mm. gun. This is in accordance with the present program for
loading gas shell and applies particularly to the 8-inch and 240 mm.
Howitzer.

=Few Ideally Persistent or Non-Persistent Gases.= Naturally there
will be very few gases that are ideally non-persistent or ideally
persistent. The groups will merge into one another. Those on the border
line will be arbitrarily assigned to one group or the other. It might
be said definitely, however, that a gas which will linger more than six
or possibly eight hours under any conditions, except great cold, will
not be considered non-persistent. For reasons of efficiency and economy
persistent gases will not be chosen unless they will persist under
ordinary conditions for two or three days or more. Accordingly, a gas
which would persist for one day only would have to be extraordinarily
useful to lead to its adoption.

=Firing Non-Persistent Gases.= Of the non-persistent gases phosgene
is the type and the one most used at present. Furthermore, so far as
can now be foreseen, it will continue to be the non-persistent gas
most used. It volatilizes very quickly upon the bursting of the shell.
Accordingly, in order that the shell fired at the beginning of a gas
“shoot,” as they are generally referred to in the field, shall still
be effective when the last shell are fired, it is necessary that the
whole number be fired within two to three minutes. The temperature
and velocity of the wind both affect this. If it be in a dead calm,
the time may be considerably extended; if in a considerable wind, it
must be shortened. Another important consideration requiring the
rapid firing of non-persistent gases is the fact that nearly all
masks thoroughly protect against phosgene and similar gases. It is
accordingly necessary to take the enemy unawares and gas him before he
can adjust his mask; otherwise, practically no harm will result. From
the considerations previously mentioned, these “gas shoots” are usually
made at night when, as before stated, carelessness, sleepiness and the
resulting confusion of battle conditions always insure more casualties
than firing gas in the daytime.

=Firing Persistent Gases.= The persistent gases will be fired by all
caliber guns, but to a less extent by the 155 mm. than by the other
calibers. Persistent gases must be sufficiently effective in low
concentrations to act more or less alone. If it be desirable to fill an
atmosphere over a given area with mustard gas, the firing may extend
for two or three, or even five or six hours and all shell still act
together. The same is true of bromobenzylcyanide. This, then, permits
the minimum number of guns to be used in firing these persistent gases.
Inasmuch as they persist and force the wearing of the mask, they are
available for use in long-range, large-caliber guns for interdiction
firing on cross-roads, in villages, and on woods that afford hiding
places, as well as on other similar concentration points.

=Firing Irritant Gases.= The irritant gases will be fired by the
various caliber guns, in the same manner as the persistent and
non-persistent gases. We will have non-persistent irritant gases and
persistent irritant gases. They are, however, considered as a group
because they are used for harassing purposes, due to their efficiency
in forcing the wearing of the mask.

Before the signing of the Armistice, the General Staff, A. E. F., had
authorized, beginning January 1, 1919, the filling of 25 per cent of
all shell with Chemical Warfare materials. The interpretation there
given to shell was that it included both shrapnel and high explosive.

Of the field guns in use, the 75 mm. will be best, up to the limit of
its range, for persistent gases such as mustard gas, and the tear gas,
bromobenzylcyanide. A considerable number, however, were filled with
non-persistent gases and probably will continue to be so, since, due to
the very large number of 75 mm. guns available, they can be used to add
greatly at times to the amount of non-persistent gas that can be fired
upon a given point.


USE OF GAS BY THE AVIATION SERVICE

No gas was used by aeroplanes in the World War. Many rumors were spread
during the latter part of the war to the effect that the Germans had
dropped gas here or there from aeroplanes. Every such report reaching
the Chemical Warfare Service Headquarters was run down and in every
case was found to be incorrect. However, there was absolutely no
reason for not so using gas, except that the German was afraid. In the
early days of the use of gas he did not have enough gas, nor had he
developed the use of aeroplanes to the point where it would have seemed
advisable. When, however, he had the aeroplanes the war had not only
begun to go against him, but he had become particularly fearful of gas
and of aeroplane bombing.

It does not seem to be generally known, but it is a fact, that after
three or four months’ propaganda he made a direct appeal to the Allies
to stop the use of gas sometime during the month of March, 1918. This
propaganda took the form of an appeal by a Professor of Chemistry who
had access to Switzerland, to prevent the annihilation of the Allied
forces by a German gas that was to make its appearance in 1918. This
German professor claimed that, while favoring the Germans winning the
war, he had too much human sympathy to desire to see the slaughter that
would be caused by the use of the new gas. The Allies in the field felt
that this was simply an expression of fear and that he did not have
such a gas. The Germans were accordingly informed that the Allies would
not give up the use of gas. Later events proved these conclusions to be
absolutely correct. The German evidently felt that the manufacturing
possibilities of the Allies would put them in a more predominant
position with gas than with anything else. In that he was exactly
correct.

The use of gas by aeroplanes will not differ from its use in artillery
or by Chemical Warfare Troops. Non-persistent gases may be dropped
on the field of battle, upon concentration points, in rest areas, or
other troop encampments to produce immediate casualties. Persistent
gases will be dropped particularly around cross-roads, railroad yards,
concentration points and encampments that cannot be reached by the
artillery. The sprinkling of persistent gases will be one of the best
ways for aeroplanes to distribute gas.

It might be said here that the aviation gas bomb will be highly
efficient, inasmuch as it has to be only strong enough to withstand the
low pressure of the gas and ordinary handling, whereas artillery shell
must be strong enough to withstand the shock of discharge in the gun.


INFANTRY AND GAS WARFARE

When one suggests the possibility of the infantry handling gas, it is
at once argued that the infantry is already overloaded. That is true,
but in the future, as in the past, the infantryman will increase or
decrease his load of a given material just as its efficiency warrants.
If he finds that gas will get casualties and help him win victories
more readily than an equal weight of any other material, he will carry
gas material. A study of the articles of equipment abandoned by 10,000
stragglers in the British Army picked up during the great German drive
towards Amiens in March, 1918, illustrates this very clearly. Of the
equipment carried by these stragglers, more than 6,000 had discarded
their rifles. The helmets were thrown away to a somewhat less extent,
but the gas mask had been thrown away by only 800 out of the 10,000.
Now the gas mask is not a particularly easy thing to carry, nor was
the English type comfortable to wear, but the English soldier had
learned that in a gas attack he had no chance whatever of escape if his
gas mask failed him. Accordingly, he hung on to the mask when he had
discarded nearly everything else in his possession. The same thing will
be true of any gas equipment if it proves its worth.


SMOKE AND INCENDIARY MATERIALS

So far nothing has been said in regard to smoke or incendiary
materials. This has been due to the fact that their use is not
dependent upon weather conditions to anything near the extent that
gas is. Second, the smokes, not being poisonous, are not a danger to
our own troops, although they may hamper movements and add to the
difficulty of taking a position, if used improperly. Of the two classes
of materials, smoke and incendiary, smoke materials may be said to be
at least a thousand times as important as the incendiary materials. A
material that will burst into flame when a shell is opened or that will
scatter balls of burning fire appeals to the popular imagination, and
yet actual results achieved by such materials on the field of battle
have been almost nil. About the only results worth while achieved by
incendiary materials have been in occasionally firing ammunition dumps
and more frequently, setting fire to warehouses and other storage
places. This will undoubtedly continue in the future.


FLAME THROWER

Of the incendiary materials the least valuable is the flame thrower. In
the Chemical Warfare Service it has been the habit for a long while not
to mention the flame thrower at all, unless questions were asked about
it. It is mentioned here to forestall the questions. Even the German,
who invented it and who, during the two years of trench warfare, had
full opportunity for developing its use, finally came to using it
largely as a means of executing people that he did not want to shoot
himself. Men falling in that class were equipped with flame throwers
and sent over the top. The German knew, as did the Allies, that each
man with a flame thrower became a target for every rifle and machine
gun nearby. The flame thrower is very quickly exhausted and then the
one equipped with it has no means of offensive action, and in addition,
is saddled with a heavy load, hampering all movements, whether to
escape or to advance.


INFLAMMABLE MATERIALS

There will probably be some use for materials such as metallic sodium,
spontaneously inflammable oils, etc., that will burst into flame and
burn when exposed to the air, though white phosphorus is probably
equal, and in most cases vastly superior to anything else so far
suggested. Phosphorus burns with an unquenchable flame when exposed
to the air, whether wet or dry. It is of great value for screening
purposes, and for use against the enemy’s troops. The German did not
use phosphorus simply because he did not have it, just as he did not
use helium in his observation balloons because he did not have it.

The value of phosphorus was just beginning to be realized slightly when
the Americans entered the war, while its full value was not appreciated
even by the American troops when the war closed.

The work of the First Gas Regiment with phosphorus against machine gun
nests proved how valuable it is against the enemy’s troops. It proved
also its tremendous value as a screen.

The Chemical Warfare Service was prepared to fill a great number of
artillery shell with phosphorus, but due to the failure of our shell
program to mature before the Armistice, phosphorus was not used by
American artillery to any appreciable extent.


SMOKE USED BY EVERYONE

Smoke will be used by every fighting arm of the Service in practically
every battle, both by day and by night. If you have ever tried on
a target range to shoot at a target that was just beginning to be
obscured by a fog, you will recognize the difficulty of hitting
anything by firing through an impenetrable smoke screen. It is simply
a shot in the dark. Future battles will witness smoke formed by smoke
candles that are kept in the trenches or carried by the troops, by
smoke from bursting artillery shell and rifle grenades, by smoke from
aeroplane bombs and possibly even from what is known as the smoke
knapsack. The knapsack produces a very dense white smoke and very
economically, but will probably not be much used. This is because,
notwithstanding its efficiency, the knapsack cannot be projected to a
distance, that is, the smoke screen is generated on the person carrying
the knapsack. On the other hand the great value of phosphorus is that
it can be fired to great distances in rifle grenades or artillery
shell, and dropped from aviation bombs. The smoke screen is thus
established in front of the object it is desired to cut off, whether it
be a battery of artillery, an advancing wave of infantry, or a lookout
station. Thus smoke, for screening purposes alone, will be used to a
tremendous extent. It will also be used in conjunction with gas.


SMOKY APPEARANCE OF GAS CLOUD

Due to the smoky appearance of an ordinary gas cloud and to the coming
use of poisonous smokes, no one on the field of battle in the future
will ever be certain that any given smoke cloud is not also a poisonous
cloud until he has actually tested it. And there lies an opportunity
for the most intense study and for the greatest use of the proverbial
American ingenuity that war has ever furnished.

In the variations that can be played with smoke containing gas, or not
containing gas, with smoke hurled long distances by the artillery or
dropped from aeroplanes, the possibilities indeed are unlimited. Every
officer will need to study the possibilities of smoke, both in its use
against him and in his use of it against the enemy. He can probably
save more casualties among his own troops by the skillful use of smoke
than by any other one thing at his command. On the other hand, the
unskilled use of smoke on the part of one side in a battle may lead to
very great casualties in proportion to those of the enemy should the
latter use his smoke skillfully. This is a subject that deserves deep
and constant study.


PROTECTION BY SMOKE CLOUDS

Smoke in the future will be the greatest protective device available
to the soldier. It shuts out not only the view in daylight, but
the searching of ground at night by searchlights, by star bombs or
other means for illuminating the battlefield. It has already been
used extensively by the Navy and undoubtedly will be used far more
extensively in the future.


SHELL MARKINGS

Modern artillery shell have distinctive colors for high explosive, for
shrapnel, for incendiary materials, and for gases. A grayish color has
been adopted as the general color of the paint on all gas shells, bombs
and cylinders. In addition a system of colored bands has been adopted.
These bands are white to indicate poisonous non-persistent substances,
and red—persistent. Yellow is used to indicate smoke. With any given
combination of red and white and yellow bands, the artillery-man at
the front can tell, at a glance, whether the gas is non-persistent or
whether it is persistent, and also whether or not it contains smoke.
There will be secondary markings on each shell which, to the trained
Chemical Warfare Service officer, will indicate the particular gas or
gases in the shell. These markings however, will be inconspicuous and
no attempt will be made to give the information to the soldier or even
to the average officer firing gas.

These secondary markings are for the purpose of enabling the Chemical
Warfare Service officers in charge to use certain gases for particular
uses in those comparatively rare cases when sufficient gas is on hand
and sufficient time available to enable such a choice to be made.




CHAPTER XXIV

DEFENSE AGAINST GAS


(From the Field Point of View)

The best defense against any implement of war is a vigorous offense
with the same implement. This is a military axiom that cannot be
too often, or too greatly emphasized, though like other axioms it
cannot be applied too literally. It needs a proper interpretation—the
interpretation varying with time and circumstances. Thus in gas
warfare, a vigorous offense with gas is the best defense against
gas. This does not mean that the enemy’s gas can be ignored. Indeed,
it is more important to make use of all defensive measures against
gas than it is against any other form of attack. Gas being heavier
than air, rolls along the ground, filling dugouts, trenches, woods
and valleys—just the places that are safest from bullets and high
explosives. There it remains for hours after it has blown away in the
open, and, since the very air itself is poisoned, it is necessary not
only that protection be general but that it be continuous during the
whole time the gas is present.


EARLIEST PROTECTIVE APPLIANCES

The earliest protection against gas was the crudest sort of a mask.
The first gas used was chlorine and since thousands of people in civil
life were used to handling it, many knew that certain solutions, as
hyposulfite of soda, would readily destroy it. They also knew that
if the breath could be drawn through material saturated with those
solutions, the chlorine would be destroyed. Thus it was that the first
masks were simple cotton, or cotton waste pads, which were dipped into
hyposulfite of soda solutions and applied to the mouth and nose during
a gas attack. These pads were awkward, unsanitary, and, due to the long
intervals between gas attacks, were frequently lost, while the solution
itself was often spilled or evaporated. The net result of all this was
poor protection and disgust with the so-called masks.


DESIGN OF NEW MASKS

After using these, or similar poor excuses for a mask, for a few weeks,
the British designed what was known as the PH helmet. In a gas attack
the sack was pulled over the head and tucked under the blouse around
the neck, the gas-tight fit being obtained by buttoning the blouse
over the ends of the sack. This PH helmet was quite successful against
chlorine and, to a much less extent, against phosgene, a new gas
introduced during the spring of 1916.

But it was warm and stuffy in summer—the very time when gas is used to
the greatest extent—while the chemicals in the cloth irritated the face
and eyes, especially when combined with some of the poisonous gases.

Probably as a result of experience with oxygen apparatus in mine rescue
work, Colonel Harrison suggested making a mask of which the principal
part was a box filled with chemicals and carried on the chest. A
flexible tube connected the box with a mouthpiece of rubber. Breathing
was thus through the mouth and in order to insure that no air would be
breathed in through the nose, a noseclip was added.

This, of course, cared for the lungs, but did not protect the eyes.
Their protection was secured by making a facepiece of rubberized cloth
with elastics to hold it tight against the face. The efficiency of this
mask depends, then, first upon the ability of the facepiece to keep out
lachrymatory gases which affect the eyes, and, second, upon a proper
combination of chemicals in the box, to purify the air drawn into the
lungs through the mouthpiece. (Details are given in Chapter XII).


PROTECTION AGAINST SMOKE

While the charcoal and soda-lime granules furnished an adequate
protection against all known true gases, they did not furnish
protection against certain smokes or against minute particles of
liquid gas. Since certain smokes, as stannic chloride, though not
deadly, are so highly irritating as to make life unbearable, it early
became necessary to devise means for keeping them from going through
the masks. This was done in the first masks by adding a sufficient
thickness of cotton batting. The cotton was usually placed in three
layers alternating with the charcoal and granules, as it was thought
the latter would be held in place better by that means.

Some time after stannic chloride came into use the Germans started
firing shells containing a small quantity of diphenylchloroarsine,
popularly known as “Sneezing Gas.” Protection against this is discussed
in Chapter XVIII.


CHOICE OF MASKS FOR U. S. TROOPS

When it became necessary, with the creation of a Chemical Warfare
Service in France in August, 1917, to decide upon a mask for American
troops, there were available for purchase two types—the British
type and the French M-2. The French M-2 consisted essentially of 32
layers of cloth impregnated with various chemicals, through which
the air was breathed both in and out. This mask was quite effective
against ordinary field concentrations of most gases, but was utterly
inadequate to care for the high concentration of phosgene obtained in
the front line from cloud gas or from projector gas attacks. It was
also poor against chloropicrin. The M-2 was, however, very light and
easy to carry and moreover was deemed sufficient to protect against
concentrations of cloud gas even, at points more than five miles
distant from the front line.

Furthermore, it was felt desirable at first to have an auxiliary or
emergency mask in addition to the principal one, for use in case
the principal mask was worn out or damaged. Accordingly both types
of masks were adopted and the day after Fries took charge of the
Chemical Warfare Service, A.E.F., on August 22, 1917, 100,000 of each
were purchased, although there were then only ten or twelve thousand
American troops in France requiring masks. Later additional masks of
both kinds were purchased to tide over the American troops until a
sufficient quantity of the British type masks could be manufactured in
the United States. The total of British masks purchased amounted to
about 700,000.

However, within a comparatively short time after American troops got
into the front line it was realized that a second mask, inferior in
protection to the first, was highly undesirable. During a gas attack
men seemed to acquire an uncontrollable desire to shift from one
mask to the other. This shifting in nearly every case resulted in a
casualty. We then came rapidly to the conclusion that one mask only
should be furnished, and that one the best that could be made, and
then to impress upon the soldier the fact that his life depended upon
the care he took of his mask. This proved to be an entirely sound
conclusion, as the number of men gassed through injuries to the mask
was comparatively small. An interesting proof of the value the soldier
placed upon his mask was shown by the articles of equipment thrown away
by 10,000 British stragglers in the great German offensive of March,
1918. Of the articles thus thrown away the gas mask came at the foot of
the list, with only 800 missing. The steel helmet is said to have come
next with about 4,000 missing.


SIZES OF FACES FOR MASKS

When adopting the British respirator in August, 1917, it was decided
that the American face as well as the American stature was probably
larger than the English. Accordingly inquiry was made in regard to
the sizes of masks issued to the Canadians as it was thought probable
they required a greater proportion of the larger size masks than did
the English. When prescribing the relative quantities of each size
of mask to be furnished Americans, the Canadian requirements were
taken as a base but with the larger sizes increased slightly over the
Canadian requirements. As a matter of fact even these increases proved
considerably too small, so that the numbers in the two sizes above
normal had to be finally more than doubled.


OBJECTIONS TO GERMAN TYPE MASK

The American Gas Service felt from the beginning that a design which
attached the box of chemicals to the facepiece was unsound in principle
(this design was used in the German mask and in the French A. R. S.
masks), since it did not allow proper flexibility for increasing the
size of the box to care for new gases. Furthermore, the weight of the
box during movement caused the facepiece to swing slightly from side
to side. This interfered with vision and tended to lift the facepiece
away from the face and allow gas to enter. That the objections of
the American Gas Service to this type were correct was proved by the
difficulty encountered toward the end of the war by both the French
and the Germans in trying to provide a suitable filter for protection
against particulate clouds and the smokes, such as stannic chloride and
diphenylchloroarsine.


STRUGGLE BETWEEN MASK AND GAS

As between the mask and poisonous gases, we have the old struggle of
the battleship armor against the armor-piercing projectile. While the
armor-piercing projectile has always had a little the better of the
game, it is just the reverse with gases. The gas mask has always been
just a little better than the gases, so that very few casualties have
occurred through failure of the mask itself. This margin of safety
has never been any too great, and that we have had a margin at all
is due to the energy, skill and enthusiasm of those developing and
manufacturing masks in England, France, and particularly in the United
States.

However, the mask at the best is uncomfortable, causes some loss of
vigor, and even with the very best American masks there is some loss in
vision. The wearing effect on troops results mostly from the increased
resistance to breathing. Accordingly a tremendous amount of study and
effort was made to decrease this breathing resistance. In the English
type masks this resistance was equal to the vacuum required to raise
a column of water about four and one-half inches. Adding the sulfite
paper to protect against diphenylchloroarsine increased this resistance
by about one inch. This put a heavy burden on the wearer of the mask
whenever it was necessary for him to do any manual labor while wearing
it. In addition earlier masks left a good deal to be desired in the
way of reducing resistance by proper sized tubes, angles and valves
through which the air was drawn. This was much more easily overcome
than reducing the resistance through the chemicals and charcoal and the
materials for protection against diphenylchloroarsine. In the latest
type canister, devised after long trials for the American forces, this
resistance was brought down to about two inches of water. What this
reduction in resistance means no one knows except one who has worn the
old mask with its mouthpiece and four to six inches’ resistance and has
then replaced that mask for one through which he breathes naturally
with only two inches’ resistance.


DESIGN OF NEW AMERICAN MASK

The American Gas Service felt from the beginning that the mouthpiece
and noseclip must be abandoned and bent every effort toward getting a
mask perfected for that purpose. The English opposed this view fiercely
for nearly a year. This position on the part of the English was more or
less natural. They developed their mask in the beginning for protection
against cloud gas. In those days the opposing trenches were close
together. Moreover, front line trenches were quite strongly manned.
The result was that a large number of men were exposed to a very high
concentration of gas, but—and highly important—for a short period
only. Inasmuch as the German feared this cloud gas even more than
the English there was no danger of his attacking in it. The English
rules of conduct during a gas attack called for all movement to stop
and for every man to stand ready until the cloud passed. Accordingly,
the man was breathing the easiest possible and hence did not suffer
particularly from the resistance.

With the advent of mustard gas, however, the whole general scheme of
protection changed. Mustard gas, as is well known, is effective in
extremely low concentrations and has very great persistency. In dry
warm weather mustard gas, scattered on the ground and shrubbery, will
not be fully evaporated for two to three days and accordingly will
give off vapors that not only burn the lungs and eyes but the soft,
moist parts of the skin as well. In cool, damp weather the gas remains
in dangerous quantity for a week and occasionally longer. Since this
gas, in liquid form, evaporates too slowly for use in gas clouds,
it is used altogether in bombs and shells. Accordingly it could be
expected to be and actually is fired at all ranges from the front line
to nearly eight miles back of that line. Hence, with the coming of
mustard gas, the need for protection changed from high protection for
a short period to moderate protection for very long periods. Indeed,
mustard gas makes it necessary for men to wear masks just as long as
they remain in an area infected with it. There is still occasional need
for high protection for short periods, but with the increase in the
efficiency of charcoal alone, it is found that the amount of charcoal
and chemicals in the canister can be very greatly reduced and still
maintain sufficient protection for the high concentrations encountered
in cloud gas and projector attacks.


EXHAUSTION AND MALINGERING

It seems physically impossible for the ordinary man to wear the British
mask with its mouthpiece and noseclip more than six to eight hours
and vast numbers are unable to even do that. How many thousands of
casualties were suffered through men losing their mental balance from
exhaustion and the discomfort of the mouthpiece and noseclip no one
knows. Such men tore off the mask, stating that they would rather
die than endure the torture of wearing it longer. Furthermore, the
poor vision of this mask led to the habit of taking the facepiece
off while still leaving the mouthpiece and noseclip in place. This
gave protection to the lungs, but exposed the eyes, and as mustard
gas affects the eyes very readily this alone led to thousands of
casualties. There was another interesting side to this situation. The
malingerer who wanted to get out of the front line and was willing to
take any action, however cowardly, to achieve that end, deliberately
removed the facepiece and thus suffered gassing of the eyes. The effect
of mustard gas soon became so well known that the malingerer knew
gassing of the eyes never resulted in death or permanent loss of sight.
With the new type of American mask, the protection of eyes and lungs
depends solely upon the fit around the face and no such playing with
the mask can be done.


Without going into further details in regard to masks it is sufficient
to state that at the end the Americans had produced a mask thoroughly
comfortable, giving complete protection against gases and smoke clouds,
and one that was easy to manufacture on the huge scale (fifty to
seventy-five thousand per day) which was necessary to provide masks for
an army of three to four million men in the field.


PROTECTION IN WAR IS RELATIVE ONLY

Napoleon is credited with saying “In order to make an omelet, it is
necessary to break some eggs.” Every student of war realizes that
casualties cannot be avoided in battle and yet one American Staff
Officer went so far as to refuse to use gas offensively unless the
Chemical Warfare Service could absolutely guarantee that not a single
American casualty could occur under any circumstances. This same
idea early got into the heads of the laboratory workers on masks.
They seemed to feel that if a single gas casualty occurred through
failure of the mask, their work would be a failure or at least they
would be open to severe criticism. Accordingly efforts were made to
perfect masks and to perfect protection regardless of the discomfort
imposed upon the wearer of the mask. This idea was very difficult to
eradicate. The laboratory worker who accustoms himself to experiment
with a particular thing forgets that he develops an ability to endure
discomfort, that is not possible of attainment by the ordinary man in
the time available for his training.

Furthermore, if the need for such training can be avoided it is of
course highly desirable. This applies to the mouthpiece of the British
respirator; to elastics that cause undue discomfort to the face; to
the noseclip and to the large boxes that cause too great resistance to
breathing.

It may be taken as a general rule that when protection requires so
much effort or becomes so much of a burden that the average man cannot
or will not endure it, it is high time to find out what the average
man will stand and then provide it even if some casualties result.
Protection in battle is always relative. A man who cannot balance
protection against legitimate risk has no business passing on arms,
equipment or tactics to be used in battle.


TRAINING

Bitter experience taught the Allies as well as the Americans that no
matter how efficient the gas mask and other defensive appliances, they
would not take the place of thorough and constant training. One of the
greatest difficulties at first was to get American troops to realize
that a thing as invisible as gas, with in many cases no offensive smell
and producing no immediate discomfort, could be deadly. Nothing but
constant drill and constant reiteration of these dangers could get this
fact impressed on them. Indeed it never was impressed sufficiently in
any of the earlier divisions of American troops in the line to prevent
their taking such chances that each division suffered heavy loss on one
or more occasions from gas attacks.

A great deal of emphasis had been placed by the English upon the
adjustment of the mask in the shortest possible time, this time having
been officially set at six seconds after the alarm. The Americans
in adopting the mask _in toto_ naturally had to adopt the rules for
adjusting it and wearing it. Experience, however, taught them in a
few months that the effort to attain too great speed was dangerous.
It tended to rattle the soldier and to result in poor adjustment of
the mask, both of which led to casualties. Accordingly in the latest
instructions for defense against gas all reference to six seconds was
eliminated and emphasis placed on the necessity of accurate adjustment
of the mask. Inasmuch as any man, practically without effort or
previous drill, can hold his breath for twenty seconds, the need for
great speed in adjusting the mask is not apparent.


HOLDING THE BREATH

The first regulations and those in general use up to near the close of
hostilities, prescribed that the soldier should hold his breath and
adjust his mask. It seemed impossible to overcome the natural inference
that “holding the breath” meant first the drawing of a full breath.
This was obviously highly dangerous if gas were actually present
before the alarm was heard, as was often the case with projector and
artillery gas shell attacks. The change was then made to the phrase
“Stop Breathing and Stay Stopped until the Mask is Carefully and
Accurately Adjusted.”


PSYCHOLOGY IN TRAINING

While the importance of impressing upon the soldier the danger of gas
was early appreciated it was deemed necessary not to make him unduly
afraid of the gas. However, as gas defense training in our Army got
a big start over gas offense training, this became a matter of very
great importance. In fact, due to a variety of causes, training in
the offensive use of gas was not available for any troops until after
their arrival in France. This resulted in officers and men looking upon
the gas game, so far as they were individually concerned, as one of
defense only. Accordingly after their arrival in France it became very
difficult not only to get some of our officers to take up the offensive
use of gas but even to get them to permit its use along the front they
commanded.

Notwithstanding all the care taken in training Americans in gas defense
there arose an undue fear of the gas that had to be overcome in order
to get our troops to attack close enough to their own gas to make it
effective. This applied to the use of gas by artillery as well as
to its use by gas troops. However, it should be said that in every
instance where gas was once used on an American front all officers in
the Division, or other unit, affected by it were always thereafter
strongly in favor of it.


GERMAN PROBLEMS IN GAS TRAINING

The Germans also had serious troubles of their own over the psychology
of gas training. As stated elsewhere they were using mustard gas nearly
eleven months before the Allies began using it. During that time, for
purposes of morale, if not sheer boastfulness, the Germans told their
men that mustard gas could not be made by the Allies; that it was by
far the worst thing the war had produced—and in that statement they
were correct—and that they would win the war with it—in which statement
they were far from correct. When the Allies began sending it back
to them they had to reverse their teachings and tell their men that
mustard gas was no worse than anything else, that they need not be
afraid of it and that their masks and other protective appliances gave
full protection against it. They thus had a problem in psychology which
they never succeeded in fully solving. Indeed there is no question but
that the growing fear of gas in the minds of the German is one of the
reasons that prompted him to his early capitulation.


GAS AT NIGHT

In the early days it was very difficult to get officers to realize
the absolute necessity of night drill in the adjustment of the mask.
For various reasons, including surprise, gas attacks were probably
eighty to ninety per cent of the time carried out at night. Under
such conditions confusion in the adjustment of the mask is inevitable
without a great deal of practice before hand, especially for duty in
trenches with narrow spaces and sharp projecting corners. There are
numerous instances of men waking up and getting excited, who not only
gassed themselves, but in their mad efforts to find their masks, or
to escape from the gas, knocked others down, disarranging their masks
and causing the gassing of from one to three or four additional men.
The confusion inherent in any gas attack was heightened in the latter
stages of the war by heavy shrapnel and high explosive bombardments
that accompanied nearly all projector and cloud gas attacks for that
very purpose. The bombardment was continued for three or four hours to
cause exhaustion and removal of the mask and to prevent the removal of
the gassed patients from the gassed area.


DETECTION OF GASES

Efforts were made by the enemy and by all the Allies throughout the war
to invent a mechanical detector that would show when gas was present
in dangerous quantities. While scores, perhaps hundreds, of these were
invented none proved simple, quick, or certain enough in action to make
their adoption desirable. In every case it was necessary to rely on
the sense of smell. Thus it was that as the war wore on, more and more
attention was given to training officers and non-commissioned officers
to detect various kinds of gases in dangerous quantities by the sense
of smell.

In the American Gas Defense School for officers this was done wholly by
using captured German gases. This was because certain gases have quite
different smells, depending upon the impurities in the gas and also
upon the solvents sometimes mixed with them. Thus the German mustard
gas has a mustard smell, while the Allies mustard gas, due to a slight
difference in the method of manufacture, has a very perfect garlic
odor. Not only must officers and men who handle gas training know the
smell of the various gases, but they must know when the concentration
of each is high enough to be dangerous. This is not easy to learn
because the strength of the various gases in dangerous concentrations
varies through wide limits. Not only does the strength of the gases
vary and the sharpness of the odors accordingly, but the mingling of
poisonous gases with other gases from high explosive and shrapnel tends
to obscure these odors and make them more difficult of detection.


DECEPTIVE GASES

A great deal of thought was given toward the end of the war to the
subject of deceptive gases which could by powerful or peculiar odors
mask the dangerous gases. This masking was to deceive the enemy when
dangerous gases were present or to admit an attack without masks while
the enemy was wearing his through thinking there was a dangerous gas
when as a matter of fact none existed.

In gas warfare, the German, as well as the Allies, was exercising his
ingenuity in devising new and startling methods of making gas attacks.
A well known trick with the German was to fire gases for several days,
particularly against green troops, in concentrations so slight as to
do no harm. When he felt that he had lulled those troops to a sense of
the ineffectiveness of his gas, he sent over a deadly concentration.
In spite of the warning that this was what was happening, he often
achieved too great a success. Before the war closed, however, the
American was beginning to out-think and out-wit the German in this
method of warfare.


MUSTARD GAS BURNS

With the advent of mustard gas which burned the body, a new and serious
difficulty in protection arose. At first it was thought mustard gas
burned only when the liquid from the bursting shell actually splashed
on the clothing or skin. This was unfortunately soon found to be not
true. The gas itself rapidly penetrates clothing and burns the skin
even when the concentration of the gas is very low. Probably the
majority of burns from mustard gas arose from concentrations of gas
consisting of less than one part of gas to five hundred thousand of
air. Furthermore, the gas is fully fifty per cent cumulative in its
effects, that is, in extremely low concentrations over a period of
hours it will produce more than fifty per cent the effect that a far
higher concentration would produce in a relatively shorter time.

The Allies were not long in discovering that oilcloth afforded very
complete protection against mustard gas. The ordinary oilcloth,
however, was too thick, too hot and too heavy for general use.
Experiments soon showed that cloth thoroughly impregnated with boiled
linseed oil would give protection. In order to make this protection
more perfect a certain amount of paraffin was added. All this made
the clothing air-tight, rather stiff and always uncomfortable.
Notwithstanding these discomforts, hundreds of thousands of oiled
suits, and as many pairs of oiled gloves were made and issued to
artillery troops, and to troops especially charged with handling
mustard gas shells, or to those employed in destroying mustard gas in
shell holes by spreading chloride of lime over them.

The importance of protection against mustard gas burns led to extensive
researches being made with a view to finding a cloth which would be
comfortable and porous and while stopping mustard gas would yet be
sufficiently durable and comfortable to be issued to infantry troops as
well as to artillery and other special troops. This, it is understood,
had been achieved, just prior to the Armistice. Still more desirable
would be the discovery of a chemical substance which could be applied
to all uniforms and Army clothing and thus protect the regulation
clothing against the penetration of mustard gas, and thereby avoid
carrying extra clothing for that special purpose.


PROTECTING TROOPS BY MOVING THEM FROM INFECTED AREAS

As soon as it was fully realized that mustard gas persisted for
several days it was decided to run complete reliefs of men into and
out of areas that had been heavily shelled with mustard gas, or better
still, where practicable, to completely evacuate the area. Inasmuch
as the gas is dangerous to friend and foe alike, this method was
comparatively safe and was used to a very considerable extent. With
the warfare of movement that existed over most of the active front
throughout the season of 1918, this moving of troops out of infected
areas became highly important and, when skillfully done, often resulted
in a great saving of troops and at the same time prevented the enemy
from receiving any particular tactical advantage from his mustard gas
attacks.

There was one very excellent example of this a few miles to the
northwest of Château-Thierry prior to the counter-offensive of July 18,
1918. At that time the Germans heavily shelled with mustard gas four or
five small woods and two or three villages. It was necessary for the
men to stay in these woods during the day, as they afforded the only
protection obtainable from machine guns, shrapnel and high explosive.
At the time this occurred American gas officers generally understood
the necessity of getting troops out of a mustard gas infected area.
Accordingly all began searching for places safe from the mustard gas.
In one particular instance the gas officer of a regiment discovered
that a portion of the woods his men were in was free from the gas,
and the regimental commander, promptly following his advice, moved
his troops into the free area. As a result of this prompt action the
regiment had only four light gas casualties, although all told there
were several hundred mustard gas casualties in this attack, the number
per thousand generally being from ten to twenty times that of the
thousand men just mentioned.


MIXING POISONOUS GASES

On this as well as other occasions the Germans fired some diphosgene
and Blue Cross (Sneezing gas), as well as mustard gas. This added to
the difficulty of determining areas free from the latter. In the future
such mixing of poisonous gases may always be expected and, in addition,
gases which have no value other than that of masking the poisonous
ones will be fired. While with practically all gases except mustard
gas a man is comparatively safe while breathing a concentration very
noticeable to the sense of smell, the only safe rule with mustard gas
is to consider as dangerous any concentration that can be smelled.

For the reason that this gas persists longer in calm areas, woods are
always to be avoided, where practicable, and also, since all gases,
being heavier than air, tend to roll into depressions and valleys, they
should be avoided. There have been a number of authentic cases where
batteries in hollows or valleys suffered severely from mustard gas,
while troops on nearby knolls or ridges were comparatively free, though
the difference in the amount of shelling of the two places was not
noticeable.

Of great importance with all gases is the posting of a sufficient
number of sentries around men sleeping within the range of gas shell.
The worst projector gas attack against the Americans was one where the
projectors were landed among a group of dugouts containing men asleep
without sentries. The result was a very heavy casualty list, coupled
with a high death rate, the men being gassed in their sleep before they
were awakened.


DESTRUCTION OF MUSTARD GAS

Prior to the introduction of mustard gas all that was necessary to get
rid of gas was to thoroughly ventilate the spot. Thus in trenches and
dugouts, fires were found to be very efficient, simply because they
produced a circulation of air. In the early days, among the British,
the Ayrton fan, a sort of canvas scoop, was used to throw the gas out
of the trenches. While this was taken up in the American Service, it
did not become very important, since it was found that, under ordinary
atmospheric conditions, natural ventilation soon carried the gas out of
the trench proper, while fires in dugouts were far more efficient than
the fans. Likewise the Ayrton fan smacked too much of trench warfare
which had reached a condition of “stalemate”—a condition that never
appealed to the Americans and a condition that it is hoped never will.

With mustard gas, however, conditions were entirely changed. This
liquid having a very high boiling point and evaporating very slowly,
remains for days in the earth and on vegetation and other material
sprinkled with it. This was particularly true in shell holes where the
force of the explosion drove the gas into the earth around the broken
edges of the hole. While many substances were experimented with, that
which proved best and most practical under all conditions, was chloride
of lime. This was used to sprinkle in shell holes, on floors of dugouts
and any other places where the liquid might be splashed from bursting
shells. It was also found very desirable to have a small box of this at
the entrance to each dugout, so that a person who had been exposed to
mustard gas could thoroughly coat his shoes with it and thus kill the
mustard gas that collected in the mud on the bottom and sides of his
shoes.


CARRYING MUSTARD GAS ON CLOTHING

There are many instances where the occupants of dugouts were gassed
from the gas on the shoes and clothing of men entering the dugout.
Not only were occupants of dugouts thus gassed but a number of nurses
and doctors were gassed while working in closed rooms over patients
suffering from mustard gas poisoning. Even under the conditions of
warfare existing where the Americans were generally in action, the
quantity of chloride of lime required amounted to several hundred tons
per month which had to be shipped from the United States. Chloride of
lime was also very convenient to have at hand around shell dumps for
the purpose of covering up leaky shells, though rules for handling
mustard gas shells usually prescribed that they be fired and where that
was not practicable to bury them at least five feet under the surface
of the ground. This depth was not so much for the purpose of getting
rid of the gas as it was to get the shell so deep into the ground that
it would not be a danger in any cultivation that might later take place.


MUSTARD GAS IN COLD WEATHER

Much was learned toward the end of the war about ways of getting
through or around areas infected with mustard gas. For instance,
if mustard gas be fired when the weather is in the neighborhood of
freezing or somewhat below, it will remain on the ground at night
with so little evaporation as not to be dangerous. The same will be
true during the day time if the weather is cloudy as well as cold.
If, however, the days are bright and the nights cold, mustard gassed
areas can be safely crossed by troops at night provided care is taken
in brush and bushes to protect the feet and clothing from the liquid
splashed on bushes. If the sun comes out warm in the morning such
areas may be quite dangerous for three to four hours following sun-up
and indeed for the greater part of the day. Quite a large number of
casualties were ascribed to this fact in the heavy attack on the
British front west of Cambrai just prior to the great German drive
against Amiens, March 21, 1918.


DEGASSING UNITS

Since mustard gas has a greatly delayed action it was found that if men
who had been exposed to it could be given a thorough bath with soap and
water within a half hour or even a full hour, the mustard gas burns
would be prevented or very greatly reduced in severity. Accordingly
degassing units were developed consisting essentially of a 5 ton truck
with a 1200 gallon water tank, fitted with an instantaneous heater and
piping to connect it to portable shower baths. Another truck was kept
loaded with extra suits of underclothing and uniforms. These degassing
units were to be provided at the rate of two per division. Then, in the
event of a mustard gas attack anywhere in the division, one of these
units would be rushed to that vicinity and the men brought out of the
line and given a bath and change of clothing as soon as possible. At
the same time they were given a drink of bicarbonate of soda water and
their eyes, ears, mouth and nasal passages washed with the same.


PROTECTING FOOD FROM MUSTARD GAS

It was very early learned that mustard gas, or minute particles of
the liquid gas settling on food, caused the stomach to be burned if
the food were eaten, just as the eyes, lungs and skin of the body are
burned from gas in the air. This made it necessary then to see that
all food liable to exposure to mustard gas attacks was protected, and
tarred paper for box linings or tops was found by the Gas Service to
furnish one of the cheapest and most available means of doing this.


ALARM SIGNALS

Numerous, indeed, were the devices invented at one time or another with
which to sound gas alarms. The English early devised the Strombos horn,
a sort of trumpet operated by compressed air contained in cylinders
carried for that purpose. Its note is penetrating and can be heard,
under good conditions, for three or four miles. When cloud gas attacks,
which occurred only at intervals of two to four months, were the only
gas attacks to be feared, it was easy enough to provide for alarm
signals by methods as cumbersome and as technically delicate as the
Strombos horn.

With the advent of shell gas in general, and mustard gas in particular,
the number of gas attacks increased enormously. This made it not only
impossible, but inadvisable also, to furnish sufficient Strombos horns
for all gas alarms, as gas shell attacks are comparatively local. In
such cases, if the Strombos horn is used to give warning, it causes
troops who are long distances out of the area attacked to take
precautions against gas with consequent interference with their work or
fighting.

To meet these local conditions metal shell cases were first hung up
and the alarm sounded on them. Later steel triangles were used in the
same way. At a still later date the large policeman’s rattle, well
known in Europe, was adopted and following that the Klaxon horn. As the
warfare of movement developed the portability of alarm apparatus became
of prime importance. For those reasons the Klaxon horn and the police
rattle were having a race for popularity when the Armistice was signed.

A recent gas alarm invention that gives promise is a small siren-like
whistle fired into the air like a bomb. It is fitted with a parachute
which keeps it from falling too rapidly when the bomb explodes and
sets it free. Its tone is said to be very penetrating and to be quite
effective over an ample area. Since future gas alarm signals must be
efficient and must be portable, the lighter and more compact they can
be made the better; hence the desirability of parachute whistles or
similar small handy alarms.


ISSUING NEW MASKS

One of the problems that remained unsolved at the end of the war was
how to determine when to issue new boxes, or canisters, for masks. One
of the first questions asked by the soldier is how long his mask is
good in gas, and how long when worn in drill where there is no gas.
This information is of course decidedly important. Obviously, however,
it is impossible to tell how long a canister will last in a gas attack,
unless the concentration of gas is known—that is, the life of the box
is longer or shorter as the concentration of gas is weak or heavy.

A realization of this need led mask designers to work very hard, long
before the necessity for comfort in a mask was as fully realized as
it was at the end of the war, to increase the length of life of the
canister. To get longer life they increased the chemicals and this
in turn increased the breathing resistance, thereby adding to the
discomfort of the soldier when wearing the mask. Finally, however, it
was found that in the concentration of gas encountered on an average
in the field, the life of the comparatively small American boxes was
sufficient to last from fifty to one hundred hours, which is longer
than any gas attack or at least gives time to get out of the gassed
area.

The British early appreciated the necessity of knowing when boxes
should be replaced. They accordingly devised the scheme of furnishing
with each mask a very small booklet tied to the carrying case in which
the soldier could not only enter a complete statement of the time he
had worn the mask but also the statement as to whether it was in gas
or for drill purposes only. The soldier was then taught that if he had
worn the mask, say for forty hours, he should get a new box. But the
scheme didn’t work. In fact, it was one of those things which foresight
might have shown wouldn’t work. Indeed, any man who in the hell of
battle can keep such a record completely, should be at once awarded a
Distinguished Service Medal.

As gas warfare developed not only were all kinds of gas shells sent
over in a bunch but they were accompanied by high explosive, shrapnel
and anything else in the way of trouble that the enemy possessed. A man
near the front line, under those conditions, had all he could do and
frequently more than he could do, to get his mask on and keep it on
while doing his bit. Consequently he had no time, even if he had the
inclination, to record how long he had the mask in the various gases.

In this connection, after the Armistice was signed we in the field were
requested to obtain for experimental purposes 10,000 canisters that had
been used in battle. Each was to be labeled with the length of time it
had been worn in or out of gas, and if in gas, the name of each gas
and the time the mask was worn in it. This request is just a sample of
what is asked by those who do not realize field conditions. One trip to
the front would have convinced the one making the request of the utter
impossibility of complying with it, for really no man knows how long
he wears a mask in gas. With gas as common and as difficult to detect
(when intermingled with high explosive gases and other smells of the
battle field) as it was at the end of the war, each man wore the mask
just as long as he could, simply as a matter of precaution.

Before hostilities ceased we were trying out a method of calling in say
fifty canisters per division once a week for test in the laboratory. If
the tests showed the life of the canisters to be short new canisters
would be issued. While we did not have opportunity to try out this
plan, it gave promise of being the best that could be done. With gas
becoming an every day affair, the only other alternative would seem
to be to make issues of new boxes at stated intervals. On the other
hand there are no definite records of casualties occurring from the
exhaustion of the chemicals in the box. Undoubtedly some did occur, but
they were very, very few. In nearly all cases the masks got injured, or
the box became rusted through before the chemicals gave out.


TONNAGE AND NUMBER OF MASKS REQUIRED

It will probably be a shock to most people to learn that with more than
two million men in France we required nearly 1500 tons of gas material
per month. This tonnage was increasing, rather than decreasing, to
cover protective suits, gloves, pastes, and chloride of lime, as well
as masks. The British type respirator was estimated to last from four
to six months. The active part of the war, in which the Americans took
part, was too short to determine whether this was correct or not. The
indications were, however, that it was about right, considering rest
periods and fighting periods.

With the new American mask, with its much stronger and stiffer face
material, the chances are that the life will be considerably increased
although the more constant use of the mask will probably offset its
greater durability. A longer life of mask would of course be a decided
advantage as it would not only reduce tonnage, but would reduce
manufacturing and distribution as well. The estimates on which we were
working at the end looked forward to requiring from the United States
about one-third pound per man per day for all troops in France, in
order to keep them supplied with gas defense material and with the
gases used offensively by gas troops. All gas shell, hand grenades,
etc., used by other than gas troops required tonnage in addition to the
above.


SUMMING UP

In summing up then, it is noted that there are several important things
in defense against gas. First, the mask which protects the eyes and the
lungs. Second, the training that teaches the man how to utilize to best
advantage the means of protection at his disposal, whether he be alone
or among others. Third, protective clothing that protects hands and
feet and the skin in general. Fourth, a knowledge of gases and their
tactical use that will enable commanders, whenever possible, to move
men out of gas infected areas. Fifth, training in the offensive use of
gas, as well as in defensive methods, to teach the man that gas has no
uncanny power and that it is simply one element of war that must be
reckoned with, thus preventing stampedes when there is really no danger.

While these are the salient points in defense against gas, above them
and beyond them lies the vigorous offensive use of gas. This involves
not only the research, development and manufacture of necessary gases
in peace time, but also the necessary training to enable our nation to
hurl upon the enemy on the field of battle chemical warfare materials
in quantities he cannot hope to attain.




CHAPTER XXV

PEACE TIME USES OF GAS


“Peace hath her victories no less renowned than war.” Thus runs the
old proverb. In ancient times war profited by peace far more than
peace profited by war if indeed the latter ever actually occurred. The
implements developed for the chase in peace became the weapons of war.
This was true of David’s sling-shot, of the spear and of the bow. Even
powder itself was probably intended and used for scores of years for
celebrations and other peaceful events.

The World War reversed this story, especially in its later phases.
The greater part of the war was fought with implements and machines
prepared in peace either for war or for peaceful purposes. Such
implements were the aeroplane, submarine, truck, automobile and
gasoline motors in general. The first gas attack, which was simply an
adaptation of the peacetime use of the chemical chlorine, inaugurated
the change. Gas was so new and instantly recognized as so powerful that
the best brains in research among all the first class powers were put
to work to develop other gases and other means of projecting them upon
the enemy. The result was that in the short space of three and one-half
years a number of substances were discovered, or experimented with
anew, that are aiding today and will continue to aid in the future in
the peaceful life of every nation.

Chlorine is even more valuable than ever as a disinfectant and water
purifier. It is the greatest bleaching material in the world, and
has innumerable other uses in the laboratory. Chloropicrin, cyanogen
chloride and cyanogen bromide are found to be very well adapted to
the killing of weevil and other similar insect destroyers of grain.
Hydrocyanic acid gas is the greatest destroyer today of insect pests
that otherwise would ruin the beautiful orange and lemon groves of
California and the South.

[Illustration: FIG. 120.]

Phosgene, so extensively used in the war both in cloud gas and in
shell, is finding an ever increasing use in the making of brilliant
dyes—pinks, greens, blues and violets. On account of its cheapness
and simplicity of manufacture, it has great possibilities in the
destruction of rodents such as rats around wharves, warehouses and
similar places that are inaccessible to any other means of reaching
those pests. Since phosgene is highly corrosive of steel, iron, copper
and brass, it cannot be used successfully in places where those metals
are present.

Instead of phosgene for killing rodents and the like in storehouses and
warehouses, cyanogen bromide has been developed. This is a solid and
can be burned like an ordinary sulphur candle. It is much safer for
the purpose of fumigating rooms and buildings than is hydrocyanic acid
gas when so used. This is for the reason that cyanogen bromide is an
excellent lachrymator in quantities too minute to cause any injury to
the lungs. It will thus give warning to anyone attempting to enter a
place where some of the gas may still linger.

Among tear gases, the new chloracetophenone, a solid, is perhaps the
greatest of all. When driven off by heat it first appears as a light
bluish colored cloud. This cloud is instantly so irritating to the eyes
that within a second anyone in the path of the cloud is temporarily
blinded. It causes considerable smarting and very profuse tears
which even in the smallest amount continue for two to five minutes.
In greater quantities it would continue longer. So far as can be
ascertained, it is absolutely harmless so far as any permanent injuries
are concerned.

Considering that it is instantly effective, that minute quantities
are unbearable to the eyes, that it can be put in hand grenades or
other small containers and driven off by a heating mixture which will
not ignite even a pile of papers, and that it needs no explosion to
burst the grenade (all that is used is a light cap, set off by the
action of the spring, sufficient to ignite the burning charge), the
future will see every police department in the land outfitted with
chloracetophenone or other similar grenades. Every sheriff’s office,
every jail and every penitentiary will have a supply of them. No jail
breaking, no lynching, no rioting can succeed where these grenades are
available. Huge crowds can be set to weeping instantly so that no man
can see and no mob will continue once it is blinded with irritating
tears. More than that, it is an extremely difficult gas to keep out of
masks, ordinary masks of the World War being entirely useless against
it.

The same is true of diphenylaminechlorarsine. This is not a tear
gas but it is extraordinarily irritating to the lungs, throat and
nose, where it causes pains and burning sensations, and in higher
concentrations vomiting. It is hardly poisonous at all so that it
is extremely difficult to get enough to cause danger to life. This
is mentioned because of its possible use for the protection of bank
vaults, safes, and strong rooms generally.

There are many other gases that can be used for this same purpose. It
is presumed that gases that are not powerful enough to kill are the
ones desired, and there are half a dozen at least that can be so used.
If desired deadly gases can just as readily be used. Already a number
of inventors are at work on the problem, with some plans practically
completely worked out and models made.

It has been suggested that one of these gases could be used by trappers
in trapping wild animals. Hydrocyanic acid gas may be so used. It acts
quickly and is very rapidly dissipated. An animal exposed to the fumes
would die quickly and the trap be safe to approach within two minutes
after it was sprung. It is said that the loss from animals working
their way out of traps by one means or another is nearly 20 per cent.
More than this, it would meet the objections of the S. P. C. A. in that
the animal would not suffer from having its limbs torn and lacerated by
the trap.

Attempts are being made to attack the locust of the Philippines and the
far west and the boll weevil of the cotton states of the South. So far
these tests have not proven more successful than other methods, but
inasmuch as the number of gases available for trial are so great and
the value of success of so much importance, this research should be
continued on a large scale to definitely determine whether poisonous
gas can be used to eradicate these pests—especially the boll weevil.

As an interesting application of war materials to peaceful uses,
we may consider the case of cellulose-acetate, known during the
war as “aeroplane dope,” the material used to coat the linen
covering aeroplane wings. With a little further manipulation, this
cellulose-acetate, or aeroplane dope, becomes artificial silk—a silk
that today is generally equal to the best natural silk—and which
promises in the future to become a standard product better in every way
than that from the silk worm.

[Illustration: FIG. 121.]

These few examples of the peacetime value of gas are worthy of thought
from another standpoint. Being so valuable, their use in peace will
not be stopped. If they are thus manufactured and used in peace, they
will always be available for use in war, and as the experience of the
World War proved, they certainly will be so used even should anybody be
foolish enough to try to abolish their use. As for this latter idea,
the world might as well recognize at once that half-way measures in war
simply invite disaster.

This chapter would not be complete without a brief statement of the
necessity of a thoroughly developed chemical industry in the United
States as a vital national necessity if the United States is to have
real preparedness for a future struggle. As will be indicated a
little later, no one branch of the chemical industry can be allowed
to go out of existence without endangering some part of the scheme of
preparedness.

Let us consider first the coal tar industry. Coal tar is a by-product
of coke ovens or the manufacture of artificial gas from coal. The coal
tar industry is of the utmost importance because in the coal tars
are the bases of nearly all of the modern dyes, a large percentage
of the modern medicines, most of the modern high explosives, a large
proportion of poisonous gases, modern perfumes, and photographic
materials.

A consideration of these titles alone shows how vital the coal tar
industry is. The coal tar as it comes to us as a by-product is
distilled, giving off at different temperatures a series of compounds
called crudes. Ten of these are of very great importance. The first
five are benzene, toluene, naphthalene, anthracene and phenol (carbolic
acid). The second group comprises xylene, methylanthracene, cresol,
carbazol and phenanthrene.

These, when treated with other chemicals, produce a series of compounds
called intermediates, of which there are some 300 now known. From
these intermediates by different steps are produced either dyes, high
explosives, poisonous gases, pharmaceuticals, perfumes or photographic
materials.

We have all heard that Germany controlled the dye industry of the world
prior to the World War. A little study of the above brief statement of
what is contained in the coal tar industry along with dyes will show in
a measure one of the reasons why Germany felt that she could win a war
against the world. That she came so desperately close to winning that
war is proof of the soundness of her view.

In many of the processes are needed the heavy chemicals such as
chlorine, sulfuric acid, nitric acid, hydrochloric acid and the like.
The alcohol industry is also of very great importance. Grain alcohol
is used extensively in nearly all research problems and in very great
quantities in many commercial processes such as the manufacture of
artificial silk and for gasoline engines in addition to its use in
compounding medicines. It is of very great importance to the Chemical
Warfare Service in that from grain alcohol is obtained ethylene gas,
one of the three essentials in the manufacture of mustard gas. While
this ethylene may be obtained from many sources, the most available
source, considering ease of transportation and keeping qualities, is in
the form of grain alcohol.

Allied to the chemical industries just mentioned is the nitrate
industry for making nitric acid from the nitrogen of the air. Nitrates
are used in many processes of chemical manufacture and particularly
in those for the production of smokeless powders. The fertilizer
industry is of large importance because it deals with phosphorus, white
phosphorus being not only one of the best smoke producing materials
but a material that is, as stated elsewhere, of great use against men
through its powerful burning qualities.

Another point not mentioned above in connection with these industries
is the training of chemists, chemical engineers and the building up of
plants for the manufacture of chemicals, all of which are necessary
sources of supply for wartime needs. Chemists are needed in the field,
in the laboratory and in manufacturing plants. The greater their
number, the more efficiently can these materials be handled, and since
chemicals as such will probably cause more than 50 per cent of all
casualties in future wars, their value is almost unlimited.

Instead of trying to ameliorate the ravages of war, let us turn
every endeavor towards abolishing all war, remembering that the most
scientific nations should be the most highly civilized, and the
ones most desirous of abolishing war. If those nations will push
every scientific development to the point where by the aid of their
scientific achievements they can overcome any lesser scientific
peoples, the end of war should be in sight.

However, we can never be certain that war is abolished until we
convince at least a majority of the world that war is disastrous to
the conqueror as well as to the conquered, and that any dispute can be
settled peacefully if both parties will meet on the common ground of
justice and a square deal.




CHAPTER XXVI

THE FUTURE OF CHEMICAL WARFARE


The pioneer, no matter what the line of endeavor, encounters
difficulties caused by his fellow-men just in proportion as the thing
pioneered promises results. If the promise be small, the difficulties
usually encountered are only those necessary to make the venture a
success. If, however, the results promise to be great, and especially
if the rewards to the inventor and those working with him promise to
be considerable, the difficulties thrown in the way of the venture
become greater and greater. Indeed whenever great results are promised,
envy is engendered in those in other lines whose importance may be
diminished, or who are so short-sighted as to be always opposed to
progress.

Chemical warfare has had, and is still having, its full share of these
difficulties. From the very day when chlorine, known to the world as
a benign substance highly useful in sanitation, water purification,
gold mining and bleaching was put into use as a poisonous gas, chemical
warfare has loomed larger and larger as a factor to be considered in
all future wars. Chlorine was first used in the cylinders designed for
shipping it. These cylinders were poorly adapted for warfare, and made
methods of preparing gas attacks extremely laborious, cumbersome and
time-consuming.

It was not many months, however, until different gases began to appear
in large quantities in shells and bombs, while the close of the war, 3½
years later, saw the development of gas in solid form whereby it could
be carried with the utmost safety under all conditions—a solid which
could become dangerous only when the heating mixture, that freed the
gas, was properly ignited.

While some of the chemicals developed for use in war prior to the
Armistice have been made known to the world, a number of others have
not. More than this, every nation of first class importance has
continued to pursue more or less energetically studies into chemical
warfare. These studies will continue, and we must expect that new
gases, new methods of turning them loose, and new tactical uses will be
developed.

Already it is clearly foreseen that these gases will be used by every
branch of the Army and the Navy. While chemicals were not used by the
Air Service in the last war, it was even then realized that there was
no material reason why they should not have been so used. That they
will be used in the future by the Air Service, and probably on a large
scale, is certain. The Navy, too, will use gases, and probably on a
considerable scale. Thus chemical materials as such become the most
universal of all weapons of war.

Some of the poisonous gases are so powerful in minute quantities and
evaporate so slowly that their liberation does not produce sufficient
condensation to cause a cloud. Consequently, we have gases that cannot
be seen. Others form clouds by themselves, such, for instance, as
the toxic smoke candle, where the solid is driven off by heating,
while still others cause clouds of condensed vapor. This brings the
discussion into the realm of ordinary smokes that have no irritating
and no poisonous effects.

These smokes are extremely valuable where the purpose is to form a
screen, whether it be to hide the advance of troops or to cut off the
view of observers. These smokes are equally useful on land and on
sea. So great is the decrease in efficiency of the rifle or machine
gun, and of artillery even when firing at troops that cannot be seen,
that smoke for screening purposes will be used on every future field
of battle. When firing through a screen of smoke, a man has certainly
less than one-quarter the chance to hit his target that he would have
were the target in plain view. Since smoke clouds may or may not be
poisonous and since smoke will be used in every battle, there is opened
up an unlimited field for the exercise of ingenuity in making these
smoke clouds poisonous or non-poisonous at will. It also opens up an
unlimited field for the well-trained chemical warfare officer who can
tell in any smoke cloud whether gas be present and whether, if present,
it is in sufficient concentration to be dangerous.

At the risk of repetition, it is again stated that there is no gas
that will kill or even permanently injure in any quantity that cannot
be detected. For every gas, there is a certain minimum amount in each
cubic foot of air that is necessary to cause any injury. In nearly all
gases, this minimum amount is sufficient to be readily noticeable by a
trained chemical warfare officer through the sense of smell.

It would be idle to attempt to enumerate the ways and means by
which chemicals will be used in the future. In fact, one can hardly
conceive of a situation where gas or smoke will not be employed, for
these materials may be liquids or solids that either automatically,
upon exposure to the air, turn into gas, or which are pulverized by
high explosive, or driven off by heat. This varied character of the
materials enables them to be used in every sort of artillery shell,
bomb or other container carried to the field of battle.

Some of the gases are extremely powerful as irritants to the nose
and throat in very minute quantities, while at the same time being
highly poisonous in high concentrations. Diphenylchloroarsine,
used extensively by the Germans in high explosive shell, is more
poisonous than phosgene, the most deadly gas in general use in the
past war. In addition, it has the quality of causing an intolerable
burning sensation in the nose, throat, and lungs, in extremely minute
quantities. This material can be kept out of masks only by filters,
whereas true gases are taken out by charcoal and chemical granules.

There is still another quality which helps make chemical warfare the
most powerful weapon of war. Gas is the only substance used in war
which can be counted on to do its work as efficiently at night as in
the daytime. Indeed, it is often more effective at night than in the
daytime, because the man who goes to sleep without his mask on, who is
careless, who loses his mask, or who becomes excited in the darkness
of night, becomes a casualty, and the past war showed that these
casualties were decidedly numerous even when the troops knew almost to
the minute the time the gas would arrive.

Accordingly, chemical warfare is an agency that must not only be
reckoned with by every civilized nation in the future, but is one
which civilized nations should not hesitate to use. When properly
safe-guarded with masks and other safety devices, it gives to the most
scientific and most ingenious people a great advantage over the less
scientific and less ingenious. Then why should the United States or any
other highly civilized country consider giving up chemical warfare?
To say that its use against savages is not a fair method of fighting,
because the savages are not equipped with it, is arrant nonsense. No
nation considers such things today. If they had, our American troops,
when fighting the Moros in the Philippine Islands, would have had to
wear the breechclout and use only swords and spears.

Notwithstanding the opposition of certain people who, through ignorance
or for other reasons, have fought it, chemical warfare has come to
stay, and just in proportion as the United States gives chemical
warfare its proper place in its military establishment, just in that
proportion will the United States be ready to meet any or all comers
in the future, for the United States has incomparable resources in the
shape of the crude materials—power, salt, sulfur and the like—that are
necessary in the manufacture of gases.

If, then, there be developed industries for manufacturing these gases
in time of war, and if the training of the army in chemical warfare be
thorough and extensive, the United States will have more than an equal
chance with any other nation or combination of nations in any future
war.

It is just as sportsman-like to fight with chemical warfare materials
as it is to fight with machine guns. The enemy will know more or less
accurately our chemical warfare materials and our methods, and we will
have the same information about the enemy. It is thus a matching of
wits just as much as in the days when the Knights of the Round Table
fought with swords or with spears on horseback. The American is a pure
sportsman and asks odds of no man. He does ask, though, that he be
given a square deal. He is unwilling to agree not to use a powerful
weapon of war when he knows that an outlaw nation would use it against
him if that outlaw nation could achieve success by so doing. How much
better it is to say to the world that we are going to use chemical
warfare to the greatest extent possible in any future struggle. In
announcing that we would repeat as always that we are making these
preparations only for defense, and who is there who dares question our
right to do so?




INDEX


    Absorbents, Requirements of, 237
      Testing, 259
    Absorptive activity, 237
    Absorptive capacity, 238
    Aeroplane, Smoke screen, 309
    American Tissot mask, 224
    Ammonia canister, 230
    Ammonium chloride smoke, 327
    Animals, Susceptibility to mustard gas, 173
    Anthracite coal, Activation of, 249
    A. R. S. mask, 203
    Arsenic derivatives, 180
    Arsenic trichloride, Manufacture, 180
    Arsenic trifluoride, Manufacture, 180
    Arsine, proposed use of, 180
    Artillery, Gas, use of, by, 396
    Aviation, Gas, use of, by, 380, 399

    Baby Incendiary bomb, 340
    Barrages, Gas, use of, in, 376
    Benzyl bromide, 16, 141
    Benzyl chloride, 16
    Berger mixture, 290
    Black signal smokes, 331
    Black veiling respirator, 195
    Blue cross. _See_ Diphenylchloroarsine
    Blue pencil, German, 346
    Bombs, incendiary, 337
    Box respirator, American, 209
      English, 198
    Break point of canisters, 262
    Bromoacetone, 16, 138
      German manufacture, 140
    Bromobenzyl cyanide, 16, 142
    Bromomethylethyl ketone, German manufacture, 140
    Bullets, incendiary, 344

    Camouflage gases, 23, 416
    Canister, life of, Gas concentration and, 132
      Temperature, effect of, 132
      Testing, 260
    Carbon dioxide, Manufacture, 129
    Carbonite, 250
    Carbon monoxide, 190
      Canister, 191
      Manufacture, 128
    Cavalry, Gas, use of, by, 378
    Cement, Soda-lime, function in, 257
    Charcoal, 239
      Active, 242
      German, 251
      Inactive, 242
      Manufacture, 242
      Raw material, 239
      Substitutes, 249
      Tests of, 253
      Theory of action, 241
    Chemical Service Section, Organization, 34
    Chemical Warfare, Future of, 435
      Gases used in, 24
      Historical, 1
      Officers, duties of, 369
      Strategy, relation to, 363
    Chemical Warfare Service, Administrative division, 36
      A. E. F., organization, 72
      Development division, 61
      Edgewood arsenal, 53
      Gas defense division, 48
      Liaison officers, 70
      Medical division, 68
      Organization, 35
      Proving division, 63
      Research division, 38
      Training division, 65
    Chemical Warfare troops, 92
    Chenard bomb, 340
    Chlorine, 116
      Manufacture, 117
      Properties, 123
    Chloroacetone, 16
    Chloroacetophenone, 16
    Chloromethyl chloroformate, 21
    Chloropicrin, 21
      Manufacture, 145
      Physiological test, 146
      Properties, 146
      Protection, 147
      Tactical use, 148
    Chlorovinyldichloroarsine, 188
    Chlorosulfonic acid, Smoke material, use as, 286
    Cloud gas, 10, 116, 390
    Coalite, 250
    Cocoanut shell charcoal, 239
    Cohune nut charcoal, 240
    Complexene, 201
      Horse masks, use in, 278
    Cottrell Precipitation Tube, 299

    Darts, incendiary, 343
    Density of smoke clouds, 295
    Development Division, C. W. S., 61
    Dichloroethyl sulfide, 22, 80, 105
      Detection, 166
      Historical, 151
      Manufacture, 152, 161
      Mixtures, melting point of, 164
      Properties, 163
      Tactical use, 175, 417
      Toxicity, 168
      Vesicant action, 171
    β, β′-Dichlorodivinylchloroarsine, 189
    Dihydroxyethyl sulfide, 160
    Diphenylchloroarsine, 22, 182
      Manufacture, 183
    Diphenylcyanoarsine, 185
    Diphosgene. _See_ Trichloromethyl chloroformate
    Dog mask, 280
    Doughnut filter, 324
    Dressler tunnel kiln, 248
    D-Shell, 134
    Dugout blankets, 283
    Dyes for signal smokes, 333

    Edgewood arsenal, C. W. S., 53
    Efficiency test, Absorbents, 259
      Canisters, 262
    Ethyldichloroarsine, 185
    Ethylene, Manufacture of, 155, 158
    Ethylene chlorhydrin, 158
    Ethyl iodoacetate, 16, 141
    Explosive dispersion, 314

    “First gas attack,” 10
    First gas regiment, 93
    Flammenwerfer, 349
    Flaming gun, 347, 401
    Food, protection of, against mustard gas, 422
    French artillery mask, 202

    Gas, Defense against, 405
      Effectiveness of, 375, 385
      Humanity of, 13, 370, 387
      Offensive use of, 385
      Permanency of, 378
      Requirements of, 116, 395
    Gas alarms, 422
    Gas cloud, height and spread, 394
      Smoke in, 311, 403
    Gas cylinder, Mobile, 17
    Gas defense division, C. W. S., 48
    Gases, Detection of, 415
      Peace uses of, 427
      Pharmacology, 353
    Gas and Flame Regiment, 34
    Gas mask, Development, 195
      Physiological features, 232
      Testing, 259
      _See also_ names of various masks
    Gas shell, Markings, 28, 404
      Value, 18, 396
    Gassing chamber, 354
    Gas training, 413
      In France, 81
      Value in peace, 373, 383
    Gas warfare, Fundamentals, 388
      Humanity, 13, 370, 387
    German mask, 205
    Greasene, 201
    Green Cross shell, 148
    Green T-Stoff, 142

    Hand grenade, incendiary, 345
    Hanlon field, 111
    Hardness, Absorbents, test of, 259
    Hague conference, Poison gases, action on, 6
    Homomartonite, 16, 138
    Hopcalite, Carbon monoxide absorbent, 193
    Horse boots, 280
    Horse mask, 277
    Humanity, Gas warfare, 13, 370, 387
    Hypo helmet, 196

    Incendiary materials, 336
      Tactical use of, 402
    Infantry, Gas, use of, by, 377, 400
    Intelligence section, 113
    Inter-allied gas conference, 79
    Irritants, Efficiency of, 389
      Testing, 359
    Ivory nut charcoal, 241

    Kieselguhr, Soda-lime, function in, 257
    Kupramite, 230

    Lachrymators, 15, 137
      Comparative value, 143
      Protection, 143
      Testing, 356

    Lachrymatory shell, Tactical value, 15
    Lamp-black, Charcoal from, 250
    Lantern test, Mustard gas, 166
    Leak detecting apparatus, 266
    Leakage, Canister, testing of, 261
    Levinstein reactor, 158
    Lewisite, 23, 187
    Liaison officers, 70
    Lime, Soda-lime, function in, 257
    Livens’ projector, 18, 391
    Livens’ smoke drum, 304

    M-2 Mask, 201
    Man test, 262
    Martonite, 16, 138
    Mask, Development, 405
      Disinfection, 269
      Field tests, 270
      Issuance, 423
      _See also_ Gas mask
      _See also_ Names of masks
    Mechanical dispersion, 313
    Medical division, C. W. S., 68
    Medical section, A. E. F., 114
    Methyldichloroarsine, 181
    Moisture, Absorbents, tests of, 259
    Mustard gas. _See_ Dichloroethyl sulfide.

    Navy, Canister, 230
      Gas, use of, by, 381
      Smoke funnel, 305
    Nelson cell, 117
    “Nineteen nineteen” canister, 325
    “Nineteen nineteen” Model American Mask, 225

    Odors, Testing of, 358
    Oleum, Smoke material, use as, 286
    Overall suit, 273

    Palite. _See_ Chloromethyl chloroformate
    Penetration apparatus, Toxic smoke, measurement of, 315
    P-Helmet, 197
    PH Helmet, 197
    Phosgene, 14, 126
      Manufacture, 127
      Properties, 130
      Protection, 131
      Shell filling, 132
      Tactical use, 134
    Phosphorus, Smoke material, 286, 382
      Stokes’ mortar, use in, 393
      _See also_ Smoke
    Physiological action, Phosgene, 135
      Mustard gas, 168
      Toxic Smokes, 316
    Pressure drop apparatus, 266
    Protective clothing, 272
    Protective gloves, 274
    Protective ointments, 275
    Proving division, C. W. S., 63
    Pumice stone, Phosgene shell, use in, 130, 135

    Research division, C. W. S., 38
    Resistance, Canister, test of, 261
      Decreased, 410
    Respirator, _See_ Gas mask, Mask

    Sag paste, 277
    Screening smokes, 285
      _See also_ Smoke
    Screening power, Smoke cloud, 285
    Selenious acid, Mustard gas detector, 166
    Shell, Gas, Filling of, 132
      Value, 18, 396
      Incendiary, 344
      Markings, 28, 404
      Pumice stone and phosgene in, 130, 135
      Smoke, 303
    Ships, Screening Smoke, 299, 305
    Shrapnel, Gas in connection with, 379
    Signal smokes, 330
      Tactics, 333
    Silicon tetrachloride, Smoke material, use as, 290
    Smoke, Intensity, measurement of, 296
      Tactical value, 310, 402
      Use in offense, 401
      _See also_, Screening, Signal and Toxic Smokes
    Smoke box, 299
    Smoke candle, 301, 372
      Toxic, 318
    Smoke cloud, Properties, 116, 285, 395
    Smoke drum, 304
    Smoke filters, 322
      Felt, 324
      Paper, 323
      Testing, 327
      Theory, 326
    Smoke funnel, 305
    Smoke grenade, 302
    Smoke knapsack, 306
    Smoke particles, Measurement of, 292
      Size of, 291
    Smoke screen, Purpose of, 309
    Smoke shell, 303, 307
    Smoke signals, 333
    Sneezing gas. _See_ Diphenylchloroarsine
    Soda-lime, Composition, 256
      Requirements, 255
    Sodium hydroxide, Soda-lime, function in, 257
    Sodium permanganate, Soda-lime, function in, 257
    “Solid oil”, 336
    Spray nozzles, 357
    Staff troops, C. W. S., 92
    Standard Box respirator, 198
    Stokes’ mortar, 20, 392
    Sulfur chloride, Manufacture, 157
    Sulfuric acid smoke, 328
    Sulfur trioxide, Smoke material, use as, 289
    Superpalite. _See_ Trichloromethyl chloroformate

    Tactical use, Chloropicrin, 148
      Dichloroethyl sulfide, 175, 417
      Gases in offense, 385
      Incendiary materials, 402
      Lachrymatory shell, 15
      Phosgene, 134
      Screening smokes, 310, 402
      Signal smokes, 333
    Tactics, Chemical Warfare and, 363
    Tanks, Smoke screen for, 309
    Thermal dispersion, 313
    Thermit, Uses, 393
    Tin tetrachloride, Smoke material, use as, 289
    Tissot mask, 202
    Titanium tetrachloride, Smoke material, use as, 290
    Tobacco smoke, 328
    Total obscuring power of smoke, 295
    Touch method, Irritants, testing of, 362
    Toxicity, Gases, testing of, for, 353
    Toxic smoke, 313
      Candle, B. M., 319
      Candle, Dispersoid, 320
      Penetration, 314
      Quantitative relationship, 316
    Training division, C. W. S., 65
    Trench mortar, 20, 392
    Trichloromethyl chloroformate, 20
    Trichloronitromethane. _See_ Chloropicrin
    β, β′, β″-Trichlorotrivinylarsine, 189
    T-Stoff, 141
    Tyndall meter, 299

    Ultramicroscope, Smoke particles, measurements of, 292

    Vapor tests, Irritants, testing of, 359
    Versatility of absorbents, 238
    Vincennite, 15, 180
    Vision chart, 271
    “Vomiting gas.” _See_ Chloropicrin

    War gas. _See_ Gases
    War, humanity of, 6
    Wave attack, Disadvantages, 16

    Xylyl bromide, 16, 141

    Yellow cross. _See_ Dichloroethyl sulfide
    Yellow smoke, 331
    Yperite. _See_ Dichloroethyl sulfide